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By E. H. Baker

Vapour pressures of sulphur have been measured over the temperature range 340-1039°C by means of boiling-point measurements, an internally heated pressure vessel being employed with argon as the pressure medium. The results are expressed satisfactorily by a four-term pressure-temperature relation. At the cited critical temperature of 1040°C the calculated critical pressure is 204 atm. From the pressure-temperature relation and available thermal data for the vapour, the approximate composition of the saturated vapour in terms of the various molecular species has been derived for the critical point

Dec 1, 1971

By J. A. Saunders, E. L. Rowan

It is now widely accepted that the metal-rich waters found in the oil wells are possible present-day analogues of the mineralising solutions that formed the Mississippi Valley-type (MVT) deposits throughout mid-continental USA and elsewhere. A study characterising the trace-metal content provides additional circumstantial evidence for a genetic link between sediment-hosted mineral deposits and basin brines: Ag, Co, Ni, As and Mo, detected in the scale, are locally present in accessory minerals in MVT deposits and the levels of Ag found in the wells support the conclusion that sedimentary sources for silver should be considered in evaluating the origin of Pb-Zn-Ag deposits in sedimentary terrains

Jun 12, 1905

By J. Gough M. D.

There are many points still obscure regarding the nature of coal-workers'- pneumokoniosis, but the interpretation of the disease has been greatly clarified in recent years. It is now known that exposure to fumes or gases or other conditions peculiar to coal-mining are not necessary factors in the production of pneumokoniosis. The same disease occurs in coal-trimmers working in the docks, and it is thus established that the inhaled dust is the primary factor. On the other hand, there is no completely satisfactory explanation of the distribution of the disease. Geological and petrological studies have not given an unequivocal explanation of the difference in incidence in different parts of the coalfield. It is an open question whether the quantity of dust inhaled is more important than its chemical composition. However, there is ample evidence from the medical side that elimination of dust and of tuberculosis from the environment of coal workers will be required to prevent pneumokoniosis. Much is being done with regard to elimination of dust, and a similar energetic action is required in regard to tuberculosis.

Jan 1, 1947

By T. A. A. Quarm

The concept of a continuous zinc smelting process which employs submerged combustion of coal char for both heating and reduction is described. An estimate of the results of smelting a marmatitic zinc concentrate indicates that both the operating and construction costs would be lower than those incurred in processes now in commercial operation. The results of smelting a complex zinc-copper concentrate are also estimated, but no simple commercial process exists with which they can be compared

Dec 1, 1971

Discussion following the presentation at the North of England Institute of Mining and Mechanical Engineers' general meeting held in Newcastle-upon-Tyne, 8th April 1916, included the author's introduction, written contributions by Bedson P.P., Gregory T.W.D. and Morgan J.D., oral contributions by Louis H., Greener T.Y. and Severs W., and the author's reply

Dec 1, 1916

By M. W. Davies, P. N. Smith

The activity of MnO has been measured in the system CaF2-MnO at 1773 and 1873 K and in the system CaF2-CaO-MnO at 1773 K by the method of equilibration with platinum. Large positive deviations from ideal solution laws have been found, but these became less as the lime content rose. The loss of a volatile component made activity measurements impossible in the CaF2-AI203-MnO system, but the boundaries of a two-liquid region have been measured at 1773 K.

Dec 1, 1971

By NA NA

Reports of discussion at sessions held in Keyworth, UK, on 22-23 April 1992.

Jan 12, 1992

By N. Powell, R. J. Pine

An algorithm is proposed for updating the probability of slope failure on the basis of sequential testing using Bayesian probability theory. The approach is novel and computationally straightforward since, unlike other methods, updating of the probability of failure is carried out directly. This is because the probability is treated as a random variable whereas other methods have considered it as a purely deterministic value or as a function of shear strength parameters that are updated individually. The prior information required for the Bayesian analysis is obtained by a conventional probabilistic analysis. An exponential distribution is then used for the probability of failure, applying the principle of maximum entropy. This distribution is continually updated for individual slope cells, where repetitive excavation creates several such cells and a corresponding series of Bayesian estimates of the probability of failure is obtained. The approach is applicable to most simulations but there are limitations on its use. A more mathematically rigorous refinement using the beta distribution is currently under development

