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By B. R. Mohal, F. F. Aplan, S. Chander

"The wetting behavior of coal has been determined in the presence of nonyl and octyl series of nonionic surfactants containing polyethoxy groups of different sizes. The wetting behavior was determined by a modified Walker technique and contact angle measurements. The results show that the wetting rate of coal varies with coal rank, structure of the hydrocarbon chain and number of ethoxy groups in the hydrophilic group of the surfactant. A close relationship has been observed between the wetting rates and the short-time advancing contact angles.INTRODUCTIONNonionic surfactants are used in many applications to improve wettability of solids. They can be used as dispersing agents [ 1 ] or dust suppressants [ 2-5] and to control the flotation, flocculation, filtration and, flowability of particulates. This study was undertaken to study the effect of a series of nonionic surfactants on the wetting behavior of coal. Two series of surfactants, namely, ethoxylated nonyl and octyl phenols were used. The nonyl phenol series con tains a linear hydrocarbon chain containing nine carbon atoms (CH3 ( CH2 )8-C6H4- ( OC2H4 ) n, where n is the number of ethoxy groups) . The octyl phenol series contains a branched hydrocarbon chain containing eight' carbon atoms ( ( CH3 ) 3CCH2C ( CH3) 2-C6H4- ( OC2H4 ) n ).Initial wetting rates — modified Walker techniqueWalker et al. [ 6 ] developed a sink test to determine the wettability of coal particles. In this technique, coal particles are dropped individually onto the surface of surfactant solutions of different concentrations, and the most dilute concentration in which coal would sink ""instantaneously"" is determine& This technique is a variation of a procedure initially developed by Draves and Clarkson [ 7 ] to determine the effect of surfactants on wettability of cotton fibers."

Jan 1, 1989

By B. R. Mohal, F. F. Aplan, S. Chander

"The wetting behavior of coal has been determined in the presence of nonyl and octyl series of nonionic surfactants containing polyethoxy groups of different sizes. The wetting behavior was determined by a modified Walker technique and contact angle measurements. The results show that the wetting rate of coal varies with coal rank, structure of the hydrocarbon chain and number of ethoxy groups in the hydrophilic group of the surfactant. A close relationship has been observed between the wetting rates and the short-time advancing contact angles.INTRODUCTIONNonionic surfactants are used in many applications to improve wettability of solids. They can be used as dispersing agents [ 1 ] or dust suppressants [ 2-5] and to control the flotation, flocculation, filtration and flowability of particulates. This study was undertaken to study the effect of a series of nonionic surfactants on the wetting behavior of coal. Two series of surfactants, namely, ethoxylated nonyl and octyl phenols were used. The nonyl phenol series contains a linear hydrocarbon chain containing nine carbon atoms ( CH3 ( CH2 ) 8-C6H4-( OC2H4 )""' where n is the number of ethoxy groups). The octyl phenol series contains a branched hydrocarbon chain containing eight carbon atoms ( ( CH3 ) 3CCH2C ( CH3 ) 2-C6H4-( OC2H4)"").Initial wetting rates - modified Walker techniqueWalker et al. [ 6] developed a sink test to determine the wettability of coal particles. In this technique, coal particles are dropped individually onto the surface of surfactant solutions of different concentrations, and the most dilute concentration in which coal would sink ""instantaneously"" is determined. This technique is a variation of a procedure initially developed by Draves and Clarkson [ 7] to determine the effect of surfactants on wettability of cotton fibers."

