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One of the most frequently asked questions at the feasibility study stage of a project is, æhow big can one go?Æ This important question effects costing and efficiency of metallurgical equipment, the real estate required and the operating plant strategy.The presentation covers both engineering and process considerations and explains the limits that exist today and explores future trends.The paper is specific about large slurry application usually found in gold applications; however, it could apply to silver and uranium or other dense media leach duties.Agitator drive sizes are examined as well as process risks associated with large tank agitation. New technology has increased the maximum tank size and designers are now experienced in tank volumes in excess of 5000 m3. Tanks of 6000 m3 have been agitated and 10 000 m3 tanks are within present engineering know-how and scale-up.Fabrication techniques for shaft and impeller designs exceed the existing standards and new specifications will be needed to cover large mixer design. The paper covers certain aspects of mechanical design and proposes alternative standards that are more appropriate. Process considerations such as fluid natural frequency as well as typical superficial velocities for efficient operations are examined. Scale-up techniques based on existing and new technology are also examined to ensure a successful installation.The presentation therefore covers the majority of large mixer design questions that are frequently asked.

Jan 1, 2006

By Beeby C. j, Fernando W. J, Ming M. Q I, Guang Li Xi

Removal of moisture in steam-fluidized, mainly steam-heated, fluidized beds makes possible significant energy savings over conventional forms of large-scale drying. The systens are described and their applications to brown coal and alumina hydrate are reviewed. In application to brown coal the use of the system to permit meeting diurnal variation in power station output, and the use of triple-effect drying to minimise coal usage and to avoid the necessity of recovering in the turbines the energy in the steam from the last dryer are discussed. To facilitate the rapid adoption of the systems proposed, studies are being made of heat-transfer to dried coal, of moisture equilibrium in pressurized and vacuum systems, of tapered beds as a means of reducing carrier steam and permitting wider size variation, and of the use of carrier solids for drying lump materials.

Jan 1, 1989

By P Bourke, S Ronkainen

Since the early days of flotation, process technicians have known that the speed at which the froth is recovered over the lip of the cell has a very direct and consistent influence on the grade and recovery of the circuit. No plant would deny that, even to this day, one of the most important aspects of a process technicianÆs job is ensuring that the froth is moving at a desired and controlled speed over the lip. Unfortunately, process technicians cannot watch the froth throughout the entire shift, as there are always other problems to attend to. A considerable amount of work has thus been done to develop a æsystemÆ that automatically measures the speed of the froth. This measurement would then be used in simple controllers to emulate the steps taken by the process technician in correcting deviations of the froth speed from its desired level. Many of the earlier attempts to measure speed were ineffective, as they were unable to cope with turbulence on the froth surface. The FrothMasterÖ instrument makes use of machine vision technologies to measure the speed of the froth over the lip of a cell at a very high sampling rate. This instrument produces an extremely reliable and accurate measurement of the froth speed (as well as other parameters such as bubble size and froth stability). As we will show, the effectiveness of the speed measurement in controlling the performance of the plant is a testimony to its reliability. Three FrothMasterÖ units have recently been installed on the Cadia Hills Gold Mine in New South Wales (Australia). The objectives of this installation were:to control the mass-recovery of two Tank Cells in series on the same level where differences in the hydrostatic head between the two cells result in the cells pulling inconsistently with respect to each other; control of the concentrate grade (per cent copper) from the first rougher; reduction in the frother consumption in the rougher circuit by monitoring the froth speed. A simple controller was designed to react to disturbances in the same way that human operators react. This was done after consultation with the metallurgists and the process technicians at Cadia. The controller had two functions: Stabilisation: The stabilising controller made use of three manipulated variables (level, frother addition rate and aeration rate) to control the froth speed to a setpoint. Optimisation: The optimising controller adjusted the froth speed setpoint based on deviations of the grade (measured in real-time by the OSA) from a setpoint. The plant metallurgist adjusted the grade setpoint based on information about the ore. The results from a 21-day trial have shown the following:The ratio of concentrate mass-recovery between two cells in series on the same level has been successfully balanced, thereby overcoming problems due to differences in hydrostatic heads. It is possible to control the speed of the froth, in mm/s, to within five per cent of its setpoint using the aforementioned manipulated variables. It has also been shown that, for reliable control, it is necessary to control more than just one variable (eg level or air). The grade of the first rougher concentrate has been controlled to within 0.3 per cent of the grade setpoint for long periods of time, which has important implications for the circuit recovery. The frother consumption has been reduced significantly. This paper will thus show that substantial progress has been made to demonstrate the value of using on-line froth speed measurements in flotation plant control to obtain real financial benefits.

