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By Quinlan M. J, Ratcliffe J. S

Chemical kinetics is a dependent process which usually correlates the rate at which a reaction proceeds with the mechanism descriptive of the manner by which reactive particles interact. Given the latter, the object gen- erally is to find the reaction rate dependency in terms of an intensive property of the system - number of reactive particles present, and of the energetics of the system - usually temperature. Chemical kinetics depend on a dem- onstration that reaction considerations alone control the phenomenological process under study. For these rea- sons, chemical kinetics are usually involved in homogeneous gaseous systems. Even in liquid homogeneous sys- tems earliness or lateness of reactant mixing rather than chemical kinetics may be controlling. Considerations of transport phenomena are involved in heterogeneous systems and often control the observable rate:an additional problem in such systems is to apportion the rate due to mass transfer - usually a linear process - and that due to reaction which may be linear or non-linear. Experimentally, conditions are often chosen so that only one consideration controls but this becomes more difficult where solid phases are involved. Kinetic modelling involves considerations of chemical kinetics, transport phenomena, and factors attributable to the physical environment in which the process takes place. The latter two considerations may be quite different as between experiment and plant. The kinetic model may be a mathematical representation of a conceptual mech- anistic model of the reaction. Alternatively, it may be an empirical relationship resulting from, for example, some curve fitting procedure applied to experimental data. The latter approach may be necessary where the system is particularly complicated.

Jan 1, 1975

Modern plate tectonic reconstruction of Mexico and Central America shows that the southeast-extend ing Precambrian backbone of Mexico, together with the east-flanking accreeted Huastecan (Appalachian-Caledonian) orogenic belt, are geotectonic elements practically absent in Central America, except west-ern and northern Guatemala and Belize, and contrib-uted little to the mineral potential of the entire region.The gradual accretion of the Cordilleran oro-genic belt took place against the western-south-western margin of the Precambrian backbone, and its consolidation required several tectonic events from the medial(?) Paleozoic to the end of the Mesozoic. The striking features of this "long-lived" orogenic belt are the massive sulphide min-eralization in the upper Paleozoic eugeoclinal as-semblage, the widespread gold occurrence in quartz veins in the lower Mesozoic volcanics and related intrusives, the carbonate-hosted silver-bearing lead-zince deposits of the Mississippi Valley-type (or Pine Point-type) around carbonate banks within the Lower Cretaceous back-arc miogeocline, that de-veloped over the Precambrian backbone and deeply-eroded Huastecan orogenic belt, the massive sul-phide (Pb-Zn) deposits in the Upper Jurassic-Lower Cretaceous sequence, transitional from miogeocline to eugeocline, which carry high grades in silver, and the iron deposits in this transitional facies, which are described in the literature as related to dioritic intrusives of Late Cretaceous age. Central America, south and southeast of the Mota-gua-Polochic fault system, forms part of the in-ternal zones of this orogenic belt.

Jan 1, 1990

The Hodgkinson goldfield contains over 50 separate lodes which have produced 9.7 tonnes of gold from ore averaging 37 g/t. The gold-quartz.lodes are spatially separate from tin and base metal mineralisation, associated with Permo-Carboniferous granitoids in the province. Host rocks consist of sub-greenschist metamorphic grade shale, conglomerate, sandstone, spilite, chert and melange. Oreshoots average 100 x 30 x I m in Size and are contained in cross-cutting quartz. filled with steep-dipping shear zones. Mineralisation in the quartz. consists of gold with minor arsenopyrite, pyrite, galena, and sphalerite with rare calcite. Scheelite and stibnite are aSSOCIated locally but are not necessary proximal or coeval. Alteration is restricted to centimetre-scale phyllic selvedges adjacent to the veins and veinlets.Most of the lodes and vems occur within six main 1.5 x 0.25 km mineralised areas whIch may indIcate separate areas of fluid flow and precipitation. Ore controls differ m melange- and sandstone-hosted lodes but several features are common to all the oreshOOlS. Most of the lodes occur within zones of duauon that are caused by splaymg, refraction through carbonaceous shale-sandstone contacts, or by rolls and changes in strike and dip.Lithologic contacts may act as areas of permeability and chemistry contrast which focus fluid and precipitation. Tensional veins are common between parallel shear zones and curved spur veins occur both in the hangingwall and footwall of the main fissure. Intersections and contacts may have enhanced local fluid flow in many of the areas.

