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By R. O. Dannenberg

This Bureau of Mines report describes the results of research to develop a process for recovering additional beryllium from a commercial mill waste product, fluoferrate leach residue. Forty-five percent of the total beryllium in the leach residue was recovered in a beryllia product assaying over 98 pct Be0 by a process comprising (1) leaching with 1 N sulfuric acid, (2) adjusting the acidity of the leach liquor to pH 2, (3) extracting the beryllium with di-2-ethylhexyl phosphoric acid (EHPA), (4) stripping the loaded extract with sodium hydroxide solution, (5) boiling the sodium beryllate strip solution to precipitate beryllium hydroxide, and (6) calcining the beryllium hydroxide. Calculated reagent requirements per pound of Be° recovered by a proposed flowsheet were 28.1 lb sulfuric acid, 0.04 lb flocculent, 0.15 lb EHPA, 0.06 lb isodecanol (IDA), 0.22 gal kerosine, and 6.3 lb sodium hydroxide.

Jan 1, 1966

By Floyd G. Anderson

The Federal Bureau of Mines promotes the use of safe and effective dust-collecting devices for rock drilling in coal mines. To insure that such devices are available to the coal-mining industry, the Bureau issues certificates of performance for dust-collecting systems and certificates of approval for dust collectors and rock drills or other mining equipment with integral dust-collecting systems that meet the requirements of an established Schedule.4/ Investigations are conducted under the provisions of the current revision of this Schedule by engineers of the Branch of Health Research. This circular describes briefly the requirements and procedure for obtaining certificates of performance or approval and lists equipment that has been certified as permissible under Schedule 25 or its revisions as of January 31, 1961. The names and addresses of companies to which certificates have been issued are listed alphabetically at the end of this circular.

Jan 1, 1961

By Ted C. Briggs

The Bureau of Mines is evaluating the thermodynamic properties of helium and helium-containing mixtures. Twenty-two compressibility runs were made with helium at 0° C and pressures to 800 atmospheres using a Burnett-type apparatus. Data from the 22 runs were treated simultaneously and as separate runs while different functional forms and weighting factors were used. A fourth-degree-polynomial equation in the pressure gives a statistically satisfactory representation of the compressibility factor when the data are treated simultaneously and a weighting factor of Pr-3/4 is used. The second virial coefficient of helium at 0° C from this investigation is 11.997±0.015 cm3 mole-1. The stated uncertainty is the random error standard deviation. Compressibility factors determined by this investigation are precise to better than 0.01 percent and are believed to be accurate to better than 0.02 percent.

Jan 1, 1969

By Raymond G. Travis

This paper, which describes mining methods and practices at the Hurricane Creek bauxite mine of Reynolds Mining Corp. in central Arkansas, is one of a series being prepared by the Bureau of Mines on mining methods, practices, and costs in various mining districts of the United States. The Hurricane Creek mine is in sec. 12, T. 2 S., R. 14 W., and sees. 7 and 18, T. 2 S., R. 13 W., Saline County, Ark., about 4 miles east of Bauxite. (See fig. 1.) Bauxite has been mined underground at the Hurricane Creek property since 1942. The operation is notable for relatively high recovery of bauxite under the adverse conditions of unconsolidated water-bearing overburden and unstable clay floor. Controlled caving, timbered stope walls, and efficient drainage systems on the surface and underground have minimized the problems and raised ore recovery about 25 percent above that formerly obtained.

Jan 1, 1961

By Walter W. Fisher

Cement copper was flash roasted in a vertical tube furnace to convert the copper to acid-soluble oxides as part of a postulated process for refining cement copper by oxidation roasting, acid leaching, and electrowinning. The results of the study showed that the oxidation was a linear function of oxygen concentration between 0 and 20 percent, but above 20 percent oxygen there was no further increase in oxidation. Therefore, air was the optimum oxidizing atmosphere in this flash roasting system. The oxidation followed a parabolic rate law as the roasting temperature was increased from 400° to 800° C. Extrapolation of the data, based on the parabolic law, indicated that at 400°, 500°,600°,700°, and 800° C, the roasting times required for complete conversion to soluble oxides were 75, 37, 21, 7.7, and 4.6 seconds, respectively. Cyclic-roasting test results did not substantiate the predictions obtained through data extrapolation.