Jan 1, 1989

By Lloyd A. Morley, Robert Stefanko

1 Abaibanel, S , "Deflection of Confining Walls by Explosive Loads," Israel Jour. Technology, vol. 4, n. 1, Feb 1966. 2 Albertoni, S and others, "Numerical Computation Methods for Implosion Processes," EURATOM Proc. of the Conf. on Megagauss Magnetic Field Generation by Explosives and Related Experiments, Milan (Italy), July, 1966. 3 Alexander, S. J , and Hambly, E. C., "Design of Structures to Withstand Gaseous Explosions," Concrete, vol. 4, n 2, Feb. and March, 1970. 4 Anonymous (Belgium Institute of Extractive Industries), "Report for 1968 (covering approved equipment for Belgiums gassy coal mines)," (in French and Flemish), Amales des Mines de Belgigue, n. 6, June, 1969. 5. Anonymous (Ghent Univ., Belgium), "The Welding of Very Thick Steels. Margin of Uncertainty of the Robertson Test," EURATOM Contract 042-61-9-RDB, May 20, 1965. 6. Anonymous, "Inportance of the Nature and Size of Weld Defects with Regard to the Mechanical Strength of Pressure Vessels, (in Flemish), A. Sys. Rev. Soudure, vol. 27, n. 3, 1971. 7. Anonymous (Raentgen Technische Dienst N V., Rotterdam), "Non¬Destructive Welding," Quarterly Report No 13, EURAEC - 1342, March 30, 1965. 8. Anonymous (Staff, USBM Safety Research Center), "Research and Technologic Work on Explosives, Explosions, and Flames: Fiscal year 1969," USBM IC8492, 1970. 9. Anonymous, "Symposium on Flameproofing Intrinsic Safety and Other Safeguards in Electrical Instrument Practice, April 27, 1962," IEEE Conf. Report Ser. 3, 1963. 10. Anonymous, "Unfired Pressure Vessels," ASME Pressure Vessel Code, Sec. 8, 1965. 11. Anonymous, "Unusual Pressure Relief Devices," Industrial and Engineering Chemistry, vol 54, n. 1, Jan., 1962. 12. Archer, G. L., "Design to Avoid Brittle Fracture in Welded Structures," Paper No. 4, Improving Welded Prod Design, vol. 1, Welding Inst., Cambridge, England, 1971. 13. Bailey, F. C., "Buckling and Failure Strength of Plating Panels Loaded in Shear," Final Report NASA Contract NObs-72290, Lessels and Assoc., Inc., Waltham, Mass., Sept. 20, 1963.

Jan 1, 1974

By Ralph L. Brown

As a preliminary step in a recent study4 of the phenols present in a low-temperature tar, the writers prepared the hydroxyacetic derivatives of the simpler available members of the phenol series in order to obtain material to assist in fixing the identity of similar derivatives obtained from the phenols of the tar. When comparing the melting points of the pure derivatives we had made with those given in the literature we were unable to find the characteristics of one of the xylenol derivatives which we had prepared--namely the 1, 3 dimethyl-2-phenoxyacetic acid, In the belief that the compound does not appear in the literature we are presenting these notes on its preparation and its melting point. The hydroxyacetic derivatives are easily prepared and in good yield, and are useful in studying mixtures of phenols. The 1, 3 dimethyl-2-phenoxyacetic acid makes the fifth of the six isomeric derivatives to be reported in the literature. Gluud and Breuer report the preparation of the 1, 3, 4, the 1, 4, 2, and the 1, 2, 4 derivatives. A fourth isomer-¬the symmentrical 1, 3, 5--has been reported by Schutz6, although no record of it occurs in the indexes. The remaining derivative--the 1, 2, 8-has not, been found and it is now being synthesized in the Organic Chemistry Laboratory of the. Pittsburgh Experiment Station. It is true, however, that from a phenolic fraction boiling 215.9 to 2180 isolated from natural petroleum, Tanaka and Kobayashi7 obtained a hydroxyacetic derivative melting at 103.3°. They state that this is the 1, 2, dime ethyl-3-phenoxyacetic acid but present no evidence for the assertion. The known derivatives are summarized in Table 1 following;

