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By Wendell H. Wiser

A comparison is presented of coal pyrolysis at temp¬eratures ranging from 4090 to 497°C and thermal dissolution of coal in tetralin at temperatures ranging from 350° to 450,°C, both utilizing a Utah high-volatile bituminous coal. The initial coal pyrolysis reactions are second order with an enthalpy of activation of 35.6 kcal per mole. The fraction of total product yield produced under second order conditions ranges from 67% at 409°C to 96% at 497°C. The process then gradually deteriorates to a first order reaction in the later stages with enthalpy of activation of 4.1 kcal, per mole. The initial reactions of solution of coal in tetralin are second order with an enthalpy of activation of 28.8 kcal per mole. The fraction of total product produced under second order conditions ranges from 63% at 350°C' to 94% at 450°C. The dissolution process then gradually changes to first order in the later stages with enthalpy of activation of 15.6 kcal per mole. A model is presented which relates the two processes and explains, the significance of the above similarities.

Jan 1, 1967

By J. H. Tylczak, R. Blickensderfer

Impact and abrasion properties of various commercial US grinding halls were evaluated and compared by the Bureau of Mines, US Department of the Interior. Laboratory tests were conducted on balls obtained from eight major US manufacturers. The halls included forged steel, cast steel, and alloyed white cast iron and were subjected to repeated impacts until they broke or until 300,000 impacts were exceeded. Pin abrasion tests also were conducted. The results showed wide differences in impact lives, ranging from a few thousand to over 500,000 impacts. The life of inferior commercial halls was increased five to six times by a laboratory tempering heat treatment. For halls that did not break, the major impact wear mode was spalling and ranged from an average rate of 0.28 to 4.46 mg per impact. The softest halls (steel) had excellent impact resistance but low abrasion resistance. The abrasion resistance of the steel halls generally increased with hardness. The alloyed white cast irons had about twice the abrasion resistance of the steel halls. Users should become aware of the wide variations among commercial halls, and ball manufacturers should be aware that their product can he improved.

Jan 1, 1990

By Byron R. Berger

Disseminated Au-As-Hg mineralization is localized along the Getchell Fault system at the Getchell Mine in north-central Nevada. Replacement ore bodies occur in Cambrian carbonaceous limestone and limy shale beds. Cretaceous granodiorite, dacite porphyry, and andesite porphyry dikes parallel the fault zone and are spatially associated with the mineralization. Hydrothermal alteration and mineralization occur continuously along 4-5 km of the fault system, and extend more than 1 km down-dip. Alteration consists primarily of removal of carbonate and deposition of quartz, pyrite, and carbonaceous material. Marcasite, sericite, kaolinite, calcite, barite, and fluorite are common. Gold content reaches more than 43 ppm in parts of the altered zones and averaged 9.3 ppm in the mined ore bodies. For the mineralized zones as a whole arsenic averages 0.28%, and occurs primarily as realgar, orpiment, and arsenopyrite. Mercury (22 ppm) is finely disseminated and mercury-bearing minerals are seldom recognizeable. Accessory mineralization includes antimony (100 ppm), copper (47 ppm) , lead (18 ppm) , molybdenum (10 ppm) , tungsten (16 ppm) , and zinc (50 ppm) . Geologic field studies and K-Ar dating suggest that the mineralization is related to a hydrothermal system produced by the granodiorite and related dikes.

Jan 1, 1975

By D. D. Runnells

In order to establish meaningful remediation goals and monitoring programs in areas disturbed by mining, it is desirable to determine the natural metals concentrations that existed in the area prior to mining. At Iron Mountain, California, several natural sources exist for acid drainage and loading of metals to Slickrock and Boulder Creeks. This paper describes methods to determine the contribution of copper and zinc to groundwater and surface water from those sources, including natural gossan rock outcrops, mineralized bedrock, and colluvial materials. Methods used include evaluation of: 1) historical information, 2) literature values of unmined, mineralized areas, 3) analyses of water from monitoring wells, 4) leaching studies, 5) statistical analysis, 6) isotopic studies, and 7) identification of background by elimination of mining sources. Results from this natural background determination show that Boulder Creek and Slickrock Creek carried elevated concentrations and loads of copper and zinc prior to mining activities. With repeated rinsing of reclaimed and remediated mine materials by rainfall, there will be a diminishing contribution from residual waste rock and tailings at Iron Mountain, and natural background will become an increasingly larger proportion of the total load.

