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By J. L. Konchesky

The Bureau of Mines investigated the main reactions of coal gasification by steam. Coal (minus 70 mesh)-water slurry was fed into a laboratory-scale tube-coil gasifier to show the effects of residence time (0.6 to 1.1 sec), steam-coal ratio (2 to 11 lb/lb), and temperature (1,600° to 1,900° F), at about 1-1/2 atm. Devolatilization was very rapid: about 70 pet of the coal's volatile matter evolved within 0.6 sec at about 1,600° F; temperature increase released more volatile matter until about 95 pct was driven off at 1,900° F. Devolatilization was not increased by raising steam concentrations and was only slightly increased by extending residence time. Below 1,600° F, there was no evidence of the steam-carbon reaction, but at 1,900° F more than 80 pct of the coal's fixed carbon was converted to gas; the conversion was increased Significantly by increased residence time and steam concentration. The water-gas shift reaction occurred simultaneously with devolatilization, and the steam-carbon reaction, approaching equilibrium with increased residence time and temperature and decreased steam concentration.

Jan 1, 1969

By William Wiehagen

This trainer?s guide is designed as a reference manual. The purpose is to offer information and examples to skills trainers to assist them in structuring training for new operators of Walk-Thru roof bolting machines. Trainers can use this manual as a resource for helping trainees learn, understand, and apply knowledge and skills. In this sense, the guide is not prescriptive. It is designed to offer information and trigger ideas on what might be done to accelerate learning to those who are new to the roof-bolting task. On-site trainers can modify this guide to fit their conditions, machines and equipment, and work procedures. They can integrate roof control plans, company policies and procedures, and operators? manuals from the manufacturers of the original equipment into this guide. Every trainee is different and will come to the job with varying levels of relevant knowledge and skills. The trainer?s decisions on where to start, how to organize the on-the-job and classroom training portions, and when and how to offer different aspects of the training will be based on (1) a pretraining assessment of the trainee?s knowledge and skills and (2) the trainer?s experience in conducting skills training. The ?Skill Check? section might be useful for deciding where training should start among miners who have underground experience but limited knowledge of roof-bolting techniques. Every job carries a learning curve and likely has a number of ?teachable moments? where significantly new knowledge and skills can be learned.

Aug 1, 2006

By David A. Monaghan, Kenneth R. Maser, Adi R. Gurdar, D. Randolph Berry

9. Remote Sealing System Sensitivity 9. 1 Introduction In the previous sections a description of the overall system has been presented along with detailed descriptions of the equipment and techniques employed with the preliminary probing system, the seal em¬placement system and the seal checking system. In addition, the use of these subsystems in a specific mine application has been described in considerable detail. A broad range of parameters of interest was specified in the contract, as summarized in Section 1. 3. Most of these are a function of the general location; i. e. , the location of the mine, and the specific location; i. e. , the location of the boreholes. These parameters of interest include passage size, shape, depth, slope and water con¬ditions. The length, diameter and location of the boreholes within the mine passage and on the surface are critical parameters as well. A few additional parameters may affect one or more of the remote sealing subsystems. These include temperature, topography, rock and soil conditions, and underground water. While variation in these parameters will not render the system inoperative, consideration of them in the planning stages will simplify and expedite the field operation. In the following sections the effect of the various parameters on the remote sealing operation will be discussed. For clarity, the several tasks, borehole drilling and casing, preliminary probing, fly ash delivery, foam topping and seal checking, will each be considered separately.

Jan 1, 1973

By T. L. Joseph

"In the January 3 issue of Iron Trade Review, Sweetser2, in referring to the problem of coke combustibility, points out that, ""Someone should formulate a rule for the rate of flow of coke through the zone of coke combustion that now appears to be confined to a comparatively restricted volume in front of the tuyeres,"" In formulating such a rule it is necessary to distinguish clearly between combustibility, a property of the fuel, and rate of combustion, which is determined by the rate at which air is supplied to the fuel bed. The rate of carbon gasified at the tuyeres of a blast furnace is independent of coke combusti-bility. A fast-burning coke will burn in a more restricted volume than a slow-burning coke, but both types of fuel will be consumed at rates determined by the supply of oxygen,A number of the definitions of combustibility that have appeared in technical literature relate more closely to rate of combustion than to combustibility. Perrott and Kinney) have correctly defined it as follows: ""Combustibility of coke from the standpoint of its use in, the blast furnace is inversely proportional to the mean rate of gasification per unit volume of the combustion zone, assuming other factors remain constant,"" Combustibility of coke refers therefore to those properties that determine the size or extent of the combustion zone. Relative differences in these properties can be measured by the depth of the fuel bed required to convert oxygen from the air into carbon monoxide."

