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By S. Heusermann, S. Fahland, J. Behlau, A. Schäfers, J. Hammer

In the course of the deep subsurface use, the Federal Institute for Geosciences and Natural Resources has been carrying out extensive geological and geomechanical research and practical project work on domal salt structures, to prove their suitability e.g. for the disposal of radioactive wastes. Recent work on disposal sites has been taking into account the 3-D geological and geomechanical modelling of the underground structures. The geological models are generated using the special-construction openGEOTM code to improve the visualisation and interpretation of the geological data basis, e.g. borehole, mine, and geophysical data. For the geomechanical analysis of underground structures the JIFE finite-element tool has being developed to analyze large 3-D structures and to consider coupled THMC processes. The results of finite-element calculations, i.e. stresses, strains, displacements, and dilatant zones, are basic values for the evaluation of the stability of the structures and the long-term integrity of the geological barrier. As an example, the results of geological and geomechanical investigations of the Morsleben repository are presented including three-dimensional modelling of the entire geological structure of the central part of the mine as well as three-dimensional geomechanical model calculations to provide the necessary results for a long-term safety prediction.

Jan 1, 2015

By K. S. Coley, M. A. Rhamdhani, G. A. Brooks

Interfacial phenomena in high temperature reactions such as between iron alloy and slag is well documented but not fully understood. It is believed that a gradient of oxygen concentration plays an important role to the occurrence of such phenomena. This article describes the results from the continuation of the study of interfacial phenomena between Fe-Al alloy droplets and CaO-SiO2-Al2O3 slag. Materials characterization techniques involving microscopic observations, depth profiling, bulk, point analysis and were carried out. The roles of oxygen as well as other factors that contribute to the interfacial phenomena were evaluated. The results and their implications to steelmaking will be discussed.

Jan 1, 2004

By Y. Okita

The Goro Nickel Process, developed over a ten-year period, uses a number of novel processing steps and treats two ore types, limonite and saprolite, together. Nickel and cobalt are solubilized using a 270°C pressure acid leach in sulphuric acid, which rejects the bulk of the Fe into the leach residue as hematite particles. The leach liquor, after CCD, is aerated to oxidize any ferrous iron to the ferric form and is neutralized with limestone to precipitate iron as hydroxides together with gypsum from the neutralization of the free acid. Further neutralization with lime, together with steps to remove suspended solids, reduces the iron to trace concentrations. Nickel and cobalt are directly recovered from the low-iron leach solution by primary solvent extraction using Cyanex 301® (SXl) in a high-strength hydrochloric acid solution. Nickel is subsequently separated from cobalt in a secondary solvent extraction circuit using tri-isooctylamine. A granular nickel oxide is made by pyrohydrolysis, and this allows the recycling of hydrochloric acid to SXl. The process is currently being commercialized to produce approximately 60,000 t/y of nickel as nickel oxide granules and approximately 5,400 t/y of cobalt as cobalt carbonate. This paper describes the process development to control the Fe concentration in the SX1 feed solution.

Jan 1, 2006

By G. Song

Magnesium has excellent bio-compatibility in terms of its density, strength, elastic modulus and toxicity. However, due to its poor corrosion performance, so far magnesium has not been successfully used in the human body as a permanent implant material. Nevertheless, there is a possibility to utilize the low corrosion resistance of magnesium to make magnesium into a temporary implant component that can gradually dissolve in the human body after surgical region heals. This will avoid the secondary operation to remove the temporarily implanted component and the chronic inflammatory discomfort caused by the implant. This paper is aimed at exploring the possibility of using magnesium as a degradable bio-material through investigating the corrosion behaviors of pure magnesium and surface treated magnesium in a simulated body fluid (SBF) solution. It was found that magnesium corroded rapidly in the SBF solution, resulting in vigorous hydrogen evolution and a strong alkalization effect. Hence, it is impractical to use magnesium as a permanent implanted material or even a degradable implant. However, a proper anodizing treatment can significantly improve the corrosion resistance of magnesium, and hence slower down the hydrogen evolution and alkalization processes, which will allow to control the corrosion or degradation of magnesium at a desired rate in the human body. With a controllable corrosion rate, it is believed that magnesium as a degradable implanted material will be eventually achievable.

