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By Georges Houlachi, Akram Alfantazi, Maysam Mohammadi

Manganese ions in zinc electrowinning electrolytes form a protective MnO2 layer that ultimately decreases Pb contamination in the zinc product. In this study, the effect of dissolved Mn2+ on the electrochemical performance of Pb, Pb-Ca and composite Pb-MnO2 anodes was investigated. The properties of the MnO2 layer formed on these anodes were studied and compared. Potentiodynamic polarization and cyclic voltammetry experiments were performed in 180 g L-1 sulphuric acid to study the electrochemical reactions occurring on the anodes. The anodes were subjected to galvanostatic polarization at 50 mA cm-2. The morphology and uniformity of the MnO2 layer on the anodes were examined using scanning electron microscopy (SEM). Experimental results revealed that the MnO2 layer formed on the composite anode was more compact and uniform compared to that formed on the Pb and Pb-Ca anode. It was also observed that the cell mud formation rate, and consequently manganese ions consumption, depended on the anode type. Although initial formation of the MnO2 layer decreased the oxygen evolution overpotential, its growth might negatively affect electrocatalytic activity of the anodes.

Jan 1, 2014

By L. I. Kiss, S. Perron, D. Toulouse, S. Poncsák, A. Perron

Bubbles play an important role in many industrial processes. In a Hall-Heroult cell, used for aluminum production, bubbles contribute to induce flow in the cell. The induced flow is important for the thermal balance of the cell as well as for the distribution and dissolution of the alumina. The existence of the bubble layer does not have advantages only. It increases the voltage of the cell and causes deformation along the cryolite-molten aluminum interface. The role of the anode inclination in the behaviour of the bubble layer as well as in the hydrodynamics of the bath is not clearly understood. In this work, the effect of the anode inclination angle on the bubble driven flow is studied in an industrial scale air-water model. The inclination angle is varied up to 5° from the horizontal. The instantaneous flow field is captured by Particle Image Velocimetry (PIV) system. The mean velocity fields were calculated by ensembleaveraging the instantaneous velocity fields measured at different time. The existence of the counter-flow in the interpolar space and the vortex in the side channel has been confirmed. Furthermore it has been observed that the effect of anode slope on the velocity field is weak.

Jan 1, 2006

By Maurice Hall Haycock

ONE result of the higher price of gold has been the exploitation of many low-grade deposits, the successful treatment of which depends upon obtaining high recovery of the contained gold. Modern methods have made it possible to recover gold from many ores formerly regarded as impossible to treat economically, but in order to apply these methods efficiently it has become desirable, and indeed in many cases indispensable, to gain precise information concerning their mineralogical and physical character. The most successful means of doing this is the use of the reflecting microscope. Reflecting microscopes had long been employed by metallurgists for studying polished surfaces of iron and steel when, thirty years ago, Dr. W. Campbell, of Columbia University, advanced the idea of using similar methods for studying opaque minerals (1). The immediate result was the completion of two microscopic studies, the first on Cobalt silver ores (2) and the second on Sudbury nickel ores (3). The idea was surprisingly slow in being adopted, and not until 1911 did it begin to spread through the universities of this continent. From then on, ore microscopy, or 'mineragraphy', made rapid progress, and, during the next fifteen years, research in universities of North America and Europe led to the development of somewhat specialized apparatus and technique. This phase of development, which resulted largely in contributions of a descriptive nature, furnished a mass of data from which the possibility of economic applications was soon recognized. Ore microscopy became an aid to the mining geologist in solving many problems of ore deposition. This soon led to its application in the study of ores and mill products in connection with their treatment. Its usefulness in this latter field has been very marked and has led to its widespread adoption by the mining industry.

Jan 1, 1937

By J. Abrahams, A. Nesbitt

Over the past half-century, researchers have commented on the complexities of ion-exchange processes, but have been forced to use gross assumptions to simplify the associated mathematics sufficiently for mathematical models to be of practical use, given the available computational power. This paper reviews the development of increasingly complex models as computational power has increased over the past half-century, from the direct application of Fick's Law in 1947, through to today's models requiring finiteelement methods. The assumptions required for and the associated limitations of the various models are presented and the associated computational complexities are discussed. A case study is presented in which a continuous loss of capacity in an acid resin was observed over about sixty cycles of loading and elution. Resin poisoning does not explain this observation. This paper presents the capacity loss data, speculates on possible causes of the phenomenon, discusses why conventional kinetic and equilibrium mechanisms cannot explain it and concludes that the need to develop a more rigorous model is apparent. The significance of this observation is that standard tests done for a new resin application could significantly overestimate the commercial performance of the resin concerned, highlighting the importance of computer simulation in this field of process engineering.