Jan 1, 1929

By Raymond L. Lowrie

Coal deposits in the Boulder-Weld County coalfield in Colorado are analyzed in relation to economic factors governing the growth, stability, and competitive potential of the coal industry. Recoverable reserves, estimated to be 571 million tons, are discussed in detail, particularly those in the Erie and Frederick Quadrangles. Geology of the coal measures, quantity and quality of water resources, and chemical and physical properties of the coal are described. Coal production factors, including mining techniques and equipment, labor requirements, transportation facilities and rates, and markets, are considered for coal's position in competition with alternate fuels. Growth of the fuels market, through increasing thermal-electric power generation in the Denver Metropolitan Area, will stimulate coal production in Colorado. Reserves of the contiguous Boulder-Weld coalfield, if mined in a sustained, year-round, high-tonnage operation, could be used to supply much of that fuel demand.

Jan 1, 1966

By Richard D. Miller

The helium resources base of the United States was estimated by the U.S. Bureau of Mines (Bureau) to be 894.6 Bcf as of January 1, 1989. These resources are divided into four categories in decreasing degree of assurance of their existence: (1) helium in storage and in proved natural gas reserves, 282.4 Bcf, (2) helium in probable natural gas resources, estimated at 237.7 Bcf, (3) helium in possible natural gas resources, estimated at 263.1 Bcf and (4) helium in speculative natural gas resources, estimated at 111.4 Bef. These helium resources are further divided into depleting and nondepleting, with the helium in storage being in a classification. The depleting resources are those associated with natural gasfields that are, or will be produced for the natural gas they contain. Almost all of the helium in potential (probable, possible and speculative) natural gas resources is included in this classification. These depleting resources are estimated to contain 775 Bcf of the total helium resource base. Helium resources contained in nondepleting natural gas resources, i.e., those in shut-in, abandoned, or otherwise nonproducing natural gas fields, are estimated to total 84 Bcf There is 35 Bcf of helium in storage in the Federal Government-owned Cliffside Gasfield near Amarillo, TX.

Jan 1, 1990

By G. R. Hopkins

According to the annual refinery-capacity survey of the Bureau of Mines, the number of refineries in the United States showed little change in 1940, increasing from 057 the first of the year to 562 at the close. Although a number of plants were dismantled in Texas and other States, more than compensating gains were made in California, Illinois, and other States. Low gasoline prices, competition for crude-oil supplies, particularly in Illinois, and the termination of a favorable distributing arrangement for independent plants in the Los Angeles area, forced about 50 refineries to close down in 1940. The number of operating plants accordingly declined from 461 on January 1, 1940 to 420 on January 1, 1941 and the number of idle plants increased from 86 to 136 in the same period. These developments were also reflected in the capacity data, the operating capacity declining from 4,196,694 barrels daily on January 1, 1940 to 4,180,588 daily on January I, 1941 and the idle capacity rising from 431,952 barrels to 53g8381 barrels in the same period. However, the completed capacity on January 1, 1941 (4,718,969 barrels daily) was 2 percent above the previous year.

Jan 1, 1941

This sheet explains your audiogram (hearing test) and gives some basic information about protecting your hearing. Keep it so you can refer to it later. What is an audiogram? • An audiogram is often called a “hearing test,” but there’s no pass or fail • It is a written record of your hearing levels • A series of audiograms can track changes in hearing over time • Your hearing threshold levels (the quietest sounds you can hear) are measured in decibels (dB) at different frequencies from low (500 Hz) to high (8000 Hz) Why should I get audiograms? • To measure your hearing ability • To identify hearing problems • To monitor success at maintaining your hearing • To see if noise exposure is affecting your hearing Do I have normal hearing? Compare your hearing threshold levels to this scale: -10 – 25dB Normal hearing 26 – 40 dB Mild loss 41 – 55 dB Moderate loss 56 – 70 dB Moderate/severe loss 71 – 90 dB Severe loss 91 – 100dB Profound loss [ ]

