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By C. M. Frost

Crude shale oil produced by gas combustion retorting of Green River oil shale was hydrocracked over a cobalt molybdate catalyst at operating pressures of 500, 1,000, 1,500, and 3,000 psig, an operating temperature of 8900 F, and a liquid hourly space velocity of 1.0. Hydrogen feed rate was maintained at 6,000 scf/bbl. The volume-percent yields of total liquid product were directly proportional to the operating pressure. Weight-percent conversion and volume-percent yields of gasoline were directly proportional to the log of the operating pressure. Catalyst deposit percentages were inversely proportional to the log of the operating pressure. Nitrogen and sulfur removal rates as well as saturation of the liquid products increased as the operating pressure was increased.

Jan 1, 1973

By Fred Baldassare, Marcia Harris, Kenneth K. Eltschlager

Surface mine blasting was recently investigated as a potential source of high concentrations of stray gases found in nearby residences of western Pennsylvania. In one incident carbon monoxide was detected in a home and in the other, high concentrations of carbon dioxide were found in a home. Both carbon monoxide and carbon dioxide are by-products of blasting. However, other potential sources of these gases may also exist in a residential setting. In each case, gas chromatography (GC) and carbon isotopic analyses were used to define atmospheric concentrations inside the homes, and to determine the source of a stray gas. Molecular and isotopic analyses provide geochemical evidence as to the origin and source of the stray gas. This paper discusses elements of a stray gas investigation and the analyses necessary to identify the source of a stray gas.

By L. C. George

The Bureau of Mines measured the vapor pressures of selected mixtures in the binary systems CdCl2 ?SnCl2, CdCl2 -ZnC12, PbCl2 ?SnCl2, and PbCl2 -ZnCl2 by the static pressure method. These data were evaluated by the second-law (sigma-plot) method. Equations expressing the vapor pressures and the heats and free energies of vaporization as functions of temperature are given.

Jan 1, 1969

By E. G. King

This paper reports measurements of low-temperature heat capacities and entropies at 298.15° K. of two copper ferrites (CUFe204 and CU0.75Fe2.2504). These substances, which occur in copper-smelting slags, have not been sujected to any previous direct thermodynamic investigation. The two copper ferrites are spinel minerals of the variate class. In previous investigations similar data were obtained for 13 other spinel minerals -7 of the normal class and 6 of the variate class. The entropies at 298.15° K. of these minerals have been compiled and revised as necessary in the light of present knowledge regarding structural randomness; entropy values, recommended for use in thermodynamic calculations, are listed.

Jan 1, 1959

By G. W. Murrie, W. P. Diamond, C. M. McCulloch

It is estimated that more than 1 trillion cubic feet of methane is contained within the coals of the Mary Lee group in Jefferson, eastern Tuscaloosa, and southern Walker Counties, Ala. Most of this methane will be encountered by mining. Coals of the Mary Lee group are presently being mined at depths exceeding 1,000 feet and will in the near future be mined at even greater depths, where the problem of methane gas affecting the mining operations will be acute. It is calculated that approximately 90 pct of the methane is at depths greater than 1,000 feet, and over half of the gas is contained within only 12 pct of the study area which is under more than 1,500 feet of over- burden. Degasification in advance of mining will increase mine safety, reduce ventilation expenditures, increase productivity, provide an additional energy source, and make it possible to mine parts of deep coalbeds that probably could not otherwise be mined.

Jan 1, 1976

By Sathit Tandanand

Geological differences among various coalfields restrain the applicability of subsidence prediction using empirical approaches previously developed. The Bureau of Mines assessed data collected from 16 longwall panels in the Northern Appalachian basin. Attention was focused on the effects of rock lithology, excavation width, and panel depth on the subsidence factor. The results show that the subsidence factor can be expressed in terms of the width-to-depth ratio by a simple exponential equation, which has a coefficient tentatively considered as the subsidence index. This index varies with the lithology of a particular site, and can be expressed in terms of percent distribution of weak and strong rocks in the overburden.

