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By I. Iwasaki, K. A. Smith, X. Cheng

A cathodic decomposition model was examined for both pyrrhotite and chalcopyrite in an attempt to analyze the formation of surface coatings in deoxygenated solutions at natural, near neutral pH. Combination potentials established between the mineral-grinding media pair were simulated by applying a potential of -0.455 V (vs. a standard hydrogen electrode) either to a pyrrhotite or to a chalcopyrite electrode. Chronoamperometry was used to study the polarization behaviors and alteration of mineral surfaces through cathodic processes. The kinetic parameters of cathodic decomposition of pyrrhotite and chalcopyrite were determined and compared. It was concluded that pyrrhotite decomposed faster than chalcopyrite in near-neutral pH solutions. Both minerals were then covered by a film consist¬ing mainly of iron hydroxides, which adversely affected their flotation.

Jan 1, 1999

By I. Iwasaki, H. Dho

The role of sodium silicate in the anionic flotation of a Florida phosphate ore was investigated using laboratory continuous flotation tests, frothabiliry tests and SEM observations. In the absence of sodium silicate, Ca I+ promoted the unwanted activation of quartz by forming calcium bearing precipitates. The addition of sodium silicate enhanced the flotation efficiency through: 1) the removal of impurity minerals and calcium-bearing precipitates from quartz surfaces by dispersion, 2) drier and more persistent froths stabilized by oily droplets containing calcium silicate precipitates, and 3) higher specific flotation rates of phosphate relative to quartz, leading to faster flotation rates and increased selectivity of separation.

Jan 1, 1991

By Y. Q. Zhang, Y. Luo, S. S. Peng

Burrier pillars in underground coal mines could eventually be subjected to a water head due to the build-up of mine water in the old workings. The water head could not only act ns a force to destabilize the pillar, but it could also cause seepage flow through the pillar and its surrounding strata. Excessive seepage flow could induce piping failure that, ill turn, could accelerate the mechanical failure process of the barrier pillars. In this paper, a finite element simulation approach was employed in the evaluation of the barrier pillars. Both the stress distribution and the seepage flow pattern in and around a barrier pillar have been simulated numerically. The effects of ground stress on rock permeability to water seepage has been taken into consideration in these simulations,

Jan 1, 2002

By R. M. Cox

Pneumatic coal loading and conveying systems provide alternative methods for the safe and efficient mining of the thin, high-grade coal seams found in the Southern Appalachians. Pneumatic systems eliminate most of the health and safety hazards associated with the operation of conventional mining and haulage equipment in small low-coal mines by removing powered mobile equipment from the mine. Ventilation is also improved by the coincidental removal of gas and respirable dust from the mine by the operation of the pneumatic loading and conveying system. Other significant advantages of pneumatic coal recovery systems are relative simplicity, operating flexibility, low capital cost, quiet operations, environmental benefits and ease of automation. The design considerations and field evaluations of experimental prototype pneumatic coal loading and conveying systems installed and operated in small thin-seam mines are presented in this paper. In addition, fundamental design criteria and recommendations for the installation and operation of a variety of pneumatic coal loading and conveying systems that offer alternative coal-recovery systems that alleviate the serious health and safety concerns of current small mine operations are proposed.

Jan 1, 2000

By B. R. Satio, P. G. West-Sells, D. B. Dreisinger, B. J. Y. Leong, G. A. Kordosky

Electrolytic techniques have historically been used to remove arsenic, antimony and bismuth from copper refining electrolytes. However, both solvent extraction and ion exchange techniques have been heavily researched and in a number of cases commercially introduced. In this study a large number of solvent extraction reagents and ion exchange resins were screened to determine the selectivity of the reagents for impurity removal. Solvating extractants were found to efficiently remove arsenic from electrolyte. The extent of arsenic extraction increased in the following order: TBP < DBBP < DPPP < Cyanex 925 < Cyanex 923. Antimony and bismuth extraction from electrolyte were demonstrated with the reagent 2EHAP04. The ion exchange resins UR-3300 and Duolite C-467 were found to strongly extract antimony and bismuth from electrolyte. C-467 appeared to be superior to UR-3300.

