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By K. I. Cunningham, C. S. Spirakis

Two types of native sulfur deposits have been found in Lechuguilla Cave: thin late-stage crusts and massive early- formed deposits. Most, if not all, of the crusts appear to have formed by remobilization of native sulfur contained within gypsum and sulfur masses. The process is occurring today and is slowly converting the sulfur to gypsum. The absence of primary gypsum or reductants in the cave indicates that the early-formed massive sulfur deposits did not form by in-place reduction of sulfate, which is the process that formed the commercial sulfur deposits in the Delaware basin. Instead, it appears that H2S dissolved in basinal brines was oxidized by oxygen in near-surface ground waters in the cave. Fluid- inclusion data, which suggest the presence of both fresh water and saline water as the sulfur formed, support this interpretation. Although individual sulfur deposits in Lechuguilla Cave are no more than several tens of metric tons, the abundance of secondary gypsum (as much as 10 meters thick) indicates that native sulfur may once have been much more extensive.

Jan 1, 1992

By Gregory A. Hope, Kym Watling, Matthew I. Jeffrey, Ronald Woods

Surface enhanced Raman Spectroscopy carried out in real time has been applied to identify surface species formed during gold leaching in chloride and thiosulfate media. Chloride ion is adsorbed prior to the gold dissolution potential, but its coverage is significantly diminished at the beginning of leaching. A gold chloride band is again observed when dissolution is rapid, together with bands characteristic of AuC14- ions in solution. With thiosulfate, a thin gold sulfide layer is formed slowly in the potential region where leaching occurs. At higher potentials, thiosulfate is oxidized to sulfur and sulfate, both products being identified by Raman spectroscopy.

Jan 1, 2005

One of the major objectives of cost analysis is to enable the manager to predict the financial outcomes of decisions. To accomplish this, the future costs and benefits of alternative courses of action must be determined. If care- fully used, information about past financial performance can be helpful in this analysis despite the fact that, by definition, financial reporting information is historical. In many cases, both revenues and costs need to be estimated for decision- making. For the production manager, additional revenue is a result of increased throughput or recovery of valuable material from the stream of mined material. A reduction in operating cost, although similar to a revenue increase in its financial impact, is estimated using slightly different techniques. Generally, the estimation of cost is more difficult than the estimation of revenue. Most cost estimates have two components: an estimate of fixed costs and an estimate of variable costs. As discussed in chapter 5, the total cost of an activity during a specified period can be expressed as: Total cost = (Variable cost per unit of activity) x (Units of activity) + Fixed cost or TC = VX+F

Jan 1, 1999

By Fabio Amaya, Andrés Marulanda, Ramiro Gutiérrez, Alberto Marulanda

The behavior of a salt rock mass is strongly related to a creep phenomenon. The amount of creep depends on the level of stress generated in the underground excavation. Additionally, security conditions and the lifespan of an underground cavern excavated under this geological conditions depend on the evolution of creep. Based on the experience of the failure of the Old Underground Salt Cathedral of Zipaquirá(Colombia) and the construction of the new one, the theoretical framework to predict the creep behavior of a salt rock mass is explained. The theoretical formulations are calibrated based on actual observations of the material behavior to predict the lifespan of this striking structure.

Jan 1, 2003

By H. Y. Sohn, R. D. Hagni, M. K. Kojo

Reflected light microscopy was used to study the mineralogy and textures of experimental reactions of a nickel concentrate with a slag. Such an interaction is an important step in the bath smelting of nickel sulphide concentrate. Concentrate particles in the central portions of the pellets are rounded and develop vermicular S02 gas porosity. In the outer portions of the pellets, the original minerals of the concentrate, i.e., pyrrhotite, pentlandite, pyrite, chalcopyrite and violarite, have agglomerated and reacted to form two intergrown phases: pyrrhotite solid solution (FeO.75Ni0.18Cu0.01S) and pentlandite solid solution (Fe0.58Ni0.51Cu 0.03S). Magnetite formed euhedral crystals, skeletal crystals and dendrites at the margins of the matte. Prismatic, ferrohypersthene and octahedral Mg-Al-Fe spinet crystals and dendrites are present in the glassy slag. Key words: Nickel sulfide concentrate, Iron silicate slag, Bath smelting, Mineralogy, Microscopy