Apr 1, 1996

By J. E. Rouse, D. L. Buchanan

"During the emplacement of the Bushveld Complex in the Potgietersrus area magma reacted with the original floor rocks— Archaean granite or Malmani dolomite and overlying Penge handed ironstone or sedimentary rocks of the Pretoria Series. The complex sequence of sulphide-rich mafic rocks that formed along the contact is known as the Platreef. Associated with the sul­ phide mineralization are important concentrations of platinum-group metals, copper and nickel. Xenoliths of Malmani dolo­ mite have been incorporated into the Platreef and previous work has suggested that anhydrite is likely to have been present in the dolomite. The sedimentarv-derived sulphur thus introduced into the magma exercised an important control on the forma­ tion of the sulphides.Petrographic studies on the Platreef rocks from the Tweefontein area indicate that the original magma reacted with the banded ironstone to form iron-rich pyroxenites. In the Turfspruit area, to the south, the footwall rocks consist of sediments of the Timeball Hill Series. Original argillaceous rocks have been metamorphosed to cordierite-, corundum- and spinel-bearing hornfelses. Graphite was present in the contact zone in both the Tweefontein and Turfspruit areas. Anhydrite-bearing hornfels rocks are also present on Turfspruit.The Platreef rocks that overlie the corundum- and spinel-bearing hornfelses on Turfspruit are peridotitie, and pyroxenites are present in areas underlain by cordierite-bearing hornfels. The absence of orthopyroxene in the peridotite is probably indicative of low silica activity in the original magma. The pyroxenites have, however, undergone silica contamination from the underlying more siliceous cordierite hornfels.Carbon isotope studies indicate that the graphite in the Tweefontein and Turfspruit samples represents organic material orig­ inally associated with the footwall sediments. Sulphur isotope determinations on the anhydrite-bearing floor rocks indicate that this phase is clearly of sedimentary origin and was probably derived from an evaporitic unit within the carbonate sequence. This provides firm support for a model of ore genesis that involved the introduction of additional sulphur into the Bushveld magma. Isotope studies on sulphides associated with the banded ironstone and graphite indicate that these units were not the source of additional sulphur. Experimental studies predict, however, that a magma contaminated with iron- and carbon-rich material would have a high sulphur-carrying capacity. Where additional sulphur is available the magma would achieve saturation early in its crystallization history and precipitate an immiscible sulphide phase. Experimental work has also shown that sulphide precipi­ tation can be triggered by the introduction of salic material into a magma close to sulphur saturation. This mechanism probably played a role in the control of the sulphide mineralization in the Turfspruit area."

Jan 1, 1984

Jan 1, 1947

By Fearnsides W. G.

The map shows the sites of collieries and important boreholes in the district, with approximate underground contours of the pre-Permian surface of the Coal-Measures and of the Barnsley Bed

Dec 1, 1916

By L. R. Chimimba

"The Trojan nickel deposit occurs within a pile of ultramafic lavas subjected to a lower amphibolite grade of metamorphism. The lavas form part of the Upper Greenstones (Bulawayan Group) of the Mazoe greenstone belt. The nickel mineralization occurs as disseminated, massive and near-massive sulphides. The massive and near-massive ore occurs along the basal contact of the serpentinite units and is overlain by the more abundant disseminated ore, which occurs within the serpentinite. The main sulphide minerals are pyrrhotite. pentlandite and chalcopvrite. Minor amounts of millerite and pvrite are present. The Ni : Cu ratio in all three types of ore averages 15:1.The intercumulus nature of sulphides in the near-massive ore and similar textures occasionally seen in the disseminated ore indicates a magmatic origin of the mineralization. The basal position of the near-massive and massive ore suggests that the sul­ phides settled out under gravity during the emplacement and crystallization of a peridotitic magma. The deposit has been deformed and some of the primary massive ore has been remobilized into veins and breccias. The disseminated mineralization now occurs mainly as blebs of sulphides intergrown with silicate minerals or as stringers of sulphides between foliation planes in the serpentinite."

Jan 1, 1984

By A. Policard

The bodies of mammals possess a very efficient mechanism for ridding themselves of inhaled dust. When the lung is healthy this mechanism works very well, and dust is quickly and completely expelled from the lung either by the respiratory tract or the lymphatics. The mechanism, however, is easily upset, and slight alterations in the condition of the ciliated epithelium or the circulation of lymph are sufficient to interfere with it, therefore the second mechanism comes into play and the dust is fixed and immobilized in some part of the lung. This, however, is not a real cleansing process, since the lung becomes a dust-trap, and may become'pneumokoniotic. The mechanism is protective at first, but later, when the accumulation of dust is considerable, it gives rise to trouble. The lung cannot become, so to speak, a physiological dust-trap, and still retain its normal structure and function; pneumokoniosis begins, which is essentially a disease due to the mechanical presence of large amounts of inert foreign material.

Jan 1, 1947

By C. P. Summerhayes, J. W. G. Gilbey, S. Henley, G. P. Glasby, J. J. T. Harvey, J. Larsson, O. Akiman, A. G. Brown

Abstracts are presented from six University of London, one University of Nottingham and one University of Durham PhD theses

Dec 1, 1971

By I. R. Hanby

A simple but comprehensive method has been developed for the simulation of a mechanical-drive dump truck that enables various parameters to be predicted as a function of time throughout its whole cycle. Uses of the simulation results are indicated with specific attention to environmental and operational or economic planning. The output of a sample run is presented. The method can be easily adapted for the investigation of a wide variety of mobile plants.

