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By S. J. Lötter

Analysis of the major and minor components of raw zircon as well as plasma-dissociated zircon was undertaken using inductively coupled plasma optical emission spectroscopy (ICP-OES). Microwave-assisted acid extraction as well as flux fusion using lithium tetraborate were investigated as digestion methods. Microwave-assisted acid extraction samples were analysed with matrix-matched standards. The most successful microwave-assisted acid extractions yielded 44.3(1), 49.75(7), 78.3(3) and 90.0(7) per cent recovery for Zr, Hf, Al, and Fe respectively using sulphuric acid. In no instance was acid extraction capable of complete digestion of the sample matrix. A standard addition method was applied to the flux-fusion samples due to the high complexity of the sample matrix. Method validation for the flux fusion procedure was performed using the SARM 62 certified reference material (CRM) with acceptable recovery ranges being based on the 95 per cent confidence intervals of the CRM. Successful analyses were achieved for Zr, Hf, and Ti with apparent content of 66(6), 1.7(1) and 0.15(1) per cent respectively.

Jan 1, 2012

1. Book reviews Tungsten: 1982. London, Mining Journal Books Ltd, 1982. 179 pp. Reviewer: G.A. Brown The geology of industrial minerals in Canada, edited by G.R. Guillet and Wendy Martin. Canadian Institute of Mining and Metallurgy, special volume 29. Reviewer: R.W.O. Kersten Foam flotation - theory and applications, by Ann N. Clarke and David J. Wilson. New York, Marcel Dekker, 1984. 418 pp. Reviewer: B.K. Loveday Industrial and financial indicators of the steel industry, by Patrick Genevaz. Paris, La Chambre des Cartes, 1982. 2 vols. Vol I: Analysis and conclusions, FF3500. Vol. 11: Tables, FF4000. Reviewer: R.J. Dippenaar An encyclopaedia of metallurgy and materials, by C.R. Tottle. Plymouth, Macdonald and Evans and The Metals Society, 1984. 481 pp. RI44,50. Reviewer: P. T. Wedepohl The role of crack growth in metal fatigue, by LP. Pook. London, The Metals Society. Reviewer: C.A. Boothroyd Hydraulic coalmining - new technology and its geological and industrial significance, by H.C. Siebert. Hamm, Zentraldruckerei BAG, 1984. 33 pp. Hydraulic coalmining - hydromining update: potential impact on coal deposits and coal mining industry, by H.C. Siebert. Hamm, Zentraldruckerei BAG, 1984. 130 pp. Victoria's brown coal. A huge fortune in chancery, edited by J .T. Woodcock. The Australasian Institute of Mining and Metallurgy, 1984. 204 pp. Reviewer: J.J. Versluis 2. Canadian publications The following reviews of the activity and developments during 1982 in respect to the chief minerals produced or consumed in Canada are now available. Zirconium. An important mineral commodity. Mineral Policy Sector, Mineral Bulletin MR 202, $6.60. Canadian minerals yearbook 1982. Mineral Policy Sector, Mineral Report 32, $40.75. Canadian reserves of copper, nickel lead, zinc, molybdenum, silver and gold as of January 1, 1983, by W.H. Laughin. $4.20. Mineral Policy Sector, Mineral Bulletin MR 201. Sulphur market profile, by B.W. Boyd. Mineral Policy Sector, MRI 84/5. 3. Mintek publications Report M123 The use of of activated charcoal in a NIMCIX column for the recovery of gold from cyanide solutions. Report M150 Energy transfer in the hearths of submerged-arc furnaces. Report M151 A preliminary investigation of the initiation of pitting corrosion in austenitic stainless steels and nickel-based alloys. Report M154 The reduction of Winterveld chrome spinel at 1300°C under an argon atmosphere in the presence of carbon. Report M165 The development of an improved on-line gold analyser. Report MI67 three nebulizers for use with an inductively coupled plasma spectrometer. 4. New publications Mineral Industry Consultants Association (as at 31st March, 1984). Parkville (Australia), The Australasian Institute of Mining and Metallurgy, 1984. 112 pp. Philosophical and procedural guidelines for the planning professions. Johannesburg, the Environmental Planning Professions Interdisciplinary Committee (EPPIC, P.O. Box 61019, Marshalltown 2107), R2.50. Directiona//y solidified materials for high temperature service, by M. McLean. London, the Metals Society, 1983. 337 pp. Tin and its uses no. 142. Greenford (England), International Tin Research Institute, 1984. Metals engineering International Symposia & Exhibitions Ltd - a subsidiary of Industrial Newspapers PLC - are pleased to announce that they will be organizing a mammoth engineering event, entitled Metals Engineering 86, comprising five important exhibitions in 1986:. Agglomeration A major symposium on agglomeration is being organized in Toronto for the 2nd to 5th of June, 1985. Speakers from around the world (Canada, U.S.A., Brazil, Australia, Japan, West Germany, Italy, India, China, Switzerland, Poland, Yugoslavia, and France) will address delegates on various aspects of agglomeration relative to iron ore, coal, coke, and fuels. Plenary theme papers will also be presented by speakers from Japan, the U.K., and the Netherlands.