Jan 1, 2003

By A. Shakoor, A. M. Hirt

The compressive strength of coal, and its variation within and between seams, was determined for four Pennsylvania coal seams (Pittsburgh, Sewickley, Upper Kittanning and Lower Kittanning). Large coal blocks were obtained from 12 coal mines (three mines per seam) and cut into 50-mm (2-in.) cubes using a low-speed saw. The cubes were tested for compressive strength, with the results used to compute actual pillar strength. Using the tributary area approach, the pillar stress was determined. The pillar stress and strength data were used to calculate the factor of safety against pillar crushing for each mine. The cube strength was also correlated with various physical and chemical coal properties (density, percent absorption, percent ash, percent sulfur and percent carbon) to see if any strong relationships exist. The coal's mean compressive strength varies from 9.1 MPa (1326 psi) in the Lower Kittanning seam to 37.8 MPa (5480 psi) in the Pittsburgh seam. Between different seams the pillar strength varies from 29.5 MPa to 48.1 MPa (4282 psi - 6981 psi). Although coal strength appears to be weakly related to carbon content, no relationship was found between compressive strength and other physical or chemical properties. Since the values for the safety factor against pillar crushing generally exceed the recommended value of two, the existing pillars are mostly overdesigned. This implies that an accurate assessment of coal compressive strength could result in the use of smaller pillars and, thus, increased coal production.

Jan 1, 1993

By R. Y. Wan, J. D. Miller, P. L. Sibrell

Three different refractory carbonaceous gold ores from the Carlin operation in northeastern Nevada were investigated to characterize the effect of passivation treatments on the nature of the carbonaceous material. The carbonaceous material was chemically isolated from the ores and passivated residues, and examined by FTIR spectroscopy, elemental analysis, and gold adsorption capacity. The main component of the carbonaceous material in these ores was found to be a naturally occurring activated carbon-type compound. Hydro-carbons were detected on rare occasions, but no evidence was seen for humic acids. Ore samples were passivated by autoclaving, or by treatment with sodium hypochlorite or gaseous chlorine. In some of the passivation tests, a new peak was observed in the IR spectra of the isolated carbonaceous material, that was due to carbonyl functionalities. However, all of the passivation treatments tested decreased preg robbing significantly. This suggested that the appearance of the carbonyl peak was due to the severity of the conditions during passivation, rather than the method used.

Jan 1, 1990

By A. W. Scaroni, C. Y. Tsai

The effect of particle size and composition on the pyrolysis and combustion of a pulverized bituminous coal in an entrained-flow reactor has been investigated. Predicted time-temperature histories of the coal particles and experimental weight loss data indicate a strong coupling of heat and mass transfer to the pyrolysis and combustion rates. A higher combustion rate following ignition was observed as particle size was increased to 112 µm (about 140 mesh). This is related to a higher particle temperature after ignition for the larger particles. Although the heating rate before ignition decreases with increasing particle size, higher slip velocities and surrounding gas temperatures for the larger particles promote early ignition. The presence of liptinite in the coal increases the weight loss rate before and immediately after ignition. Similar behavior was observed for pyrolysis. Fractions of an HVA bituminous coal that were rich in mineral matter or semi-fusinite were found to have a higher heterogeneous char combustion rate than vitrinite-rich samples.