Jan 1, 1973

By E. G. King

In continuation of the study of thermodynamic properties of the common interoxidic compounds of ferroalloy elements, this report gives the results of low-termperature heat-capacity measurements and entropy evaluations of the monotungstates of sodium, magnesium, and calcium. Previous reports4 5/ of this laboratory dealt with low-temperature heat capacities, entropies, and heats of formation of the sodium vanadates. Heat-capacity measurements of the monotungstates of sodium, magnesium, and calcium (Na2W04, MgW04, and CaW04) were conducted throughout the temperature range 51° to 298° K. The entropies at 298° K. were evaluated and then combined with entropy data for the elements and oxides to obtain entropies of formation. This information is an essential part of the data needed for thermodynamic appraisals of chemical reactions of these substances. No similar data for any tungstate are to be found in the literature.

Jan 1, 1961

By Walter D. Holland

LFE Environmental performed an Industrial Hygiene survey of the Paraho Oil Shale Mining and Processing facility in Anvil Points near Rifle, Colorado, on August 6 and 7, 1975. This survey consisted of an investigation of the underground operations for diesel emission contaminants and of the above ground work areas for all inhalation contaminants other than silica dust. Samples were collected to investigate the following contaminants: respirable dust, total dust, NO2, NO, H2SO4, formaldehyde, CO2, S02 and CO. None of the determinations of contaminants in the underground operations indicate air concentrations exceeding their standards. The results for the samples collected above ground indicate only one operation where the employee's exposure exceeds the standards. It is a welding operation where the standards for total dust and lead are exceeded. Since the survey the employer has installed an exhaust ventilation system which has significantly reduced the welder's exposure.

Jan 1, 1976

By R. E. Stiles

The modified perchloric--EDTA method devised by the Bureau of Mines for the determination of copper in high-grade samples gives results that are more precise and more accurate than those from the classical sulfuric-iodometric method. Although the perchloric--EDTA method is more costly than the conventional method, the savings in time alone largely offsets this difference. Specifically, the modifications wade in the more conventional procedure comprise (1) use of perchloric acid instead of sulfuric acid for dissolution of copper minerals, (2) precipitation of copper as copper sulfide from dilute perchloric acid solution, (3) wet oxidation and dissolution of the precipitated copper sulfide, (4) use of larger amounts of indicator than those employed in the Schwarzenbach method of titrating low-tenor copper solutions with disodium ethylenedinitri10-tetraacetate and murexide indicator, and (5) use of refrigeration to partially stabilize aqueous solutions of the indicator.

Jan 1, 1966

By E. G. King

Cerium and thorium sulfides have found use as crucible materials for melting certain radioactive metals. However, thermodynamic treatment of these sulfides has been hampered by lack of experimentally derived entropy values. This Bureau of Mines report describes heat-capacity measurements between 51° and 298° K, and entropy evaluations at 298.15° K, for cerium monosulfide (CeS), cerium sesquisulfide (Ce2S3), and thorium disulfide (THS2). The entropy values, with Literature results for the heats of formation, are used to obtain free energies of formation at 298.15°K. MATERIALS The samples used in this work were supplied by Prof, Leo Brewer of the Department of Chemistry, University of California. The methods of preparation and some of the physical and chemical properties of these sulfides were given by Eastman and coworkers.3 4/ Chemical analyses, conducted in our laboratory, gave the following results:

Jan 1, 1959

By C. D. Litton

The results of full-scale fire tests are used to determine optimum distributions of fire sensors for the protection of conveyor belt haulageways in underground coal mines. Empirical relationships are derived that relate the spacing of fire sensors to the rate of development of the fire hazard. For this application, a critical fire size is defined as that size of fire for which belt ignition and subsequent flame spread down the belt is assured. Detection and alarm, regardless of sensor type or sensing methodology, must be achieved at some point in time before the critical fire size is reached. Based upon this approach, it is found that the horizontal spacing for products-of-combustion sensors is in the range of 300 to 600 meters, while the required thermal sensor spacing is found to be ~4 meters or less. Additional design criteria are discussed for product-of-combustion fire sensing systems.

