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By K. J. Stratford

The selection of a suitable mathematical function for the modelling of the partition curve for dense medium cyclones is discussed. Five alternative functional forms (based on three basic functions) are compared using data obtained in the course of an extensive experimental study of a 610mm dense medium cyclone. It is shown that, for adequately sampled tests, any of the functions may be used, although a function based on the Weibull distribution is shown to be most suitable. Where data are poor, all functional forms exhibit disadvantages, notably in terms of a reduction in precision of parameter estimation. This problem can be exacerbated by the complex numerical techniques required to estimate the parameters of a particular function. A set of ideal requirements for a performance function are presented.

Jan 1, 1986

By Thomas C. Wilder, Firoze E. Katrak

As part of a survey on the long range supply of gallium, a comprehensive review of the chemistry of commercial gallium extraction was undertaken Owing to its very small concentration in all commercial minerals, gallium can be produced economically only as a by-product of major extraction processes for other materials. A summary is presented for the chemistry of gallium extraction from many of these process streams included are several procedures for gallium recovery from bauxite, currently the most prevalent source Other processes described are from waste streams from the production of zinc, phosphorus from phosphates, aluminum from kaolin clays, and from coal ash, the largest potential resource A brief review of development of solvent extraction as a unit process for gallium recovery is also presented

Jan 1, 1983

By R. J. Sawyer

*An earlier version of this paper was presented at the IMM meeting, "Use of Cultivated Carbon in Extraction of Gold and Other Metals," held in London in January, 1983, and was subsequently published in Trans. IMM (Sect. C: Mineral Process. Extr. Metall.) in December, 1983. Reprinted with permission of The Institution of Mining and Metallurgy, London. INTRODUCTION This paper describes the development of the processing route for the Alligator Ridge Mine which commenced operation in 1980. It also reviews the modifications which have been made to improve operating efficiency during the three years that the mine has been in production. Alligator Ridge is located 70 miles Northwest of Ely, Nevada. The mine is a joint venture between Amselco and Nerco with Amselco acting as operator. The deposit consists of micron sized disseminated gold imbedded in siltstone. Although definitive conclusions have yet to be drawn as to the age and origin of the deposit, it is probable that it is young by geological standards, perhaps only 5 million years old. It is likely that the gold was brought to the surface by hot springs. As the superheated solutions rose through the porous siltstone, they redeposited minerals in the rock, forming the present ore bodies.

Jan 1, 1984

By Yannis Faitakis, Brenda M. Wright, Gail Powley, Mark Hamblin, Randy B. Paine

A major problem in the ore extraction process is the high degree of variation in the mix of materials that make up the mined ore. The mix of materials makes it extremely difficult to characterize and predict the behavior of the ore when it is processed. The Quality Production Database (QPD) tool was successfully used in order to predict and transfer information regarding the quality characteristics of the ore being delivered to the extraction and hydrotransport unit operators. This paper describes the use of QPD in the prediction of various ore characteristics at the Syncrude Canada Ltd. processing facility.

Jan 1, 2000

By Haydn H. Murray

The three major catalyst markets that utilize industrial minerals as raw materials are petroleum refining, chemical processing, and emission control. Because of economic, competitive, and regulatory pressures, catalyst producers are pushed to develop products with improved performance to meet changing environmental standards. Also, refiners are demanding new families of cracking catalysts that will crack residual fuels. In 1987, worldwide cracking catalyst sales amounted to $457 million (Occelli, 1988a). Recently enacted federal and state laws to improve air quality have prompted strong growth for environmental catalysts, which in 1989 accounted for more than a third of the $1.9 billion catalyst market in the United States (Farrauto, Heck, and Speronello, 1992). A catalyst is a material that promotes or enhances a chemical reaction but does not itself enter into the reaction. One of the more important mineral groups used as catalysts is clays. The first recorded use of clay as a catalyst was its use in the dehydration of alcohol (Bondt et al., 1797). Clay minerals that are used as catalysts are kaolinite, halloysite, smectite, palygorskite, and sepiolite. Minerals used as catalysts, catalyst supports, or as a raw material to make zeolites are kaolinite, halloysite, sodium montmorillonite, calcium montmorillonite, hectorite, palygorskite, sepiolite, talc, calcined kaolinite, gibbsite, chlorite, and titanium dioxide.