Jan 1, 2006

By P. H. Rodriguez

The aquatic hazard classification system of the OECD and EU requires that sparingly soluble metal substances (SSMS) be tested using the OECD Dissolution/Transformation protocol in order to quantify the release of the ecotoxicological relevant species (dissolved ions). The SSMS category contains massive forms of metals, which due to their low solubility and slow transformation characteristics are a special case. The main factors that produce the release of metal into solution are exposed surface loading, pH, and stirring rate. The classification system at present prefers the use of mass loading as opposed to surface loading, in which case the amount of metal released will primarily be a function of the pH, and mass loading. Within the framework of the European Copper Voluntary Risk Assessment, coordinated by the European Copper Institute, we have proposed and developed a methodological procedure in which we demonstrate that surface area is an intrinsic property of a SSMS and we link the exposed surface loading to the toxicity reference value in order to obtain an aquatic hazard classification for massive metals. As example, the aquatic hazard classification for copper massive will be discussed. This approach is recommended for metal massives and metal powders.

Jan 1, 2007

By S. Perez

Core drilling is a fundamental process in the mineral exploration industry. As deep exploration in hard rocks is accelerated due to the depletion of near ground mineral resources, deep-drilling operations need to reduce their reliance in operators experience and begin to implement new technologies in order to increase efficiency and cost-effectiveness of the overall process. Currently, lack of real-time information on the bit/rock interaction is a major problem. Therefore the mechanism behind the acoustic emission, which is a proven technique for remote monitoring, generation in mechanical rock cutting must be understood in order to provide real time information about the rock. This paper aims to identify the influence of mineral composition of granitic rocks on the acoustic emission (AE) during rock abrasivity test with a single contact tool and to evaluate the feasibility of AE as a means to infer Cerchar Abrasivity Index (CAI). Single contact tool will provide precise and accurate description of the source of AE. To provide constant grooving speed Cerchar apparatus was modified to monitor AE during rock/tool interaction. Tests on the modified Cerchar apparatus are carried out under the static load of 70N and cutting speed of 1 mm/s. A Scanning Electron Microscope (SEM) is utilized to visualize the groove in the rock and to identify the mineral composition through Back-Scattered Electrons (BSE) reflected from the rock sample. Based on the microscope images, it was found that biotite shows a larger groove area and plate-like fractures accompanied with burst-type AE signal, whereas plagioclase and quartz, which are characterized by similar hardness and BSE brightness, possess shattered-like fractures and more continuous-type AE signals. In addition, a-value of the Gutenberg-Richter scale has been found to well correlate with Cerchar Abrasivity Index (CAI).

Jan 1, 2015

By M. Stogran-Baker, E. Legault-Seguin

"Fluorspar mining in the St. Lawrence area of Newfoundland and Labrador began in the 1930s and ended in the mid-1980s. In 2013, Canada Fluorspar (NL) Inc (CFI) discovered a new ore body, the AGS vein, which proved amenable to more economic open pit mining methods and began developing this resource. This paper discusses the flowsheet development of the AGS vein deposit. Testing at SGS began in 2009 with samples from other deposits in the area. The testwork included pilot-scale dense medium separation (DMS), laboratory-scale flotation tests to develop the flowsheet and a flotation pilot plant. The more recent work that is presented here has been devoted to the AGS vein, and included a variability testing program that gave tremendous insight into the metallurgical drivers of processing the deposit. The ore was found to be fairly variable in terms of fluorite grade, but also gangue mineralogy, which had greater implications on the DMS performance. The gangue mineralogy was also found to significantly impact the grindability characteristics of the DMS product. This paper will detail the testing conducted and the mitigating steps which were identified for the operation.INTRODUCTION Fluorspar is the industrial trade name for the mineral fluorite (CaF2), which is the primary industrial source of fluoride. There are a number of categories of fluorspar, most notably acid-grade fluorspar and metallurgical fluorspar (metspar). Acid-grade fluorspar has stringent specifications and is suitable for the production of hydrofluoric acid that is used for many applications. The typical specifications of acid-grade fluorspar are >97% CaF2 and less than 1% each of SiO2 and CaCO3, with a particle size distribution in the order of 80% passing 100 µm. Metspar is typically used for metallurgical purposes, typically as a flux in smelting, and has significantly more relaxed specifications (< 15% SiO2). The principle source of fluorspar in Canada has been from the Burin Peninsula in Newfoundland and Labrador. More than 3 million tonnes of fluorspar were produced there between 1940 and 1978 and from 1987 to 1990, when production ceased (Fulton & Montgomery, 1994)."

