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By K. N. Han, Q. Xu

The adsorption behavior of gold in ammoniacal solutions on activated carbon was studied. The gold adsorption capacity of the activated carbon and the recovery efficiency were examined. The parameters affecting the adsorption of gold on the activated carbon included temperature, agitation speed, the concentration of cation and anion and the concentration of ammonia. It was found that the maximum gold adsorption was about 10 kg/t of carbon. The recovery of gold by the adsorption, from ammoniacal solutions was found to be dependent upon the initial gold concentration. Under experimental conditions, a gold recovery of 98% was obtained after 120 hrs of adsorption. It was also found that the initial adsorption rate was relatively fast, when compared to the entire adsorption period. The apparent activation energy for the adsorption was determined to be 15.8 kJ/mol. It was believed that the kinetics of gold adsorption on the activated carbon was controlled by pore diffusion.

Jan 1, 1997

By Robert G. Moorhead

Fine-coal screening can be one of the most critical operations in a modern coal-cleaning plant. The yield and quality of clean coal produced in fine-coal circuits is controlled as much by how efficiently 0.15 mm (100 mesh) particles are sized as on the performance traits of the fine-coal cleaning device itself. In addition, the increased interest in effective fine-coal sizing operations indicates that many operators have also discovered its importance in affecting the quality and yield of clean coal produced in fine-coal circuits. This paper describes the three most prevalently used fine-coal screening technologies and discusses their sizing mechanism, performance, and application.

Jan 1, 1988

By Andrew F. McKown, Lewis L. Oriard

Advances in explosives engineering are moving forward in several different aspects. These include improvements and new development in explosives products, the application of these products to blasting technologies, and the study of the peripheral effects of the use of explosives, such as ground vibrations and airblast. Topics of special interest in the last several years include new explosives and detonators, cap timing, explosive casting, high-speed photography, perimeter and slope control, air decking and mathematical modeling of blasting processes.

Jan 1, 1988

By D. J. McKee, D. M. Wiseman

The usefulness of simulation as a technique for metallurgical process design and optimization studies has been greatly extended over the last few years by the development of a number of general purpose simulation packages. The packages, or simulators, all have the common objective of presenting the mathematical models and simulation methods in a form which is readily usable by plant engineers and metallurgists. To date, most simulators have been concerned with steady state simulation, but packages capable of dynamic simulation are now becoming available. The paper outlines the essential features of versatile steady state and dynamic simulators. Typical applications are presented by considering examples of design and optimization studies. Limitation on the use of simulators are also presented.

Jan 1, 1991

By Ernst Raphael

Mechanical drives of belt conveyor drives have experienced a huge amount of improvements concerning technology, manufacture and product structure that reduced investment and maintenance cost significantly. Most of these improvements were of technological nature in the'70s and '80s of this century; whereas, the present decade requires products that meet technical excellence as well as commercial advantages such as quick delivery, low cost and reliable spare parts supply. The best approach to meet these requirements is a highly modular and standardized system of reliable components that cover all demands a conveyor drive might require.

Jan 1, 1998

By André Vien, Robert Edwards, Rob Perry

A metallurgical control application can only succeed if the system's lowest common denominator, its instrumentation and regulatory control is implemented and maintained correctly. This paper describes the basics of regulatory control implementation including some practical guidelines for instrumentation installation, operator interface design, loop tuning, and continuous loop performance analysis. Tuning and analysis techniques are illustrated by step-by-step industrial examples. A small investment in basic control pays dividends in better overall plant performance and provides a solid foundation for advanced control efforts such as expert systems.

Jan 1, 2000

By Richard R. Klimpel

This paper discusses some important industrial interactions between size reduction and downstream froth flotation processes. Experience gained at the industrial level is clearly indicating that how size reduction circuits are designed and/or operated can have a significant impact on froth flotation beyond normal considerations of particle size, liberation, etc. Three specific interactions will be discussed: 1) the impact of steel grinding media versus autogeneous grinding on the efficiency of sulfide mineral flotation with varying thiol collectors and water sources; 2) the importance of appropriately utilizing the electrochemical window that is created in the grinding to enhance sulfide mineral recovery by froth flotation; and 3) the interaction of particle size distribution with collector dosage and frother type.

Jan 1, 1995

By D. R. Nagaraj

The practice of nonsulfide minerals flotation can be best characterized as an evolutionary blend of scientific theory and art. Although extensive fundamental studies have been carried out in the past several decades, and significant theoretical aspects have been developed, plant practice has developed the art form, often ahead of the theory, which is somewhat in contrast to sulfide minerals flotation. Several excellent review articles have been published in the past highlighting both the theoretical aspects and plant practice. An overview of nonsulfide flotation is presented here. Major differences in sulfide and nonsulfide flotation are highlighted. An assessment of the state of nonsulfide flotation, recent advances made in flotation processing, and industry needs are also given.