Jan 1, 1994

By Hajime Miki, Michael J. Nicol

Relatively simple techniques have been developed which enable the electrochemistry of sulfide minerals to be studied with particles varying in size from above 100 pm to less than 1 pm. Both oxidative and reductive processes have been studied wing the minerals pyrite, arsenopyrite and chalcopyrite. It has been shown that it is possible to completely oxidise or reduce the minerals during a single voltammetic sweep. The resulting voltammogram produces peaks which are characteristic of each mineral and can be used to qualitatively identify the minerals. In the case of chalcopyrite, it has been demonstrated that the charge involved in the anodic oxidation can be quantitatively related to the amount of copper dissolved. Quantitative information can be obtained using peak fitting techniques. Interesting differences in the behaviour of the minerals in sulfuric and hydrochloric acids have been observed, particularly in the case of pyrite for which a second major peak is obtained which has been attributed to the oxidation of elemental sulfur in the presence of chloride ions. The technique offers the possibility of providing mineralogical information of individual particles based on an electrochemical voltammetic finger print.

Jan 1, 2005

By J. W. Leonard, C. L. Jiang, B. K. Parekh, X. H. Wang

The selective depression of pyrite from the Kentucky No. 9 coal seam was systematically examined using various kinds of inorganic and organic chemicals. Most of the organic chemicals tested showed little selectivity in pyrite depression. It was found that both orthophosphate and pyrophosphate were effective for the selective depression of coal pyrite in coal flotation using fuel oil as a collector. At substantially low concentrations of pyrophosphate, the flotation of coal pyrite was completely depressed over a wide pH range, while the coal flotation remained unaffected. The mechanism of the selective depression of pyrite by phosphates was explained with the help of thermodynamic calculations of iron-phosphate-water systems and zeta-potential measurements. It was shown that pyrophosphate reacts strongly with the iron ions of pyrite to form stable hydrophilic iron pyrophosphate complexes on pyrite surfaces.

Jan 1, 1999

By Tim Neil, O&apos

Introduction Compania de Carbones de Chile (Cocar SA) has brought into production Chile's first large-scale, open-pit coal mine, located in the Magellan Province. The US $65 million project includes a 1.1-Mt/a (1.2-million stpy) subbituminous steam coal mine and a mechanized bulk loading marine terminal with water depth sufficient to receive 60 kt (66,000 st) Panamax vessels. The loading terminal will be one of the largest in Chile. The Pecket coal project is expected to save Chile about $40 million in energy production costs and a further $100 million in oil imports, or about 25% of the country's oil import costs. Pecket coal will generate electricity for Codelco and will also supply general electricity needs for northern Chile. The Pecket coalfield is located on the Brunswick Peninsula, about 30 km (19 miles) northeast of Punta Arenas, the provincial capital, as shown in Fig. 1. Pecket is part of a large, coal-bearing basin. It extends from Punta Arenas 250 km (155 miles) north to Puerto Natales and across the border into the Rio Turbio coalfield in Argentina. A fleet of large and small O&K hydraulic shovels and backhoes is used to dig and load overburden and coal into mining trucks while O&K graders maintain the haul roads in and around the pit. Coal occurrence in the Magellan area of Chile has long been

Jan 1, 1988

By D. Elsworth, M. Bai

The influence of mining on the hydro-geo-mechanical environment can be greatly modified by alternating mining geometries. The limiting magnitudes of surface subsidence and groundwater flow over the mining area, as a result of mine geometric changes, can be reasonably predicted through the coupled finite-element model introduced in this paper. The model has been verified using real and conceptual case studies which reveal that changes in strata conductivities are strongly related to the strata deformation induced by mining. The greatest modification of hydraulic conductivities occurs within the caving or severely fractured zones. The study indicates that narrowing the panel face width will substantially reduce both the intensity and extent of mining damage to the overlying strata, limit surface subsidence and constrain the change in hydraulic conductivity to a reduced scale and smaller extent, particularly as mining depth increases.

Jan 1, 1995

By R. E. Johnson, W. Kat, B. R. Palmer, van Sandwijk A., G. Van Weert, S. Honingh

In-plant recycling of dust from iron making BF's creates undesirable circulating loads of volatile trace elements such as zinc and lead. Disposal of such dusts creates environmental problems, hence a separate treatment is indicated. Since the bulk of the zinc and lead compounds occurs in the fine dust fraction; hydrocycloning the slurry from the BF gas cleaning operation results in upgrading the material for treatment. A process has been proposed, whereby the zinc and lead are solubilized from the fine fraction with spent hydrochloric acid from steel pickling. The stoichiometry of this autoclave oxidation process is adjusted to simultaneously precipitate, by oxyhydrolysis, most of the iron for recycling to the BF's. Lead and zinc are successively recovered from the filtrate as low chloride precipitates. This paper describes additional testwork, leading to the design of a pilot plant which was planned to begin operation in 1992.