Jan 1, 1985

By P. R. Jochens, D. D. Howat, R. B. Atmore

INTRODUCTION The Miller chlorination process has assumed a preeminent position in the refining of gold bullion, a position it has maintained for over half a century. In the early sixties considerable interest was aroused by the idea of producing a consistently high grade bullion at the mine smelthouses themselves. However, as the use of chlorine in industrial plants is associated with considerable hazards, oxygen was considered a natural alternative, apart from bing less expensive than chlorine. Partial refining at the mine smelthouses would considerably decrease the requirements made on Rand Refinery Limited as well as indicating the possibility of reducing final refining costs. An added factor would be the purer silver chloride obtainable, after prior removal of the base metals by oxygen injection, which would facilitate the production of high-purity silver. The free energies of formation of the oxides of the metals;- silver, copper, lead, zinc, iron and bismuth indicate that, with the exception of silver, these metals should be capable of removal as oxides by oxygen injection. Rose1 had shown that during injection of gold bullion, considerable loss of silver to the boraxsilver slag occurred and, furthermore, that copper removal was not efficient and oxide attack on the refractories was severe. Plant test work2 had confirmed the difficulty of copper removal, but had shown that zinc and lead were almost completely removed. The difficulty of copper removal by oxygen injection warranted further investigation. Also, the high decomposition pressure of silver oxide suggested that by suitable control of the slag composition it might be possible to reduce to very small proportions the silver carried into the slag as oxide. The oxidation of copper by oxygen injection and subsequent dissolution of the oxide in a slag may occur according to the following reactions; Reactions 4 and 5 were considered because of the relatively high solubility of oxygen in molten silver and silver alloys. Thermodynamic data indicate that there is little possibility of any reaction involving the formation of CuO occurring at temperatures above 1 000 °C. To ensure that the operative reactions 1 and 4 take place to the maximum extent, the following factors He significant. (a) an increase in the activity of the copper in the bullion, (b) an increase in the partial pressure of oxygen in the system, (c) an increase in the activity of the oxygen in solution in the metal, (d) a decrease in the activity of cuprous oxide in the slag. From practical considerations, the operative variable most easily susceptible to control is the composition of the slag. SOLUBILITY OF COPPER OXIDES IN BOROSILICATE SLAGS Very scanty information exists on systems containing copper oxides but the indications are that slags containing considerable amounts of boric oxide would possibly prove to be the best solvents for cuprous and cupric oxides. This is attributed to the fact that the activities of copper oxides are much lower in boric oxide slags than in slags in which silica is the main network former. The number of possible slags containing boric oxide was limited by consideration of liquidus temperature, viscosity, corrosive action on refractories, volatilization, and ultimately cost (for industrial application). Slags in the systems soda-boric oxide-silica and lime-boric oxide-silica were selected paying due attention to the above limitations. Additions of 5, 10 and 15 per cent cupric oxide were made to the finely ground, premelted slags. These mixtures were then reground and 2g quantities held in re crystallized alumina crucibles at temperatures of 1150°C and 1 250°C respectively for 30 minutes. The crucibles were removed from the furnace, rapidly cooled, cut in half longitudinally, and a thin section taken from one half was subjected to microscopic examination.

