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By Mulong Yu, Yosry A. Attia

Beneficiation of high magnesium Florida phosphates requires ultrafine grinding to liberate the dolomite (the main source of magnesium), and a separation process capable of dealing with ultrafine sizes such as selective flocculation. The objective of this study was to investigate the feasibility of separating dolomite from apatite ultrafines by selective flocculation. To achieve this objective, selective polymeric reagents to either dolomite or apatite must be first designed and synthesized. This challenging task was accomplished by carefully selecting complexing/chelating agents which are selective to either the Ca or Mg ionic sites on the minerals, and incorporating these reagents into the structure of long chain water soluble polymers to obtain either selective flocculants (with high molecular weight, MW, polymers), or selective dispersants (with low MW polymers) to either the dolomite or the apatite particles. Synthesis and testing of these polymers on individual and mixed mineral slurries, and on a sample of natural high magnesium phosphate ore, have been attempted and the results are described in the paper. The preliminary results showed encouraging signs for the feasibility of selective flocculation separation of dolomite from apatite.

Jan 1, 1993

By Richard C. Smith, Steven H. Brown

Commercial scale in-situ leach uranium facilities (i.e., solution mining) have operated since late 1975, and have begun to appear in increasing numbers in the last few years. Solution mining involves the pumping of ground water, fortified with oxidizing and complexing agents, into an ore body, leaching and solubilizing the uranium in-situ, and then pumping the solutions to the surface where they are fed to a mill. Milling is by conventional means, involving ion exchange, precipitation, calcining and packaging processes. This paper presents an overview of the solution mining process, and discusses an empirical method that has been used to determine the radon gas release rate in Bq (curies) per year for the overall operation of the facility including wellfields, milling processes and waste storage reservoirs. In addition to radon generation on the surface from radium decay, it has been determined that the major component of radon release is associated with the dynamic generation of radon from solutions returning from underground. Process parameters impacting this evaluation and the mathematical expressions developed are discussed. The preliminary data accrued is presented.

Jan 1, 1981

By Malcolm J. McPherson

Mine shafts that are used as primary ventilation routes are different in their airflow characteristics to other subsurface openings because of the aerodynamic effects of guide rails, buntons, pipes, cables, ropes, and shape, size and velocity of conveyances. As many shafts contribute heavily to the overall resistance of a mine ventilation circuit, it is important to be able to predict the resistance of a planned shaft with reasonable accuracy. This paper describes part of a study on the ventilation characteristics of hoisting shafts, conducted for the Basalt (Nuclear) Waste Isolation Program (BWIP). Methods of quantifying each of the four components of shaft resistance are developed; namely the shaft walls, fittings (buntons, pipes, etc.), the skips or conveyances, including the dynamic effects of their motion, and shaft stations. Practical guidance is given on ways of reducing the shaft resistance. The paper concludes by giving a step by step procedure for the ventilation aspects involved in the design of combined hoisting/ventilation shafts.

Jan 1, 1987

By K. S. Narayanan, Marcia L. Bartges, K. S. Venkataraman

The starting powders' physicochemical properties and consistency are essential for technical ceramic products to meet their performance specifications. The need for finer and more consistent powders has opened new technologies for synthesizing powders from atoms and molecules. However, submicron and near-micron powders obtained from conventional comminution and classification techniques are still competitive. This paper shows several examples from electronic ceramic applications of how we can use powder characteristics for micromanaging by design the ceramic properties such as the green and fired densities, slurry rheology, shrinkage during sintering, and the microstructure of the sintered bodies. The cross-disciplinary nature of the technology requires that the researcher not only should have a firm grip on the fundamentals of one or more disciplines, but also should be generally aware of the intricacies of other disciplines as well.

Jan 1, 1992

By Gemei Yang, Pierre Mousset-Jones, Felipe Calizaya, Malcolm J. McPherson

Laboratory tests on controlled airflow recirculation have shown the development of transient states in response to changes in system prevailing conditions such as those generated by a sudden start-up and stoppage of fans. Researchers in many European countries have developed various models to explain these phenomena. However, these models failed to consider some important factors such as diffusion and dispersion of gas in turbulent flows. For both in-line and cross-cut recirculation, tests have shown that after the start- up of a booster fan, the gas concentration in the system fluctuates, reaching high levels at the initial states and slowly dying out with time. These fluctuations cannot be represented adequately by simple step-wise functions but rather by smooth, albeit complex equations. In this paper, the phenomena are explained by the convection-dispersion theory, and represented by a mathematical model. Based on a few simplifications and applying Fourier's Transform Method to the differential equations of the flow recirculation model, an integral form of gas concentration function was derived. The Simpson Integration Method was used to compute numerical results for two laboratory tests. The paper also discusses the range of the dispersion coefficient to improve the accuracy of the model.