Jan 1, 2008

By George S. Rice, O. P. Hood

The need of protecting mines from the danger of inflow of natural gas from neighboring wells has become more apparent each year since it was found that oil and gas underlie the productive coal measures of Pennsylvania, West Virginia, Ohio, Indiana, Illinois, Kansas, Oklahoma, Colorado, and Wyoming, and, to some extent, the coal measures of other States. The proximity of the known gas and oil areas in the United States to the coal fields and the manner in which the fields overlap in certain States are shown in the map comprising the frontispiece (Pl. I). As the result of many requests received from various sources a conference to consider the protective measures necessary to insure the safety of mining operations in gas and oil fields was called by the Director of the Bureau of Mines to assemble in Pittsburgh, Pa., Feb- ruary 7 and 8, 1913. To this conference were invited a considerable number of gas-well, oil-well, and coal-mine operators within conven- ient distance from Pittsburgh, as well as State geologists and State mine inspectors from a distance. Gas and oil wells are also found near other kinds of mines, such as shale and limestone mines in western Pennsylvania, but these cases are so few that for this and other reasons it was deemed best to con- fine the present inquiry to the consideration of the questions involved in connection with coal mines. It was also not thought advisable to consider the protection of mines from other kinds of bore holes than those for gas and oil, such as coal-prospecting holes, drilled either with churn or diamond drills, or salt wells and artesian wells, because little trouble has been ex- perienced in mining operations from these classes of wells. There- fore the following papers and discussions concern almost entirely the following relations between coal mines and gas and oil wells: (1) Protection of coal mines froin gas and oil wells penetrating -through: (a) Open workings; (b) inaccessible spaces or goaves; (c) pillars, or coal which may be left as pillars. (2) The manner of drilling gas and oil wells passing through workable coal beds so as to provide protection for future mining. The preliminary inquiries of the engineers of the bureau had dis- closed that there was no uniformity in the methods of protecting mines against the leakage of gas from wells, that thousands of wells in coal fields are abandoned yearly without adequate plugging, and without surveys or records being kept to show the location of the holes, from which the casings are generally pulled. According to the State geologist of Pennsylvania, as many as 3,000 wells are being drilled annually in Pennsylvania, 2,000 of these holes being aban- doned within a single year. It is such unplugged, uncharted wells that are the greatest menace in mining. The quantity of gas that the wells produce, although not sufficient to be commercially avail-

Jan 1, 1913

By K. Shimamoto

This study has been prompted by the anticipated demand for rhenium by the petroleum industry and the concern for an adequate supply of rhenium to meet the demand. The present and projected outlook for rhenium relative to its distribution and occurrences, the recovery factors involved in ore beneficiation, capital and operating costs, changing technology, and the projected uses and market growth of rhenium are presented in this report as part of the Bureau of Mines program to determine the availability of recoverable rhenium in a developing market.

Jan 1, 1973

"The Generic Mineral Technology Center on Respirable Dust was established in August 1983, at the request of the Bureau of Mines, to conduct research that affords ""...each miner the opportunity to work underground during the period of (his/her) adult working life without incurring any disability from pneumoconiosis or any other occupational disease"". The Center consists of the Mining and Mineral Resources Research Institutes (MRI) of The Pennsylvania State University (PSU) and West Virginia University (WVU) in association with the MRIs of the Massachusetts Institute of Technology (MIT) and the University of Minnesota (UMN). (FIGURE 34) Michigan Technological University (MTU) is also affiliated with the Center in the area of diesel particulates.The Center brings together experts concerned with particles causing potentially disabling or fatal diseases including pneumoconiosis (""black-lung""), silicosis, and asbestosis. The latter is of deep concern not just to workers in the mineral sector of the economy but also to the general populace. The primary goal of the Center is to reduce the incidence and severity of respirable dust disease through advancing fundamental understanding of all aspects of respirable dust associated with mining and milling, and the interaction of dust and lungs. The research program of the Generic Mineral Technology Center explores these scientific, engineering or medical concerns with the objective of refining existing strategies and developing new respirable dust control techniquesand technology that are consistent with the fundamental dust-lung interaction processes that lead to mine worker disability. The work concentrates on five areas (FIGURE 35):"