The industrial relations handbook, by A. Pons. Juta (P.O. Box 14373, Kenwyn 7790). 1989. "'"250 pp. Looseleaf binder. R180 + GST. Industrial laser materials processing. World Business Publications Ltd (4th Floor, Britannia House, 960 High Road, London N12 9RY, England). 1989. 180 pp. £310. Mining 1990. Longmans, Financial Times International Year Books, 1989. 592 pp. £90.00. Innovations in materials processing using aqueous, co/oid and surface chemistry, by F.M. Doyle, S. Raghavan, P. Somasundaran, and G.W. Waren (eds.). 300 pp. $125. Light metals 1989, by P.G. Camp bel (ed.). No. of pp. not available. $150. Process control and automation in extractive metalurgy, by R. Partelpoeg and D.C. Himmesoete. 225 $98. Process mineralogy VIl, by D.J. Carson and A.H. Vassiliou (eds.). 4oopp. $150. Super plasticity and super plastic forming, by C.H. Hamilton and N.E. Paton (eds.). 700 pp. $140. Supera/oys 1988, by S. Reichman, D. Duhl, G. Maurer, S. Antolovich, and C. Lund (eds.). 880pp. $99. Surface modification technologies, by T.S. Sudarshan and D.G. Bhat (eds.). 305 pp. $49. World survey of nonferous smelters, by J .C. Taylor and H.R. Traulsen (eds.). 365 pp. $90. Second Parsons International Turbine Conference. London, The Institute of Metals, 1989.270pp. £40. Mineral processing in the United Kingdom. London, Institution of Mining and Metalurgy, 1989. £25. Today's technology for the mining and metalurgical industries. London, Institution of Mining and Metalurgy, 1989. 623 pp. £60. 1989/1990 E&MJ international directory of mining. Chicago, Mining Information Services (P .0. Box 6500, Chicago, IL 60680, USA). 620 pp. US$95. Advances in project scheduling, edited by R. Stowinski and J. Weglarz. Amsterdam, Elsevier, 1989. 540 pp. Dfl. 270. Proceedings of the 3rd International Conference on Molten Slags and Fluxes. London, Institute of Metals, 1989. 335 pp. £38. Brochure on industrial screens. Obtainable from Philippe Lavernhe, Johnson Filtration Systems S.A., Z.I. Availes-en-Chatelerault, 86538 Naintre, France. 16 pp. Free. Numerical techniques, edited by P. Spiling. London, The Institute of Metals, 1989. 226 pp. £25. Phase diagrams of ternary iron aloys, Part 2, by V. Raghavan. New Delhi, Indian Institute of Metals, 1988. 360 pp. £95 (from the Institute of Metals, London). cas publications These publications are available from the Centre for Resource Studies, Queen's University, Kingston, Ontario K7L 3N6, Canada. Economic aspects of gold exploration: How much is too much, by B.W. Mackenzie and M. Dogget. 30 pp. $10.00. Mineral exploration and mine development potential in Ontario: Economic guidelines for government policy, by B.W. Mackenzie, M. Bilodeau, and M. Dogget. 180 pp. $25.00. Economic potential of base metal and gold mining in Newfoundland: Assessing the impact of regional developmentpolicy options, by B.W. Mackenzie, M. Bilodeau, and M. Dogget. 188 pp. $25.00. Publications of the AusIMM The folowing publications are available from The Australasian Institute of Mining and Metalurgy, P. O. Box 122, Parkvile, Vic 3052, Australia. Prepayment is required with al orders. The AusIMM 1989 Annual Conference 1989. $A 50. Mineral fuel alternatives and the greenhouse efect. July 1989. A$ 35. NQ gold '89. Apr. 1989. $A 50. Second Large Open Pit Mining Conference. Apr. 1989. $A 50. Explo '88. Nov. 1988. $A45. Mineral deposits of New Zealand, edited by Dr D. Kear. Monograph 13. 244 pp. $A 60. Field geologists' manual, compiled by D.A. Berkman. 3rd edition. 1989. : 350pp. $A45. The rocks speak. Essays in geology-some personal responses of a wiling listener, by Haddon F. King. 300pp. $A45.

Jan 1, 1990

1. Mining directory The mining directory, 1990. Mines and mining equipment companies worldwide. Don Nelson Publications Limited (P.O. Box 193, Barnet, Herts EN4 BLP, England).2. Mintek reports The following reports are available from Mintek, Private Bag X3015, Randburg, 2125 South Africa. They are available at R25 (plus R3,25 GST) per copy to South African addressees, and US$25 per copy (including airmail postage) to addressees elsewhere. There is also an annual-subscription scheme for reports - R400 locally (plus R52 GST) and US$400 (including airmail postage) abroad. The subscription covers al the unrestricted reports published between 1st April and 31st March of successive years, which usualy amount to between 20 and 30. Report M392 Computer programs for optimization by the modified simplex method, by G.L. Moore. Sep. 1989. 25 pp. R25 + R3,25 GST in South Africa; US $25 elsewhere. Report M393 The preparation and certification of fourteen South African silicate rocks for use as reference materials, by E.J. Ring. Sep. 1989.21 pp. R25 + R3,25 GST in South Africa; US $25 elsewhere. Report M395 The separation of trace elements in high-purity rhodium and iridium materials, by R.V.D. Robet and S.M. Graham. Nov. 1989. 10 pp. R25 + R3,25 GST in South Africa; US $25 elsewhere. 3. Publications from Trans Tech The publications listed in this section are available at the prices given from Trans Tech Publications, P .0. Box 1254, D-3392 Clausthal-Zelerfeld, West Germany. Handling of bulk solids. Theory and practice, by P.A. Shamlou. 1988. 200 pp., US$ 59.50. Acoustic emission lmicroseismic activity in geologic structures and materials, by H.R. Hardy and F.W'. Leighton. Vol. I: 1977, 490 pp., US$45.00. Vol. 11: 1980, 500 pp., US$45.00. Vol. Il: 1983, 680pp., US$6O.00. Vol. IV: 1989, 720pp., US$ 75.00. Open pit mine design models. An introduction with FORTRANI77 programs, by E. Alaphia Wright. Early 1990, approx. 200pp., US$75.00. Bucket wheel excavator, by W. Durst and W. Vogt. 988, 450pp., US$118.00. Continuois-surjace mining, by T.S. Golosinski and F.G. Boehm (eds.). 1987, 720pp., US$128.00. Mining-science and technology. 1987, 1430pages, US$ 118.00. Practical handbook for underground rock mechanics, by T.R. Stacey and C.H. Page. 1986, 150pp., US$ 38.00. Professional users handbook for rock bolting, by B. Stilborg. 1986, 150pp., US$38.00. The lighting of underground mines, by D.A. Troter. 1982, 220pp., US$48.00. Elements of hydraulic coal mine design, by M.L. Jeremic. 1982, 16Opp., US$38.00. Continuum theory of rock mechanics, by Cs. Assonyi and R. Richter. 1979, 365 pp., US$ 58.00. Shear and bond in reinforced concrete, by G. Florin.1980, 86 pp., US$ 24.00. Theory and design of surface structures: slabs and plates, by G. Florin. 1980, 222 pp., US$ 24.00. Mineral processing laboratory manual, by A.-Z. Abouzeid. January 1990, approx. 200pp., US$48.00. Weighing and proportioning of bulk solids, by Hendrik Colijn. 2nd ed. 1983, 4OOpp., US$60.00. Solid-liquid flow. Slurry pipeline transportation, E.J. Wasp et al. 1977, 240pp. US$ 58.00. Optimum pipe size selection, by C.B. Nolte. 1978, 304 pp., US$ 60.00.Field instrumentation in geotechnical engineering, T.H. Hanna. 1985, 854pp., US$98.00. The 1990 yearbook and directory. Powder and bulk solids handling and processing. 1989/90, approx. 300 pp., US$ 124.00.