Jan 1, 1993

By R. D. Grove

The control of Florida phosphate flotation plants is largely based on the visual observations of experienced operators, both in recognizing good and bad froth conditions and in making judgments about the composition of feed, concentrate and tailing streams. Chemical analyses lag the process by at least two hours and, therefore, only assist in recalibrating the operators&apos; vision when major deviations occur. An image analysis system was developed by IMC Fertilizer to improve the accuracy and precision of the composition estimation process. It still relies on the operator taking a representative sample, but provides a measurement in about 15 minutes after that sample is obtained. Background The search for a quick and inexpensive technique for estimating phosphate flotation stream composition continues. There have been attempts at using "wet chemistry," nuclearmagnetic resonance, neutron activation, X-ray diffraction and other techniques reported on in the past several years. None of these have yet found its permanent place in the flotation plants of the Florida phosphate industry. IMC attempted to use wet chemistry to provide 7.5-minute estimates of final concentrate insol and tailings BPL. This was aborted after 36 months of plant operation due to the high operating costs for chemicals and an operator. There was also no significant economic improvement in the plant&apos;s operation. Another factor was the necessity to limit these crude analyses to only a few process streams, which were insufficient to achieve improved plant operation.

Jan 1, 1993

By Peter Sullivan, Johan van Heerden

Increased use of continuous miners and roadheaders in the underground coal mining industry in South Africa has led to improved productivity and efficiency of operations. Of major concern, however, is the increased amount of airborne dust generated during mining. Dust is a health hazard in terms of respiratory diseases, can impede productivity and is the major contributor to the potential of underground explosions. The concern of the South African coal mining industry with regard to the underground dust problem has led to the establishment of a Dust Control Section in the Coal Mining Division of COMRO. In the field of dust suppression system evaluation and design, collaborative work has been undertaken by COMRO and FLOSEP. This paper gives a review of the application of Computational Fluid Dynamics (CFD) in evaluating and improving environmental conditions in continuous miner and roadheader sections. A brief history of the development of the CFD model as well as a discussion of a typical application is included.

Jan 1, 1993

By J. G. Groppo, B. K. Parekh

A series of performance studies were conducted using countercurrent column flotation to recover a marketable clean coal product from existing preparation plant fine waste streams. The test work was conducted at several preparation plant sites in Kentucky and Virginia using a 150-mm (6-in.) inside diameter column that was 5.8 m (19 ft) high. Both thickener feed and classifying cyclone overflow with a typical size distribution of 150 µm (100 mesh) X 0 were tested. The percent solids of the column flotation feed varied from 1.5% to 15% while the ash content ranged from about 30% to 60%. The concentrates produced contained 2% to 10% ash with Btu recoveries of nearly 90% using 0.12 to 1.25 kg/t (0.25 to 2.5 lbs per st) fuel oil and 0.12 kg/t (0.25 lbs per st) MIBC. These results were consistent with or better than results obtained in preliminary laboratory scale column flotation evaluation. Test results from seven different seams are discussed as well as scale-up relationships used to design a full-scale installation presently in operation.

Jan 1, 1991

By R. C. Ford, J. Kelsey, S. A. Pierce, M. D. Ankeny

Evaluation of acid drainage risk from spent (leached) ore in arid climatic zones consists of two components: (1) whether residual and secondary minerals will release acid and metals when exposed to rainfall, and (2) whether ambient rainfall is likely to infiltrate, and eventually impact surface or ground water resources. The risk of acid drainage from spent ore at the El Abra on-off copper leach pad operation was evaluated using conventional geochemical methods and unsaturated flow models. Although geochemical testing indicated poor quality water would result from any seepage, unsaturated flow modeling demonstrated that infiltration and seepage were unlikely given the arid climatic conditions. Modeling further demonstrated that the residual moisture content of the spent ore when it is removed from the leach pad controls the risk of seepage. To further reduce the risk of seepage, operational controls were developed and implemented at the El Abra site.

Jan 1, 2000

By R. E. Weeks, D. J. Millenacker

Utilization of true in situ technologies for mining copper in Arizona will involve a complex environmental permitting process. This process is a key factor in determining the feasibility, costs, and implementing time- frames required for development of this innovative mining method. The regulatory structure in Arizona is presently changing due to enactment of the Environmental Quality Act (EQA) of 1986 and development of new aquifer protection rules and regulations. The US Bureau of Mines has reviewed the comprehensive hydrogeologic characterization, ground water monitoring, mechanical integrity testing, well construction, contingency planning, and other regulatory elements that will serve as mechanisms to assure protection of ground water resources. The purpose of this paper is to inform the domestic copper industry of the significance of the new Arizona regulatory structure and its implications for prospective in situ operators.

Jan 1, 1987

By R. K. Devala

In this paper, numerical approximation schemes, for solution of the mass transfer problem in mine ventilation have been developed by using three implicit finite difference schemes. Results from these schemes have been compared with the analytical solution for spatial and time increments, using the concept of Root Mean Square error. For implicit finite difference schemes, in general, the modified central difference scheme is better than the two other schemes at lower velocity. Also, at lower air velocities, implicit schemes underpredicted the concentration values. At higher air velocities, the Crank-Nicholson and Laasonen schemes provided better results than the Modified Central Difference scheme.