Nov 1, 1988

By S. M. Shelton, J. B. Zadea, M. M. Fine, T. L. Johnston

"INTRODUCTION The Mayfield manganese property is about 25 miles south of Van Horn, in Jeff Davis County, Tex. The ore deposit is developed by a large open-cut and a small stope.An 8-ton sample was received for testing; it was taker at random from material on the mine dumps and consisted of a mixture of manganese oxides, barite, and siliceous gangue minerals. The manganese occurred largely as hard, massive, crystalline psilomelane, with a small amount of pyrolusite. The gangue minerals consisted of intermixed iron-stained sand stone, quartzite, chalcedony, calcite, quartz, and barite. Chemical analysis showed 8.9 percent manganese, 3.3 percent iron, 38.4 percent silica, 6.6 percent calcium carbonate, 7.1 percent barium, 3.1 percent alumina, 0.09 percent phosphorus 0.01 tungstic oxide, and less than 0.05 percentAnalysis of selected clean pieces of manganese minerals, free of gangue, showed 48.1 percent manganese end 13.4 percent barium, of which only 0.2 percent was present as barium sulfate. This indicated a limit in concentration. Barium was also present in the gangue as a separate mineral, barite (BaSO4), which has approximately the same specific gravity as the manganese oxide."

Apr 1, 1942

By Nicholas Kyriazi

A performance comparison of 14 rescue breathing apparatus was undertaken as an assessment of past and present worldwide technology. Rescue breathing apparatus are self-contained, closed-circuit breathing apparatus used for entry into areas having atmospheres that are immediately dangerous to life and health. Apparatus tested were the Biomarine BioPak 45, 60, and 240; the Draeger BG 4 and BG-174A; the Litton LITPAC II; the MSA Custom 4500 II Air Mask, Chemox, and McCaa; the Sabre Selected Elevated Flow Apparatus (SEFA); the Scott Rescue-Pak; the Siebe Gorman Aerorlox and Proto Ten; and the SurvivairLP-120. The apparatus were tested on an automated breathing and metabolic simulator at the Pittsburgh Research Laboratory of the National Institute for Occupational Safety and Health (NIOSH). Physiological parameters monitored during the testing were average inhaled CO2 and O2, minimum inhaled CO2, inhaled wet-and dry-bulb temperatures, and peak inhalation and exhalation breathing pressures. The metabolic demand on the apparatus was 1.35 L O2/min for most of the test with two 5-min intervals of 2.5 L O2/min, the first beginning 10 min into the test and the second beginning 10 min before the end of the rated duration of the apparatus. Results presented include apparatus service life and test-averages of monitored physiological parameters. Schematic drawings and photographs of the apparatus are also included. The Draeger BG-174A and BG 4 had the highest durations—295 and 291 min, respectively. The BG 4 hadthe lowest minimum inhaled CO2 levels, attesting to the effectiveness of its CO2-absorbent canister. The SabreSEFA had the lowest average inhaled CO2 levels, due mostly to the apparently low-dead-space mask andnose cup. The MSA Air Mask, the only open-circuit device tested, had the lowest wet- and dry-bulb temperatures, with the liquid-O2-source Siebe Gorman Aerorlox having the next lowest temperatures. The only apparatus with a CO2-absorbent not in a packed-bed design, the BG-174A, had the lowest exhalation pressures. The BG 4 had the highest level of positive pressure, with the Biomarine BioPak 60, Survivair LP-120, SEFA, and Litton LITPAC II nearly as high. The BG 4 had the lowest pressure swing, with the SEFA a close second.

