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By Michael J. Brnich

Since 1991, Pittsburgh Research Center (PRC- formerly part of the Bureau of Mines) researchers have recorded extensive interviews with 30individuals who are experts in the area of mine emergency response. These individuals, who have an average of 35 years of mining experience and 29 years of mine emergency response experience, related stories and observations from events that they experienced during their combined 850 plus years in mine emergency response. The purpose of this effort was to gather information that could be passed onto both today?s and tomorrow?s mine emergency responders to train and guide them in handling future events. This is the second of two articles which report experts responses to questions about training for future mine emergencies. During the interviews they discussed how training should be conducted, who should be trained, and what topics should be included. This article will cover the third area: Topics that should be included in training for mine emergency response managers.

Jan 1, 1997

By Thomas E. Green

A solvent extraction procedure using 8-hydroxyquinoline and chloroform was investigated by the Bureau of Mines as a preconcentration technique for the determination of aluminum, calcium, cobalt, copper, iron, lead, magnesium, manganese, nickel, and zinc in large samples of high purity tungsten. X-ray spectrographic and atomic absorption methods were used to determine the trace metals after preconcentration. The presence of 10 grams of tungsten had a pronounced effect on the distribution of 8-hydroxyquinoline between the aqueous and chloroform phases. This change in the 8-hydroxyquinoline distribution in turn had an adverse effect on the extraction of the trace metals. Extraction efficiencies can also be adversely affected by an increase in the quantity of extractable metals present, as shown by radiotracer tests using 65Zn. Excess 8-hydroxyquinoline in the extracts did not interfere with the determination -of the serious interference in the combined ion exchange paper--X-ray spectrographic method. Although preconcentration by 8-hydroxyquinoline extraction was found to be partially successful, other preconcentrationn methods based on ion exchange and dithizone extraction were found to be superior.

Jan 1, 1968

By B. Dimitriades

Experimental work has been done to refine and to confirm an analytical procedure by which gas-liquid chromatographic (GLC) spectra are interpreted from retention time data alone. The rationale of this spectra interpretation technique involves whether or not a given peak invariably represents the same component or component mixture; if not, what factors influence changes in peak identifications. To answer these questions, peak-identification procedures, based mainly on the use of subtractive columns, were developed and applied to interpret GLC spectra of several exhaust (and fuel) samples.

Jan 1, 1972

Control surface stream loss by identifying and selectively sealing water loss zones in stream channels overlying underground mines. Approach Electromagnetic terrain conductivity surveys, coupled with stream gaging, are performed within a stream channel to identify saturated fracture zones associated with loss of stream water. This information is used to target locations for the injection of expandable polyurethane grout. The grout is injected two to three feet beneath the surface of the strcambed, across each loss zone, to seal the fractured strcambed and restore stream flow across the damaged area. How It Works Multiple zones of infiltration (natural and induced) normally exist in stream channels overlying mined areas, causing water handling and/or acid drainage problems in the mines as well as loss of stream flow. It is typically difficult to accurately locate these loss points. Therefore, Conventional methods of stream repair, such as using plastic membranes or clay and rock rip-rapping, are applied to long lengths of a stream channel. The two step approach developed by the Bureau of Mines First quickly and accurately locates loss zones using electromagnetic ground conductivity survey and gaging instruments. Conductivity is measured at fixed spacings (typically 25-50 ft depending on the instrument and desired observation depth), Ground conductivity increases when saturated conditions exist at depth. These apparent flow loss zones are confirmed by gaping, to eliminate possible effects due to unobservable metal debris adjacent to or buried in the stream sediment.

Jan 1, 1991

By Seth C. Schaefer

As part of the Bureau of Mines, U.S. Department of the Interior, effort to provide thermodynamic data for the advancement of minerals technology, the Gibbs energy of formation of sphalerite (zinc sulfide) was investigated with a high-temperature galvanic cell employing stabilized zirconia as the electrolyte. In the temperature range 948 to 1,210 K, potential measurements were obtained for the cell Pt, ZnS + ZnO, S02 = 1 atm // Zr02 // Cu20 + Cu, Pt, with the overall cell reaction ZnS(c) + 3 Cu20(c) = ZnO(c) + 6 Cu(c) + S02(g). (1) These results, combined with the best available values of ?Gf° for ZnO, S02, and Cu20 from the literature, give the Gibbs energy of formation of zinc sulfide for the reaction Zn(l,v) + 1/2 S2(g) = ZnS© (2) ?Gf° = -64.223 + 24.02 X 10-3T ± 0.650 kcal/mole (3) (948-1,180 K; standard states - pure liquid zinc and S2 gas at 1 atm), and ?Gf° = -92.720 + 48.17 X 10-3 ± 0.650 kcal/mole (1,180-1,210 K; standard states - pure zinc vapor and S2 gas at 1 atm). A third law analysis yields for the formation reaction Zn(1) + 1/2 S2(g) = ZnS(c), (5) a standard enthalpy of formation as follows: ?Hf298.15 = -63.64 ± 0.700 kcal/mole.