Jan 1, 1990

By E. Dadzie

This paper will review some methods used to manage geotechnical risk at Damang Pit Cutback. The pit depth is designed up to 250m with push back on the eastern and western walls of the existed and depleted Railway Cutback (RCB) pit. The geotechnical design was presented by SRK Perth, focussing on the optimisation of the bench face angle which finally evolved with ?steep slope strategy?; 24m at 800 and 24m at 750 on the eastern and western walls respectively. The east wall was designed strategically to optimise the proximity of the tailings dam to the final pit crest of the push back. The pit has experienced failure in the weathered profile transgressing through the transitional material into the fresh rock at different location of the east wall since development in July 2005. To ensure stability and to minimise ore loss, the east wall has been redesigned using 700 batter angles and reduced berm width of 4m compared to 800 and 8.5 berm width of 24m bench height. The paper will also discuss how slope failures to the east wall had been sustained, managed and monitored to enhance production. Emphasis is placed on slope management at Damang which includes the principles of wall control blast, visual inspection, slope depressurisation and the state-of-the art of slope monitoring using Autoslope automated prism monitoring. Future slope monitoring is considering the use of 3D Laser and Radar to provide early warning so that evacuation could be effected. The intension is to provide mine personnel the means to identify risk areas during mining activities.

Jan 1, 2008

By R. D. Alorro, B. Tadesse, E. Aghaei

Cinnabar (HgS) and native mercury (Hg) are the most common naturally occurring forms of mercury found in most gold ores subsequently released into the environment during processing. Mercury and its compounds are extremely toxic and recognised as serious health and environmental hazards. This research investigates the possibility of mercury (Hg) removal from waste solutions from gold processing using iron-aluminium (Fe-Al) bimetallic particles. The synthesis of Fe-Al bimetallic particles using zero-valent aluminium and ferric chloride as precursors were performed following the optimisation of influencing factors. The presence of both metals in the prepared bimetals was confirmed by XRD analysis. The experiments for mercury removal by bimetals were designed using the central composite design and Minitab software based on two variables including contact time and adsorbent dosage. The best result of Hg(II) removal (>90%) was achieved using 4 g/L bimetals and contact time of 75 min. However, the statistical analysis of results indicated that these parameters have only a minor contribution to the removal of Hg(II) by Fe-Al bimetals. Higher bimetal dosage and contact time resulted in a higher Fe dissolution from the Al surface which can be attributed to the presence of nitrate (# $) ions in the solution. However, adding 0.1 M NaCl to the Hg solution had a positive impact on Hg removal by improving the conductivity and electron transfer within the solution. The Fe-Al bimetallic particles are promising substances for further testing of Hg removal from gold processing waste solutions with different conditions and constituents. Keywords: Mercury removal, gold processing, Fe-Al bimetals, optimisation