Jan 1, 1993

By N. Choi, W. D. Cho

Distribution coefficients of gold and silver between matte and slag during the pyrometallurgical treatment of nickel-copper sulfide concentrates were evaluated as a function of matte and slag compositions in the temperature range of 1,250oC to 1,300oC. It was observed that the composition of the matte phase, including matte grade and copper content in the matte, significantly affected the distribution behavior of gold and silver in the matte-slag system. Both gold and silver preferentially concentrated in the matte phase as the matte grade increased With increasing temperature and copper content in the matte, the distribution coefficients of silver increased, while the gold distribution coefficients decreased. It was also, found that slag additives such as CaO, MgO, and A12O3 caused a significant decrease in the solubility of both gold and silver in silica-saturated iron silicate slag. An activity coefficient of gold in matte was derived from the experimenta1 results.

Jan 1, 1999

By M. S. Janssen

The development of a design equation for, and the testing of, a constant- flow airlift pump IS described. The predictions of the new airlift model agree with the results of experiments carried out using riser diameters between 0.025 and 0.300 m, submergence depths between 5 and 10 m, suspension densities between 1000 and 1650 kg/m3, and a solids dg of 70 to 100µm. The predictions o the model also agree with data from the literature for submergence depths that reached 130 m. This airlift model was employed to simulate the pulp flow through a series of tanks, each of which was fitted with an airlift pump to transfer the suspension to the next tank. Particular attention was paid to the riser diameter, submergence of the airlift pump, and control of the air supply to the airlift pump during the simulated operation of a series of tanks. The results of the simulation highlight some design parameters that could affect the efficiency and operation of a plant that employs airlift pumps to transfer suspensions.

Jan 1, 1989

By M. Stefanakis, A. Kontopoulpus, K. Adam

The application of Bacterial Oxidation as a pretreatment step for the extraction of gold from the Olympias refractory pyrite concentrate is described. A wide review of Bio-oxidation is presented focusing on the current process developments and commercial applications relevant to the treatment of gold bearing sulphide ores and concentrates. Preliminary batch and semi- continuous tests on the Olympas concentrate indicated that with Bacterial Oxidation quantitative gold liberation may be achieved. fie effect of such parameters as pH, Eh, temperature, particle size, operating pulp density and retention time on the extent of sulphur oxidation and subsequent gold extraction by conventional cyanidation are also examined. Finally, a preliminary evaluation of Bacterial Oxidation as a potential process alternative for the treatment of the Olympias concentrate is presented.

Jan 1, 1989

By D. A. Stanley, B. J. Scheiner

The U.S. Bureau of Mines has thoroughly investigated the flocculation of phosphatic clay waste with polyethylene oxide (PEO). The studies included both theoretical and applied aspects of the flocculation sequence. The screen dewatering technique developed by the Bureau was field tested at four different Florida phosphate mines. The results of these field studies are presented. Also, to determine the mechanisms of the interaction of PEO with montmorillonite clays common to the phosphatic clay waste, a number of theoretical studies were conducted. An empirical equation was developed to describe the amount of PEO needed for flocculation. Infrared, ion exchange, and rheology techniques were used to study the interaction of PEO with Florida clays. The results of these studies are also presented.

Jan 1, 1993

By Jianping Sheng, Francis Otuonye

The potential for methane and coal dust explosions in underground coal mining operations has increased in recent years with the introduction of fast coal-cutting machines. Dust explosions usually follow accidental ignition of a methane pocket. The dynamics of the explosion may be strong enough to pick up and disperse coal dust deposited on mine surfaces and ignite the mixture. A self-sustaining dust explosion can then develop and propagate at large distances. Ignition of dusts can result in a fire, and this may also lead to a dust explosion if the burning dust becomes airborne. Entrainment of dust and the resulting dust concentration in the gas stream are some factors which determine the features of the subsequent explosion and flame propagation. A model of coal dust transport in the gas stream due to the initial explosion is presented. In this model, equations for the conservation of mass, momentum and energy are coupled with the convective-diffusive model of dust transport. The system of equations is solved numerically to obtain dust concentration, convective velocity and gas pressure profiles.

