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By R. H. Jefferson

An electrochemical method to selectively determine sulfur dioxide in the presence of sulfur trioxide was investigated. A hydrophobic gas-permeable membrane separates the gas sample solution from an internal filling solution containing a fixed quantity of chloride ion and a sufficiently large excess of sodium bisulfite so that its concentration may be considered constant. Sulfur dioxide diffuses through the membrane to dissolve in the internal filling solution and liberates an equivalent quantity of hydrogen ions. The electromotive force between a precision-ground, flat-ended pH electrode, which acts as the sensing element, and a chloride sensing electrode, which acts as the reference element, gives a direct measure of S02 in the gas sample solution. Calibration curves in water, tetrachloromercurate (TCM) , and citrate buffer absorption solutions were closely parallel with slopes in their linear segments, ranging from 57 to 52 mv/decade of S02 concentration. The slopes compare reasonably well with the theoretically expected slope of 58 millivolts at 21° C. The water standard curve was linear with respect to the logarithm of S02 concentration from 1 to 1,000 ppm S02; the TCM standard curve was linear from 10 to 2,000 ppm S02; and the citrate standard curve was linear from 30 to 5,000 ppm S02' The high efficiency and nontoxicity of citrate favor it as a substitute for the conventionally used TCM in the absorption solution.

Jan 1, 1976

By W. L. Heidenreich

This report describes the methods and results of field investigations conducted by the Bureau of Mines between December 1956 and December 1957 on seven deposits of nickel-cobalt-iron-bearing laterite and weathered serpentine near the west coast of Puerto Rico east and south of Mayaguez. These deposits were named, for purposes of identification, Guanajibo, Punta Guanajibo, Las Mesas, north and south deposits of the Rosario Southeast group, and the west and east deposits of the Maricao Southwest group. In addition, the lower 17 miles of the Guanajibo River Valley was tested at widely spaced intervals for possible concentrations of magnetite and chromite in the alluvial sands. The objective of the investigations was to appraise, by drilling and sampling, the two largest deposits--the Guanajibo and Las Mesas. Testing of the smaller deposits was much more restricted. Field investigations consisted of mapping, drilling with power auger, sampling drill-hole sections, and pre-paring samples for chemical analyses, mineralogical studies, and metallurgical tests. The work was financed jointly under a cooperative agreement by the Bureau of Mines and the Economic Development Administration, an agency of the Puerto Rican Commonwealth.

Jan 1, 1959

By R. F. Droullard

The Bureau of Mines has developed test facilities for use in a research program that deals with radiation hazards in mining. This report describes the radon test chamber located at the Denver Research Center and the Twilight experimental mine located near Uravan, CO.

Jan 1, 1984

By Floyd G. Anderson

This report reviews and summarizes information on prevention and suppression of dust in mining, tunneling, and quarrying published in the United States from 1961 through 1967. Unpublished pertinent data developed or assembled by the Bureau of Mines during this period also are included.

Jan 1, 1969

By Martin H. Stanezyk

The Bureau of Mines investigated leaching of selected copper sulfide minerals and a composite of impure flotation concentrates at elevated temperatures and pressures with ammoniacal solutions. Copper 1 (tractions of 96 percent were obtained by leaching chalcopyrite at 75° C under oxidizing conditions for 60 minutes. An extraction of 99 percent of the copper contained in the composite concentrate was obtained by leaching the product for 90 minutes at 75° C. In tests of bornite, chalcocite, and covellite, 90 to 97 percent of the copper was extracted at 20° C provided an 8-hour reaction period was used. At 75° C essentially complete dissolution of the copper from these three minerals was accomplished in 60 minutes. Additions of ammonium sulfate to the leach solutions were required to obtain high-percentage extractions of the copper from bornite, chalcocite, and covellite. Although ammonium sulfate was not required when digesting chalcopyrite, copper extraction was enhanced and less free ammonia was required when ammonium sulfate was added to the leach pulps. The chemistry of leaching copper minerals was studied. It was C, termined that chalcocite altered to covellite as one step in the dissolution When leaching iron-bearing copper sulfides, hydrated iron oxide formed on the mineral surfaces, indicating that a diffusion process prevailed. No evidence of covellite was detected.

Jan 1, 1966

By D. N. Tallman

The electrokinetic properties of MgO have been utilized to simultaneously filter suspended solids and remove trace amounts of dissolved heavy metals from synthetic mine water. Greater than 95 pct removal of metals from influent at neutral pH containing 1 to 6 mg/L of dissolved Cd, Cu, Mn, Ni, and Zn can be routinely achieved by filtering through a granular bed of MgO at flow rates typical of rapid sand filtration (0.3 cm/s). Filtrate concentrations of most metals can be maintained below 0.1 mg/L for 160 bed volumes or more loading. The more mobile metals (those with larger solubility products) are more difficult to remove, and are strongly bonded to the MgO granules so that chemical stripping with chelating agent is required to clean the bed. Less mobile ions are easily removed by the filter and are effectively stripped by conventional filter backwashing. The fraction of metals recovered by chemically stripping the loaded MgO filters correlates to the zero points of charge of the metals. This process may be applicable to removal and recovery of trace amounts of heavy metals in mine drainage that is partly neutralized by liming. Also, since many of these metals are critical and strategic, the technique can be adapted not only to recycle process water from mineral and milling waste streams, but also to reclaim their metal values.