Jan 1, 1999

By Alex Stewart

Most iron bearing ores treated by the R=N Direct Reduction Process yield products lower in phosphorus than the initial ores. The sulfur is also removed and generally is in the range of 0.02 to 0.05 percent in the final R=N product, independent of the sulfur content of both the ore and carbon fuel used. The mechanism and thermodynamic justification of the principal reactions leading to the removal of both phosphorus and sulfur and the control of sulfur in the iron concentrate produced are discussed and supported by the results of laboratory experiments. In substantially all iron ores (containing up to 4% sulfur as sulfate) and solid carbon fuels (containing sulfur from 1 to 8%) tested, the rejection of sulfur has been in the order of 90-95%, with not more than 0.02 0.05% sulfur in the final metallic iron product. With respect to phosphorus-bearing iron ores ranging up to 0.70% P205, the rejection to tailings has been in the order of 70-95%, resulting in not more than 0.03 - 0.07% phosphorus in the final product.

Jan 1, 1958

By C. E. Capes

The continuous balling? operation whereby a moist particulate mass is tumbled in a horizontal revolving drum with recirculation of the undersize product can be extremely unstable. Product and recycle rates are subject to wide fluctuations. Although the problem seems to be well-recognized, there is little published information or quantitative data readily available, especially in relation to industrial-scale circuits. Probably the best available published results are in the Russian literature, an illustration of which is given in Figure 1. These data, taken from a study') of some of the factors which influence the stabilization of the pelletizing process, illustrate the wide variations in circulating load and circuit productivity which may be encountered over a period of operation. The problems of balling circuit stability may be traced to random seed or nuclei generation and uncontrolled agglomerate growth. The situation is analogous to that in crystallization processes where (4 considerable attention is given to nucleation control. Traditionally attempts have been made to optimize system and operating variables to stabilize the balling process. A supplemental approach which is taken here is to build on the considerable

Jan 1, 1975

By D. A. Rice

As part of a cooperative effort between the U.S. Bureau of Mines and the Florida Institute of Phosphate Research (FIPR), with input-from the phosphate industry, the conversion of phosphor-gypsum to sulfur is being investigated. The proposed process incorporates a thermal reduction of phosphogypsum to calcium sulfide (CaS) and a hydrometallurgical treatment to convert calcium sulfide to ammonium bisulfide (NH4SH), which is then oxidized using a catalyst to produce elemental sulfur. The paper summarizes the results of continuing laboratory studies using an activated carbon catalyst which was loaded with sulfur through oxidation of ammonium bisulfide solution. The extraction of the sulfur that forms in situ on the catalyst is a key area in the development of the sulfur recovery process. Two approaches for removing the sulfur are being investigated: 1) thermal treatment to volatilize sulfur, and 2) leaching the sulfur using liquid anhydrous ammonia. The research has shown that it is technically feasible to recover over 90% of the sulfur from the carbon by either volatilization or ammonia leaching. Locked-cycle testing has demonstrated that the carbon has the potential to be recycled after ammonia leaching.

Jan 1, 1988

By J. Jordan, D. K. Denton, D. Tesarik, D. F. Scott, T. J. Williams

Personnel from the Spokane Research Laboratory of the National Institute for Occupational Safety and Health integrated the results of studies from a seismic tomographic survey, a finite-difference analysis, laboratory measurements of compression wave (ultrasonic) velocities in rock cores, and site geology to evaluate the use of seismic tomography for identifying induced pressures in an underground pillar at the Edgar Mine, Idaho Springs, CO. The key findings were that (1) the seismic tomograms showed that seismic velocities in rock adjacent to mine openings were low, (2) a difference tomogram in which in situ stresses on the east and west sides of the slot were compared showed that velocities increased west of the slot but decreased east of the slot, (3) geologic features (rock types and a fault) identified through geologic mapping were recognizable in the seismic tomograms, (4) ultrasonic velocity measurements on the rock cores agreed with seismic velocity measurements in the tomograms, and (5) results from a finite-difference analysis compared well to the seismic tomograms west of the slot but not east of the slot. The significance of this research is that seismic tomography is a useful tool for determining relative stress in underground pillars.