Jan 1, 1989

By Lijun Xu, Ragula Bhaskar

The transport of dust particles from a turbulent air stream on to the surface of a mine entry is mainly due to the effect of diffusion, sedimentation and inertial impaction. While the literature in aerosol science contains many references on particle deposition, most studies apply to smooth surfaces in small, short tubes. The deposition data from those experiments may not be applicable to deposition in mine airways that have large areas of rough surfaces and extend several thousand meters. This paper describes the mechanisms of mine dust transportation and deposition, specifically, by estimating the turbulent deposition velocity for coal dust in mine airways. Data from in-mine experiments on ambient dust concentration and dust deposition along a straight entry were used. A statistical model for dimensionless turbulent deposition velocity was developed, and compared with the models developed by other researchers. The model shows that the distance from the dust source is an important factor in the turbulent deposition of mine dust.

Jan 1, 1995

By M. W. Rutland, E. Manev, R. J. Pugh

Data collected from several different fundamental surface chemical techniques were compared to study the interfacial interactions in the dodecylaminelmica flotation system. In the present study, the method used was the microinterferometric free foam film technique of Scheludko (1967) in which the stability, thickness and interfacial potentials at the air/dodecylamine solution interface were determined. These results were compared to previously published data, obtained from surface force measurements (Rutland et al. 1992), in which the interaction and hydrophobic adhesion (pull-off force) between molecularly smooth mica sheets in the amine solution had been reported. Also equilibrium contact angle measurements were used for comparison. The data was collected over a range of pH values and related to the batch flotation response of mica in dodecylamine solution. It was found that maximum flotation occurred at pH 8, but this did not correlate with the minimum in double layer interaction potential. However, it appeared to correspond with a tightly packed collector monolayer giving maximum hydrophobicity to the mica surface. Finally, from the extended DLVO theory, it was shown that heterocoagulation between the bubble and the mica could only occur, providing there was a very long range hydrophobic interaction force to counterbalance the repulsive van der Waals and electrostatic forces.

Jan 1, 1995

By J. K. Ahlness

The US Bureau of Mines investigated technologies for determining the integrity of in situ leach mining wells. A self-contained trailer-mounted well integrity testing system (WITS) was designed and built to enable rapid testing of well casings for leaks as required by environmental regulations. The WITS utilizes two inflatable packers to seal off the entire casing length or any portion thereof. Water pressure is built between the packers to the desired test pressure, and the presence or absence of casing leaks is determined by monitoring the pressure drop between the packers. A winch and steel cable are used to run the packers in and out of the well. The WITS underwent an industry field test at the Irigaray in situ uranium leaching mine near Buffalo, WY. A total of 37 wells with an average depth of 69 m (225 ft) were tested at an average rate of four wells per eight-hour shift with a two-person operating crew. This represents a 75% time savings and an 83% labor savings compared to the rigid-pipe method previously used at the mine, with which a three-person crew tested an average of one well per shift.

Jan 1, 1988

By Gary Buchan

During several months in 1996 and 1997, Cyprus Twentymile Coal Co. (TCC) set world production records at its Twentymile Mine in northwestern Colorado. These records were due to the company's implementation of a state-of-the-art longwall mining and conveyance system along with a -highly dedicated work force. This article is a case study of the design of long panels at the mine from conception to implementation. Obstacles that needed to be overcome included subsidence engineering, environmental regulations, conveyance, ventilation, equipment design and continuous miner (CM) development timing.

Jan 1, 1998

By H. Bernatowicz

The Nucoalyzer (On-Line Nuclear Analyzer) is a new method recently made comercially available for monitoring the elemental composition of a process stream. Applications for the Nucoalyzer include grading ore on a conveyor belt before or after it has gone through primary crushing, monitoring the slurry being transported in a pipe to the concentrator, and monitoring the stream of concentrate or the tailings from the concentrator. The Nucoalyzer may also be used at the smelter to monitor elements in the feed that include copper, sulfur, iron and silicon where a uniform feed is desired. The advantage of the Nucoalyzer over most other techniques are (a) it performs the measurement directly on the process with no sampling necessary, (b) the analysis can be performed on streams of particulate and slurries, and (c) the system does not have to make contact with the material it measures. These Nucoalyzers are operating at coal fired power plants and several more are about to be placed in service. This paper discusses the principles of operation of the Nucoalyzer, our experience in the field, application of minicomputers to data reduction, and potential applications in the ferrous and non-ferrous industries.

Jan 1, 1982