Jan 1, 2020

By X. Chen, G. Wang, D. Wan

Computational fluid dynamics have been applied for detailed modelling of particle-bubble collisions. The most accurate approach in the previous work is using the point particle method to treat particles and bubbles. Nevertheless, the sizes of particles and bubbles are generally bigger than the Kolmogorov scale in the high turbulence of the flotation environment, which makes the point particle method inappropriate. This paper describes particle-resolved direct numerical simulation on the collisions between particles (denoted as heavy particles) and bubbles (denoted as light particles) in a homogeneous isotropic turbulent flow field, and a comparison with the point particle method.. A largescale stochastic forcing scheme was implemented within the mesoscopic multiple-relaxation-time LBM approach to maintain turbulence intensity at targetted levels. Both kinematic and dynamic collision kernels were evaluated to study the correlation of total collision events and turbulent kinetic energy (TKE) dissipation rate. The results show that collisions between particles increase with the TKE dissipation rate as radial relative velocities between particles increase with it. In the particle-resolved simulations, the dynamic collision kernels were found to not match with the kinematic collision kernels as in the point particle method. Quantitatively, they were approximately 4 to 10 times smaller than the corresponding dynamic collision kernels. Therefore, it is not reasonable to estimate the kinematic collision kernel in particle-resolved simulations as its rationales are not valid. However, the collision behaviour can still be accounted for by means of the dynamic collision kernel since it is obtained from the direct statistical analysis of the collision events. Keywords: Lattice Boltzmann Method; particle-resolved simulation; multiphase flow; collisions

Jan 1, 2020

By K. L. Riemer

The West Wits Line first began yielding gold in the mid-1930s and is among South Africa's leading gold-producing areas. Gold mining operations are carried out amidst the occurrence of seismic events which cause both damage to underground excavations and injury and loss of life to production personnel. The feasibility of establishing a system to minotor the seismicity on all the Gold Fields mines was investigated during the early 1980s. This led to the establishment of a centralized seismic network in 1981. The system was structured around three major objectives. It uses Perkin Elmer (now Concurrent Computer Corporation) 16 and 32 bit mini-computers. The hardware in use at both the central and remote sites is outlined, giving a good insight into the role of computers in the system. The system software reveals the fast flow of data through the network; it can be divided into three categories: (1) data logging and transmission - remote sites, (2) data capture and communications - central site, (3) applications and research - central site. Several examples are given which show how the system is measuring up to its objectives. These case studies also indicate how the computers are effective in representing the seismic data collected. It is concluded that the use of computers enables the pin-pointing of seismic events on the West Wits Line within about 3 -4 minutes of their occurrence. The choice of hardware is largely dependent on the objectives of system, and the Gold Fields Network has chosen mini-computers because of the speed of communication and the large amount of data and storage required for research applications.

Jan 1, 1987

The mathematical models of semivariograms can be classified according to whether or not they correspond to situations where the second order stationarity conditions are satisfied (§ 3.3.4). If second order stationarity exists, the a priori variance s2 of x (z) also exists and is finite. For large distances h such that x (z) and x (z + h) are not correlated, the semi- variogram ? (h) will reach a value equal to s2 [this is a consequence of (3.27) above]. This limiting value is called the sill C of the semivariogram, and the distance at which ? (h) reaches the sill is called the range. The range of the semi- variogram obtained from a given type of sample corresponds to the distance of influence of these samples. If only the intrinsic hypothesis is satisfied, the sample variance is an increasing function of the size of the area or volume in which the samples are located, and the semivariogram ? (h) will be a continuously increasing function of h. Remark: It will be shown in Chapter 7 that the variance s2 of x (z) in the ore body O is equal to the average value of ? (h) in O. If ? (h) is a non-decreasing function with sill C, the average value of ? (h) in O will be less than C. s2 and C will be equal only if for some values of h in O, ? (h) exceeds C. In practice, if the range of the semivariogram is small with respect to the dimensions of the ore body, the difference between C and s2 will be negligible.

Jan 1, 1978

Branch Minutes of the General Meeting held at President Steyn Gold Mine canteen on Wednesday, 10th May, 1978, at 4.00 p.m. Erratum We apologize to Mr J. G. Taylor for the error in one of his qualifications. Bio-engineering monograph The selection of papers presented at the International Bio-engineering Conference at the University of Cape Town organized by the South African Institution of Mechanical Engineers and held in April 1977, and which are appearing in The South African Mechanic al Engineer during April to June this year, will shortly be available in book form. Mathematics The Institute of Mathematics and Its Applications is planning the following conferences and symposia: The Nand F Proposals in Relation to Mathematics, 1st July, 1978: London School of Pharmacy. NIM reports Report no. 1917 The instrumental neutron-activation analysis of granites from the Bushveld Complex. (31st Mar., 1978.) Report no. 1951 Potentialities and limitations of four-parameter equations for the correlation of formation constants of metal-ion complexes in aqueous solution.(15th May, 1978.) Report no. 1963 An evaluation of the methods used at the National Institute for Metallurgy for the analysis of base-metal concentrates. (28th Apr., 1978.) Report no. 1964 The separation, by anion exchange, of noble metals on substituted cellulose. (28th Apr., 1978.) Guide To The Preparation Of Papers For Publication In The Journal Of The South African Institute Of Mining And Metallurgy The following notes have been compiled to assist authors in the preparation of papers for presentation to the Institute and for publication in the Journal.