Jan 1, 1987

By Joseph W. Kupfner

It is a recognized fact that a good maintenance program is a pre-requisite for minimum delay costs and maximum availability of equipment. To develop such a program and to make it effective, one must establish detailed instructions pertaining to inspections, lubrication, servicing, and/or replacing of various parts. A schedule must also be established for these maintenance checks, whether they be weekly, monthly, or whatever period is essential for the equipment. The number of tasks to be performed becomes monumental, and the administration is beyond error-free human capacity. It is for this reason that the computer must be an essential element in any efficient and economical preventive maintenance program. The evolution of a computerized maintenance program began some 18 years ago in the Mining Division of USSteel. It started with a manual system of preparing cards containing preventive maintenance instructions that had to be performed on some regular basis. We were very quickly overtaken by the massive task of administration and distribution of instruction cards to the users. The task became insurmountable as more mines were added to the system, mines that were spread over a large geographic area. It also became evident that the ability to make changes in equipment assignments and in the "what to do" instructions would require more time than had been anticipated.

Jan 1, 1986

By Arthur E. Lord, W. Martin McCabe, Robert M. Koerner

Following the driving of each new section of tunnel, a prompt decision is required regarding the type and extent of primary support to control convergence and prevent ground failure. Sometime thereafter, the effectiveness of the in-place support must be evaluated over the entire length of excavation. It is therefore extremely desirable to have available a lightweight, portable, easy to install and interpret, cost effective monitoring system to assist with these ground control functions. Such a system can be assembled based on the acoustic emission (or microseismic) technique. This monitoring technique uses a piezoelectric transducer to detect subaudible noises associated with deformation of and/or crack propagation in the soil or rock being monitored. After detection, the signals are then amplified, filtered and electronically counted to provide a quantified assessment of the stability of the structure. In the simplest sense, the absence of emission, or counts, signifies no deformation and thus stability. Conversely, the occurrance of counts signifies instability to varying degrees. The higher the count rate, the greater the instability and the need for immediate or additional support. Described in this paper is an overview of the acoustic emission (microseismic) method, details of its use in a laboratory study measuring convergence and stand-up time in soil, and the behavior of rock samples under similar stress conditions. Field use of the method is recommended for ground control monitoring in tunnels, and some suggestions regarding monitoring procedure are presented.

Jan 1, 1979

By A. M. Al Taweel, S. M. El Mofty, T. A. Hassan, M. R. Moharam, A. M. Ramadan

The axial mixing characteristics of a pilot-scale flotation column were investigated with the objective of identifying means to mitigate the extent of axial mixing that adversely affects its grade/recovery performance. A wide range of design and operating conditions was investigated and the experimental results, obtained using the dynamic response method, were analyzed using three axial mixing models. The dynamic response of the column can best be described using the axial dispersion model. The results obtained suggest that the value of the axial dispersion coefficient, EL. can be signi6cantly reduced by judicial selection of hydrodynamic conditions and/or the use of column inserts that suppress the onset of hydrodynamic instabilities inherent to the operation of conventional flotation columns. Up to 40% reduction in the value of EL was thus obtained by using spargers that produce more uniform bubble sizes, while up to 30% reductions were obtained by controlling the residual frother concentration.

Jan 1, 1995

By G. Reed Marchant

In 1967 the US Congress passed the "Clean Air Act." This act was amended in 1970. As a result it soon became obvious that American industries were going to have to make significant changes in their methods of operation to be able to comply with quickly developing federal regulations. One of the first regulations developed was on sulfur dioxide. For this reason, the nonferrous smelting industry was immediately affected by these new regulations. This is true because the smelting process produces sulfur dioxide as a natural product of combustion when the sulfur-bearing ore is oxidized to purify the metal. The federal government's approach for setting standards included public hearings at which government, industry, and private citizens were allowed to make comments. For this reason, it was apparent to Kennecott's Metal Mining Div. that it was desirable to make a maximum effort in working with the agency to see that correct input was provided at the hearings to assist the government in setting fair and realistic standards. It was also obvious that more complete monitoring would be required. It soon became apparent that the efforts required input from many levels of the corporation from the chief executive to the plant operators. In order to accomplish both the administrative and the technical needs, an organization was needed that could respond quickly to these needs, obtain information from diverse sources, and bring it to focus in an organized approach to the problem.