Jan 1, 1978

By Syd S. Peng

The design of retort interchamber pillars is important in determining surface stability over in situ retort mines and to the health and safety of miners, particularly with respect to possible escape of heat and toxic gases from retort chambers. Stress distribution in retort interchamber pillars, roof, and floor was examined with the aid of linear, finite-element analysis using data from experimentally determined mechanical properties. Properties determined included elastic moduli, strength, and creep constants in laboratory tests on core covering a 100-foot depth interval in the oil shale from the Piceance Basin in Colorado. The most critical stress concentration was found in the rib side of the interchamber pillar at a height above the floor line of 1.25 times the width. Guidelines for pillar design that consider pillar strength, creep, and retorting temperature effects are proposed.

Jan 1, 1981

Provide the mining industry with a wireless surveying system for increasing efficiency in the drilling of methane drainage or exploration boreholes. Approach The Bureau of Mines has pioneered the technique of methane control by drilling long, horizontal drainage holes from within the mine complex. It was recognized during the early drainage projects that a major portion of the drilling operation was dedicated to hole surveying. In some cases more time was actually being spent on the surveying operation than on drilling. The large amount of time required for hole surveying was the result of having to pump an instrument to the bottom of the hole, then retrieve it with an attached wire line. Naturally as hole depth increased, so did the amount of time needed to perform the survey operation. If the survey operation could be improved it was obvious that overall efficiency in drilling of long, horizontal methane drainage holes would be greatly increased. The Bureau of Mines, therefore, developed, fabricated and tested in an operating coal mine a permissible wireless survey system specifically designed for small diameter methane drainage drilling. The prototype survey system was completed in 1982 and was given the IR-100 Award by Industrial Research and Development Magazine. A second generation survey system is currently being constructed using updated state-of-the-art electronic technology. The second generation system will be more portable, more reliable, easier to maintain, and less costly.

Jan 1, 1984

Develop a method to evaluate the effectiveness of coal scam fire surface seals so that potential problems may be corrected at an early stage, before the integrity of the surface seal is lost. Background Surface seals are the primary coal seam fire abatement method being used in the western United States. Surface seals smother a fire by denying it oxygen. The seal is usually constructed by placing a mantle of soil, four to ton feet thick, over a coal scam fire area to exclude air from the fire. The soil is compacted to increase effectiveness, and a soil cement may be used to augment the soil. In some cases, burning coal may be excavated and separately smothered or otherwise extinguished in another area; in other cases, a trench maybe excavated and backfilled with incombustible material to isolate a fire. More often, a surface seal is simply applied over and around the entire known burning area. In the 1950's, the Bureau of Mines administered a large program to treat numerous coal seam Fires across the western United States. Methods used in this program were described in Bureau of Mines Information Circular (IC) 7932, dated 1959. More recently however, various coal seam fires have been treated with surface seals under the direction of state Abandoned Mine Land Reclamation authorities. It has frequently taken years to evaluate the effectiveness of surface seals. By the time problems become evident, it has often been too late to take corrective action within the scope of the original abatement project. For this reason, the Bureau of Mines developed a means for tracking temperature trends at coal seam fire projects to obtain a better and earlier handle on the effectiveness of surface seals.

Jan 1, 1991

Now you know why there is concern about mine illumination. You have some idea about how the human eye works and about the problems of glare, peripheral vision, and accommodation. And you know that lighting in a mine presents special problems because of the dark surroundings and low reflectance. This chapter describes what can be done to improve conditions. This chapter begins with a short discussion about Federal Standards on mine lighting -- what they are and what is being done to carry them out. The chapter then describes different types of lamps that can be used for mine lighting, and discusses their advantages and disadvantages. Finally, the chapter lists some things that you can do personally to improve lighting, or can point out to others so that improvements can be made. The Federal Government is doing its part to improve mine lighting by establishing regulations. Lamp manufacturers are constantly studying new lamps to provide better equipment. And your company will do its part to comply with regulations. Better lights may not be here yet, but they will be soon. But in the end, you are the one who will be using the lights, and you are in the best position to see the improvements. You are also in the best position to see and tell others where further improve¬ments can be made.