Jan 1, 1989

By G. B. Misra

Attempts have been made during the last three decades to establish a correlation between respirable dust dosage and the degree of progression of pneumoconiosis or silicosis amongst mine workers. Fair correlation has been possible only after the Johannesburg Pneumoconiosis Conference established mass concentration of dust in the respirable size range as the true measure of the incidence of pneumoconiosis. The author had established a good correlation between cumulative total respirable dust dosage as well as cumulative silica dosage and the category of pneumoconiosis according to ILO classification at Mufulira Copper Mine. Studies at Hutti also show a linear relationship between the average cumulative dust and silica dosage md the category of pneumoconiosis. However the maximum tolerable cumulative dust dosage for - prolonged exposure is 182 mg month/m3 - at Hutti as compared to 275 mg month/m3 at Mufulira. Similarly the maximum tolerable silica dosage for - prolonged exposure is Only 35 mg month/m3 at Hutti as compared to 55 mg month/m3 at Mufulira. The TLV for dust concentration at Hutti works out at 0.6 mg/m3 compared to 1.1 mg/m3 at Mufulira and the TLV of silica concentration at Hutti is 0.117 mg/m3 compared to 0.25 mg/m3 at Mufulira. The Hutti figure is however, closer to the TLV of 0.1 mg/m 3 recommended by ACGIH.

Jan 1, 1987

By A. Cordonnier, Ch. Obry, R. Evrard

In spite of the large annual expenditures and the vast field of activity covered, it cannot be said that many new grinding machines have actually come to light and modified the existing market for more than half a century. Manufacturers have mainly made advances in increasing machine sizes, efficiency and reliability, and in machine automation. The relatively recent emergence of roller presses is the only exception to this homogenisation of machine ranges. The development of roller presses in pregrinding has shown the advantages of compression grinding over the ball mill from the power consumption point of view. But classical roller presses still have maintenance problems due to the high grinding pressure. The FCB Research Centre has carried out much work in this field and in particular has studied the advantages of this process in pregrinding and integral grinding. These researches lead to the development of two new compression grinding machines. The first one, HOROMILL®, presented for the first time on the 8th European symposium on comminution at Stockholm, finds its application in the field of fine to very fine grinding in dry process. The second one, RHODAX®, presented at INTERMAT in Paris, covers the field of secondary and tertiary crushing and the first stage of grinding for most of the minerals in dry or wet process. Its high reduction factor permits to do with only one machine the work realised today with two or three crushing/milling stages. These two complementary machines offer a wide range of combination summarised on [Figure 1].

Jan 1, 1995

By B. J. Arnold, F. F. Aplan

A model incorporating rate and residence time to describe the froth flotation process was used to provide data for the evaluation of various kinetic flotation models and to provide scale-up information from laboratory to industrial scale coal froth flotation. Rate constants were determined in laboratory and plant froth flotation tests and the residence time distribution was measured for a bank of four 21 ft 3 (0.6 m3 ) WEMCO cells treating Upper Freeport seam coal and a bank of four 300 ft 3 (8.5 m3 ) cells treating Lower Kittanning seam coal. It was found that a lag time for continuous flotation should be incorporated into scale up models and that a kinetic froth factor ratio of between about 2.0 and 2.8 should also be used to scale up data from laboratory to plant scale.