Jan 1, 1979

By N. Colvin, J. W. Gulyas

HISTORY The Surigao Nickel Refinery of Marinduque Mining and Industrial Corporation is located on Nonoc Island off the northwestern coast of Mindanao in the Philippines. Nonoc Island is part of the Surigao Mineral Reservation which had been identified as early as 1912. Initial interest in these deposits was due to their iron content, and their value as a nickel deposit was not seriously entertained until the late 1950's. The Philippine government undertook extensive test pitting and sampling programmes at that time and in the early sixties Marinduque became involved in helping to establish firmer ore reserves. Evaluations of the test pitting programme indicated reserves of 75,000,000 tonnes of ore averaging 1.22% Ni, 0.1% Co and 38.5% Fe. The Philippine government called for bids on the reservation in 1962 and Marinduque and Sherritt Gordon carried out some feasibility studies for the recovery of nickel from the deposit. However, it was not until 1968 that Marinduque was granted proper authority to exploit the Surigao deposits. Marinduque and Sherritt then entered into an agreement which allowed Marinduque to utilize a process developed by Sherritt for treating lateritic ores. During 1968, a 25 st/d pilot plant was erected in Fort Saskatchewan, Alberta for the purpose of modelling all process steps. A 10,000 tonne ore sample was sent from Nonoc as feed stock for the pilot plant.

Jan 1, 1979

By E. M. J. A. Pallone, F. N. Cunha, W. S. Resende, R. M. Stoll, R. C. Bradt

Utilization of the magnesium aluminate spinel in refractor' applications is briefly reviewed. The synthesis of a magnesia aluminate spinet aggregate from natural raw materials is considered in terms of the crystal chemistry of the spinet structure and expected impurities. Principles for the formation of this spinet refractory aggregate from different natural raw materials are presented. The basic concepts were then applied to the reaction of a bauxitic clay with a natural magnesite. This combination of raw materials has the potential to produce a low-cost refractor' aggregate that is a composite of spinel and forsterite. Experimental results are reported to produce a spinel refractor.' aggregate containing a small amount of forsterite. It possesses low apparent porosity and high bulk density suitable for industrial refractor' applications, including steelmaking, aluminum and copper foundries and cement production.

Jan 1, 2002

By Bruce W. Cavender, Brian L. Granger

The leaching characteristics of non-homogeneous ores have traditionally been difficult to assess in laboratory tests. A result of the large sample size necessary to ensure representativity, this difficulty is most acute for ores containing nuggets or other irregular occurrences of precious minerals. Consequently, small-scale leaching tests are often regarded as indicative rather than conclusive. The predictive nature of leaching tests can be improved by applying the experimental design concepts of blocking and randomization. In the case of column leaching, experimental 'blocks" are constructed with the same number of columns as there are separate test conditions. These blocks are treated identically throughout the test, with differences between columns within each block being the variables of interest. To maximize the uniformity of the blocks, randomization procedures are employed in the preparation of the sample and conduct of the test. The initial ore sample is screened and individual column charges composited from randomly selected increments from each size fraction. The leaching order, daily solution analyses, and processing of leach residues are similarly randomized. The observed differences in leaching performance between the columns in each block are compared to determine the over-all outcome of the test. A statistical analysis using t distributions gives a quantitative measure of the reproducibility of the outcome.

Jan 1, 1995

By Adrian Smith, Debra W. Struhsacker

There is now overwhelming evidence that, despite concerns to the contrary, natural degradation of cyanide and cyanide attenuation by hydrogeochemical processes are capable of minimizing or eliminating potential water qua1ity impacts from heap leach systems. A1 though there was some recognition of these data by the regulatory authorities, for example the initial USEPA modification of cyanide standards to an advisory level, many states have codified standards inappropriate to the clearly site specific nature of heap leach operations. As an overview to this problem, this paper will integrate the theoretical chemical data on cyanide with the observed geochemical behavior of cyanide in the decommissioned heap leach environment. The cyanide species that are likely to exist within an abandoned heap leach system will be identified, and the relative toxicity and potential environment effect of these cyanide species will be discussed. These data will then be used to evaluate cyanide detoxification regulations for decommissioned heap leach projects in 14 states.