Jan 1, 2004

By Peter Zhang, Daniel Su, Bo Kim, Zoheir Khademian

Building on the research results and knowledge obtained from the ongoing National Institute for Occupational Safety and Health (NIOSH) Gas Well Stability Research, researchers from the NIOSH provided detailed analyses on potential longwall mining and gas well casing interactions at an unconventional shale gas well pad in a West Virginia longwall mine. Following the recommendations from recent research findings, the 5-1/2-inch production casings in all five wells were left uncemented from 4,200 feet below the surface to the surface. Prior to the first longwall panel excavation, NIOSH researchers conducted sophisticated three-dimensional numerical modeling to predict longwall-induced deformations and gas well casing stresses, which were compared with post-first panel and post-second panel mining 40-arm caliper surveys. The pre-mining predictions and comparisons with post-mining 40-arm caliper surveys were presented to all parties involved, including the coal and gas operators, Mine Safety and Health Administration (MSHA), Pennsylvania Department of Environmental Protection (PADEP), and West Virginia Department of Mines (WVDOM), prior to the re-entry operation on December 13, 2022. To date, the re-entry operation is a resounding success.

Jul 1, 2023

By H. Huang, J. C. Wu, C. H. Xie, Y. Q. Xue, Z. H. Zhang

Two- and three-dimensional groundwater flow models for dewatering in an opencast mine are presented. The models focus on solving special problems using numerical simulations of the opencast mine. These special problems include the drying up of the aquifer, the movement of the model boundary and the prediction of the residual head. These models are used to describe the decline of groumdwater levels in the Yuanbaoshan Opencast Coal Mine and its neighboring area during the drainage period. The simulated values agree very well with the field data. There have been several successful examples of numerical simulation for predicting the mine dewatering rate in an opencast mine. However, The hydrogeological conditions for the Yuanbaoshan Opencast Coal Mine are rather complex, and the total average flow rate is very high at 4.676 x 105 m3/d (1.65 x 107 cu ft/day). In this paper, a two-dimensional groundwater flow model in a large area is developed to solve the problems mentioned above by simulating regional drawdowns of the groundwater level during the drainage period, and a three-dimensional flow model is developed to simulate the residual head near the open-pit bench.

Jan 1, 1998

By Chen L. Lin, Luis R. M. Bittencourt, Jan D. Miller

Recently research efforts have been made to obtain a high-purity gibbsite concentrate, suitable for first-class alumina refractories, from a Brazilian bauxite ore containing gibbsite (50%), quartz (35%),and kaolinite (15%). Detailed polished-section microprobe analysis was used to describe the liberation characteristics of the ore. Experimental results suggest that the kaolinite liberation characteristics can be described by King's liberation model and that only about 11% of the kaolinite is expected to be liberated at a particle size of 75 µ. Bench-scale experiments for the flotation of gibbsite/kaolinite from quartz using alkyl sulfates as collectors were particularly successful at pH 2, and under appropriate conditions a concentrate containing 93.0% A1 0 (calcined basis) was obtained 2 3 at a gibbsite recovery of about 96%. Subsequently, the more difficult separation of kaolinite from gibbsite was accomplished by kaolinite flotation from the alumina concentrate with a quaternary ammonium salt at pH 6 to produce a high-purity gibbsite product, 97.4% A12O3 (calcined basis), at an overall gibbsite recovery from the bauxite flotation feed of about 90%.

Jan 1, 1990

By Donald A. Brobst

The minerals barite (BaSO, -barium sulfate) and witherite (BaCO, -barium carbonate) are the chief commercial sources of the element barium and its compounds, whose many uses are nearly hidden among the technical complexities of modem industrial processes and products. Barite, the major ore mineral, is extremely vital to the petroleum industry, which in 1990 consumed about 90% of the world's production of 4.9 Mt as a major ingredient of the heavy fluid called mud that is circulated in rotary drilling of oil and gas wells. The remaining 10% of the barite production was consumed chiefly in the manufacture of barium chemicals and glass and as a pigment, filler, and extender. Barite is found throughout much of the world and is available from three major geologic types of deposits-vein and cavity-filling, residual, and bedded-in sufficient quantity at competitive prices to meet current demands. The world's demand for barite is expected to increase because of the world's need for oil and gas. Geologic circumstances are favorable for the discovery of new deposits of commercial value. Witherite, desirable as a raw material for the production of barium chemicals, is much less common and abundant than barite.