Jan 1, 2005

By C. A. Young, H-H. Huang, L. G. Twidwell

Solid particles, especially oxides/hydroxides, develop an electrical charge on their surface when submerged in aqueous solution. Parks was able to relate PZC (point of zero charge) of an oxide to its minimum solubility and isoelectric point. Dzombak has compiled an extensive database for adsorption reactions on ferrihydrite surfaces using the double layer theory. The equilibrium calculational program, STABCAL has been used to extend the considerations of Parks and Stumm. The PZC for many hydroxides, complex oxides, and non-oxides have been investigated and the results are reported in the literature. Removal of arsenic and metals by adsorption on ferrihydrite as the substrate has been computed using ST ABCAL and the computational results are compared to experimental data. Absorbents other than ferrihydrite such as aluminum hydroxide are also discussed.

Jan 1, 2005

By J. J. Jonas, G. R. Stewart, N. Pokutylowicz, S. Yue, R. Varano, A. Elwazri

Differing thermal histories in and around a weld can lead to differences in grain size, phase composition and morphology of precipitates; mechanical properties will vary accordingly. Hardness testing gives limited information and the machining and testing of tensile and/or impact specimens that would reveal these variations (which may occur over very small distances) is not practical. Therefore, in this investigation, shear punch testing was applied to measure the variation in the room temperature mechanical properties of a welded pipeline steel.

Jan 1, 2005

By E. Godin, M. Rigaud, S. C. Panigrahy, I. Malinsky

"RésuméDes boulettes de concentres d'hématite spéculaire à basse silice ont été produites en substituant la bentonite par de la tourbe, adéquatement traitée, additionnée d'une faible quantile de soude caustique durant le boulettage. La réductibilité de telles boulettes et leur gonflement pendant la réduction ont été évacues, en utilisant quatre mélanges gazeux différents, formes de H2 - CO - N2.L'influence du pouvoir réducteur du gaz utilise, sur le gonflement des boulettes, à été mis en évidence. Quelles que soient ces conditions réductrices, les propriétés mesurées sur les boulettes liées a la tourbe sont comparables aux propriétés obtenues avec des boulettes traditionnelles liées à la bentonite.ABSTRACTAdditions of peat moss and small quantities of NaOH during balling of low silica specular hematite concentrates have eliminated the need to use bentonite as a binder. The reducibility and swelling of such pellets have been evaluated using four different gas mixtures, consisting of H2 - CO -N2. The influence of the reducing power of the gases, on the swelling behaviour of pellets has been documented. Under the different reducing conditions, this new type of pellets exhibit properties similar to the ones obtained using bentonite."

Jan 1, 1987

By N. M. Soonawala

Detailed regional geophysical and geochemical surveys, ground surveys and drilling were undertaken to follow-up the federal-provincial Uranium Reconnaissance Program (URP) over the 27,OOO-km2 Kasmere-Munroe area in northwestern Manitoba. An analysis of the URP data showed a fair correlation between the regional airborne radiometric results and lake-bottom geochemical results, both of which also correlated with the regional geology. More detailed surveys defined anomalies with greater precision within the broad zones outlined by the URP. The ground follow-up indicated that URP anomalies can be caused by varying degrees of uranium concentration in the rocks. Mineralization of interest was found in leucogranites at several locations within the survey area. Anomalous uranium concentrations were also found in coarse pegmatites and Hudsonian granitic intrusions. It can be concluded that large-scale regional surveys can be followed up in relatively short periods of time to yield meaningful results if a properly planned exploration sequence is employed, each stage of which successively narrows the area of interest.