Jan 1, 1994

By F. C. Loughnan, Shane B. Sadleir

Bauxite is currently produced at three centres in Australia: - Weipa in northern Queensland; Gove on the northeastern tip of Northern Territory; and in the Darling Range near Perth, Western Australia. At each of these centres the bauxite is of Tertiary age and occurs as blanket-like, lateritic crusts in which gibbsite is the predominant mineral. Development was essentially in situ although possibly the deposits, particularly at Gove, are in part of transported origin. All of the deposits formed from quartz-rich parent rocks with those at Weipa and Gove being derived from kaolinitic sands while in the Darling Range, granite and other crystalline rocks of Precambrian age immediately underline the lateritic bauxite.

Jan 1, 1984

By D. Koch

Bentonites and bentonite containing sealing materials are used since many years for sealing purposes in foundation, dike construction, hydraulic engineering and landfill construction, especially for encapsulation of old waste deposits In the near future compacted bentonites will be important components of multi-barrier systems for dry charge of old mines, for underground disposal of hazardous or radioactive wastes. Because of their exceptional physical, structural and chemical properties, bentonites are offering manifold possibilities to protect the environment against the negative effects of dumping grounds. Often the compliance with legal regulations for waste dumping or the isolation of contaminated areas is possible only by using bentonite containing sealing systems. The essential properties of bentonite, bentonite containing building materials and the different techniques of making horizontal technical base liners and vertical cut-off walls are explained. For horizontal technical base liners the adsorption ability, the ion exchange capacity and the swelling behavior of bentonites are important. For cut-off walls bentonite controls the rheological behavior of the slurry and is responsible for the low permeability of the hardened bentonite-cement-wall. In the multi-barrier systems of repositories for chemical or radioactive wastes compacted bentonites are considered to be favourable sealing and backfilling materials because of their high swelling capacity, their adsorption and ion-exchange ability and their plasticity in water saturated state.

Jan 1, 2005

By G. A. Munoz, J. D. Miller

Gold leaching of an auriferous pyrite ore from the Portovelo deposit in Ecuador indicates that noncyanide leaching systems, such as thiocyanate and thiourea, are not as effective as the traditional cyanide system. For example, whereas approximately 95% of the gold can be leached from the ore with cyanide, only about 50% gold dissolution can be achieved with a thiocyanate leaching system. Electrochemical measurements indicate that gold is not cathodically protected by pyrite in these systems. Based on the results of preliminary diagnostic experiments, it appears that gold dissolution in thiocyanate and thiourea systems is limited by passivation due to the formation of either elemental sulfur or sulfur compounds on the gold surface.

Jan 1, 2000

By D. J. McCracken

The lithium review did not arrive in time for publication in the June issue The estimated consumption of lithium minerals as raw materials to the glass, ceramic and metallurgical industries in 1992 was 85.5 kt (94,200 st). That equates to about 12 kt (13,200 st) of lithium carbonate equivalent (LCE). An additional 150 kt to 200 kt (165,000 to 220,000 st), or 7.5 kt to 10 kt (8200 to 1100 st LCE), were used in the production of lithium chemicals. The 1992 consumption represents an overall decrease of 3.5 kt (3800 st), or 500 t (550 st) LCE, from 1991. This was a direct result of a worldwide reduction in glass demand due to the economic recession. There are three major producers of lithium minerals. Gwalia Consolidated Ltd. (formerly Lithium Australia Ltd.) in Western Australia and Tantalum Mining Corp. (Tanco) in Manitoba, Canada, both produce spodumene ore. Bikita Minerals, in Zimbabwe, is the largest producer of petalite. Bikita also has the capacity to produce small volumes of spodumene concentrate. The Cyprus Foote spodumene operation at Kings Mountain, NC, ceased production in 1992. It once produced about 2 kt/a (2200 stpy) of "high iron spodumene" for uses other than in the manufacture of lithium chemicals. The lithium products of the major producers are shown in Table 1. The current resources of 13 Mt (14.3 million st) of LCE in the western world will supply demand for more than 50 years.