Jan 1, 1976

By Joseph Cervik, J. H. Perkins

The Bureau of Mines has conducted desorption work on fine coal particles at near atmospheric pressure. An apparatus has been developed that uses a capacitance manometer to measure desorption of methane from coal particles up to 2 inches in diameter and pressures up to 1,000 psi. This will make it possible to duplicate the desorption process as it occurs in its natural under- ground environment.

Aug 1, 1970

By Robert P. Vinson, Fred N. Kissell

This report describes three coal mine ventilation studies by the Bureau of Mines in which sulfur hexafluoride (SFG) was used as a tracer gas. One of these studies was conducted to determine air movement and leakage in a sealed area. Another was run to determine the ventilation efficiency of a bleeder system. Finally, a study was made of air leakage across permanent stoppings of parallel intake airways. These studies proved sulfur hexafluoride to be a useful addition to the equipment commonly used in coal mine ventilation analysis.

Jan 1, 1976

By Robert L. Lagace, Alfred G. Emslie

This report presents a mathematical model for the propagation of UHF radio waves in the large cross-section tunnels of a room and pillar limestone mine, and describes the analysis of a small amount of propagation data obtained in a limestone mine. The model and analysis is based on the waveguide mode theory developed earlier for the transmission of UHF waves in coal mine tunnels, with allowance for propagation losses due to refraction into the tunnel walls, to scattering by wall roughness, and to long range random tilt of the walls. Propagation around corners and through pillars is also examined based on a ray theory approach, together with the beneficial effects of placing reflectors at intersections to significantly reduce corner losses. The theory is found to be in fair agreement with the data; however, additional in-mine measurements are needed to provide a more conclusive test of the model.

Jan 1, 1979

By Sarah P. Guerrino

This chapter summarizes data on crude nonfuel mineral production for the United States, its island possessions, and the Commonwealth of Puerto Rico. Included also are the tables that show the principal nonfuel mineral commodities exported from and imported into the United States and that compare world and U.S. mineral production. The detailed data from which these tables were derived are contained in the individual commodity chapters of Volume I and in the State chapters of Volume II of this edition of the Minerals Yearbook. Although crude mineral production may be measured at any of several stages of extraction and processing, the stage of measurement used in this chapter is what is normally termed ?mine output.? It usually refers to minerals or ores in the form in which they are first extracted from the ground, but customarily includes the output from auxiliary processing at or near the mines.

Jan 1, 1987

By J. R. Allsup

The Bureau of Mines studied the characteristics of simulated coal gas as an automotive fuel in two multicylinder vehicles in a standard and high-compression-ratio engine configuration. While using simulated coal gas fuel, increasing the engine compression ratio improved the fuel economy and vehicle performance but increased hydrocarbon emissions by 40 pct. photochemical reactivity of exhaust hydrocarbons was found to be extremely low using the coal gas fuel. An oxidizing catalyst used with the simulated coal gas fuel eliminated all but trace amounts of carbon monoxide and reactive hydrocarbons in the exhaust. Spark gap geometry and firing voltage were varied and, within the range tested, had little effect on vehicle performance and emissions using simulated coal gas fuel.

Jan 1, 1975

By Joseph Cervik

Gas occurs in coalbeds in an adsorbed and a free gas state. Adsorbed gas is stored in the micropore structure and its transport is governed by Fick's law. The free gas occurs in the fracture system and flows according to Darcy's law. These two modes of mass transport are interdependent. Production decline curves of coal-gas wells are of the constant percentage decline type and, thus, show no indications of flow characteristics peculiar to coal-gas reservoirs. The effectiveness of surface boreholes as a degasification scheme depends upon both good fracture permeability and a high fracture density. Conventional methods of reservoir engineering analysis are not applicable to coalbeds

May 1, 1969

By Richard E. Hucko

The bureau of Mines conducted a laboratory scale investigation of the process of selective flocculation with the objective of developing a method to effect separations on suspensions consisting predominately of ultra-fine-size (minus 400-mesh) particles of coal and refuse. Selective flocculation of coal from coal-refuse slurries could be achieved with a wide variety of reagents. Typically as much as 15 to 20 weight-percent of high-ash solids (70 to 80 percent ash) could be retained in suspension. The flocculated sediment remained a high-ash product, however, and would require further treatment to be regarded as clean coal. No combination of reagents and conditions led to selective flocculation of the refuse component. The dispersing agent was found to be the critical factor; dosages of 3 to 8 lb/ton2 were necessary to stabilize the suspension for subsequent selective flocculation. In addition, most of the dispersants that worked were most effective at substantially elevated pH (11 or so). It was concluded that this process would be prohibitively expensive and, because of yield and quality constraints, it would be of questionable utility in today's coal preparation industry.