Jan 1, 2018

By H. J. H. Pieterse

Agitation requirements in oxidation autoclaves can vary widely depending on the mineralogy of the feed material and the specific process selected. Before selecting an agitation system it is important that the client specify the desired throughput, mineralogy, chemistry, kinetics, compartments, overall retention time, and the desired oxygen utilization. In selecting the agitation system, the factors mentioned above as well as oxygen solubility, oxygen mass transfer coefficients, and specific power are evaluated. Much research effort has been directed toward open tank systems for fermentation and oxidation processes. However, for high pressure autoclave oxidation processes little information is available. In this review the author&apos;s experience in the autoclave industry and some of the available literature are utilized to compare the installed power per unit volume with some of the methods proposed for open tank oxidation. Equations that appear to give results close to that experienced in the industry have been identified. Further work is required in this area to develop a higher degree of confidence in the ability to predict the power required for any given case.

Jan 1, 2004

By L. E. Collins

"In western Canada, many new wells contain a significant fraction of H2S. As well, many older wells become increasingly sour over their operating lifetime. For these reasons, there has been increased demand for linepipe and casing for sour service applications in recent years. This paper will review the metallurgical factors which must be considered in designing steels for such applications. IPSCO’s development of linepipe and casing, and experience in fabricating products to meet test standards specified for sour service applications will be summarized. IntroductionWestern Canada produces the majority of Canada’s domestic crude oil and natural gas. A complex system of pipelines has been built to gather the oil and gas from the fields for transport to refining and/or cleaning operations. The gas carried in these pipelines can be either sweet or sour (i.e. containing no H2S or containing H2S) depending on the nature of the field from which it came. Many new fields contain a significant fraction of H2S and many older fields become more sour as their time in production increases. This uncertainty regarding product condition influences the user’s choice of materials for both casing and pipeline applications.It is well known (Merrick, 1989) that hydrogen induced cracking (HIC) will occur in steel when three conditions exist simultaneously: (1) the presence of H2S gas, (2) moisture, and (3) a susceptible material. Steelmakers can only address the latter of these factors. Development of steels to meet test requirements of sour service has been a major focus of IPSCO’s development work for several years."

Jan 1, 1998

By N. H. J. Freire, D. Majuste

In this paper, the effects of some organic compounds on the current efficiency, cell voltage and specific energy consumption during nickel electrowinning, and on the deposit features (morphology, crystallographic orientation and nanohardness) were described. The organics tested here (extractant, diluent, flocculant, lubricating oil and acid mist suppressant) are currently used in industrial plants. The results indicated that only the flocculant and acid mist suppressant exhibit relevant negative impacts on the current efficiency and energy consumption. The current efficiency dropped from 93.6 % (organic-free solutions) to 86.0 % and to 92.8% in electrolytes containing 100 mg.L-1 of acid mist suppressant and flocculant, respectively. At this concentration, their addition to the electrolyte led to increases of the specific energy consumption in the order of 18 % (acid mist supressant) and 2 % (flocculant). Cyclic voltammetry showed that Ni nucleation occurs at more negative potentials at 50 and 100 mg.L-1 of these organics in the electrolyte, thus indicating an inhibition of the deposition process. The deposit quality decreased at the higher concentration of all organics, when more hydrogen pitting was observed. The acid mist suppressant caused delamination of the Ni deposit at 50 and 100 mg.L-1. The addition of 100 mg.L-1 of flocculant and acid mist suppressant to the electrolyte increased the nanohardness of the deposit around 31 and 72%, respectively. The increase in Ni deposit hardness may lead to a decrease in the material ductility, thereby affecting the stripping and cutting of Ni sheets. Our findings may be helpful since strong adverse effect of some organics that may be present in the electrolyte were identified, thus the industry can control and optimize the organic´s dosage in the corresponding operations.