Jan 1, 1994

By Stanley C. Suboleski

The increase in productivity which has been achieved in mining during the past two decades has been attained largely through the replacement of manpower with electrical power. Power demands should continue to increase, requiring electrical distribution systems to be well planned to avoid inadequate voltage levels caused by underdesign and excessive costs resulting from overdesign. To aid the mining electrical engineer in designing proposed power systems or analyzing changes to existing systems, a digital computer program has been developed. This program will analyze alternating or direct-current networks with up to 10 voltage sources, 75 loads and 300 total segments. A maximum of nine levels of voltage is permitted in the system. This project was part of a package of programs developed at Virginia Polytechnic Institute (WI) for the mining industry under sponsorship of the Office of Coal Research. Included in this package are also programs to: 1. Schedule mine production and predict cost of mining 2. Simulate rail haulage systems 3. Simulate belt haulage systems 4. Analyze ventilation networks 5. Analyze pumping networks These programs are available from the Department of Mining Engineering, VPI, Blacksburg, Virginia 24061 for a nominal processing cost.

Jan 1, 1970

By Robin P. Gardner

The mechanistic or phenomenological approach to ball milling involving the, concepts of particulate selection and breakage functions with particle population balance models has been well established over the past decade (c.f., the review articles by Austin (1) Herbst and Mika, (2) and Snow (3)). Initial efforts to apply this approach concentrated on batch milling, but since most milling in industrial practice is continuous, much recent research has been directed to extending this approach to continuous milling. The primary difference between batch and continuous milling processes is the relative importance of material mixing and transport in the mill in the latter case. Much analytical (4-8) and some experimental (9-15) work on the effect of mill mixing and transport on milling has been recently reported. Much of the analytical work has naturally centered around extension of the well-developed concepts that have been applied to chemical reactors, (16-18) Fortunately, it has been found(1) that most milling processes are analogous to first-order chemical reactions so that the combined effects of material transport and reaction (breakage) can be handled by the relatively simple segregated flow concepts. (8)

Jan 1, 1973

By R. W. Smith

A number of investigators have studied the electrokinetic potential (?) of kaolinite as a function of pH. (1,2,3,4,5) These investigators all agree that the ? is negative except at quite acid pH values. The actual shapes of the curves reported by the several authors vary considerably. In spite of the general negative character of kaolinite the mineral has a rather high anion exchange capacity. (6,7,8) The cation exchange capacity is the lowest for the clay minerals. (6) It has been shown that anionic surfactants adsorb readily onto the mineral even up to neutrality, often in quantities exceeding the reported anion exchange capacity. (7,8) At least part of the anionic adsorption should be onto positive edge sites thought to exist on the mineral. (9,10) In the present study ? of kaolinite was measured as a function of pH using both the streaming potential (sp) and microelectrophoresis (m.e.p.) methods. In addition ? was measured at various pH values as functions of sodium dodecyl sulfate (SDS) and trimethyldodecylammonium chloride (TMDAC) concentrations. In some experiments decyl alcohol (DA) was added.

Jan 1, 1968

By Robert A. Jankowski, John J. McClelland, Charles Babbitt

The purpose of this study was to develop guidelines to enable mine operators to maximize longwall dust reductions, while optimizing the use of ventilating air and shearer water consumption. A recent investigation by Foster-Miller Incorporated, under a Bureau of Mines contract, quantified the effect of increased face airflow and shearer water supply on face dust concentrations. A 70 pct reduction in respirable dust levels was achieved at the shearer operator's position during tail-to-head cutting by an incremental increase in average face air velocity from 83.8 m/min (275 fpm) to 123.4 m/min (405 fpm), while holding shearer water consumption constant. A 60 pct reduction was achieved through an increase in shearer water pressure and flow from 9.1 kg/cm2 (130 psi) at 0.19 m3/min (50 gpm) to 19.7 kg/cm2 (280 psi) at 0.28 m3/min (75 gpm), holding airflow constant. The combined effects of increasing both parameters produced an 85 pct reduction. Optimal usage of ventilating air and shearer water consumption can be achieved by defining a "point of diminishing returns" above which further increases no longer reduce dust concentrations, proportionately .