Jan 1, 1979

By H. Karakul

Determination of P-wave velocity (Vp), which is closely related to intact rock, is a nondestructive, easy and less complicated procedure. Due to these advantages, there is an increasing trend to predict the geomechanical properties of rocks from Vp. In addition to mineral content, cementing material and porosity, degree of saturation (Sr) are also other factors influencing geomechanical properties of the intact rock. However, up to the present, in the studies on the prediction of geomechanical properties of rocks from Vp, the effect of Sr has not been investigated. By considering this issue, in this study, it was aimed to correlate strength properties (uniaxial compressive and tensile strengths) and Young’s modulus with Vp of various rock types under different degrees of saturation. In addition, geomechanical properties of rocks were estimated from theoretical P- and S-wave (Vs) velocities, which were calculated based on their mineralogical compositions. For this purpose, fourteen different rock types were collected from several parts of Turkey and a comprehensive laboratory testing program was conducted. In the statistical analyzes, a series of different prediction relationships were developed by using independent variables such as Vp, Sr and effective clay content (ECC). Simple regression analysis results indicated that although prediction of the geomechanical properties of rocks from Vp at different degrees of saturation was possible, the equations developed would yield some under- or over-predictions. On the other hand, the multivariate equations developed have very high prediction performances and are very useful tools to estimate the geomechanical properties from the measured Vp at any Sr value. In addition to mineralogy, the variation in geomechanical properties with increasing Sr is also associated with the combined effect of porosity and clay content, which is first described in this study by the term Effective Clay Content (ECC). It is also noted that strength properties of rocks at any Sr may also be estimated using the empirical relations based on the theoretical Vp and shear-wave velocity (Vs) values, which are calculated from their mineralogical compositions.

Jan 1, 2015

By A. Mehinrad, F. Rafia

"The Dez River flows from the Zagros Mountains into the great Khuzestan plain, Southwest of Iran. The 203 m high Dez Dam is a double curvature thin concrete arch dam, with a Pulvino, founded on thick bedded to massive conglomerate of Bakhtiary Formation, mainly horizontal and very less jointed at the dam site. Construction work was completed in 1963, creating a reservoir with a total storage volume of 3’315 million m3. The dam body, with some 350’000 m3 volume and (W/H=1.1/1.0), is the dominant feature of the project.Geological and geotechnical studies at the dam site started in 1957 and continued during the whole period of dam construction. Simultaneously, two extensive programs of laboratory testing were carried out in New York and Milan.Most of the results were recorded in the project design documents and in two very well-known papers of Talobre et. al. (1964) and Dodds (1966), however, no detail results are available for most of tests.In order to estimate geomechanical parameters of the rock mass foundation for numerical modeling of the dam body and its foundation, reassessment of the in-situ and laboratory test results using the recent rock mechanics methods was required.This paper explains how the outcomes of those tests, performed more than 50 years ago, were reevaluated and how the definitions and parameters presented in the project reports were re-interpreted using the recent rock mechanics concepts and definitions. Also, the results of classification of Bakhtiary conglomerate using GSI system and application of Hoek & Brown failure criterion for estimating rock mass parameters have been described.INTRODUCTIONThe Dez River flows from its headwaters in the Zagros Mountains into the great Khuzestan plain. Just before entering the plane, the river passes through a narrow, steep gorge that is about 17 km long. The Dez Dam is located at the entrance to this gorge, some25-km upstream of the city of Dezful and 150-km upstream from the provincial capital Ahwaz (Figure 1)."

Jan 1, 2015

"The Cooperative Research Centre for Mining Technology and Equipment (CMTE) is funded by the Commonwealth Government, by its mining research members — the Universities of Queensland and Sydney and the CSIRO1, and by its industry members — BHP Coal, RioTinto R&TD, Hamersley Iron, Mining Technologies Australia, Pasminco, Shell Coal, WMC Resources, Advanced Mining Technologies, and Aberfoyle. The Centre conducts work aimed at improving the competitiveness of the Australian mining industry. The current work is focused in four areas: new mining and drilling systems, geological sensing, automation, and equipment maintenance and reliability. This paper describes much of the work in these program areas that relates to metalliferous mining. Mechanized Rock ExcavationThe disadvantages of the drill-and-blast excavation method are widely recognized and the last half of the 20th century has seen mining companies and mining research organizations aggressively pursue technology to excavate rock by other means. As discussed below, despite considerable effort and large amounts of funding, the quest for mining’s “Holy Grail” has been unsuccessful in all but the weakest rock types.COMRO (the Chamber of Mines Research Organisation) supported by the South African gold mining industry, spent three decades and (probably) tens of millions of dollars developing prototype drag bits and, later, impact breaking machines aimed at the mechanized stoping of narrow, tabular reefs. This work has not yet produced a commercially-attractive mining system. Work continues in South Africa to mechanize these stoping operations although now the emphasis is on the use of diamond-wire sawing techniques. This work remains in the experimental phase.Both British Coal and Germany’s Bergbau- Forschung spent many years developing techniques trying to extend the range of rock types which roadheaders could cut economically. Again, although new knowledge was produced, it is difficult to claim that any new commercial mining systems emerged from this work."