Jan 1, 2000

By K A Plumb

New structural studies in the Walker Fault Zone of eastern Arnhem Land are integrated with basin-wide reconnaissance observations, made to refine models for the structural evolution of the McArthur Basin and provide new insights into the nature of metal logenetical ly important pre-inversion phases of the basin's evolution. At least five principal events may be identified during the Proterozoic: The Tawallah Group and equivalents were deposited throughout the McArthur Basin during an extensional event. Rifting of an incipient Batten Trough occurred at this time, in a terrain characterised by orthogonal, linked extensional faults. Uplift and erosion of the Tawallah Group accompanied continuing extension and was penecontemporaneous with continuing deposition of the overlying Parsons Range Group, within a precursor to the Walker Trough. Dt (of the Walker Fault Zone) relates to a new rifting event, penecontemporaneous with deposition of the McArthur Group and its equivalents in the Walker and Batten Troughs. This rifting accompanied dextral strike-slip faulting along northerly-trending bounding faults, as a result of northwesterly-directed oblique extension, leading to pull-apart basins. D2 inversion of the Batten and Walker Fault Zones pre-dates deposition of the Roper Group. In the proposed model WNW-ESE directed shortening (D2.), accompanied by folding and thrusting, and by local development of cleavage in the Walker Fault Zone, is seen to be followed by northerly-trending sinistral faulting (D2b), about a SE to ESE-directed compression. D3 is basin-wide and post-dates the Roper Group. It is characterised by conjugate faulting and folding about ENE to NE-directed compression. The latest Proterozoic event to be identified (D4) comprises widespread north-trending strike-slip dextral faulting of Roper Group, coupled with N-S directed thrusting across the Urapunga Fault Zone and Murphy Inlier This is accompanied by late dextral reactivation of NNW to NNE-trending faults in the Walker and Batten Fault Zones.

Jan 1, 1994

By G W. Wilson, P Ritchie, N A. Currey

The design and rehabilitation of potentially acid forming (PAF) waste rock dumps is site specific, being a function, among other factors, of the rock types, the dumping and storage method employed, and the climatic setting. The æstore and releaseÆ cover system developed to manage acid rock drainage (ARD) from mineralised waste rock dumps at Kidston Gold MinesÆ open pit operations in the semi-arid climate of North Queensland, Australia, has been monitored for seven years. The paper describes the philosophy behind the design of the PAF dump and æstore and releaseÆ cover system and the adaptation of the cover system over time to suit KidstonÆs conditions. The results of monitoring over the seven years since the first cover was constructed are presented, and the approach being taken at Kidston to ensure that the risk of impacts from any residual ARD is accommodated and to facilitate lease surrender are described. The Kidston story is a valuable case study of a successful approach to remediating an identified source of ARD in a semi-arid climate, which has actively engaged all Stakeholders.

Jan 1, 2003

By Neill T. J, Howarth D. F, Malcolm J. McPhersqn

For many years Isa Mine has seen the need for a continuous mining machine which will economically cut hard rock. Tunnel borers are unsuitable due to the size and inflexibility of the machine and the shape of excavation mined. The design of roadheader type machines will not permit the use of the necessary cutting technology. in 1983 a joint project was undertaken by The Robbins Company and Mount Isa Mines Limited to develop and to trial a machine suitable for cutting hard rock in an operating mine. The project was based on the proven technology of raiseboring applied to horizontal development. The Mobile Miner was fabricated and trialled in a disused quarry in the U.S.A. during early 1984. Following these trials, the machine was transported to Mount Isa and commenced mining in September that year. The initial duty was to continue the development of a decline commenced by conventional mining for a conveyor system to serve the deeper southern areas of the 1100 copper orebody. This system will permit direct tipping of copper ore to a new crusher complex and conveying of the - crushed ore approximately 2 kilometres to the central hoisting shaft facilities. The Robbins Mobile Miner MM120-3001 uses a vertical rotating cutting wheel mounted on a horizontal swinging boom to excavate a nominally rectangular shaped heading. The cuttings are collected on an apron and conveyed back through the machine. The resulting excavation is smooth-walled with no blasting damage to the surrounding rock. This provides a safer working environment than does conventional drill and blast development mining. Ground support requirements are considerably reduced.