Jan 1, 2016

By A. Vasenev

The quality and durability of asphalted roads strongly depends on the final step in the road construction process; the profiling and compaction of the fresh spread asphalt. During compaction machine operators continuously make decisions on how to proceed with the compaction accounting for project specific aspects as: ambient conditions, road geometry, roller type, asphalt mixture characteristics and behavior of other machines. In discussions over quality improvement in road construction it is often suggested to robotize rollers. To operate such robots would of course require operational strategies and routines. The reality of this moment is that these operational strategies and routines are not documented. To identify the existing best working practices and, ultimately, to proceed with developing automated robotized compactors, the knowledge of machine operators should at first be explored and described in a formalized way. Unfortunately operators have difficulty verbalizing their expertise. Observation of behavior, as machine movement patterns, could be helpful to extract the operational strategies, but such observations are time and labor consuming. To overcome this burden we developed a Virtual Reality (VR) environment. In this VR environment operators perform compaction virtually, and their operational choices are traced and analysed. This paper describes this VR development and explains how it helps in following machine operators and extracting their (tacit) professional knowledge. The road geometry and the working conditions are visually represented; the operators show - rather than explain - how they would proceed with the compaction process in the given conditions. Movements of virtual machines are documented, analysed, visualised and discussed. This VR approach is expected to contribute to learning, to more formal description of operational strategies; stepping stones towards compaction algorithms for roller robotisation.

Aug 1, 2013

By P. J. Oakley, W. M. Thomas, S. W. Kallee, D. G. Staines

A Friction stir welding (FSW) is now extensively used in aluminium industries for joining and material processing applications. The (FSW) technology has gained increasing interest and importance since its invention at TWI almost 15 years ago. The basic principle, recent applications and the continuing development of the FSW technology are described. The paper will introduce some of the variants of FSW, such as Dual-rotation, Twin-stir(TM), and the Stir-lock(TM) technique.

Jan 1, 2006

By C. J. Clayton, A. J. Haynes, D. A. Hickson, B. Thiele

The Meadowbank Gold Project, formerly owned by Cumberland Resources Ltd. and currently owned by Agnico Mines Ltd., is currently being developed approximately 70 km north of Baker Lake, Nunavut, in the eastern Canadian Arctic region. The Meadowbank Gold Project currently consists of a series of gold-bearing deposits within relatively close proximity to one another, which are planned to be mined primarily as a truck-and-shovel open pit operation using conventional gold milling and extraction. The mining plan indicates that approximately 20 million tonnes of ore will be mined over a mine life of eight to ten years. The operation will generate approximately 160 million tonnes of mine waste rock and about 20 million tonnes of tailings. The site is located in an area of continuous permafrost with mean annual average air temperature of -11°C and average annual precipitation in the range of 100 to 200 mm. Lakes cover a large portion of the site, including some of the ore deposits. The location of the site and the physical environment pose challenges to development. This paper presents some of the designs considered to effectively manage and utilize the waste products of mining at the project. Note that volumes, tonnages, construction concepts, and data presented in this paper are accurate for the time of writing and are subject to change and modification as the project progresses, additional modelling is carried out, and additional data are obtained.

Jan 1, 2007

By James K. B. Booth

The natural crustal abundances of the principle metals of commerce are examined in relation to production and prices for each metal. Two factors, the abundance x price ratio (BP factor) and abundance/production (B/T factor) are listed for each metal. Ideally, for these desirable commercial metals, each factor should be a constant and the same for all metals; comparing the divergences for the full list of metals allows conclusions to be drawn on the relative degree of natural availability of each metal and the ease or difficulty of winning the metal from the earth's crust. Plotting the two factors for each metal over the past decade of steady industrial usage illustrates the anomalous position of copper and, to a lesser degree, molybdenum and it is concluded that over the long term the price of copper will continue to rise steeply. Possible future prices for copper are examined and a suggested preferred order of ranking of the metals as exploration targets would be copper, nickel, tin, zinc, silver, molybdenum and lead, for the near term, with molybdenum possibly increasing its ranking in the list within the next decade.