Jan 1, 2001

By L. Don Leet

Abstract Earthborne vibrations from blasting and other sources, including rock bursts, can now be recorded effectively. The nature and magnitude of vibrations from various sources have been investigated and certain applications of the knowledge thus gained have been made. Vibrations from blasting have been measured on special equipment over a range from an electric blasting cap at a few feet, through the largest quarry shot in history to date ( 1,-362,985 lb.), to the first atomic bomb, in uew Mexico on July 16th, 1945. Laws relating amount of explosive to amount of vibration at different distances have been developed and tested. Special studies have been made of the effects of vibrations on buildings, particularly from the standpoint of possible structural damage. Recorded vibrations are used to study the effects of modern short-period delay shooting. It ?has been found that short-period delay firing is extremely effective in reducing vibrations under the right conditions, but with certain limitations. In quarry shooting, there appears to be a minimum number of holes below which vibrations are not appreciably reduced by short-period delay firing. In several instances this minimum has been near 7. Vibrations in the ground from rock bursts and the effects of mining in stresesd ground have been studied both underground and on the surface in a search for a rock burst warning system. Introduction Earthborne vibrations from blasting and other sources, including rock bursts, can now be recorded effectively. Analyses of blasting records have been yielding increasing funds of information of practical as well as theoretical interest. The nature and magnitude of the vibrations have been investigated with special reference to their effects on structures.

Jan 1, 1951

By F. Rivard, M. G. Drouet, W. S. Ruff, P. Carabin

"In both the hot rotary-salt-furnace (RSF) treatment of aluminum dross and the cold ball-millsieving (BMS) treatment of zinc dross, enormous amounts of energy and recoverable metal are wasted and large amounts of greenhouse gas are produced. Such wastes and the environment pollution could be avoided by using the DROSRITE PLUS™ technology. Economic and GHG production comparisons between the presently used industrial treatment processes and DROSRITE PLUS™, supported by over one hundred tests conducted in Canada, the US and Europe, are presented. The savings, with DROSRITE PLUS™, would be about $191 and $418 per MT of aluminum and zinc dross, respectively.INTRODUCTIONDross is a material, which forms on the surface of molten non-ferrous metal, such as aluminum or zinc, during melting, metal holding and handling operations when the molten metal is in contact with a reactive atmosphere. Dross normally consists of metal oxides entraining a considerable quantity of molten free (unreacted) metal, and for economic reasons it is desirable to extract the free metal before discarding the residue. In the case of aluminum dross, recovery of the metal is usually carried out by treating the dross in a furnace at a high temperature (Peterson et al., 2002). By contrast, cold zinc dross is crushed in a ball mill followed by sieving to separate the coarse metal portion from the fine oxide residue.The conventional aluminum dross treatment process, using gas or oil-heated rotary salt furnaces (RSF), is thermally inefficient and environmentally unacceptable because of the salt slag and CO2 produced from the combustion of fossil fuels. In the past several years, a number of salt-free processes have been developed and some of these have found limited commercial use (Gripenberg et al., 1994; Lavoie et al., 1990). In all these dross treatment processes, heating of the cold dross in a rotary furnace requires an external energy input that varies between 375 and 2,500 kWh per (metric) tonne of dross. Molten metal separated during processing of the heated dross is tapped, and the remaining solid residue is discharged from the furnace."