Jan 1, 1999

By Irwin R. Higgins, Richard S. Dennis

Acid recovery employs ion exchange resin as an adsorption media for the separation of inorganic acids from mixtures of acids and their metallic salts. This technology has been used to treat spent pickling and plating liquors to recover acid for reuse in the bath and to reduce waste acid neutralization costs. Acid recovery can also be used for electrolyte treatment to facilitate valuable metal recovery and to improve product quality. Conventional fixed bed ion exchange (I-X) systems are impractical for acid recovery because of complex control design and large resin inventories needed to process strong acid concentrations. TETRA'S CCIX™ continuous I-X contactor has been used successfully in a simple, continuous operating mode to separate acid from its salt. Efficient separation is enhanced by refluxing which allows acid to be produced as a salt-free product at nearly its original strength. Continuous treatment also recovers heat to the bath and improves metal quality due to consistent acid quality.

Jan 1, 1995

By Kenneth N. Han, Jianshe Liu

Various techniques used in the removal of metal ions from effluent streams have been reviewed. These techniques include recovery of metals by biological treatment, chelating agents, adsorption, ion- exchange and chemical precipitation. The main thrust of this paper however, is concerned with the removal of cadmium and zinc ions from the solution by adsorption utilizing liquid fluidized beds. The bed particles used were silica of 150x200 mesh. The range of the concentration of these ions studied was 10-3 to 10-5 M. Important variables examined included flow rate, concentration of metal ions and amount of bed particles. A mathematical model describing the concentration profile of metal ions in the axial direction in liquid fluidized beds has been developed. The equation of continuity was solved numerically and the results were used to predict the recovery of metal ions in fluidized beds.

Jan 1, 1992

By H. D. Freeman

The Pacific Northwest Laboratory (PNL) is developing cover technology for uranium mill tailings that will inhibit the diffusion of radon to the atmosphere. As part of this cover program, an improved radon flux measurement system has been developed. The radon measurement system is a recirculating, pressure-balanced, flow-through system that uses activated carbon at ambient temperatures to collect the radon. With the system, an area of 0.93 m2 is sampled for periods ranging from 1 to 12 h. The activated carbon is removed from the radon trap and the collected radon is determined by counting the 214Bi daughter product. Development of the system included studies to determine the efficiency of activated carbon, relative calibration measurements and field measurements made during 1980 at the inactive tailings pile in Grand Junction, Colorado. Results of these studies are presented.

Jan 1, 1981

By E. Topuz, M. J. McPherson, J. Banik

This paper summarizes the analyses of ventilation layouts for mines that experience both spontaneous combustion. The major focus is placed on the longwall coal mine layouts used in several countries. Each of the different layouts is modeled in the form of a ventilation network. The gob of a longwall panel is the most critical location for the occurrence of spontaneous combustion. Airflow leakage paths inside the gob are simulated by using a simplified grid-like network. Computer simulations with this model indicates that the W-system of ventilation is most effective in minimizing air leakage into the gob. Homer, the U-system of ventilation, with pressure balancing behind the face support line, is also found promising for longwall panels. The magnitude of air leakage into the gob is observed to change with the advance or retreat of bee, thus requiring appropriate balancing of pressure to maintain the leakage at a minimum.

Jan 1, 1995

By Eugene Honeycutt, David Gallagher, R. E. Melley, Nick Madison

Drummond Co. Inc.'s Shoal Creek Mine slope conveyor is the highest lift, highest horsepower, highest tension conveyor system in North America. The system has a capacity of 4950 t/h (5500 tph), a vertical lift of 360 m (1180 ft) and a total connected power of 6000 kw (8000 hp). The mine will include 2 longwall machines and 5 to 7 development sections. Annual raw production will approach 9 million tly (10 million tpy). This paper describes the early investigation of system capacity, haulage system options, and the final selection of a single flight belt conveyor. It will review the basic system de- sign and equipment selected. Also included will be some highlights of the installation of the conveyor system.

Jan 1, 1996

By L. Xiao, P. Somasundaran

Three major types of solution chemical equilibria-involving minerals, solution, and flotation reagents such as collectors, frothers and modifiers-play a crucial role in determining the behavior of complex flotation systems. Minerals of phosphates (apatite and francolite), tungsten (wolframite and scheelite) and associated carbonates (calcite and dolomite) are sparingly soluble in aqueous solution and form dissolved mineral species in bulk solution. Such dissolved species interact with mineral solids, often resulting in surface conversion of the minerals. In addition, they can interact with various floation reagents and lead to surface or bulk precipitation and loss of selectivity in the flotation. Relevant solution equilibria of such sparingly soluble minerals and their interactions with oleic acid and structurally modified reagents were determined in this study using a multi-pronged experimental approach. Methods to manipulate and control the solution chemical equilibria and thus achieve selectivity in flotation systems are discussed.