Jan 1, 1991

Commercial or potentially commercial deposits of coal occur in Australia in strata ranging in age from Permian to Tertiary. The coals of each period tend to show a community of petrographic character and significant differences as compared with coals of other ages. In particular- many of the Permian coals are unusually rich in inertinite whereas the Jurassic and Tertiary coals are typically very rich in vitrinite. The majority of the coals show evidence of deposition in environments subject to relatively minor marine influence. Except for some Tertiary and Permian coals the content of mineral matter tends to be high. Outcrops of coals of bituminous rank appear to be largely restricted to the eastern margin of the Australian continent. In this region vertical rank gradients are generally higher than in the other sedimentary basins and uplift and the removal of cover has occurred to a greater extent. To the west of the Tasman geosyncline, coal of bituminous rank generally occurs at considerable depths (usually in excess of 1 km and in some areas only at depths of over 2 kms), and in most areas coals at shallow depth are of sub-bituminous or brown coal rank. The controls of the distribution of coal type and rank have considerable economic significance and the unusual characteristics of Australian coals, especially with respect to coal type, make the direct application of overseas technology to Australian coals inappropriate.

Jan 1, 1975

The preamble to the mining Act sets out that such Act is to provide for the encouragement and regulation of mining within the State of Queensland. This paper will attempt to follow the legislative path of such aim and in particular to show what part Mining Wardens play in the administration of the Mining Act.The Mining Act empowers the Governor in Council to constitute Mining Districts and Mining Fields and to appoint any duly qualified officer of the Public Service of Queensland to be a Warden or a Mining Registrar. As a matter of practice Stipendiary Magistrates who hold office in the major centre within a Mining District are appointed Wardens and Clerks of the Court are appointed Mining Registrars. In some districts where there is no Stipendiary Magistrate the Clerk of the Court is appointed an Acting Warden with all the powers of a Warden. Every Warden so appointed is a Warden for the whole State.To achieve impartiality Section 74 of the Mining Act provides that a Warden shall not hold or be entitled (directly or indirectly) to the benefits of any share or interest in a mining tenement or mining venture and provides a penalty of $1000 or imprisonment for six months or both, for contravention of such section.

Jan 1, 1986

Conventional treatment of oxide and oxidised sulphide minerals by flotation involves the use of sodium sulphide for sulphidisation. Sodium sulphide is generally applied in a "slug" dosing fashion with manual regulation. However, it is recognised that "over addition" or "under addition" of sulphidising reagent can result in poor flotation recoveries. Thus, control of sodium sulphide additions is an important aspect of a sulphidisation circuit, both commercially and metallurgically. In any plant where the flotation feed is "constant" it is possible to operate at a constant rate of addition of sodium sulphide. In actual plant practice, however, it is difficult to maintain a truly constant feed for any reasonable duration because this implies not only a constant feed-rate, but also constant mineral composition and particle size range. These factors can vary significantly and ideally require corresponding variations in the additions of sodium sulphide to maintain optimum recoveries. To cope with variations in the feed, it is essential to have automatic rather than manual regulation of the sulphide reagent addition. The CPS process achieves this control by utilising a sulphide ion-selective electrode as a control instrument in sulphidisation. The CPS process which uses a selective electrode, enables the sulphide ion concentration in the flotation pulp to be monitored and controlled continuously throughout the stage of sulphidisation.

Jan 1, 1989

HoistEM is a helicopter-towed time domain electromagnetic system. This paper presents details of the towed array structure (the Hoist) as well as a description of the instrumentation. A comparison between HoistEM and ground TDEM (from which HoistEM was derived) is given. Over 50 000 line kilometres of HoistEM have been completed to date and datasets for structural mapping, nickel, base metals, manganese, ground water and bathymetry are presented and discussed.

Jan 1, 2004

By Harmse C

Gold mining in Vatukoula had been a low tonnage/high grade operation for much of its 55-year life. During 1991 it became clear that a change in direction was needed if the mine was going to continue to prosper. The challenges of ore reserves of only three years, the prevailing gold price and high infrastructure and fixed costs combined to force changes in mining strategy.A more productive mining method was required to lower the unit mining cost, lower the pay limit and make more effective use of the resource.The flat dipping mineralised faults or flatmakes had been mined by updip, handheld room and pillar methods with a more recent trackless development adaptation. Furthermore, up to 40 per cent of the resource was left in pillars and broken rock.