Jan 10, 1999

By R. V. Ramani, V. T. Burgos, J. A. McClay

The data for Test I describes an underground bituminous coal mine operation in a 48 inch seam, with an estimated production rate of 1,056,000 tons per year. The system includes four continuous mining sections, conveyor belt haulage, and a rail network for supply and personnel transportation. This section illustrates the input data sequence and the various report formats which may be selected for the printing of results. As explained earlier, at the present time, the elements of the Cost Data Library must be read in with the regular data input. Thus, in the input data listing, immediately following the required user input, are cards which contain the inputs of the cost library. Examination of the cost reports indicate the absence of cost values for some categories for which the system would normally be expected to incur costs. This situation has arisen due to the format of the cost data provided in the U. S. Bureau of Mines reports. An example of this is the charge of $20/ton for brattice cloth while no charge is indicated for stoppings. The test report data provided a single figure for ventilation cost without a supplemental breakdown. Thus the cost indicated for brattice cloth is actually the total ventilation cost. These explanations hold true for the data input and output for Test II, Appendix III.

Jan 1, 1975

By D. E. Redmon

Linear programing provides a mathematical technique by which activities can be planned in such a way that an optimal result is obtained. Routine applications of linear programing require only a knowledge of algebra. However, a complete understanding of the fundamentals of linear programing requires a knowledge of advanced mathematics. The purpose of this publication is clarification of terminology and illustration of applications in comparatively simple mining problems. Two mining situations are considered: Mine stopes from which ore is to be produced at a minimum production cost; also, uranium mines from which ore is transported to one mill, a maximum monetary value is desired. The details of data arrangement for solution by linear programing are described and the solutions are presented. Results of these solutions indicate successful applications of linear programing to mine production scheduling.

Jan 1, 1964

By Alfred E. Schwaneke

The surface tension from 240° to 844° C and the density from 236° to 583° C of 99.999 percent purity liquid tin has been measured using the maximum-bubble-pressure method. Results for surface tension (y) show y (dynes/em) = 566.84 -4.76 X 10-2 T (° C) with a standard error of 1.9 dynes/cm. Results for density (p) show p (g/cm3) = 7.16 -6.3 X 10-4 T (° C) with a standard error of 0.012 g/cm3. Comparisons with other data found in the literature are discussed. The experimental results are considered to be as good as any data presently available.

Jan 1, 1970

By B. E. Davis

As part of its program to increase the domestic availability of critical minerals, the Bureau of Mines conducted characterization and beneficiation studies on a St. Johns County, Fla., phosphate ore that was mined by borehole mining. Results revealed that the ore from this test mine was mostly sand-size carbonate-fluorapatite and quartz and contained 24.6 percent P205. Concentration by various flotation techniques produced phosphate concentrates that ranged, in percent, from 30.0 to 31.4 P205, 0.73 to 0.80 MgO, and 2.8 to 7.2 acid insoluble. Recovery of the phosphate from the ore ranged from 89.4 to 96.3 percent.