Jan 1, 1989

By Stephen J. Reynolds

Arizona's geologic history is complex, resulting in a diversity of rock types and earth materials, including those of commercial interest. Regional variations in geologic history gave rise to three geologic provinces and an inequitable distribution of both metallic and nonmetallic mineral wealth. The Colorado Plateau is largely composed of flat-lying Paleozoic and Mesozoic sedimentary rocks and late Cenozoic volcanic fields and sedimentary deposits. Associated resources include gypsum, halite, sylvite, clays, specialty sand, flagstone, volcanic products, and aggregate. The adjacent Transition Zone features a large expanse of Proterozoic rocks, economically important Devonian and Mississippian carbonate rocks, and Tertiary volcanic and sedimentary materials. Nonmetallic resources in this province include facing and dimension stone, aggregate, decomposed granite, chrysotile asbestos, gypsum, clay, barite, fluorspar, zeolites, and limestone used for lime, cement, and railroad ballast. The Basin and Range Province has the most complex geologic history and, therefore, the most diverse assemblage of industrial mineral occurrences. These include halite, gypsum, clay, aggregate, decomposed granite, diatomite, zeolites, perlite, pumice, kyanite, limestone, marble, stone, and others. In addition, young stream deposits yield vast quantities of sand and gravel, Arizona's most economically important nonmetallic mineral commodity.

Jan 1, 1987

By A. Zorychta, T. Cyrul, Z. Kleczek

INTRODUCTION Underground mining causes disturbances of the primary state of stresses. Resulting from those disturbances a loss of stability of rocks that surround excavation may occur interrupting the production and creating life danger for the personnel. One of the manifestations of such an instability is a rock burst phenomenon which mainly occurs at great depths. From the mechanical mint of view the rock burst is a loss of stability /Filcek et a1.,1984; Pietuchow and Linkow, 1976/ due to : - quasi-static stress changes in the surrounding rocks; we will call it s seam burst , - dynamic stress changes in the surrounding rocks caused by rock shocks ; we will call it roof burst. Possibility of the rock burst occurrence Is uniquely determined by the state of stresses existing in the rock mass. In the following sections of the paper we will consider different aspects of this question. Moreover distributions of displacements and failure criteria for a coal seam at longwall mining will be defined. STATEMENT OF THE PROBLEM Determination of the vertical stresses and displacements resulting from longwail mining will be based on the Budryk’s idea of a stress wave /Salustowicz, 1955/. The idea originates from the analysis of a roof plate /beam/ resting on the deformable foundation /Sean/ and subjected to the cylindrical bending. Equation of the bending lice uniquely defines vertical stresses and displacements which are induced in the seam. The equation will account only the shear force effect. Elimination of the bending moment has been shown and discussed by Zorychta and Bcrecki /Zorychta, 1985; Borecki and

Jan 1, 1986

By R. J. Cornelius

Gold with minor associated copper mineralization in the area of what is now the Bougainville porphyry copper deposit has been known since the 1920s and was probably known in German colonial times, pre- 19 14, although no records persist other than a reference by Stanley (1922) to copper specimens from Kieta that he saw in Rabaul. Stanley did not at the time believe that they came from Kieta. Gold was first discovered at Kupei by Jack Comb in 1929 and the Kieta Goldfield was proclaimed in May 1930. In December 1932, the Tapu Reward Claim at Moroni - the site of the Bougainville Copper concentrator, was pegged by C.W.M. Evans who prospected up river from the West Coast. The Pumkuna (Panguna) Reward Claim on the site of the subsequent porphyry copper deposit was granted in February 1934 to G.A. Myers. n May 193 1, the Kupei Reward Claim was transferred to Bou- gainville Gold Options NL and later reverted to Jack Comb and then the Bougainville Syndicate, as did the Pumkuna and Moroni claims. Most of the interested parties had come from the Edie Creek rush on the New Guinea mainland. In 1935, N.H. Fisher, the geologist in Rabaul for the New Guinea administration who later became director of the Australian Bureau of Mineral Resources in Canberra, reported on the three gold areas. Norm Fisher described the gold and copper mineralization and its habit in great detail and this report had a major influence on the events leading to the discovery in the 1960s. Gold production up to the Japanese invasion probably did not exceed $50,000 in value. Half a ton of copper-gold ore from Kupei was sent to O.T. Lempriere's in Sydney for assay in the early 1930s.