Jan 1, 1986

By R. L. Benner

The Bureau of Mines investigated the ZnO-Fe2O3-Fe3O4 system at 1,000°, 1,300°, and 1,400° C, with oxygen pressures between 1.0 and lx10-4 atmospheres. The results, divided into the thermodynamic properties as related to the spinel structure, and the thermodynamic properties as related to zinc concentrate roasting, were used to calculate the activities of ZnO, Fe2O4, and Fe3O4 within the spinel solid solution region of the ternary system, and the pseudo-binary activities of ZnFe2O4 and Fe304. The activities of both systems show large positive deviations from Raoult's Law, especially at high Fe3O4 concentrations. The free energies, the enthalpies, and the entropies of mixing for the binary system were calculated from the binary activities, and the entropies of mixing were compared with two statistical models, one representing an ideal solution, and one representing the mixing of a normal with an inverse spinel. The binary entropy of mixing seemed to be better represented by the latter statistical model, indicating that the tetrahedral and octahedral cations of the reactants tend to remain in the product, even at the high temperatures of the study. This comparison also indicated that the cations of the components are the major contributing factors to the thermodynamic properties.

Jan 1, 1966

By D. J. Parker

Before the various States began to enact workman's compensation laws accidents were considered inherent in many industries, and little or no effort was made to prevent or reduce them. The hazard was accepted by the employee with the job, and the avoidance of accidents by mental alertness or physical agility was largely his responsibility. After the employee had given evidence of enough skill inn performing his allotted task efficiently the responsibility of the employer apparently ceased with respect to the personal safety of the employee. However, following the enactment of workmen's compensation laws, at least two facts that had not before been fully appreciated soon became apparent: (1) The majority of accidents can be prevented if the management firmly determines to prevent them; (2) frog a monetary point of view alone accidents are decidedly expensive, both to employer and to employee. It is now evident that savings effected by conscientious safety effort add substantially to net profits of operation.

Jan 1, 1934

By N. S. Dalal, V. Castranova, X. Shi, W. Wrr, V. Vallyathan

"SUMMARY Data presented here indicate that freshly fractured silica exhibits surface characteristics and biologic reactivity distinct from aged silica, and on this basis we propose that these surface features may lead to enhanced manifestations of lung Injury. Grinding of silica produces ~10"" Si and SI-O (silicon-based) radicals per gram of dust on the particulate surface which are characterized by an electron spin resonance (ESR) spectrum centered around g = 2.0015. These silicon-based radicals react with aqueous media to produce OH radicals, which are demonstrable using a DMPO spin trap. The concentration of silicon-based radicals in silica decreases with aging in air and exhibits a half-life of ~30 h, whereas its ability to generate OH radicals in aqueous solution decreases with a half-life of ~20 h. However, on storage in aqueous media, the concentration of silicon-based radicals end the dust's ability to generate OH radicals decrease significantly within a few minutes. Freshly ground silica is also more biologically reactive than aged silica, because freshly crushed silica activates a greater respiratory burst In alveolar macrophages than aged silica, i.e., storage of ground dust in air decreases silica-Induced superoxide anion secretion, hydrogen peroxide release, and NBT reduction by 25%, 68%, and 43%, respectively. Furthermore, compared to aged silica, freshly ground silica exhibits a greater cytotoxic effect on cellular membrane Integrity, i.e., a 1.5-fold increase in LDH release from macrophages, a 36-fold increase in hemolytic activity, and a three-fold increase in the ability to induce lipid peroxidation. Because acute silicosis is frequently associated with occupations in which freshly fractured crystalline silica of respirable size is generated, the present study suggests that fracture-generated silicon-based radicals may play a significant role in the pathogenesis of this disease. AM REV RESPIR DIS 1955; 133:1213-1218IntroductionOccupational exposure to crystalline silica can be associated with either chronic or acute pulmonary disease. Chronic silicosis becomes manifest 20 to 40 years after first exposure and is characterized by development of concentric hyalinized nodular lesions in the lung with the de-velopment of dyspnea over a period of several decades. Acute silicosis, on the other hand, is manifested by a rapid on-set after exposure and is characterized by the accumulation of an amorphous granular lipoprotein exudate in the airspaces and rapid development of respiratory disability within a few years (1-3).Information is growing concerning the etiology of chronic silicosis. Studies sug-gest that several mechanisms may be in-volved in the development of fibrosis. Lung injury may result from silica-induced release of lysosomal enzymes from alveolar macrophages (4, 5). In ad-dition, silica-induced activation of su-peroxide anion and hydrogen peroxide release from alveolar macrophages may result in oxidant-induced damage to lung parenchyma (6). Silica exposure can also result in the release of mediators from alveolar macrophages which enhance the proliferation of fibroblasts and the syn-thesis of collagen by these pneumocytes (7, 8)."