Jan 1, 1992

By George J. Bujtor, Anthony K. Scott, Haddon F. King

In 1982, the result of a 3-year study was published as "A Guide to the Understanding of Ore Reserve Estimation". The principal conclusions were that computation formed only part, and perhaps not the most important part, of an estimate and that the estimate should recognize that geological, mining engineering and metallurgical judgements formed an essential part of the eventual result. Subsequent expectation/realization studies of several mines have produced case histories which form the principal basis of the paper. These imply that geology is even a larger factor than thought earlier.

Jan 1, 1992

By D. Robert Weir, M. J. H. Ruscoe, R. M. Berezowsky, M. A. Clegg

The metallurgical processing involved in the produc-tion of the new Canadian one dollar coin is reviewed starting with the hydrometallurgical production of pure nickel powder, followed by the powder metallurgy process for the production of nickel strip and coinage blanks, and concluding with the Aureate bronze electroplating and heat treatment procedure. Coinage requirements are then reviewed with regard to economic, public acceptance, and service requirements. Finally the properties of Aureate nickel coinage are presented in the light of the many and varied coinage requirements, and it is concluded that the new Canadian dollar coin exceeds the requirements admirably.

Jan 1, 1990

By S. G. Malghan

This paper reviews uses of sodium sulfide in the flotation of oxide minerals of copper, lead, and zinc. The activation and depression effects of sodium sulfide are of particular importance because of their applications with oxidized lead and copper ores. In spite of its industrial importance, the nature of the heterogeneous reactions between sulfide ions in solution and the surface of oxidized minerals has not been fully understood. Hence, proposed mechanisms of the sulfide action in flotation, methods of measuring and monitoring sodium sulfide in flotation pulps, and variables influencing the sulfide addition are analyzed. Recent studies on sodium sulfide addition to flotation pulps, monitoring its concentration, and the optimum dosage control using platinum and/or sulfide specific ion electrodes are discussed.

Jan 1, 1987

By E. Suoninen, K. Laajalehto, L. Kartio

Efficient separation of pyrite from other sulfides is of great importance for the metallurgical performance of flotation processes. In this work Fourier Transform Infrared Spectroscopy (FTIR) and X-ray Photoelectron Spectroscopy (XPS) were used to study the surface chemistry of pyrite in depression, activation and xanthate adsorption under conditions of controlled potential. Modifications of pyrite surfaces after treatment with depressants (lime, sulfur dioxide, sodium cyanide) and after activation with metal ions (Cu, Pb) were studied. The principal adsorption product identified on pyrite was dixanthogen whose formation started at about +0.15 V and +0.25 V (vs, SHE) in ethyl and amyl xanthate solutions, respectively. Copper xanthate was formed on copper(II) activated pyrite. Activation mechanism of pyrite by copper(II) salts is likely to be electrochemical where copper occurs as copper(I) on the surface of pyrite. Effective depression is achieved by sulfur dioxide and sodium cyanide. Depression at high pH is due to formation of iron(III) hydroxides. Calcium ions do not affect the electrochemistry but adsorb on pyrite and reduce the surface sites for dixanthogen adsorption.

Jan 1, 1995

By W. K. Tolley, D. G. Kotlyar

Oxidized sulfide minerals, commonly formed by weathering, are becoming increasingly important resources as primary sulfide deposits are depleted. Oxidation, in general, reduces selectivity and recovery in flotation. The objective of this research was to determine the mechanisms of oxidation and collector adsorption in sulfide systems as a step towards developing improved technologies for beneficiation of oxidized sulfides. Data from microcell flotation tests are combined with electrochemical and spectrophotometric measurements. The adsorption of ethyl xanthate (EX) on oxidized sulfides was characterized using AC impedance and voltammetry techniques, and correlated to flotation response. Oxidation resulted in an electrically resistive, nonporous surface layer. The floatability of chalcocite, chalcopyrite and pyrite was dependent on the extent of oxidation. Oxidation for one day or more at 65ºC suppressed chalcocite flotation. Oxidized chalcocite also inhibited flotation of chalcopyrite and pyrite. Oxidation caused decreased chalcopyrite flotation. Pyrite flotation, however, increased after oxidation.

Jan 1, 1995

By G. T. Adel

During the past decade, researchers at Virginia Polytechnic Institute and State University have worked to develop a novel flotation process for treating very fine particles. This process, which is now commonly known as [microbubble column flotation] (MCF), has been shown to be very effective in a number of applications related to fine coal processing. These applications include the retrofit of existing preparation plant circuits and the recovery of additional coal fines from refuse streams. In addition, work conducted under the sponsorship of the United States Department of Energy indicates that the MCF process is capable of producing superclean and ultraclean coals from many eastern U.S. coals. This paper describes some of the basic problems associated with fine particle flotation and the design and operational features of the MCF process used to minimize these problems. Also presented are the results of ongoing pilot- and field-testing programs.

Jan 1, 1989