Jan 1, 1978

By C. R. S. Needes, M. J. Nicol, G. T. W. Ormrod, N. P. Finkelstein

The industrial application of a dioxide electrode uranium by C. R. S. NEEDES, Ph.D. (London) (Visitor), M. J. NICOL, Ph.D. (Rand) (Visitor), N. P. FINKELSTEIN M.Sc. (Rhodes), Ph.D. (Liverpool) (Fellow), and G. T. W. ORMROD (Visitor) A correlation between the potential of a U02 electrode and the rate of recovery of uranium has been proved in laboratory and plant trials. When the recovery rates change because of variation in the concentrations of Fe(III), Fe(II), SO4 'and H+, a positive correlation is observed. However, an 2- increase in the concentration of phosphate in solution produces an increase in the U02 electrode potential but a decrease in the rate of leaching of U02. The correlation between the U02 electrode potential and the rate of leaching of U02 is then negative. It is concluded that, as a control device, the electrode cannot compete with the platinum electrode for use on certain plants. Nevertheless, the U02 electrode will act as a useful warning device if the total concentration of iron in solution decreases to below a level concomitant with the economic recovery of uranium. Furthermore, because of the positive correlation between the U02 electrode potential and the phosphte concentration, the electrode will also be of value in the detection of an increase in the phosphate level in solution. When it was incorporated in a suitable industrial probe, the electrode was found to be able to withstand the rigours of the leaching conditions in a large pilot-plant pachuca, and only failed after six weeks' operation.

Jan 11, 1975

By W. Wittke, J. Gattermann

ABSTRACT: One alternative to close a radioactive waste repository in rock salt is the construction of a “Cross Section Closure (CSC)“ sealing barrier. The proposed material for the CSC is highly compacted bentonite. To investigate the swelling behaviour of a highly compacted bentonite a large number of laboratory tests were performed. In addition, large scale model test were carried out to demonstrate the development of a nearly homogeneous and isotropic swelling pressure. The results of the large scale model tests were interpreted numerically based on the models for stress-strain behaviour and water uptake which are implemented in the finite element codes FEST03 and HYDOPO. The investigations show a good agreement of the results of the model tests and the corresponding analyses and show, that the theoretical models are capable of describing the behaviour of sealing structures based on highly compacted bentonite. ZUSAMMENFASSUNG: Eine Möglichkeit für den Verschluß eines Endlagers für radioaktive Abfälle im Steinsalz ist die Konstruktion einer Querschnittsabdichtung aus hochverdichtetem Bentonit. Zur Untersuchung des Quellverhaltens von hochverdichtetem Bentonit wurden eine große Anzahl von Laborversuchen durchgeführt. Um die Entwicklung eines nahezu homogenen und isotropen Quelldrucks nachzuweisen, wurden darüber hinaus auch Modellversuche in größerem Maßstab durchgeführt. Die Ergebnisse dieser Modellversuche wurden im Hinblick auf die Wasseraufnahme und das Spannungs-Verformungsverhalten mit Hilfe numerischer Berechnungen mit den finite Element Programmen FEST 03 und HYDOPO interpretiert. Die Untersuchungen zeigen gute Übereinstimmungen zwischen Versuchs- und Berechnungsergebnissen. Die numerischen Modelle sind somit geeignet, das Verhalten von Abdichtungsbauwerken aus hochverdichtetem Bentonit zutreffend zu beschreiben. RÉSUMÉ: Une possibilité pour fermer un dépôt final de déchets radioactifs dans sel gemme est la construction d'un étanchement de coupe transversale, fabriqué de bentonite fortement compacté. Pour étudier le comportement de gonflement de bentonite fortement compacté, de nombreux essais en laboratoire ont été exécutés. En outre, des essais sur modèle sur une plus grande échelle ont aussi été exécutes afin de prouver le développement d'une pression de gonflement à peu près homogène et isotrope. Les résultats de ces essais sur modèle étaient interprétés en vue de l'absorption d'eau et du comportement contraintes-déformations par le moyen de calculs numériques avec les programmes d'éléments finis FEST03 et HYDOPO. Les études montrent de bonnes conformités entre des résultats d'essai et de calcul. Les modèles numériques sont ainsi capables de décrire justement le comportement d'ouvrages d'étanchement fabriqués de bentonite fortement compacté.

Jan 1, 2003

By M. Royker

Gold has been demonstrated as a possible catalyst for oxidation reactions. Some evidence for a possible promotion effect of platinum has also been recorded. The influence of platinum as promoter for Au/?-Al2O3 prepared via anionic ion-exchange for the oxidation of glycerol was investigated in a batch reactor at 60°C. It is inferred that the addition of platinum reduces the catalytic activity and therate of deactivation, resulting in an overall higher final conversion of glycerol with increasing platinum loading. The addition of platinum to the catalyst favours the formation of the desired product, glyceric acid.