Jan 1, 1988

By D. I. Bleiwas

Bureau of Mines personnel evaluated the potential availability of nickel from 151 deposits in 18 market economy countries and selected 126 for detailed analyses. An evaluation was made of tonnage-cost relationships indicating the quantity of nickel available at various total costs of production expressed in dollars per pound nickel, including a 15-pct rate of return on the invested capital. The 126 deposits studied contain approximately 73 million metric tons (t) of nickel. An estimated 52 million t is available from laterite deposits, of which less than 2 pct could be produced at $3.50/lb Ni, about equal to the average published price of nickel in 1981. Approximately 21 million t of nickel is available from sulfide deposits, of which about 10.0 million t can be produced at $3.50/lb. Sensitivity studies performed for both laterite deposits and sulfide deposits indicate that the total cost of nickel from laterites is most sensitive to increases in energy costs, and that sulfides are most sensitive to increases in labor costs; sulfides are also sensitive to changes in byproduct revenues. In 1983 the Nickel Mountain mine in Oregon was the only U.S. producer, though development continued on the Gasquet property in California. Of the total 5.1 million t of recoverable nickel in the United States, about 20 pct is available at or below $3.50/lb.

Jan 1, 1984

By Synthia N. McIntosh

The U.S. Bureau of Mines investigated the feasibility of using ammonium carbamate (NH2CO2NH4) leaching to recover manganese from steel plant slag. This investigation showed that treatment of the slag in hydrogen prior to leaching enhanced manganese extraction. Up to 80 pct of the manganese and 50 pct of the iron could be extracted from a silicon steel slag that had been pretreated in hydrogen at 700° C. Two 4-h leaching stages conducted at ambient temperature with a solution containing ammonia and carbon dioxide dissolved manganese and iron as their carbamate complexes. Heating the pregnant solution to 65° to 85° C decomposed the complexes and precipitated the metals as insoluble carbonate salts. Ammonium carbamate leaching of other slags from several steelmaking plants produced lower manganese extractions, which suggests that the method cannot be applied satisfactorily to all steelmaking slags

Jan 1, 2010

By G. W. Reimers

Conditions in the underground mine environment can cause self-heating of sulfide ores as a result of exothermic oxidation reactions, which may result in mine fires. This Bureau of Mines report describes thermal analyses of finely ground chalcopyrite, chalcocite, galena, pyrrhotite, marcasite, and arsenopyrite, to characterize their responses under oxidizing conditions. Thermal gravimetric analysis (TGA) and differential thermal analysis (DTA) were used, in the temperature range 1000 to 5000 C. Chalcopyrite showed an initial weight gain, due to formation of sul-fates, a weight loss, caused by ignition of iron sulfide to iron oxide, and a final weight gain, indicating the conversion of copper sulfide to sulfate. Chalcocite did not ignite in the temperature range studied but exhibited a rapid weight gain, because of the rapid conversion of copper sulfide to sulfate. Likewise, galena failed to ignite but underwent a steady weight gain when oxidized in a moist atmosphere, showing conver-sion of lead sulfide to sulfate below the ignition point. Marcasite underwent a rapid weight loss, indicating ignition, at 2000 C. Moisture in the oxidizing atmosphere lowered the ignition point of marcasite and arsenopyrite but not that of pyrrhotite. All the sulfides exhibited exothermic behavior at temperatures below the ignition point.

Jan 1, 1987

By William W. Adams

Not since complete records of accidents first became available has the safety record of the quarrying and related industries of the United States been as favorable as it was in 1940. The combined accident-frequency rate was lower and therefore better than in any year since 1916, the first year for which complete and comparable figures are available. Although operating companies began to furnish accident reports to the Bureau of Mines in 1911, the reports for that year and the next few years were obviously incomplete as to number of accidents reported, especially slight injuries involving only 1 or 2 days of disability of the injured employees. By 1916 the reports from operating companies appeared to be reliable as to completeness of coverage of slight injuries. Although the number of men employed in 1940 was by no means a record, it represented a gain over each of the 2 preceding years. Likewise, the number of man-hours worked during 1940 was larger than in 1938 and 1939.