Jan 1, 2012

By H. J. McQueen

Aluminum was hot worked at 400 - 500°C and strain rates (e ) of 0.004 -0.1s-1, under reversing strains (c) of 0.5 to 0.2 or 0.5 to 0 and also advancing from 0.5 to 1 or 0.5 to 5. Under similar test conditions for different parts of the strain paths, the average measured flow stresses are found to agree with each other. In the forward and backward strain path tests, the almost identical steady state plateaus affirm the occurrence of dynamic recovery (DRV). On reversal of strain direction at constant e , there was generally negligible Bauschinger effect. In specimens annealed at 400°C, static recrystallisation (SRX) was followed microstructurally. mainly by disappearance of elongated grains with serrated boundaries because the new grains were only little a finer than the old due to low strain energy. The only influence of reversing strain path observed was the effect of change of grain boundary area as grains elongated or returned towards equiaxed. In optical microscopy, elongated grains with serrations and deformation bands confirmed DRV in forward path specimens. In reverse path specimens, equiaxed grains were gradually restored with retention of serrations and bands. In low magnification polarized optical microscopy, grain alignment increased with strain for forward path specimens; whereas it decreased in reverse path ones, supporting DRV. Orientation imaging microscopy (OIM/SEM) revealed that elongated grains are broken up as deformation bands rotate during the forward path and that grains return to equiaxed appearance on backward straining. Comparative studies using optical microscopy in polarized light (POM), OIM/SEM and transmission electron microscopy (TEM) revealed that while subgrains remain equiaxed and constant in size and character during the forward and backward paths, the fraction of low angle facets decreased while that of high angle grain facets increased with increasing strain; these are coupled with a fairly low fraction of medium angle boundaries. The results contribute to the understanding that dynamic recovery in aluminum maintains sub-boundaries with low misorientation but as grains elongate and more subgrain become adjacent to grain boundaries the fraction of high angle boundaries rises (with backward straining it was vice versa).

Jan 1, 2007

By N. J. Shackleton, N. A. Chapman, V. Malysiak, C. T. O’Connor

In this study, the effect of using conventional crushing and high-pressure grinding rolls (HPGR) in combination with dry or wet milling was investigated using a base-metal sulphide (BMS) sphalerite and a platinum group mineral (PGM) ore to determine how these processes affect the flotation performance. In sphalerite, irrespective of the crushing procedure (HPGR or conventional), dry milling resulted in the highest grades and recoveries of zinc, whereas in PGMs, similar treatment produced the poorest results. The results were investigated further by the effect of factors such as percentage liberation and particle size on the flotation results.

Jan 1, 2012

By F. D. Forgeron

"ONE OF THE FIRST DOCUMENTED APPLICATIONS of soil geochemistry in the Canadian Shield was that carried out by Chisholm in the Kenora district in 1949. This survey proved successful in outlining sulphide-associated gold veins utilizing cold-extractable metals. Since then, mining companies, government agencies - both provincial and federal - and universities have conducted soil investigations. Some of the results are documented in publications, others are on open file in provincial and federal mines departments and, unfortunately, many other investigations with both successful and unsuccessful results are buried in company files or have been discarded. This paper deals with soils within the scope of chemical studies of overburden in the Canadian Shield. The subject is a broad one and some definition is required. The soil investigations discussed herein are those aimed at the testing of specific targets more or less in the source area. This definition distinguishes soil investigations from other overburden studies which commonly monitor metal accumulations at some substantial distance from the metal source. Naturally this distinction is relative, because in many instances there is overlap."

Jan 1, 1971

By Robert J. Uffen

YOU will likely recall the accomplishments of the International Geophysical Year of 1957, with its polar expeditions, the discovery of the Van Allen radiation belts and the spectacular launchings of the first artificial earth satellites. Our know ledge of the exterior of the earth was greatly increased by this international, friendly, cooperative scientific investigation. The Inter-national Union of Geodesy and Geo-physics has now been joined by the new International Union of Geological Sciences in sponsoring a similar study of the earth's interior. The program will extend from January, 1962 until December. 1964, and is known as the International Upper Mantle Project. During the T.G.Y studies of the interior of the earth were relatively neglected, even though the same international •Cooperation in obtaining simultaneous world-wide observations, by similar instruments, is required to locate and study earth-quakes, for example, as it is to study the earth's upper atmosphere. The upper mantle is 1•emote from man, as it extends from a depth of about 10 km. to perhaps 1000 km., but its practical importance is great.