Jan 1, 1987

By K. Sharman

Quintette Coal Limited (managed and 50% owned by Denison Mines Limited) operates an open pit coal mine located in northeastern British Columbia, in the foothills of the Rocky Mountains. (See Fig. l). Mining commenced in 1982. The mine currently produces 4.75 million tonnes of medium volatile bituminous coal per year from three pits (Mesa, Wolverine and Shikano), using a truck/ shovel operation. (See Fig. 2). Conveyors and trucks transport run-of-mine coal to the heavy media/froth flotation process plan t, where it is cleaned and loaded into rail cars for delivery to the Ridley Island port at Prince Rupert, British Columbia. All coal is sold to the Japanese steel industry under a long term contract. The coal seams mined at Quintette are contained in the Lower Cretaceous Gates Formation. Mineable seam thicknesses vary from 0.6 m to 10 m. The regional structure of the area is typical of foreland fold and thrust belts, with open to tight folds and imbricate thrust faulting. The range of structural features found in the three pits, and their effect on mining, forms the subject of this paper.

Jan 1, 1991

By Yixian Zhao

Although many ultimate pit limit design algorithms have been developed for the past one- quarter century, only the well known Lerchs-Grossmann's (LG) algorithm is capable of producing a truly optimum ultimate pit limit today. This paper presents a graph theory oriented algorithm for optimum ultimate pit limit design. This algorithm produces a true optimal solution and maximizes the total undiscounted net profit for a given 3-D block mine model. The algorithm performs much better than the well known LG algorithm, in terms of the reduction in computation time and computer memory requirements. More importantly the new algorithm is easier to understand and implement than the LG algorithm. Specifically, this paper discusses: 1) the computer representation of arcs and the rules of arc generations which dictate the formation of trees in the graph, 2) the mechanism of joint support and re-allocation, 3) the properties, the general procedures of the algorithm, and the suggested specific steps to implement the algorithm, 4) comparison between the new algorithm with LG algorithm, and 5) some experience in implementation of the algorithm and two case study results.

Jan 1, 1992

By Paula N. Wilson, W. T. Parry

Carbonaceous and metalliferous black shales occur in close proximity to Mercur-type gold deposits in the southern Oquirrh Mountains, Utah. These shale units, the Manning Canyon shale and the Long Trail shale, have undergone regional hydrothermal alteration. Hydrothermal solutions oxidized organic matter and pyrite, replaced shale by hydrothermal phyllosilicates and silica, and replaced fossils by phyllosilicates. The shales are depleted in organic carbon, calcium carbonate, alkali and alkaline earth metals, and enriched in aluminum and hydrogen. Hydrothermal veins containing illite, chlorite, pyrophyllite, kaolinite, Fe-oxides, and sulfides are present throughout the study area.The illite in veins is an ammonium illite that contains up to 2 % NH4 and is correspondingly depleted in K. Correlations among Au, As, Hg, TI, Sc, and rare earth elements indicate that hydrothermal fluids responsible for formation of ammonium illite were gold bearing. K/Ar ages of illite veins and illite-rich, clay-size separates of altered shales indicate hydrothermal activity occurred in the time range 193 to 122 Ma. Several ages from clay-size separates within the Mercur district cluster near 160 Ma. These ages are coeval with thrust faulting recognized to the north and west.

Jan 1, 1990

By H. Wesley Peirce

Although not generally recognized, Arizona has rock salt deposits unique in the United States. This uniqueness stems from a combination of two factors: (1) relatively youthful geologic age and (2) nonmarine origin. Although Arizona shares one deposit with Nevada (Figure 1, No. I) there are three others within the State (Nos. 2, 4, 5) that are believed to be both late Cenozoic in age (less than 15 million years) and nonmarine in origin. The only other recognized nonmarine salt deposits in the U.S. are much older, being in the early Cenozoic (Eocene) Green River Formation of Colorado and Wyoming. According to Johnson and Gonzales (1), the remaining rock salt deposits in the United States are marine and either Paleozoic or Mesozoic in age. Of the seven localities shown in Figure 1, six in the Basin and Range geologic province are believed to represent nomarine late Cenozoic phenomena and one (No. 7) in the Colorado Plateau geologic province is Paleozoic (Permian) in age and marine in origin. The following comments are intended to update the general geologic highlights of these deposits and to summarize the nature of their present utilization.

Jan 1, 1979