Jan 1, 1982

By Willard L. Hunter

The separation of tantalum and columbium by solvent extraction was under-taken as part of the Bureau of Mines research program to improve methods for extracting, separating, and reducing these elements to metal. The diethyl ketone aqueous HCl-HF system was one of several systems studied to determine the effect of metal and acid concentrations in aqueous solutions upon the transfer of tantalum and columbium into selected ketones. The tantalum-columbium oxide mixture used in this investigation was obtained by chemical extraction from Geomines slag. The investigation showed that tantalum 99.4 percent pure and columbium 97.2 percent pure can be produced by the selective transfer of tantalum into diethyl ketone from a solution of 2-N HF and 1-N HC1. The relatively low acid concentration necessary for tantalum transfer and the excellent selectivity of the system recommend its use for the separation of tantalum and columbium.

Jan 1, 1961

By Stephen A. Hare, O&apos

The melting, casting, and welding of the Raney nickel alloy (42 pct Ni-58 pct A1), a methanation catalyst useful in coal gasification, were investigated. Melting was done in graphite crucibles by heating aluminum and adding nickel using a cryolite slag cover. Casting conditions were found to be optimum when the melt temperature ranged from 1,125° to 1,200° C and the mold temperature ranged from ambient to 250° C. Suitable mold materials were found to be quartz, heat-resistant glassware, olivine, and zircon. Welding of the alloy can be accomplished using tungsten inert gas process. Tensile strength of the alloy, in the as-cast condition, was found to be 2,000 1b/sq in with an impact strength of less than 1 ft-1b. The coefficient of thermal expansion was determined to be 18.4 x 10-6/° C after heat treatment.

Jan 1, 1977

By Tobias W. Goodman, Joseph Cervik

This Bureau of Mines report investigates the horizontal trajectory of boreholes drilled in coalbeds using the rotary drilling technique. Test holes drilled in coalbeds showed that the path of a borehole in the horizontal plane depends on drilling assembly configuration, drill bit rotation, and coalbed geologic features. An assembly that contained an 18-ft (5.53) long drill collar and two centralizers had the best horizontal stability evidenced by trajectories that deviated less than 16 ft (4.9 m) from a target at 1,000 ft (305 m). Removal of one of the centralizers resulted in a loss of control of hole trajectory in the horizontal plane. Generally, holes tended to turn to the right, presumably because of right-hand rotation of the bit. Deviations from the original bearing line were as much as 200 ft (61 m) or more at a depth of 1,000 ft (305 m).

Jan 1, 1988

By K. O. Bennington

Cancrinite is one eonstituentof "red muds," a high-volume waste product of alumina production by the Bayer process. The Bureau of Mines determined the thermochemical properties of cancrinite as part of a program to provide such data for minerals of industrial importance. Cancrinite [Na7.68(A16Si6024)(N03)1.68 (H2O)4.1] was synthesized by reacting aluminum silicate gel with a solution of NaOH and NaN03, and the composition was determined by chemical analysis, differential scanning calorimetry, and thermogravimetric analysis. The heat of solution was determined by hydrofluoric acid solution calorimetry. The standard enthalpy of formation at 298.15 K, ?Hf°298, is ?Hf°298 = -3,487.97 ±2.6 kcal/mol, and the standard enthalpy of formation from the oxides and NaN03, ?H°298, is ?H°298 = -215.20 ±l.8 kcal/mol.

Jan 1, 1983

By A. W. Hall

Cylindrical plastic scintillators were investigated for efficiency in detecting neutron-induced prompt gamma rays. Scintillator performance was compared on the basis of half-resolution and peak-to-trough ratios for gamma spectra obtained from Co-60 (1.17 and 1.33 MeV), Th-228 (2.62 MeV), and PuBe (4.43 MeV). Various sizes of Pilot Chemical scintillators (types B, F, M, and Y) were tested. The best half-resolution, 7.7 percent for PuBe, was achieved with a 5-by 5-inch Pilot Y?scintillator and dual photomultipliers. Comparison with sodium iodide (NaI) scintillators and the use of plastic scintillators for on-stream analysis of sulfur in coal is discussed. Plastics were found to be unsuitable for on-stream analysis of materials having complex prompt gamma ray spectra; however, they could conceivably be used for those yielding Simpler spectra.