Jan 1, 1962

By McGill Metals Processing Centre, S. Chang, L. Calzado, X. K. Cao, C. H. Hsin, M. Isac

"Due to the increasingly stringent cleanliness requirements for final steel products, there has been a growing interest in the possible use of micro-bubbles for the removal of inclusions with diameters smaller than ~50µm, present within the steel passing through a steelmaking tundish. However, several technological barriers have prevented the adoption of this technique in industry. These are related to a) the generation of micro-bubbles in liquid steel, b) the measurement of bubble size distributions, and c) the optimization of bubble injection conditions to create micro-bubbles. In the present study, a novel Aqueous Particle Sensor (APS) system was developed for the in-situ, on-line, detection of micro-bubbles in water, generated by a newly designed full-scale ladle shroud, located at McGill Metal Processing Centre (MMPC). Measurement results from the sensor were validated against bubble size data collected through a high speed camera and post-processed through the commercial software, Image J.Control variables and orthogonal experiments were designed to assess the dependence of average micro-bubble sizes and bubble size distributions on key experimental parameters. Those chosen were the air inlet flowrate, the distance of the gas injection port from the slide gate, and the number of injection ports used. The investigation demonstrated that the APS system can be successfully adapted to detect micro-bubbles up to ~800 micron diameters. Using this novel sensor, it was shown that multi-port injection using low air inlet flowrates, closer to the slide gate, were useful in forming small micro-bubbles within the flow through the ladle shroud. The results from the APS system were compared and validated against data resulting from an optical technique. INTRODUCTIONModern industry expects increasingly stringent cleanliness requirements for final cast products. Therefore, the numbers and sizes of inclusions need to be strictly controlled in steelmaking operations. Thus, the cleanliness of steel products depends on the amount, morphology and size distributions of nonmetallic inclusions in steel (Zhang L. & Thomas B., 2003). Since large, deep, tundishes provide longer nominal residence times for liquid steel passing through it to the exit SEN’s, this can provide the ideal place to separate inclusions, and bubbles can assist by removing help attach inclusions and float them to the top surface."

Jan 1, 2016

By R. D. Browns

In his Budget Speech on March 31, 1 977, the Honourable Donald S. Macdonald expressed concern about the financing of investments through new equity issues. He mentioned the need to render more attractive participation in the equity market by investors in all in come brackets. One of the measures introduced in the budget to accomplish this goal is the proposal to increase the dividend gross-up and tax credit in respect of most dividends received by an individual from Canadian companies. The following comments and tables serve to illustrate the impact of this particular proposal.

Jan 1, 1977

By M. W. Bartley

"The Steep Rock iron mine is 141 miles west of Port Arthur, Ontario, and 50 air miles north of the Vermilion iron range in Minnesota. The property lies 27'2 miles north of the village of Atikokan on the south line of the Canadian National railway.The orebodies underlying the bed of Steeprock lake, since de-watered, were known to exist 60 years ago. References to the possibility of iron ore at this location were made in early geological papers and reports. In 1937 the locations of the orebodies were determined by dip-needle surveys, and from 1938 until 1943 diamond and churn drilling were carried on to prove their extent and configuration. It was found that the ore, in addition to being associated with definite types of wall-rock, was controlled by structural features, such as faulting and brecciation. From this geological knowledge the presence of other deposits has been inferred, and these are now being explored and developed.Production at the property commenced in October 1944. During that season 17,000 gross tons of ore was shipped. In 1945, 506,000 gross tons and in 1946, 830,000 gross tons was mined and shipped. In 1946, 164,000 gross tons additional was placed on stockpile for future shipment.TYPES OF 0REBODIES AND MINERALIZATIONThe orebodies at Steep Rock iron mine are tabular. They have an average width of 250 feet, lengths up to 5,000 feet, and persist to known depths of 1,200 feet. They are replacement deposits in brecciated carbonate rock at the contact of underlying pseudo-limestones and overlying volcanics. The ore is composed of hematite and hydrous hematite in the form of goethite, turgite, and limonite. These minerals replaced the brecciated host rocks metasomatically as a result of hydrothermal action. The replacement followed a definite structural pattern along the unconformable contact between the sediments or other rock (now replaced by carbonate) and the volcanics, subsequent to disturbances in the form of minor faulting and shearing. The faulting and shearing provided the channels through which the replacing solutions percolated. It is believed that the late basic intrusions outside the ore zones were genetically responsible for the introduction of the ore-bearing solutions."

Jan 1, 1954