Jan 4, 1992

By L Casari

A study of samples from three sectors of the mine, which was worked from Roman times to 1991, revealed different textures, mineral associations and distributions of trace elements in the sulphides. In the last decade before closure, grades of sphalerite concentrate were in the range 51.67-53.30% Zn and 2.21-2.86% Pb and of galena concentrate 69.43-71.62% Pb and 4.70-8.36% Zn, while the estimated by-product germanium content of sphalerite concentrates sold was 300-400 g/t. Passing the different run-of-mine materials through the same concentrator flowsheet produced middlings and tailings during the preconcentration processing. Separate and alternative treatment of run-of-mine products would have yielded improved recoveries of sphalerite and galena and better values of by-product germanium and cadmium

Jun 18, 1905

By B. Sonmez, B. Aksanl, S. Ersaym, I. F. Erkal, S. L. Ergun

The comminution circuit at the plant has experienced severe problems arising from a feed containing much larger amounts of clay and having a higher moisture content than expected. Three solutions were proposed: replacement of the crushing circuit by tooth roll-type crushers; using washing drums; and introducing primary autogenous/semi-autogenous millling instead of crushing. Computer simulations studied the effects of the first two solutions on the circuit capacity. Laboratory and industrial scale ball mill batch grinding tests were carried out. The parameters of a kinetic model were determined. The ball mill circuit was sampled and operating model parameters were calculated. The ability of batch grinding parameters to represent the operating conditions was studied. Tests failed to find acceptable model parameters, but parameters from an industrial size batch mill were found to be suitable for simulation studies. The simulations indicated that a continuous feed of -12 mm provided by tooth roll crushers would maintain the desired capacity. Increasing the feed size to -25 mm would reduce the capacity by 8-15%. The use of washing drums could also solve the capacity problem, but small fluctuations in water flow rates might result in problems of excess water in the grinding circuit.

Jan 4, 1993

By J. Plant

Stream-sediment sampling undertaken to define the regional geochemistry of northern Scotland is described with particular reference to the errors involved. The region is underlain essentially by Moine schists, Caledonian granites and Old Red Sandstone sediments, which are generally characterized by low geochemical relief. Factors in the secondary environment obscure the relationship between trace-metal concentrations in stream sediments and bedrock geology. Investigation of sampling and sample preparation methods indicates that the -100-mesh material is the optimum size fraction for the regional survey of this area: it provides adequate geochemical contrast: it reduced the incidence of spurious high values in the samples investigated and it is available in amounts which are adequate for all the analyses required. Grinding samples improves precision and reduces the preferential volatilisation of metals coprecipitated with hydrous manganese and iron oxides for the optical emission spectroscopic method used initially. A study of the dispersion of metals in the drainage system of an area of Pb-Ba-Mo mineralisation and an area of U-Pb mineralisation, respectively, indicates that a sampling interval of 1 per 2 km2 based on second- or third-order streams is adequate to define anomalous metal concentrations. Regional variation can also be represented on the same interval. Modifications to the sampling procedure to reduce the effects of the secondary environment are complicated by the primary association of Mn and Fe with mineralisation in the area. The ratio of analytical and sampling error to regional variance shows that procedural precision is adequate to prepare regional geochemical maps of northern Scotland, with the exception of Cr, Cu at low concentrations and Pb.

Dec 1, 1971

By T. Sharma, T. C. Rao

Laboratory studies have been carried out on acid leaching as a possible route for the extraction of potassium from glauconitic sandstone. Leaching efficiencies with sulphuric, hydrochloric and nitric acids were investigated. The effects on potassium dissolution of temperature, concentration and type of acid, stirring speed and leaching time were also studied. The results show that it is possible to recover 87.5, 93 and 85% potassium with 5 M H2SO4, HCl and HNO3, respectively. During the initial stages of the sulphuric acid leaching process the chemical reaction at the mineral surface is the rate determining step, whereas during the later stages diffusion through the product layer is rate-controlling. Overall, the process follows a mixed-control model that includes both chemical reaction and diffusion. The activation energy for the dissolution of K was found to be in the range 25.79-106 kJ/mol.

Jan 12, 1992

By M. C. Amiri

The plant produces 130 kg slag per tonne of crude steel, to add to the basic oxygen steel-making converter slag stockpile of around 2 500 000 t. The slags contain 1.81% V2O5, which can be rendered water-soluble by salt roasting with NaCl and an alkali such as Na2CO3. Preliminary tests gave less than 3% V recovery from slag under optimum roasting conditions when NaCl, NaCO3 or Na2SO4 was used, but showed that sodium phosphate could make all the V water-soluble when roasted with slag in a ratio of 3:1 at 1 100-1 200 degrees C. Almost complete leaching was obtained within 2 h with water at boiling point. Sodium vanadate was precipitated by acidifying the leach liquor with HCl to a pH of about 2.2

Jun 21, 1905