Jan 1, 1993

There are two mechanisms in the flo- tation process by which particles are transported from the pulp to the con- centrate: bubble-mineral aggregation and entrainment. It is the chemical processes which occur in the pulp which are critical to the success of flotation since they control the floatability of different min- erals and the selectivity which can be obtained. However, these chemical pro- cesses are so complex that metallurgists are still limited in their ability to predict the floatability of particles in industrial circuits by consideration of the minerals present and the chemical environment. The alternative approach to understand- ing flotation is to examine the behaviour of minerals in industrial flotation pro- cesses, to recognise similarities and differences, and to define the "laws" which appear to apply. Using this ap- proach it has been found that minerals float at a rate which is proportional to their concentration in the pulp, and that the rate of flotation of different min- erals is influenced by variables which' affect the pulp or the froth phase. The ultimate application of this approach is the use of models for circuit simulation purposes. It is this alternative approach which is the theme of this paper. One of the most important problems in understanding the technology of flotation has been in defining the characteristics of the particles being floated. Particles entering flotation vary widely in size and mineral composition, and different par- ticle types float at different rates. These rates do not change uniformly as operating variables change. It has been conventional practice to assess flotation performance in terms of the metal contents of total streams because no better method has been available, and this procedure has obscured important effects which occur in

Jan 1, 1984

A field trial of the prompt neutron-gamma SIROLOG technique was undertaken by the CSIRO - Division of Geomechanics at Callide Coalfields during July 1989. The trial investigated whether the sonde could reliably be used for the determination of Ash and Iron Oxide (Fe2O3) in coal seams, which had a highly variable iron content. Ten boreholes were logged, being water filled of a nominal diameter of 120 mm. The logging probe employed a 1.6 ¦g 252Cf neutron source and a 51 x 51 mm BGO detector. The source to detector distance was 15 cm. The results from one exploration borehole at the Dunn Creek Mine are discussed in the paper. The rms deviations for ash and iron determination between the neutron-capture predictions of the geophysical logs and the laboratory - chemical assays were 1.9 per cent Ash and 0.88 per cent Fe respectively. Using existing empirical equations which relate iron oxide concentration in coal ash to Initial Deformation Temperature (reducing conditions) at Callide, it may be possible to indirectly determine ash fusion properties as least as accurately, on a more detailed ply-by-ply basis, and more cost competitively than current laboratory techniques allow.

Jan 1, 1991

Silver-lead ores are widely distributed through- out the Mount Lofty and Flinders Ranges, but none of the deposits is large. Historically the Glen Osmond Mines are the most significant as the site of the first metalliferous mining in Australia, but Talisker was one of the three largest producers of silver-lead in a state whose mining history is dom- inated by copper. The mine is located in a magnificent natural setting on Talisker Conservation Park, near Cape Jervis, southwest of Adelaide (Figure 1). It is exempt from the operations of the Mining Act and listed on the Register of State Heritage Items. The mine and associated township of Silverton were dominated by Cornish influences during the period of principal activity between 1862 and 1872. Silverton, located on a ridge overlooking the mine, grew to a population of about 300 at its peak in 1870 and the area was very much another 'little Cornwall'.

Jan 1, 1987

By Katom M

Each of the two 32 feet diameter Semi Autogeneous Grinding (SAG) mills at Ok Tedi's copper and gold concentrator was treating at best 1500 tph at about 65 per cent mill availability in 1988. The process was effectively unmeasured and used manu

Jan 1, 1997

By KenGemar P, Perembo R. C B, Winn R. D

The New Guinea orogen comprises terranes that have accreted to the northern margin of the Australian craton. The history of the accretion of terranes begins earlier (in the Late Cretaceous) and is more complex than has been suggested previously. There was a collision in the central highlands in the Late Paleocene or Early Eocene, and a Finisterre collision that precedes and is distinct from the later (Pliocene) Bismarck volcanic arc collision.

Jan 1, 1997

The Division of Minerals and Geochemistry in collaboration with three mineral exploration companies, Mawson Pacific Ltd, Ramsgate Resources Ltd and Tectonic Systems Pty Ltd commenced a two year research project to investigate the application of remote sensing techniques to exploration for mineral deposits in access of the Yilgarn Block in Western Australia. The project utilizes satellite data such as day and night imagery from the NOAA-AVHRR (National Oceanic and Atmospheric Administration - Advanced Very High Resolution Radiometer) satellite. The recent research with the imagery in the Kalgoorlie, Southern Cross and Mt Magnet regions has highlighted the advantages of the mid infra-red and the two thermal response channels of NOAA-AVHRR for geological investigations. These three channels have the spectral resolution to distinguish stratigraphic units and younger intrusive bodies, and to delineate fracture zones and shear zones associated with Proterozoic dykes. But most important is the capacity to distinguish thermal signatures from geological structure, near-surface outcrop and palaeochannels which have been covered by unconsolidated sediments. The research project applies remote sensing methods including enhanced satellite imagery optimised to the Western Australian environment. It encompasses data from both space and airborne monitoring platforms that have obsreved a significant spectral response for the classification of alteration zone lithologies. It includes the collection of multiseasonal data from areas of interest which is essential both for the understanding of thermal characteristics of important lithologies and for the extrapolation from field work investigation to potential exploration areas. No comprehensive investigation of this type has been carried out within the Yilgarn goldfields.