May 1, 1924

By Theodore Christos

The Bureau of Mines sponsored an investigation of the thermal oxidative degradation characteristics of certain solvents and hydraulic fluids used in underground mining operations. The following halogenated solvents were studied in view of their usefulness and their flame retardant property: tetrachloroethylene, C12C = CC12; 1, 1, 2-trichloroethane, CIH2CCHC12: and trichloroethylene, C12C = CHC1. The hydraulic fluids studied were representative of five groups approved by the Mine Safety and Health Administration for underground operation, namely: glycol-water solutions, mineral oil-water emulsions, synthetics other than phosphate esters, synthetic phosphate esters, and mixtures of phosphate esters with mineral oils and other ingredients. It was observed that the partially halogenated solvents present a greater potential toxic hazard than the fully halogenated materials, due not only to the easy production of hydrogen chloride but also to their ease of oxidation leading to the formation of phosgene and carbon monoxide. The pure phosphate esters exhibited the best thermal oxidative stability of the five groups of hydraulic fluids tested. A fluid containing phosphate esters mixed with mineral oils and other unidentified ingredients appeared to be the most hazardous On the basis that it produced very toxic acrolein and phosphine.

Jan 1, 1980

By Harold R. Newman

The performance of Ecuador's mineral industry continued to be affected not only by depressed oil prices in recent years but also by natural disasters. In March 1987, Ecuador canceled foreign debt payments for the rest of the year and appealed for international aid because of a series of earth-quakes that destroyed villages and crippled the nation's oil industry. The earthquake destroyed a key section of the country's main oil pipeline and forced a halt to production and shipment of Ecuador's most important export product. Ecuador produces 240,000 barrels of oil per day and exports 144,000 barrels daily. Oil accounts for 60% of the nation's hard currency earnings. The Government of Ecuador asked the Organization of Petroleum Exporting Countries and other oil-producing countries to assume Ecuador's oil sales commitments. Ecuador agreed to pay the countries back in an equivalent amount of oil when it was able to resume exports.

Jan 1, 1989

By E. C. Lane

The motor gasoline that is being marketed in the United States this winter (1928-29) is slightly more volatile than that gold a year ago. This characteristic is shown by a slight lowering of the distillation temperatures, particularly at the average initial and 20 per cent boiling points. Daring the past mine and a half years the Bureau of Mines has made semi annual surreys of the gasoline marketed in the United States; the Survey just completed is the nineteenth in the series. The 12 cities in which samples have been collected were chosen as representative of the more important marketing territories, as it was obviously impracticable to obtain a sample of every gasoline sold in the entire country.

Jan 1, 1929

By I. L. Nichols

Laboratory characterization studies have investigated the processing variability of carbonaceous uranium-bearing materials found in-sandstone deposits. This work was conducted by the Federal Bureau of Mines in support of its goal to maintain an adequate supply of minerals to meet national economic and strategic needs. Conventional processing produces only partial uranium recovery from these ore materials. Ore samples from New Mexico, Texas, and Wyoming were examined, and each responded differently. Using direct acid leaching techniques, some of the ores required acid additions of only 50 pounds per ton, while others required 300 pounds per ton of material. Maximum extractions ranged from 83 to 94 percent in the six ores tested. Roasting those ores prior to leaching improved extraction of the uranium to the 90 to 99 percent range. An oxidative autoclave treatment used with five of these ores resulted in extraction of 78 to 97 percent of the uranium. The experimental studies also showed that some carbonaceous materials can be concentrated by froth flotation. The flotation tailings were amenable to acid leaching, and up to 98 percent of the uranium was extracted from this type of material.

Jan 1, 1979

By David S. Yantek, Paul Jurovcik, Eric R. Bauer

Workers in coal preparation plants, where vibrating screens are significant noise sources, are often exposed to sound levels exceeding 90 dB(A). The National Institute for Occupational Safety and Health, a major coal company, and a vibrating screen manufacturer conducted a cooperative study of vibrating screen noise. Rubber isolators reduced sound levels by 1 dB. Urethane screen panels did not reduce sound levels in this case. Drive noise was determined to be the dominant noise source on the screen. Damped side plates reduced vibration levels on the screen sides by 1 to 7 dB(A). Detailed results of the study are presented.

By Charles Vaught

This is the second in a series of four articles that discuss underground firefighting preparedness. As with the first article in the May-June issue, it is based on interviews with 214 miners conducted at 7 underground mines (?A? through ?G?) by researchers of the National Institute for Occupational Safety and Health?s (NIOSH) Pittsburgh Research Center [Vaught et al. 1996].In the first article, the authors presented an overview of the study conducted by NIOSH on mine fire response preparedness and provided a general perspective on underground mine fires. In this article, we will describe miners? preparedness to evacuate a fire and their experience with incipient fires.