Jan 1, 1982

By Thomas V. Falkie, R. Venkataramani

The empirical nature of this investigation required measurements of variables under operating conditions in underground coal mines. The variables to be measured were based on the postulated character¬istics of the loading function, as described in the previous chapter. One class of variables presumed to influence the loading function are geological variables. Accordingly, the sites for data collection were selected in different bituminous coal seams at dispersed locations in order that variation in geological conditions would exist. Seven mines in central and western Pennsylvania and one mine in northern West Virginia were selected as data collection sites. Five different coal seams were represented by these mines. The remaining classes of variables - geometric, mechanical, and procedural - were measured as they occurred in the mines. A description of the measurements, and the conversion of these measurements to forms which could be-analyzed for effect on the loading function is given. Mining Dimensions At the underground working face, the following dimensions were measured: a. Thickness of coal excavated. b. Thickness of shale excavated. c. Total height excavated. d. Width excavated. e. Depth of penetration of each machine cut. With the exception of the last of these dimensions, all were measured

Jan 1, 1972

By M. MacLaughlin, J. Whyatt

A case study is presented that relates statistical descriptions of joint sets to the distribution of local wedge failures along the crest of a catch bench at the Yellowstone Talc Mine. The fracture sets and bench width were mapped by teams of geological engineering students from Montana Tech under the direction of Dr. Mary MacLaughlin. The students analyzed the fracture data, conducted physical property tests, and used a beta version of a NIOSH program “Bwedge” to predict the distribution of surviving bench widths. In the course of this analysis the students developed evidence of software performance issues that, unfortunately, frustrated their analysis. These have now been addressed and a full analysis completed. The analysis confirms the validity of the student mapping program and provides insight into the effects of blasting and excavation practices on the bench. It also provides a tool for exploring the pattern of bench crest failure that would result from variations in both bench geometry and blasting practices.

By W. H. Engelmann

The electrokinetic (zeta) potentials of a charcoal granite in an aluminum chloride (AlCl3) solution and in an oleylanunonium acetate (C18H35NH3+ -OCOCH3) solution have been correlated with the specific damping values as measured by the pendulum sclerometer. This investigation shows that the pendulum specific damping attains a minimum at the isoelectric point for the charcoal granite-aluminum chloride and charcoal granite-oleylammonium acetate systems, and thus indicates that the penetration of the diamond points is a maximum at the isoelectric point.

Jan 1, 1967

By R. V. Ramani, V. T. Burgos, J. A. McClay

Cost Systems Cost systems are organized methods of collecting, allocating, and accumulating resource utility expressed in terms of money. There are two major spheres of cost accumulation: financial accounting and cost accounting. Financial accounting deals primarily with historical costs and provides a means of measuring and recording cost events which have al¬ready taken place. While there are no legal requirements to control the methods of recording and reporting cost data in the United States, the procedures in use are guided by professional organizations such as the American Institute of Certified Public Accountants. The final pro¬ducts of financial accounting practices are the income statement and balance sheet which describe the financial status of the organization under study. Cost or managerial accounting is an expansion of financial ac¬counting procedures, providing more detailed cost breakdowns on present operations with one objective being the projection of present costs into the future. The projection process tends to limit the accuracy of the information; however, to management and project justification per¬sonnel, data on future operations tends to be of greater value. The basic principle behind cost accounting is the cost cycle. As products are developed from raw materials, the value of the work-in¬process increases due to the cost input of the various fabricating ele¬ments. Thus, from the basic input elements of facilities, labor, and raw materials, costs are added to each unit of production as a function of the work performed on that unit.

Jan 1, 1975

By John C. Machisak

THIS CHAPTER of the Minerals Yearbook relates to employment data and injury experience in the metal, nonmetal, and quarrying industries. Combined statistical data on the mineral industries as a whole can be found in volume Ill. Each industry in the chapter is shown separately, and no attempt has been made to combine and show an overall picture. The voluntary reporting of data on injuries and employment by operators of metal and nonmetal mines and quarries has contributed substantially to the promotion of safety in these industries. Data on injury and employment in the clay mining and milling industry are included for the first time. Table 6 contains data for clay mines only for 1955 and for clay mines and mills for 1956. The clay-mill figures are included with other nonmetallic mills in table 5. The information for norunetallic mills was compiled and published for the first time in the 1955 issue of this report.