Jan 1, 1987

The rocks of the Serranias Chilla massif of Bolivia are a suite of metamorphosed Palaeozoic basalts and associated continental sediments. Whole-rock trace element geochemistry of the basalts suggest a calc-alkaline affinity and indicate that subduction extended as far north as the Bolivian Altiplano during lower Palaeozoic time.

Jan 1, 1990

By Albano C, Antila A, Flykt B

A method for relating operating variables and dewatering parameters of Thunes disc filters in the LKAB pelletizing plant at Malmberget in Sweden, via empirical mathematical models is described. Near orthogonal experimental design was used, where all independentvariables were allowed to span over their domain of variation and pseudo-randomly distributed among the experiments. The dewatering parameters are dependent on many variables and instead of using a traditional mechanistic model, an empirical model based on multivariate data analysis was chosen. The way of expressing the relation is by regression coefficients obtained from partial least square regression (PLS). Two empirical models were generated. The models were validated using an extra set of 56 experiments. The dewatering parameters were related to the design variables with few experiments, and user-friendly response surface methodology was used to determine the optimal conditions.

Jan 1, 1989

The introduction of large diameter drill holes and mass firings in underground metalliferous mines has led to an increase in the number of reported sulfide dust explosions in Australia and overseas. Adaptation of the coal mining technique of using limestone to inhibit or prevent dust explosions has not been entirely successful as the development and inhibition of a sulfide dust explosion is somewhat different from that of a coal dust explosion. Tests were carried out on two pyritic ore samples, sulfur contents of 41 and 36 per cent, in 8 and 20 litre explosion chambers to evaluate the effect of the addition of limestone on the maximum explosive pressures developed and rates of pressure rise. Significant values were obtained in both chambers with dusts containing 60 per cent ore and 40 per cent limestone. The percentages of limestone required to inhibit the pyritic dusts were considerably higher than those values generally accepted by the mining industry and the current methods used to inhibit sulfide dust explosions should be re-evaluated.

Jan 1, 1986

By Bunting HR

Developments since 1959 in major excavators to meet the high outputs of overburden and coal under the changing nature of the Morwell Coal Deposits of the Latrobe Valley are described. Particular reference is made to investigations of designs of the bucket wheel head configurations for the digging of flat batters on high faces, and examples are given of the wide use ofmodelsin these studies.An explanation is given of considerations leading to selection of the Long Boom or the Compact type of bucket wheel excavator for various applications. The past decade has seen increasing manufacture in Australia of components for excavators and similar machines. The measures undertaken to integrate these components with those from overseas (Germany) are described. A section of the paper deals with advances in Electrical Engineering for large excavators in Australia and its interdependenee with mechanical design and construction. Finally, as an example of the versatility of the bucket wheel excavator a description is given of a recent application for the mining of mineral sands in Northern N.S.W.

Jan 1, 1970

A new experimental procedure for determining the solids flux curve is detailed. The procedure is based on measuring the concentration at various heights of a bed of settled solids formed during a semi-continuous sedimentation test. Unlike conventional thickener area calculations, the test procedure demonstrates the dependence of the flux curve on the system feed flux. At a given feed flux, there was good agreement between the solids flux curve determined by the method and continuous sedimentation results. The widely used method of Kynch was found to be restricted to relatively high effective feed fluxes and consequently there was poor agreement with continuous tests at low feed fluxes. The flux curve determined by the method of Coe and Clevenger was invalid for all feed fluxes. A case study shows how the required thickener area would vary for a number of fine coal processing options.

Jan 1, 1989

By Murphy A. S, Budod A

The Philex concentrator represents the first time Jameson Cells have been used in a cleaner scavenger application or in large scale flotation in roughing and scavenging. This necessitated a major change in Jameson cell design as well as a chan

Jan 1, 1997