Jan 1, 1982

By Nunna Malakondaiah

Plant samples collected from the mined sites of Beulah, Center and Zap and the test sites of North Beulah 1, North Beulah If, South Beulahh and Center were analyzed for their nutrient concentrations. The vegetation from the mined areas generally showed lower concentrations of Na, P and Cu and failed to meet the nutritional requirements for beef cattle as defined by National Research Council (minimum requirements are: Na, 600; Cu, 4; P, 1800 µg/g dry weight). Plants from Beulah showed generally higher concentrations than from Center or Tap. Tissue concentrations of K varied significantly between sites for 5 species due to the low tissue concentrations at Center. Deficiencies are difficult to isolate as the sampling was done in mid-summer and generally during that season the tissue concentrations tend to decrease in several species. All of the plant species at the unmined sites, with the exception of western wheatgrass at Zap, had lower concentrations of P than the minimum nutritional requirements for beef cattle. Sodium concentration was low but Cu was marginal to adequate in plant species at the unmined sites. Concentrations of K, Mn and Cu in western wheatgrass were greater at Center than at Zap while the opposite was true of the concentrations of Zn, Cu and P in blue grama and Cu in green needlegrass. Amending the spoil with slack at North Beulah I decreased the concentrations of Zn, Cu and P in wheatgrasses grown on spoil from 0-2, 5-10, and 20-25 foot depths, respectively. In general, the mean tissue K+/Na+ ratios were greater in plants on slack amended spoils, primarily due to the reduced Na concentrations in the tissue. At North Beulah II test site, only wheatgrasses grown on spoil amended with slack showed significant increase in K and decrease in Na and Mn concentrations. At South Beulah test site which received 12" topsoil over graded spoil, leonardite amendment decreased P concentrations in all of the grasses as compared to control, whereas fertilizer treatment increased the same. Nutrient concentrations were lower in both fescue and needlegrass with leonardite treatment and higher with fertilizer treatment although not significantly different from control. The concentrations of Ca, Mg, Na, Fe, Cu and N in grasses grown on topsoil at Center test site were significantly higher than on slack amended spoil. Legumes grown on topsoil at Center site contained higher concentrations of P than those grown on spoil; there were no significant effects due to slack on spoil or topsoil. The data presented in this report act only as an indication of between-treatment and between-species differences in tissue composition of plants harvested in mid-summer season. With respect to the nutrients analyzed, since none were found to be toxic, the cattle can safely feed on the vegetation of these mined areas.

Jan 1, 1982

By R. L. Hopkins, H. T. Rall

A continuous method has been developed for preparing thiolacetic acid . Acetic anhydride and hydrogen sulfide are passed concurrently over an amine ion- exchange resin , under 20 - psi pressure . The thiolacetic acid , a product of the reaction , is flashed continuously from the crude reaction mixture and is purified by fractional distillation . The yield of thiolacetic acid is in excess of 80 percent based on the acetic anhydride charged . INTRODUCTION In the synthesis of reference compounds needed in the identification of sulfur compounds in petroleum , thiolacetic acid has become an important reagent because of its use in the synthesis of thiols by addition to appropriate olefins : R - CH = CH₂ + CH3 - COSH R- CH2 - CH2 - S - COCH R - CH2 - CH₂ - SH + CH3COONa NaOH (1 ) The commonly used procedures for its preparation , as described by Clark and Hartman (1 )4 and by Ellingboe (2 ) , are based on the batchwise reaction of acetic anhydride with hydrogen sulfide :

Jan 1, 1964

By W. A. McKinney

A sample of oxidized copper ore from a large deposit located in Pinal County, Ariz., about 50 miles northeast of Tucson, was treated by the Federal Bureau of Mines in a small-scale continuous pilot plant by a procedure which comprised acid curing complemented by water leaching and countercurrent decantation washing in a series of drag classifiers. A feed was prepared by pugging minus 1/4-in, ore with concentrated sulfuric acid and about 10 pct, of eater, followed by curing in batches for about 24 hr. The cured ore was fed continuously to a leach drum, where it was mixed with advance solution from the countercurrent washing system to dissolve the sulfated copper. The pulp was thickened and washed in four Esperanza-type classifiers, using a flocculating agent to obtain rapid settling and thickening. The leached ore pulps thickened satisfactorily in the drag classifiers when about 0.8 lb. of a polyacrylamide flocculant per ton of dry feed was used. Clear overflow liquors were obtained, and classifier rake products containing about 60 pct. solids were produced, As much as 90 lb./hr. of ore was treated in the plant, with a recovery of 60 pct. of the total copper or 80 pct, of the acid-soluble copper when 2 tons of water per ton of feed was used in washing. The acid consumption was 4.3 lb./lb. of copper recovered. On the basis of the maximum feed rate employed and the effective pulp-settling area of the classifiers, a total of 1 sq. ft. of pool area was required per ton of dry feed per day for the thickening and washing operations. The washing efficiency in the test was 95 pct.

Jan 1, 1960