Jan 1, 1991

By M. Alnot, J. A. Mielczarski, J. J. Ehrhardt, J. M. Cases

The flotation behavior of minerals depends on the balance between hydrophobic and hydrophilic species present at the surface of the minerals. The direct characterization of the interfacial products formed by the interaction of water and an aqueous solution of amyl xanthate with chalcopyrite, tetrahedrite and tennantite (the two former contain antimony and arsenic) were carried out by X-ray Photoelectron Spectroscopy (XPS) and infrared (IR) reflection spectroscopy. The experimental data collected from in-situ (IR ATR) and ex-situ (XPS, IR External Reflection) measurements have let us determine the types of the adsorption products and to propose mechanisms of interaction between the aqueous solution of surfactant and surface of the investigated minerals. It is shown that two major processes take place at the mineral interfaces: (i) the interaction with water and oxygen resulting in the formation of the oxidation products which are mainly hydrophilic (but also a hydrophobic product was found), and (ii) the adsorption of xanthate producing different types of hydrophobic surface products. The results obtained show differences in the composition of the outermost atomic layers of the investigated minerals which obviously will produce differences in the flotation behavior of these minerals. This work forms a good fundamental basis for a better separation between copper minerals containing arsenic and antimony, and chalcopyrite.

Jan 1, 1995

By K. Osseo-Asare

Metal recovery from solution, i.e., the formation of a solid product from a purified aqueous electrolyte solution, is increasingly becoming more than a simple matter of bulk precipitation. In many cases, operating conditions must be carefully manipulated to control the rate and yield of the precipitation/crystallization process, as well as the purity and physical characteristics of the solid product. A review is presented of the underlying physico-chemical processes, with emphasis on solution and interfacial chemistry. Opportunities for the integration of hydrometallurgical metal recovery and materials processing operations are discussed.

Jan 1, 1989

By D. A. Curry

This paper describes a study of the influence of non-normal loading on the indentation behaviour of single bit-teeth. Indentation experiments have been performed on a soft, isotropic limestone using both sharp and blunt 60 degree wedge-shaped indentors constrained to penetrate the rock at 0, 15, and 30 degrees to the rock surface normal. For both sharp and blunt indentors, the normal force required to produce a given normal penetration decreased as the offset of the penetration direction from the rock surface normal increased. The crater volume produced by a given normal penetration with the sharp indentor was largely independent of the penetration direction. In contrast, the crater volume produced by the blunt indentor was increased markedly by non-normal penetration at small penetration depths, because the threshold penetration for chip formation decreased with non-normal loading. The crater volume produced by a given normal force was significantly increased by non-normal penetration, and this increase was particularly pronounced with the blunt indentor. The energy required to form unit crater volume was correspondingly reduced by non-normal indentor penetration. A simple method for predicting the reduction in the rock's resistance to chip formation is outlined, which is supported by the experimental data. The implications of these findings for rotary drilling are considered.

Jan 1, 1986

By J de Cuyper, E. J. Parkins, H. L. Shergold, W. Freyberger

The paper is divided into two parts. The first part describes an investigation of the effect of temperature on the conditioning and flotation of an ilmenite ore with a 1:l oleic acid-fuel oil mixture as collector. During conditioning the pulp underwent characteristic changes of flocculation, deflocculation and dispersion which were monitored by measuring the power consumption of the conditioner motor. Optimum flotation results were obtained at the end of the deflocculation period. High ilmenite recoveries were obtained at high temperatures and high concentrate grades at low temperatures. The second part of the paper describes a study of the effect of temperature on the adsorption of oleic acid at the ilmenite/water interface. At high adsorption densities it was chemical and exothermic. Contact angles showed that the hydrophobicity of the collector-coated minerals increased with an increase in temperature.

Jan 1, 1976

By Alain GSELL

The aluminous nature of the laterites capping the Minim Martap plateaus - named after two neighbouring villages - and the small nearby upland of Ngaoundal, was discovered by the Cameroon Mines and Geology Division in 1958. These deposits of worldwide importance, are located in the Ngaoundere region, some 500 km (300 miles) north-east from the port of Douala (as the crow flies). They constitute the major part of the Cameroonese mining potential. The study of the deposits and their economic development has been entrusted to SEBACAM, Societe d'Etudes des Bauxites du Cameroun, a company in which the Cameroon government participates. The bauxites originate from the transformation into laterite of lavas which covered a Precambrian basement during the Upper Cretaceous period and the Lower Tertiary era. The entire Minim Martap deposit comprises bauxite plateaus ranging in area from a few acres to several square miles. The average thickness of the bauxite layer varies from 10 metres at Minim Martap to 17 metres at Ngaoundal. The mineral constituents of the bauxite are gibbsite trihydrate, kaolinite and the usual iron and titanium oxides. Treatment of the ore does not involve any particular technical problems. Proven exploitable reserves amount to 560 million tonnes of dry bauxite with a reactive silica content of 1.80% and an available alumina content of 43.70% at Minim Martap, and 120