Jan 1, 1987

By Krzysztof Filek, Anindya Sinha, Bernard Nowak

Taking into account the possibilities of condensation of water vapour contained in air during its flow through a series of spot coolers as well as formation of eventual fog, a mathematical model of dynamic temperature, specific humidity and degree of fogging of cooled air in underground mining galleries with direct ventilation is developed. In the gallery, there situated various heat and moisture sources both of distributive and of concentrated types. The model is represented by three partial differential equations of first order. The cases of cooling with full as well as with partial air stream flowing through the gallery are distinguished. Owing to the fact that in practical designing, more important is the knowledge of the variation process of temperature, specific humidity and fogging of cooled mine air at steady state conditions, the model is modified to a set of three nonlinear ordinary differential equations. Based on the presented algorithm, the obtained set of ordinary differential equations is numerically solved which enables to: • specify the distribution of temperature, specific humidity, relative humidity and degree of fogging of cooled air in mining galleries; • determine the cooling powers of air coolers for their known locations; • indicate the locations of the coolers of known cooling powers. Exemplary calculations of temperature and relative humidity of cooled air are presented graphically in a number of diagrams.

Jan 1, 1997

By Gordon R. Luster

Mineral-processing plants commonly rely on homogenization and proportioning facilities to reduce the variability of incoming raw materials and to blend different materials together to satisfy quality specifications. To determine appropriate designs for these facilities, plant designers need information about the variability of the mined materials, measured as the materials enter the plant. But if the materials to be mined in the future differ greatly from those used in the past, only information extracted from exploratory drilling of the materials in the around may be available. Fortunately, useful information for plant design may still be obtained by combining simulated mineral deposits with simulations of likely mining procedures. The output of a mining simulation is a time series of simulated raw-material characteristics that should mimic the behavior of the real materials to be delivered to the plant in the future. This paper shows how conditional simulations of coregionalized ore grades can furnish information useful in the design of homogenization and proportioning systems.

Jan 1, 1986

By J. E. Gebhardt, J. A. Herbst, K. Y. Lee

Benefits of proper control of reagent usage in flotation circuits are typically improved metallurgy and savings in reagent costs. Improved metallurgy can mean more consistent product quality, i.e., final concentrate grade, better recovery of product values from the feed, or higher plant throughput at existing target recovery, and grade values. Flotation performance is sensitive to a variety of process disturbances which occur in operating plants, such as changes in flow rate, percent solids, size distribution. flotability of mineral species, etc. A way to handle these variations is to fully understand the dynamic flotation responses to disturbances and to implement a suitable control strategy to compensate for these disturbances. Depending on the objectives of the control system, various types of control strategies are available which employ different levels of refinement to achieve the desired performance. Typically, variables such as collector and frother dosages and reagent addition points can be manipulated to affect the performance of the circuit. In the case of sulflde mineral flotation, manipulation of the process electrochemical potential, in flotation and in grinding, offers another degree of process control. Because of the complex and interactive nature of flotation process variables, optimized reagent control requires consideration of all, or at least the most important, interactive variables of the flotation circuit. Model- based optimizing control provides a framework to handle the complex and dynamic nature of flotation reagent process control.

Jan 1, 1994

By J. M. Dean, R. L. Grayson, R. D. Begley, G. L. Winn

Evidence has accumulated indicating that cultural change toward safer workplace behaviors is beginning to occur systematically in the coal industry. Through a range of programmatic mining company successes, enforcement and litigative actions, economic responses to competition and integrated efforts by federal and state agencies, a broader participation of safety and training professionals is being achieved to address prioritized workplace problems at mines. Small steps in workplace-related improvements have been realized already, but the trends in industry safety statistics, coupled with focused programmatic initiatives, indicate that more definitive and systematic steps are occurring to improve safe behavior in the workplace routinely.

Jan 1, 1998