Jan 1, 1971

By Suzie Poulin, N. Geoffroy, G. P. Demopoulos

Most metallurgical industries generate toxic waste that must be treated prior to being released to the environment. However, in a lot of cases, the waste materials are poorly characterized or the analytical results are not well interpreted. These shortcomings often result in the development of inefficient industrial procedures, thus causing economic waste and difficulty meeting environmental regulations. Fortunately, a wide range of analytical techniques are available to guide researchers and engineers into making sound process development decisions. In this work, an industrial selenium and mercury removal process is used as an example to illustrate the application of X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) coupled with Energy-dispersive X-ray spectroscopy (EDX) and powder X-ray diffraction (PXRD) on solid waste. Furthermore, samples of analytical results are presented and interpreted and the modifications to the industrial process that resulted are explained. Finally, a brief description of the advantages and limitations of the aforementioned analytical techniques is given with an emphasis on industrial solid waste material.

Jan 1, 2011

By Sean Hillacre, Arthur Lieu

NexGen’s approach to uranium processing design including the crushing/grinding and leaching of raw ore through to yellowcake precipitation and tailings management focuses on minimizing surface footprint, freshwater consumption, and human radiation exposure. Applying the concept of best available technologies economically achievable (“BATEA”), NexGen continues to research, evaluate, test and validate various advanced technologies that can be incorporated into the Project design, including distinctive tailings storage techniques. Additionally, NexGen is proposing that tailings generated from the mill processes be used as cemented paste backfill of stopes, as well as stored in a purpose-built, Underground Tailings Management Facility (“UGTMF”) comprised of several dedicated chambers. The paste backfill method of tailings storage is used globally, however, constructing purpose-built tailings chambers in waste rock is a new concept in uranium mining, which would typically be cost prohibitive for most projects given the expense to develop non-economic material for the sole purpose of storing tailings. The Rook I Project is uniquely positioned to implement the UGTMF due to robust Project economics and favourable technical setting which provides NexGen with the opportunity to set an elite standard for tailings management. When compared to conventional surface tailings management facilities, storing tailings underground as cemented paste reduces geotechnical, geochemical, environmental, and human health risks associated with tailings management. Additionally, the UGTMF vastly reduces the area of surface disturbance and allows for progressive decommissioning during the life of mine operations.

Jan 1, 2020

By R A. Burwash

In the Yellowknife geologic province, 2,600-million-year-old granites are cut by three sets of diabase or gabbro dyke : (1) large dykes striking 70°E to E-W, (2) rare dykes striking N-S to 30°E and (3) an abundant swarm striking N 10°-300W. Preliminary potassium-argon dating has been carried out on whole-rock samples of the chilled margins and coarse centers of the dykes, and on mineral separates from the dykes and contact aureoles. Data from seventeen dated samples suggest that the dyke sets were intruded during three periods of basaltic magmatism -2,200, 1,500 and 1000 million years ago. The two earlier periods closely follow the time of emplacement of granites in the Yellowknife and Churchill geologic provinces. The latest diabase dykes occurring in the Yellowknife province are temporally related to a widespread basaltic magmatism, for which the term Keweenawan is not appropriate. D DRING the past ten years, methods of physical age determination have been widely applied to date the time of intrusion or metamorphism of Precambrian rock