Jan 1, 1984

By Gerrit V. R. Goodman, Fred N. Kissell

The issue of miner safety in case of an underground mine fire has been extensively examined by both government and industry. These efforts have intensified in recent years following a number of fatal fires at underground coal mines. As a result, there is an increasing interest in the reliability of coal mine escapeways during a mine fire. This paper discusses the use of fault tree analysis for evaluating escapeway reliability. A fault tree is developed using standard logic formulations. It is later evaluated using commercially available software. The computer model uses Boolean reduction to obtain the minimal cut sets and minimal path sets of the tree. A brief analysis is also conducted to determine the occurrence probability of the TOP event. This study shows that fault tree analysis is a viable means of analyzing escapeway reliability. The cut and path sets reveal those event sequences leading to fatalities. Such information is useful in safety training and accident prevention. The probability of the TOP event shows the frequency of occurrence for fatalities in an underground mine fire. The usefulness of this value, however, is limited by the accuracy of the data for the initiating events. For mining events, the data is difficult to estimate precisely.

Jan 1, 1989

By E. F. C. Ferrett

The benefits derived from the use of main fan evasees or diffusers are well known. If a well designed evasee is fitted to a fan either more air will flow through it or the same air flow rate will be discharged at a lower fan speed. This latter possibility will reduce the air power requirement of the mine, the fan input power and the overall energy costs. Despite these apparent advantages, many reports have been received from the industry of poor evasee performance. After examination, it appears that these problems are often caused by installation difficulties or inaccurate design procedures. The performance of an evasee is affected by several independent factors. Some of these factors describe the evasee geometry whilst others are concerned with the behaviour of the air as it passes through the evasee. This paper shows that the divergence angle is by no means the only ;important parameter which affects evasee performance and that the size of the inlet boundary layer has a significant influence. The performance of evasees of differing geometric shape are compared and the criterion to be used for optimum performance is discussed. It is shown that the commonly used evasee efficiency is a poor indicator of good performance. Recent work by the author and others is evaluated and a simple design. guide discussed. For more sophisticated work, details of a. computer program are provided. Finally, a brief resume of the performance of truncated diffusers is given. Since compressibility effects can be ignored for most mining applications, incompressible flow has been assumed for most of this paper.

Jan 1, 1980

By D. Constantinides

In 1981 a Zn-Ag-Pb deposit was discovered in the vicinity of Molai, Greece. Subsequently, it was determined to be of the Kuroko type. The geology of various areas in the southeast Peloponnesean Peninsula is similar to that of the Molai deposit. Since favorable geologic criteria are present, absent, or unknown in varying degrees in all areas, it was deemed necessary to classify and rank the prospective areas according to the level of information available. For each level of information, an ore discovery model based on pragmatic exploration criteria was developed, enabling the favorability of occurrence to be calculated for each area. A Monte Carlo simulation was used to calculate the probabilities, the input data consisting of quantitative and qualitative estimates of the geologic criteria for each area. Three levels of information were modeled : Level A consisted of 9 criteria, level B of 12 criteria, and level C of 20 criteria. The three levels of information were tested on the Molai area. The results exceeded expectations, showing the gen¬eral trends which control mineralization at the lowest level of information. With an increase in the level of information, geological trends become more evident and a differentiation can be made between areas containing Cu mineralization, exhibiting a low probability, and areas likely to contain Zn-Ag-Pb mineralization. The models were then applied to the neighboring areas - only level A and B were available.

Jan 1, 1986

By R. W. Smith

Though generally rather non-selective in nature long chain collectors nevertheless function in different ways in accordance with their own particular physical characteristics. Altering various parts of their structures such as chain length, type of chain, etc. can therefore substantially alter the adsorptive behavior of the collectors in a set environment. The effect of such structural differences of the collectors on physical parameters such as solubility, critical micelle concentration, acid or base strength, tendency to be expelled from the aqueous phase is discussed, as is also the effect of these parameters on flotation behavior.

Jan 1, 1989