Jan 1, 1997

By Barbara J. Halpern

There?s no denying that mining is a male-dominated industry. Yet thanks to technologies developed over the last 20 years, societal changes in sex role stereotyping, individual determi­nation, and the willingness of companies to train women, there are no jobs in mining today where women are not represented. Women are drillers and electricians as well as drivers of heavy equipment and haulpack trucks. They perform jobs ranging from field exploration and metallurgy to clerical and janitorial and warehousing positions, from prospectors and underground blasters to geologists and land reclamation experts, from communicators to legal experts on mining law and more. The Women?s Mining Coalition, founded in 1994 to shepherd responsible legislative mining reform, estimates that 20 percent of the workers in the mining industry are women. Although women are concentrated in clerical and adminis­trative jobs, at least 10 percent are in non-traditional, hardhat jobs, claims the group. There are women in management, but the numbers in senior management remain small, especially in larger companies.

Feb 1, 1998

By Philip A. Holland

The Bureau of Mines has developed a method for determining helium in water for use in sampling and analyzing surface and subsurface waters for geochemical survey work. The accuracy of the analytical method is within ±10 percent for samples containing above 20 x 10-8 cm3 He (STP)/cm3 H20. The minimum detectable helium-in-water concentration is calculated to be 2 x 10-8 cm3 He (STP)/cm3 water. Water samples are collected in 500-cm3 stainless steel cylinders. The dissolved gases are extracted into a cylinder of equal volume containing a known quantity of neon. The resulting gas mixture is subsequently analyzed for helium and neon-21 by mass spectrometry. The volume of helium in the sample is calculated from the mass spectrometric determination of the helium-to-neon-21 ratio, the known quantity of neon used, and the extraction efficiency of helium.

Jan 1, 1981

By R. L. Montgomery

The literature has been surveyed and values recalculated for the heats and free energies of formation of solid rare-earth compounds at 298° K. In most instances it was necessary to estimate the entropies. Thermodynamic properties of aqueous rare-earth ions have also been calculated. INTRODUCTION The accumulation of thermochemical data on rare-earth compounds in recent years makes it possible to review the subject and to obtain more consistent and more reliable information than was available previously.

Jan 1, 1959

By W. E. Lamont

The Federal Bureau of Mines conducted research to develop methods of removing phosphorus from the earthy, calcareous hematite ores of the Birmingham, Ala., iron district while simultaneously improving the grade and recovery of the iron values prior to furnacing. An attempt was also made to identify the phosphorus minerals present in the ores. The ores contained about 36 percent iron, 12 to 16 percent CaO, 15 to 20 percent hydrochloric acid insolubles, and 0.30 to 0.36 percent phosphorus. Fractions containing 5 to 15 percent phosphorus were isolated from the ores. Collophanite, Ca3P2O3?nH2O, a member of the apatite group, was the only phosphate mineral identified. Beneficiation methods using flotation and reduction roasting with magnetic separation yielded good grade iron concentrates, but were not as effective for reducing the phosphorus content of concentrates. Reduction roasting followed by fine grinding, magnetic separation, and acid leaching gave iron concentrates containing 62.5 percent iron and 0.04 percent phosphorus with an iron recovery of 82.9 percent and a phosphorus rejection of 93.7 percent. Reoxidation of reduced magnetic concentrates followed by acid treatment gave iron concentrates containing 58.1 percent iron and 0.02 percent phosphorus with 89.6 percent recovery of the iron and 96.5 percent rejection of the phosphorus.

Jan 1, 1973

By Charles P. Lazzara, Charles D. Litton, Frank J. Perzak

This U.S. Bureau of Mines report details the results of a series of large-scale experiments where small coal fires were used to ignite the conveyor belt at air velocities ranging from 0.76 to 6.1 m/s. In the tests, electrical strip heaters imbedded within a pile of coal were used to heat the coal to a point of flaming ignition. The flaming coal subsequently ignited the conveyor belt located approximately 5 to 10 cm above the coal pile. During the tests, temperature, CO, and smoke levels were continuously measured in order to determine both alarm time and level as the fire intensity progressed through the stages of smoldering coal, flaming coal, and flaming coal plus flaming belt. Analysis of the data leads to certain conditions of air velocity and sensor alarm levels that are required for early detection of conveyor belt entry fires. Two nomographs are presented, which define sensor alarm levels and sensor spacings as a function of belt entry cross-sectional area and belt entry air velocity.

Jan 1, 1991

By M. C. Chapman, E. C. Westman, A. T. Iannacchione

Examination of seismic records during the time interval of the Sago Mine disaster in 2006 revealed a small amplitude signal possibly associated with an event in the mine. More needs to be understood about the seismicity from mine explosions in order to properly interpret critical seismic information. A seismic monitoring system located at NIOSH’s Lake Lynn Experimental Mine has monitored experimental gas and dust based explosions and impact tests. The seismic signatures from these different events were analyzed using standard waveform analysis procedures. The magnitude of seismic energy during a gas and dust explosion was found to be more dependent on mine entry geometry and seal behavior rather than on the amount of explosive fuel present. The results suggest a large explosion that’s not restricted can generate potentially the same magnitude as a small explosion that is restricted.