Jan 1, 1942

By J. P. Morris

A diphenyl ether calorimeter for measuring high-temperature heat contents of ferrous alloys and iron-and steelmaking slags was constructed and calibrated with specimens of molybdenum, alumina, and platinum that were heated to temperatures ranging from 1,720° to 1,875° K. The standard deviation of the calibration measurements was 0.37 percent. By measurements of the enthalpy of delta and liquid iron, the heat of fusion of iron was found to be 3,298 ±100 cal per mole.

Jan 1, 1966

By Richard G. Burdick

The Bureau of Mines conducted this research to determine the feasibility of using soil redox measurements, a relatively new method in mining geophysics, to locate or define a variety of conditions that are hazardous or otherwise of interest to the mining industry. The method was used in three widely separated areas in an attempt to de- fine subsurface concentrations of methane, the edges of coal-burn areas, and a hydrothermal vein set. Both a description of the method used and test cases are given in this report.

Jan 1, 1982

By J. J. Dowd

1. The Pittsburgh bed is the most important bed in Ohio County, and virtually the entire production of coal in the county comes from this bed. 2. Known measured and indicated reserves in all beds, based on a minimum thickness of 14 inches and 1,800 tons per acre-foot of-coal in place, are estimated at 365 million short tons as of January 1, 1954. Of this total, 356 million short tons is in beds 28 inches and more thick. Areas in each bed were omitted from the estimate because available data relative to the bed characteristics are too meager to make an estimate that conforms with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to the total estimated reserves.

Jan 1, 1955

By G. W. Birge

This report describes the carbonizing properties of the principal coal beds of McDowell County, W. Va. Coals from 14 coal beds were selected for study: Upper Cedar Grove, Middle Cedar Grove, Lower Cedar Grove, Eagle, Douglas, Iaeger, Sewell, Welch, Beckley, Fire Creek and Pocahontas Nos. 3, 4, 5, and 9. Selection was based upon estimated minable reserves. McDowell County coals rank either as high-volatile A, medium-volatile, or low-volatile bituminous coal, and this variation in rank is reflected in the wide diversity of the carbonization properties of the coals. All coals tested were either satisfactory as mined or could be upgraded to meet present chemical standards for metallurgical coke; the coals produced strong coke, as determined by ASTM shatter and tumbler tests.

Jan 1, 1958

By Henry E. Perlee

Air compressor explosions that are caused by the ignition of combustible vapor mixtures cannot be explained by a single reaction mechanism or sequence of events. Explosions have been caused by the sudden release of large quantities of lubricating oil, by the rapid vaporization of oil that had accumulated slowly in high-pressure piping, and by the production of decomposition products from carbonaceous deposits. Ignitions can be caused by the heat produced in a catalytic reaction, in a compression process, or when a shock wave is propagated through a combustible vapor-air mixture. The frequency of these ignitions can be minimized by establishing proper maintenance and cleaning schedules. Further study is needed to satisfactorily correlate the various factors involved in compressor explosions.

Jan 1, 1963

By Deno M. Pappas

The objective of this Bureau of Mines investigation was to identlfy and evaluate alternative binder materials for use in stabilizing and consolidating highly fractured roof along longwall faces and gate roads. The desirable characteristics of a stabilization material were defined, and an extensive search was conducted to find materials satisfying these characteristics. Of 20 materials originally scrutinized, 9 were chosen for laboratory analyses. The laboratory tests evaluated bond strength and tensile strength under both dry and wet conditions. An optimum material was not found. The laboratory analyses indicated two possible candidate materials for longwall stabilization: high-aluminous cement and two-component epoxy; however, the tensile strength of the high-aluminous cement was mediocre, and the epoxy cement is toxic, flammable, and fairly expensive. The potential market demand for an effective and economical stabilization macerial is discussed in the appendix.

Jan 1, 1988

By P. D. Laverty

This report describes a processing method developed by the U.S. Bureau of Mines to produce high-quality flake graphite from the steelmaking waste known as kish. The kish produced by current steelmaking practices is a mixture of graphite, desulfurization slag, and iron that is skimmed from the molten iron feed to the basic oxygen furnace. It is estimated that the graphite content of kish discarded by U.S. steel plants is more than sufficient to meet the total U.S. demand for flake graphite. That need is now filled by natural graphite from foreign sources. Kish was treated by a combination of screening and hydraulic classification to produce a concentrate containing greater than 70 pct graphite. Leaching of the concentrate with hydrochloric acid solution gave a graphite product with 95-pct purity. An optional secondary leaching operation with hydrofluoric acid produced graphite with a purity of 98 pet or greater. The flake size of graphite from kish ranged from 10 mesh down. Evaluation of test samples by industrial graphite users indicated that kish graphite is a suitable substitute for the natural material for most uses. A process flowsheet and material balance for pilot plant design are presented.

Jan 1, 2010