Jan 1, 1958

By John Ward Smith

The Bureau of Mines derived equations expressing the theoretical relationship between density of oil-shale rock and its organic content. Effects on theoretical shale density produced by variations in mineral composition and organic matter properties were evaluated. The theoretical relationship was extended to relate oil-shale density to oil yield in both oil weight and volume units by considering the fraction of organic matter converted to oil and the specific gravity of the oil produced. Corollary equations relating organic content by volume to organic content by weight and to oil yield were developed. The general relationships apply to an oil-shale deposit uniform in character. Application of the theoretical relationships to Green River Formation oil shales was demonstrated.

Jan 1, 1969

This study presents a reservoir modeling approach to investigate the relative effects of different coalbed parameters on the migration of methane into development entries. A base coalbed reservoir model of a three-entry development section, where grids were dynamically controlled to simulate the advance of mining at a constant section advance rate, was created and calibrated for a Pittsburgh Coalbed mine in the Southwestern Pennsylvania section of the Northern Appalachian Basin. The values of coalbed parameters were varied to evaluate their effects on predicted methane emissions for various development distances. The results of these parametric simulations were then used to derive linear expressions relating these parameters to methane emissions into the workings. These models were analyzed to assess their significance and adequacy for predictive purposes. This work shows that coupling reservoir simulations with linear modeling yield a technique that can be applicable to different coalbeds. The reservoir parameters used by the linear models (coalbed thickness, pressure, sorption time constant, Langmuir parameters, permeability) can be determined by running relatively simple laboratory tests, such as adsorption equilibrium and permeability determination, on coal samples obtained either from the mining operation or from the exploratory boreholes drilled ahead of mining.

Jan 1, 2008

By Gordon H. Dechman

This Bureau of Mines report presents an iterative approximation method for microseismic source location that was developed to adapt microseismic techniques for rock structure analysis to investigations of surface problems, such as slope failure in an open pit mine. The source location method and two derivative location algorithms are described in detail, and the speed and accuracy of the two algorithms are compared.

Jan 1, 1977

By Jeffrey Johnson, Thomas Brady, Radford Langston, Mary MacLaughlin, Hendrik Kirsten

The magnitudes and directions of in situ stresses affect the stability of mine openings, as well as the type and amount of ground support needed to maintain a safe working environment for miners. Using hollow inclusion stress cells, researchers from the Spokane Research Laboratory of the National Institute for Occupational Safety and Health obtained two in situ stress measurements from the face of two footwall lateral drifts at the Stillwater Mine near Nye, MT. The first measurement, obtained in 1997, was collected under the valley beneath the Stillwater River. The second measurement was obtained in 2002 under the main frontal massif of the Bear tooth Mountains in the western sector of the mine. Although few data are available, the major principal stress under the valley has been recorded as nearly horizontal in a north-south direction perpendicular to the ore body, while beneath the mountains, stress runs east-west parallel to the ore body. This paper documents the measurements, describes the in situ stress state, and discusses a finite-difference analysis of the biaxial test.

By Wilbur I. Duvall

The borehole deformation gage and overcoring techniques developed by the Bureau of Mines form one of the primary methods of determining in situ rock stress. This report describes a least squares method of calculating the average rock stress components in the horizontal plane from more than three diametral deformation measurements in a vertical borehole. This least squares analysis provides a means of determining the multiple correlation coefficient, the variance, and the scatter for a set of deformation measurements. From this information, confidence limits can be calculated for the secondary horizontal principal stresses and their directions. The material presented in this report can be used as a guide to the development of least squares solutions for stress measurement techniques other than the borehole deformation method. Since the statistical information that results from the least squares method is extremely useful in the interpretation of results, it is recommended that a least squares analysis be used on stress measurement data whenever possible.