Jan 1, 2012

By Kurt RP Petersen, Hendriena van der Walt

With the decline in fine diamond production from the Argyle mine in Australia, there is a greater emphasis on efficiently treating the finer size fractions through a DMS circuit. Although it is generally well understood that smaller diameter cyclones are more appropriate for this application, practical results do not necessarily meet this expectation. In this paper the operational performance of particular sized cyclones throughout the group was compared. Based on the results there is evidence that under certain practical operating conditions, small cyclones are not necessarily best for fine size particle treatment, particularly given the production pressures faced by all mines. However, there seems to be considerable merit in using larger sized cyclones, which tend to exhibit less performance variability, irrespective of operation conditions.

Jan 1, 2006

By M. W. Hildyard, M. O. Kataka

Seismic integration schemes aim to incorporate the rock mass response provided by the historical seismic activity to improve the ability of numerical models to reproduce future response to mining. Up to now, integration schemes considered the events using quasi-static models. This paper presents case studies that consider some of the seismic and modelling issues needed to extend these schemes to include the dynamic characteristics of seismic events. The ultimate aim of an automated integration scheme seems impractical for dynamic modelling. The predictions of the WAVE elastodynamic finite difference program are, however, suitable for modelling limited numbers of events to determine either the near-field velocities and damage or the effect of fractures and excavations on the far-field low frequency response. Les projets d’intégration sismique ont le but d’incorporer la réponse de la masse rocheuse à l’activité sismique historique pour améliorer la capacité des modèles numériques à reproduire la réponse future à l’exploitation minière. Jusqu’à présent, les projets d’intégration étudiaient les évènements avec des modèles quasi-statiques. L’étude présente révèle des études de cas qui considèrent certaines des questions concernant modelage et séismes qui sont nécessaires pour porter plus loin ces projets en incluant les caractéristiques dynamiques des évènements sismiques. Le but final d’un projet d’intégration automatisé semble impraticable pour la modélisation dynamique. En revanche, les prédictions du programme élastodynamique par la méthode des différences finies WAVE sont appropriées à la modélisation d’un nombre limité d’évènements de façon à déterminer soit les vitesses à petite échelle et les dommages, soit les effets des fractures et excavations sur la réponse de basse fréquence à grande échelle. Seismische Integrationsschemata zielen darauf ab, Reaktionen der Gesteinsmasse, die von den Berichten seismischer Aktivitäten stammt, zu inkorporieren um numerische Modelle in die Lage zu versetzen, künftige Antwort zum Bergbau zu reproduzieren. Bis dato betrachteten Integrationsschemata die Fälle mit quasi-statischen Modellen. Diese Arbeit stellt Fallstudien dar, die einige der seismischen und modellierenden Fragen betrachten, die benötigt werden, um diese Schemata auszuweiten, um die dynamischen Charakeristika seismischer Fälle einzuschließen. Das Endziel eines automatisierten Integrationschemas erscheint für das dynamisches Berechnen undurchführbar. Die Vorhersagen des WAVE elastodynamisch begrenzten Unterschiedprogramms sind jedoch verwendbar für das Berechnen von begrenzten Anzahlen von Fällen, um entweder die Nahfeldgeschwindigkeiten und Schaden oder den Effekt von Brüchen und Extraktionen auf der Fernfeld Niederfrequenzantwort festzustellen.

Jan 1, 2003

By Garry M. Johnston, Matthew L. Sutcliffe, Nicholas J. Welham

"The predominant current processes for the treatment of oxidized copper–cobalt ores use a reductive acid leach to bring the desired metals into solution. However, the indiscriminate nature of acid leaching results in a solution, akin to a metal soup, containing not only the Cu and Co but also an extensive suite of other metals. These other metals, notably Fe, Mn, Al, Ca, Mg and Si, all have to be eliminated from solution before the copper and cobalt can be recovered. Generally precipitation processes are used, but these tend to result in significant losses of copper and/or more usually cobalt from solution, leading to reduced recoveries. The AmmLeach® process uses ammonia-based chemistry to selectively leach the target metals, leaving the rest behind in the leach residue. This approach eliminates any need to clean the solution of unwanted metals and the consequent metal losses. After solid–liquid separation, the leach solution is immediately subjected to separation and concentration of the copper and cobalt using solvent extraction and electrowinning. INTRODUCTION The Copper Belt extends through the northern part of Zambia and the southern province of Katanga in the Democratic Republic of Congo (DRC) and contains the richest and highest grade deposits of copper and cobalt remaining in the world. Whilst there are a number of mines that produce sulphide concentrates, using froth flotation, the largest deposits are those where near-surface sulphides have been weathered over time to form oxides. The oxides cannot be concentrated by conventional physical means to give high recoveries. Despite this, a number of dense medium separation plants have been installed and used to produce a higher grade concentrate which is typically exported (while the rejects, typically 2 to 3% Cu are stockpiled for treatment at a later date). These plants generally have low recoveries and can only be used on the dwindling supply of high grade materials. In exporting the concentrate, little value adding is undertaken within the country, thus greatly reducing the economic benefits to the country. Recent changes to the regulations in the DRC will effectively ban the export of low value ores, concentrates and intermediates in favour of high value metals. This will necessitate mines to install new processing circuits in order to comply with these regulations. The head grade of ores currently being treated in the DRC is slowly decreasing as the extremely high grade materials are being selectively mined out. In many cases, the removal of a small volume of high grade materials leaves a much larger volume of economically marginal ore behind. This is due to a desire for short-term profits overtaking long-term prosperity. The remaining ore, which in many cases is still of relatively high value by world class standards, is likely to be only treatable by low cost heap leaching. There are some initial trials of heap leaching within the DRC, but implementation at a large scale has yet to be adopted."