Jan 1, 1977

By Dennis R. Dolinar, Eric R. Bauer

Skin failures of roof and rib in underground coal mines continue to be a significant safety hazard for mineworkers. Skin failures do not usually involve failure of the support systems, but result from rock or coal spalling from between the support elements. For instance, in 1997 more than 800 miners were injured by roof and rib falls, of which 98% were the result of skin failures [Bauer et al. 1999]. Also, nearly 80% of the roof and rib failure injuries occurred at or near the working faces in development sections. The face area is a zone where the potential for skin failure accidents and injuries and for roof and rib failures is high because of mining activity, ground readjustment due to changing stress conditions, and the higher exposure of mine workers. In addition, failures occur where the roof and rib are unsupported. This paper reviews the roof and rib accident statistics resulting from skin failure, and highlights the incidences by type, numbers and percentage, in-mine location, supported and unsupported roof, and worker activity at the time of injury. Also discussed are the causes of roof and rib skin failures, current and improved support methods and materials for skin surface control, and machine design modifications for improved roof bolter operator protection. It also reviews the historical literature on skin failures and control methods.

Jan 10, 2000

To pinpoint dust sources and to improve dust control on longwalls. Approach Use short-term gravimetric sampling to determine the severity of various dust sources, and to evaluate dust control techniques used in longwall mining. Short-term gravimetric sampling can be used to isolate dust levels produced by various dust sources. How It Works Traditionally, gravimetric samples have been collected over an 8-hour shift, yielding time-weighted, average dust concentrations. This method gives a good indication of the full-shift respirable dust exposure of underground workers, but is less than satisfactory for identifying dust sources, determining their severity, or for evaluating the effectiveness of dust control techniques. Short-term gravimetric sampling uses equipment available to all mine operators. Two individuals composing the survey team each collect multiple (three to four) gravimetric samples during selected segments of the mining cycle. Multiple samples are necessary to insure accuracy, and to obtain a valid average measurement of the respirable dust concentration when sampling for short periods of time (typically 20 to 30 minutes). The gravimetric instruments may be carried in a sampling package or in a "sampling vest." A fishing vest with four large pockets can be used for this purpose. The sampling pumps are carried in pockets and the sampling head assemblies arc hung across the front of the vest.

Jan 1, 1982

By Michael S. Wieland

The work-principle from thermodynamics was used to formulate a model for predicting toxic fumes from mining explosives in underground chamber tests, where rapid turbulent combustion within the surrounding air noticeably changes the resulting concentrations. Two model constants were required to help characterize the reaction zone undergoing rapid chemical transformations in conjunction with heat transfer and work output: a stoichiometry mixing fraction and a reaction-quenching temperature. Rudimentary theory with an unsteady uniform concentration gradient was taken to characterize the combustion zone, yielding 75% for the mixing fraction. Four quenching temperature trends were resolved and compared to test results of ammonium nitrate compositions with different fuel-oil percentages (ANFO). The quenching temperature 2345 K was the optimum choice for fitting the two major components of fume toxicity: carbon monoxide (CO) and total nitrogen oxides (NOx). The resulting two-constant model was used to generate comparisons for test results of ANFO compositions with additives. Though respectable fits were usually found, charge formulations which reacted weakly could not be resolved numerically. The work-principle model yields toxic concentrations for a range of charge formulations, making it a useful tool for investigating the potential hazard of released fumes and reducing the risk of unwanted incidents. Keywords: Toxicity; Fumes; Explosives

By Margaret R. Egan

The U.S. Bureau of Mines investigated the product-of-combustion (POC) characteristics of combustible materials used in typical coal mining operations in a series of experiments conducted in an intermediate-scale fire tunnel. The materials examined include wood cribs, transformer fluid, coal, conveyor belting, brattice cloth, and ventilation ducting. Smoke and toxic gases evolved from burning materials contribute to panic conditions and hinder escape. Smoke irritates and obscures vision, while toxic gases physically debilitate and disorient the victims. However, POC emissions may be used for early warning fire detection. POC levels will vary not only between materials but also between stages of combustion and the conditions in which they are burning. This report summarizes the POC characteristics of each material and evaluates their effectiveness for early warning mine fire detection. Results show that smoke was the POC most readily detected from the smoldering materials tested.