By M. J. Kovalik

The effects of the process variables on the production of chemical coke on a chain grate stoker, a type of traveling grate, were studied. Six bituminous coals, ranging in volatile matter from 16.7 to 43.8 percent, were successfully carbonized, yielding chemical coke with acceptable physical properties. The coke yields were dependent on the volatile-matter content of the coal. The air fuel ratio had the most marked effect on the yield and characteristics of the resultant coke, and the general furnace performance. Results can only be predicted; the actual yield and quality of coke obtained from any given coal can only be determined by actual tests using the optimum processing variables to obtain a coke with minimum volatile-matter content and to retain as much of the fixed carbon in the original coal as possible.

Jan 1, 1967

By M. M. Jones

A procedure for the spectrophotometric determination of uranium has been developed in support of minerals research being conducted by the Bureau of Mines. Uranium is separated from the sample by tributylphosphate extraction from acid solution containing added aluminum nitrate and (ethylene dinitrilo)-tetraacetic acid solutions. The colored uranium-dibenzoy1methane complex is developed in the organic phase by adding an ethanol solution of dibenzoylmethane buffered with triethanolamine. Absorbance is measured at 410 nanometers, and the response is linear up to at least 100 micrograms U30S in the aqueous aliquot taken for analysis. Aliquots containing as little as 8 micrograms U30S may be analyzed with relative errors no greater than ±5 percent. For aliquots containing at least 35 micrograms U308, relative standard deviation at the 95-percent confidence level is about ±2.2 percent. Appropriate procedures are given for analyzing a wide variety of samples.

Jan 1, 1980

By Yael Miron

ANFO blasting agents may undergo an exothermic reaction when they contact warm ore bodies that contain pyrite and its weathering products. The reaction is very fast at temperatures above 80° C. Urea, when present in sufficient amounts, inhibits this reaction at temperatures below 180° C. But urea-ammonium nitrate mixtures are very hygroscopic and, in certain climates, may be difficult to handle in the field. Reaction-inhibiting characteristics of three compounds were reported by the Bureau of Mines in 1979. Recently, the Bureau investigated the reaction-inhibiting qualities of five additional compounds. Mixtures of ANFO, pyrite, weathering product, and prospective inhibitors were slowly heated, under conditions simulating a hot borehole, to determine prospective inhibitor capability at temperatures up to ~175° C. Small-scale thermal tests of the same mixtures were used for verification and clarification of results. Two organic compounds, phthalimide and xanthine, similar in structure to urea, failed to inhibit the reaction. Zinc oxide and calcium carbonate were found inferior to urea, though zinc oxide raised the onset of reaction from 80° C to about 140° C. Only magnesium oxide was found to be similar to urea in its inhibitory ability at temperatures below 175° C. Based on results from analysis of quenched residues, the use of more than 5 wt-pct magnesium oxide is recommended.

Jan 1, 1982

By Gregory J. Chekan

In This Chapter [Drilling, blasting, and crushers Diesel particulate Enclosed cabs Ventilation with jet fans Stopping construction methods Propeller fans as main fans] This chapter explains how to control dust in large-entry stone mines, including both silica dust and diesel particulate. Most stone mines are limestone mines, but a substantial minority are marble, sandstone, and granite mines. These mines differ from most others in that entry widths are 30 ft or more and entry heights are 25 ft or more. Such mines, developed with room-and-pillar methods, have large open areas that can make ventilation and dust control more difficult. Because of the difficulty of ventilating stone mines, improved ventilation is a major focal point of this chapter. However, the chapter also covers the control of dust from drills, blasting, and crushers. Another part of the chapter covers enclosed cabs, an effective dust control technique for some workers. BACKGROUND The major dust compliance problem in stone mines is caused by silica (quartz) in the rock. Mines in high-silica rock, 8% or more, are far more likely to have a dust problem than those where there is less silica. Geographically, the limestone in the Northeastern and South Central United States has higher silica than the rest of the country. Chekan and Colinet [2002] have analyzed Mine Safety and Health Administration (MSHA) dust sampling results [MSHA 2001] from the stone industry. They have concluded that, on average across the United States, the workers exposed to the highest dust concentrations are rotary drill operators, front-end loader operators, truck drivers, and crusher operators. However, there are many regional differences. Also, occupations that work outside of cabs, such as blasters, roof bolters, and laborers, can be exposed to high dust levels.

Jan 6, 2003