Jan 1, 1993

By J. Hanna, R. Kalathur

Over the years, Alabama&apos;s coal industry has generated, during mining and cleaning operations, about 150 million st of fine waste coal, with this total increasing at a rate of 2 million stpy. Reclamation of the fine-size wastes (containing 20% - 60% clean coal by weight) provides, free of charge, mined and crushed feed stocks for coal recovery. Also, the removal or recovery of pyrite from the tailings should eliminate a major source of acid-water pollution. Tests were made on the impounded wastes and current plant discharges to recover the coal fraction by sizing, gravity and flotation techniques. Gravity separation of the +100-mesh material produced commercial-grade coal averaging 7.6% ash, 0.8% sulfur and 13,471 Btu/lb. However, the coal yield, at about 31 % - 56%, was relatively low. Froth flotation, using mechanical and froth column methods, gave similar coal products at much higher coal recovery rates of 87% - 93%. This coal analyzed 10% ash and 1.1% sulfur.

Jan 1, 1993

By S. Svoronos, B. Moudgil, R. Stana, A. El-Midany

Due to their similar surface properties, it is not always easy to separate carbonate minerals from other salt type minerals by froth flotation. A particular example is the difficulty of separating dolomite impunities from phosphate minerals. Such challenging fundamental and practical problems have inspired several research efforts in various laboratories around the globe to find methods for economically removing the dolomite. However, a universal and cost effective process is not in commercial use. In this paper, a new process for separation of carbonate minerals (dolomite or calate) from other associated minerals is presented. Differential solubility of carbonates in slightly acidic solution is utilized to generate micro GO, bubbles at the carbonate mineral/ water interface. Particle (e.g., dolomite)/ bubble aggregates float to the surface leaving phosphate concentrate with low MgO content. Interestingly, up to 6.0 mm particles can be floated by such micro bubble/particle aggregates. Different sutface-active agents were tested to stabilize the bubbles. Results of these tests are presented and the mechanisms involved are discussed.

Jan 1, 2005

By C. P. Mangelsdorf

Introduction During the 13 years since C. C. White introduced the Birmingham roof truss there has been a revolution in permanent roof support technology. While not all of the emerging concepts have their origins in the truss-resin bolting is a prime example - the combinations and permutations of devices presently available to the underground mining industry reflect a well-spring of creative activity. The purpose of this report is to chronicle a number of roof support system that have same physical similarity to the Birmingham truss, and to report on their application. Definitions The application of the tern "truss" to the device developed by White of the Birmingham Bolt Company in 1967 may be derived from the classical technique of stifwood, by the attachment of an underslung, sometimes pretensioned metal strap, rod or cable. If the beam is separated from the reinforcement by a single block or vertical post it is called a "King&apos;s Post Truss". If two equally spaced blocks or posts are used it is referred to as "Queen&apos;s Post". When the immediate roof of a mine is visualized as a beam, the Birmingham device completes a structure resembling this latter form.

Jan 1, 1982

By F. M. Swain

High-calcium limestones occur in the upper part of the New Market Formation, of Lower Middle Ordovician age, in Franklin and Cumberland Counties, Pennsylvania. The high-calcium facies of the New Market Formation is represented by sublithographic limestone or vaughanite, which probably formed in quiet water; low-energy environments such as intershoal lagoons, or in protected bays similar to the present-day Florida Bay environment. Rapid facies changes are characteristic of the strata. The better grade of stone lies in the upper 100 to 125 feet of the New Market Formation and averages 95-97% calcium carbonate. Silica and magnesia are about equal in amount as impurities. One high-calcium belt extends from the Maryland state line through Chambersburg and Newville to beyond Carlisle. The strata in this belt are structurally complex, which requires careful field study&apos; and core-drilling prior to exploitation. Stone suitable for blast-furnace flux is present in relatively large amounts, but stone for open-hearth use or portland cement requires more selective quarrying.

Jan 1, 1966

By S. Frimpong, N. Demirel

Overburden excavation is an integral component of the surface mine production chain. The walking dragline is the most economic production equipment for overburden excavation in strip mining. Draglines are capital intensive, and thus, investments in multiple units severely impact the economic viability of projects. The use of few dragline units results in highly concentrated production focus, which must be efficiently managed to derive the potential economic benefits. Efficient use of draglines requires a thorough knowledge of the powered functions, the 3D rotational and translational motions and machine-formation interactions within the operating environment. Dragline kinematics and dynamics are required to understand and characterize machine performance and efficiency. In order to sustain the high productivity in difficult operating conditions, the dynamics of the dragline must be modeled and analyzed based on comprehensive kinematics. This paper investigates the planar kinematics of the front-end assembly and its interactions with the formation during excavation using the “Vector Loop Analysis” formulation with comprehensive simulation modeling in MATLAB Simulink. The kinematic models are used to examine the translational, rotational and angular displacement, velocity and acceleration components of the dragline front-end assembly along defined bucket trajectories during excavation. The results are the precursors for comprehensive modeling to examine the load deformation, torque requirements and dragline stress loading profiles for improving machine health and longevity.

Jan 1, 2006