Jan 1, 2015

By R. Burger, M. Masukawa

Cato Ridge Alloys (CRA) is a joint venture company between Assmang of South Africa, Mizushima Ferro Alloy Company (MZK) and Sumitomo Corporation from Japan. Negotiations for the formation of the company started in 1992 with the joint venture agreement signed on the 19th September 1996. MZK was to supply the technical know how for the production of Medium and Low Carbon FeMn while Assmang was to manage the day to day activities of the company. Sumitomo Corporation was to act as facilitator between Assmang and MZK and, together with Ore and Metal are responsible for the marketing of the refined products. The conceptual design of the plant started in December 1996 and the first charge of molten high carbon ferromanganese metal was charged on the 19th January 1998. Problems experienced during the initial startup period were addressed resulting in substantial operational improvements. A build-up in the stock of fine metal was addressed through the development of a process to remelt the fine metal, the development of a market for fine metal and the upgrading of the crushing and screening plant to reduce the generation of fine metal. The mass yield from High Carbon Ferromanganese to Refined Ferromanganese was increased through the implementation of statistical process control, changes to the blowing patterns and the development of a sampling device for taking samples during the process. Converter refractory consumption was reduced. This was achieved on the converter by improving the cooling of the converters with the installation of cooling fans and cooling fins. The heating schedule of the converters was changed for improved refractory life. Production schedules were modified to allow cooling of the refractory between low carbon erromanganese charges. Additional changes made to improve operations were: ? Changing from mehanite casting trays to metal fines beds. ? Installation of sonic horns in the baghouse to prevent the bridging of dust. ? Improved welding on the lance tips.

Jan 1, 2004

By D. Yu. Paleev, O. Yu. Lukashov, A. Yu. Krainov, E. R. Shrager, I. M. Vasenin

The gas-dynamic method is presented of calculation of explosion-proof distances during an explosion of the methane-air mixture in mine working. On the basis of this method is modelled of shock waves interaction with explosion protective parachute partitions, obstructions and water barriers. Calculations have been carried out of attenuation factors of shock waves during their interaction with explosion protective structures, arranged near conjugation zones of mine workings. Possibilities have been analysed of suppression of intensity of shock waves and of propagation of shock waves control in mine working network of coal mines by installation of explosion protective structures.

Jan 1, 2003

By Jacolien P. Wyethe

Zincor uses a Roast-Leach-Electrowinning circuit to process zinc sulphide concentrates. It also processes zinc oxide fume, originating from a slag smelting operation in the Democratic Republic of the Congo (DRC). Zincor achieved an average zinc recovery of 90.3% during the period January 2006 to May 2007. The bulk of the losses occurred in the iron and lead silver residues, both as soluble and un-dissolved losses. The un-dissolved losses in the iron residue constituted around 33% of the total zinc lost from the circuit, and were largely attributed to the presence of zinc-ferrite in the calcine used for neutralization during iron removal. As part of Zincor?s continuous improvement programme, the un-dissolved zinc losses in the iron residue were targeted by: the partial replacement of calcine with zinc oxide fume (from the DRC); and the preferential use of ?low-ferrite content calcine? as neutralizing agents in the iron removal circuit. These initiatives, coupled with other operational factors, resulted in a marked improvement in recovery to 92.6% during June to December 2007. The zinc oxide fume, directly fed to the circuit, required investigation of the halide rejection capacity of the Zincor circuit. Rejection of chloride via the magnesium bleed operation was considered adequate. Fluoride was mainly rejected via the iron (~70%) and lead silver (~27%) residues. Fluoride rejection via the lead silver residue varied significantly, probably as a result of variations in the sparingly soluble CaF2 content in the feed. The mechanism for fluoride rejection in the iron residues is uncertain. The fluoride rejection capacity of the Zincor iron residue (comprising of mainly jarosites, schwertmannite and ferrihydrite) at 2 ? 4 mg/L F in solution, was estimated at 0.14 ? 0.19 kgF/tFe residue.

Jan 1, 2008