Jan 1, 1974

By Donald O. Capstick

In 1481, U.S. Bureau of Mines personnel conducted a survey of mines, prospects, and mineral resources in the Table Mountain RARE II area. There are no mines or active prospects in the study area. One prospect in the study area, the Waterfall Prospect, is estimated to contain 480 tons (440 t) of indicated subeconomic tungsten resources averaging about 0.18 percent tungsten trioxide (W03). Other tungsten occurrences are at the Stevens Prospect, just northwest of the area. Stone and sand and gravel deposits in the area are not considered to be resources because equal or better quality material is available closer to major markets. INTRODUCTION The 4,400-acre Table Mountain study area is 13 mi (21 km) southwest of Bishop, California, on the eastern flank of the Sierra Nevada range. The John Muir wilderness adjoins the study area on the southwest (fig. 1).

Jan 1, 1982

By C. I. Pierce

The Bureau of Mines conducted laboratory tests to determine if ultrasonic energy could reduce either the residual water or oil content of petroleum reservoir-rock samples from Appalachian area oilfields. Brine-saturated core samples were flooded with oil to residual brine saturation and subjected to 20 kilocycles per second ultrasonic energy. Then they were flooded with brine to residual oil saturation and again subjected to ultrasonic energy. Additional water displaced as a result of the application of ultrasonic energy to the flow system ranged from 0 to 4.3 percent of the original brine and averaged 1.9 percent. The increase in oil recovery as a result of the ultrasonic energy ranged from 0 to 9.0 percent of the original oil and averaged 3.1 percent. On the basis of the tests, it appears that 20-kcps acoustic waves would not have field application for oil recovery.

Jan 1, 1968

By L. B. Pankratz

Heat contents were measured for Na2CaSi04 and Na2Ca2S02 between 298° and 1,300° K, for Na2Ca2Si309 between 298° and 1,500° K, and for Na4CaSi3O9 between 298° and 1,350° K. Copper-block drop calorimetry was employed. Reversible, first-order transitions were found for Na2CaSi04 and Na2Ca2Si309. The transition for Na2CaSi04 is at 830° K with a heat absorption of 160 cal/mole; that for Na2CagSi309 occurs at 750° K with a heat absorption of 1,550 cal/mole. Results for the other two silicates showed no irregularities. A table of heat content and entropy increments above 298.15° K and heat con-tent equations are included for use in thermodynamic calculations.

Jan 1, 1968

By F. P. Haver

A procedure is described for recovering both lead and sulfur from galena flotation concentrate, comprising the following steps: (1) Aqueous oxidation of the concentrate, using ferric sulfate to convert lead sulfide to sulfate and to give elemental sulfur; (2) regeneration of the ferric sulfate by electrolysis in a diaphragm cell; (3) treatment of the leach residue with ammonium carbonate solution to change the lead to an acid-soluble form and to produce ammonium sulfate as a byproduct; (4) solution of the lead carbonate in hydro-fluosilicic acid followed by electrolysis to recover the lead as metal and regenerate the acid; and (5) extraction of the elemental sulfur from the final residue with an organic solvent. About 90 percent of the lead can be recovered by the above method as 99.9-percent-pure metal, together with two-thirds of the sulfur--half in the elemental form and half as ammonium sulfate.

Jan 1, 1970

By L. B. Pankratz

Enthalpies were determined for synthetic chalcopyrite (CuFeS2) between 298° and 1,050° K and for synthetic bornite (Cu5FeS4) between 298° and 1,100° K by copper-block drop calorimetry. Two transitions were found for each compound. The lower transitions were both crystal transformations from tetragonal (low-temperature form) to cubic (high-temperature form). The chalcopyrite transformation occurred at 830' K with a heat of transformation of 2,405 cal/mole; the bornite transformation was at 485° K with a heat of 1,430 cal/mole. The other transitions were of the second order and were presumed to be magnetic in character. The second-order transitions for chalcopyrite occurred at 930° K, and the one for bornite at 540° K. Enthalpy increments, entropy increments, and heat capacities are tabulated at even temperatures above 298.15° K. Equations of enthalpy are also given.

Jan 1, 1970