Jan 1, 1979

By Charles C. Boley

The Bureau of Mines dried and carbonized two wood wastes, one softwood (redwood) and one hardwood (oak), using continuous, vertical entrainment techniques previously developed for use with coal. It was demonstrated that these techniques are readily applicable to wood waste and that appreciable changes in the yields of carbonization products can be obtained by varying operating conditions. A limited amount of experimental work was done on briquetting the charcoals. Firm briquets were formed with oak charcoal, although greater quantities of starch binder than used commercially for kiln-produced charcoal were required. Redwood charcoal did not briquet successfully under the test conditions employed.

Jan 1, 1969

By Seth C. Schaefer

The Bureau of Mines studied thermodynamic properties of Al-Ni alloys con¬taining 0.54 to 30.04 atomic percent nickel with the aid of the high-temperature galvanic cell Al(1) // Al+3 (AlCl3 in NaCI.KC1) // Al-Ni alloy (1 or s). Activities of aluminum and nickel (compared with pure liquid metals as the standard state) show pronounced negative deviation from Raoult's law at 1,273 K. The properties [?G, ?Gxs, ?G ideal, ?GA1, AGxs1, ?Gni , and ?GNixs] have been derived from the experimental data and are summarized in tables and illustrations. At 1,127 K, the thermodynamic stability for the invariant three-phase equilibrium consisting of a saturated liquid, A13Ni, and A13Ni2 has been uniquely defined by an activity for aluminum of 0.751. A free energy of formation at 1,127 K of -7,940 cal/g-atom was derived for the compound A13Ni.

Jan 1, 1975

Provide the U.S. mining industry with the means to measure and control exhaust emissions of diesel engines used in underground mines. Approach Diesel research is divided into four primary areas: exhaust aerosol measurement, particulate control, gaseous emission control, and chemical and biological characterizition of particulate matter. Diesel research is frequently cosponsored by industry; collaborative research ventures between industry, academia, other government agencies, and the Bureau arc common. Diesel research at the Bureau is conducted in the diesel engine research facility at the Bureau?s Twin Cities Research Center (TCRC). This facility is a state-of-the-art laboratory capable of performing emissions testing, exhaust control evaluations, and safety tests. Background Exposure of mine workers to airborne contaminants from diesel engine exhaust is potentially harmful. The National Institute for Occupational Safety and Health has recommended that whole diesel exhaust be regarded as "a potential occupational carcinogen" and that ?reductions in exposure to diesel exhaust in the workplace would reduce the risk." The U.S. Mine Safely and Health Administration (MSHA) convened an Advisory Committee on Standards and Regulations for Diesel-Powered Equipment and is beginning to implement its recommendations, which cover health, safety, and certification and approval issues surrounding the use of diesels underground. In January 1992, MSHA published an advance notice of proposed rulemaking to regulate diesel particulate matter in underground mines.

Jan 1, 1992

By A. B. Cecala

A cooperative research effort was established between the Tilden Mining Company LC, the United Steelworkers of America, and the National Institute for Occupational Safety and Health to lower respirable dust levels in an iron ore grinding and concentrator plant. This cooperative effort involved three field studies to evaluate different techniques to lower respirable dust levels. The greatest impact on lowering respirable dust concentrations throughout this facility was achieved through ventilation changes. The most significant improvement was realized by changing the ventilation profile throughout the entire facility. The ventilation to this grinding and concentrator facility was provided by approximately 40 roof fans operating in either the intake or exhaust mode. The operation of these fans was significantly changed in an attempt to pro-vide more of a directional flow pattern throughout the facility, as well as to more closely balance the intake and exhaust air volume. This change accounted for a 31 pct reduction in respirable dust levels in the primary grinding area of the mill. Another successful modification was to improve the sealing of a reclaim tunnel to the outside and by barricading the access point from the reclaim tunnel to the concentrator plant. This minimized the dust liberated in the conveyor tunnels from traveling through the reclaim tunnel and into the plant. These two modifications illustrate the impact that improvements in ventilation can have on lowering respirable dust concentrations in iron ore processing facilities.