Jan 1, 1963

"The Hardy Cross algorithm offers a reliable method of solving network systems of fluid flow and has become widely used for solving water and ventilation flow networks. A limitation is that computational iterations and time to solve a network rises rapidly with the size of the model and modern detailed ventilation networks have typically grown to thousands of airways. Non-linear matrix solving methods can offer improved performance, however these are more complex and may be unstable if initial estimates are poor. This paper presents improvements that can be applied to the traditional Hardy Cross algorithm to greatly reduce iterations and solving time for large ventilation models. INTRODUCTION The Hardy Cross algorithm (Cross, 1936), was originally developed to solve water flow in city and urban pipe networks. Using principles of Kirchhoff’s electricity current laws, Hardy Cross developed an iterative algorithm for solving non-linear equations associated with network water flow. Traditional network analysis research refers to the various members of system networks as branches, nodes and meshes. This terminology has been changed in this paper to airways, junctions and loops respectively which are terms more familiar to engineers in mine ventilation. When Kirchhoff’s laws are applied to fluid networks, the following assumptions can be made: •The sum of fluid flows into a junction must equal the sum of fluid flows out of the junction.•The sum of pressure losses around any loop through a network system must be equal to zero.An iterative solution can therefore be achieved by initially guessing flow in a network, calculatingthe pressure losses around the network loops (Figure 1), and applying flow corrections using Newton’s method for each loop if the sum of the pressure losses does not equal zero. To solve the system, a loop must be defined for every segment or series of segments between a junction of 3 or more airways.The Hardy Cross algorithm has been used extensively for ventilation network analysis since the introduction of the first electronic computers (Tien, 1997), however numerous other variations and methods have since been developed through the use of matrices to solve the required system of nonlinear equations. Commonly used algorithms such as the Newton Raphson method (Brown, 1969), the Gradient method (Todini & Pilati, 1988), the Linear Theory method (Gupta & Prasad, 2000), and Coupled Network Solver (G. Danko, 2008) have found general use in fluid flow network solvers (Rossman, 2000). Despite poor and sometimes unpredictable convergence performance however, the Hardy Cross algorithm still has unique properties that make it attractive for ventilation models. Some benefits are:"

Jan 1, 2019

By Shawn Harvey

HIGHLIGHTS of STAR DIAMOND PROJECT Initial underground bulk sample 4,048 ct / 25,253 tonnes: US$135/carat: 3,050 ct March 2005 $116 million financing: Newmont takes 9.9% SGF Prefeasibility study commenced on Star Merger with Kensington: 42.245% FALC-JV Voting agreement with Cameco in FALC-JV November 2005 $120 million financing: Newmont maintains 9.9% SGF Diamond valuation: 5,950 ct/ 36,529 tonnes: US$135/carat

May 1, 2006

By I. Southern, S. Kelebek

"Smelting furnace bricks contain significant quantity of base metals trapped in refractory material. A series of flotation tests were carried out on samples of old bricks from Sudbury area to examine upgrading behaviour for recycling purposes. Depending on the grind size used nickel recoveries varied from 60 to 90.6% with corresponding grades of 20% and 14.7%Ni. There is a trade-off between nickel and copper. The nickel has responded well to fine grinding, however, the copper recovery suffered from it. Mineralogical characteristics and flotation behaviour of the brick material are discussed in reference to those from the primary ore. INTRODUCTIONMineral processing is well recognized as a mature technology not only for the mining industry, but also for the environmental industry for the purpose of remediation and recycling. Materials available for recycling are usually the products of many years ago. There are multiple stake holders in this area. In general, when the processing results in a product that can be reused or sold, the company carrying out the remediation makes a profit, while the regulators and the public are pleased due to a cleaner environment. From these points of view, there have been many papers published over the years on various mineral processing techniques applied to separation of many different materials including from mining and metallurgical industries (Wilson et al., 1994; Tsunekawa et al., 2005; Saikia et al., 2012).Flotation may be viewed as the backbone of the mining and metallurgical industry since its invention for separation of solids from one another almost a century ago. It is capable of recovering a variety of finely divided different solids following their liberation from each other. Its versatility and highly competitive nature in terms of cost per tonne of material processed, accounts for its occasional uses in the environment engineering area. In the mining industry, flotation is the standard method used for the sulphide ores. It can be applied as a bulk flotation and/or differential flotation. Bulk flotation, which refers to co-flotation of several components from their source, is most suitable for environmental cleanup objectives. Desulphurisation of various plant tailings is a typical example of this (Benzazzoua et al., 2000)."

Jan 1, 2012