Jan 1, 1986

By C M. Sennitt, M J. Spadafora

Systematic field evaluation of known gold and clay occurrences in South Korea has led to the recognition and discovery of both high and low sulphidation gold-silver epithermal systems. These are associated with Cretaceous acid-intermediate volcanic centres in the southern parts of the peninsula. The high sulphidation deposits such as Seongsan and Kohung are characterised by pervasive silica-alunite-dickite-pyrophyllite alteration with anomalous arsenic geochemical signatures. Gold mineralisation is associated with fine grained marcasite and pyrite. A low sulphidation quartz vein system observed at the Tongyoung mine comprises multistage colloform banded quartz-carbonate assemblages, with minor manganese and base metals. Gold and silver occur as electrum and tellurium minerals. Some deposits such as Gasado and Dogcheon display both high and low sulphidation alteration assemblages. Early pervasive silica-alunite-pyrophyllite alteration caps formed by acid fluids with a significant magmatic component, occur above cryptocrystalline colloform banded vein systems. The quartz vein stage hosts the precious metal mineralisation and appears to have been deposited by later neutral fluids generated in part through mixing with meteroric water.

Jan 1, 1999

The old Trekelano mining area is situated in the Cloncurry Gold and Mineral Field 14 km east-south-east of Duchess. It connected with the main Cloncurry-Dajarra railway line by a private line from Juenburra, a distance of 10 km. The distance by rail from Townsville is 561 km. The area was first mentioned circa 1902 - 1903 when a very short report said, that a Tony Allis had taken a parcel of copper ore out of a mine which, he called æThe InheritedÆ. After that report, nothing further was printed until about 1906, when traces of copper were noticed on a wagon track going to Kiama Well. The Trekelano deposit did not outcrop, with the cap covered by about two metres of soil. The deposit was named after an early pastoral holding. The early prospectors were however disappointed by TrekelanoÆs low copper grades, approximately five per cent Cu. This is understandable when, in those days, about 25 per cent was the cut-off grade for mines in the district. Meanwhile, The Hampden Mining and Smelting Company were constructing a smelter to treat their sulphide ores at Kuradala that was replacing their high grade oxides ore. By about 1910, the Hampden Mining and Smelting Company was experiencing smelting problems, and needed suitable oxidised copper ore to blend with the Kuradala pyritic ore. Someone must have remembered the Trekelano low-grade oxides, resulting in agreement to mine and cart the ore to Duchess, from where it was railed to Hampden, as Kuradala was known at that time.

Jan 1, 1998

By M.J. Mitchell

Platinum-group minerals (PGM) are recorded from a number of localities along the Waiau River, western Southland, and the south coast of the South Island, New Zealand. At each locality, small amounts of PGMs were recovered as by-products of historical gold mining operations. During the period 1890-1950 an estimated 1000-2000 oz. of "platinum" were recovered from the region, the only area within New Zealand where PGM have been commercially exploited. The PGM suite of southern New Zealand consists of Pt-Fe alloys, IPGE (iridium subgroup, platinum-group elements) alloys, sperrylite (PtAs2), cooperite (PtS)and braggite ((Pt,Pd)S). The composition of Pt-Fe alloy exhibits considerable variation and two compositional populations are recognised. Some Pt-Fe alloy grains are chemically zoned. Iridium is the most abundant IPGE alloy phase and often contains considerable Pt, in contrast to osmium and ruthenium alloys. Cooperite and braggite grains are characterised by extremely low concentrations of Ni. R^~

Jan 1, 1995

By P Hatherly, A Melkumyan, D Wyman

Chemical species distributions in rock sequences can be modelled using Gaussian processes (GPs) to predict the weight percentage between known data points. This method can be improved by dividing the modelled area into regions of different mineralogy. In the context of many iron ore deposits, marker shales give the initial guidance of where these regions may lie. These shales give rise to distinctive peaks in the natural gamma downhole logs, which are conventionally identified by hand. A GP method has been developed to automate this task.Once the appropriate boundary has been located on the basis of shale occurrences, chemical assays from exploration drill holes are used to find the exact boundaries of interest. These boundaries divide the drill hole stratigraphy into regions of different mineralogy, each of which display their own distinct correlations between the main elements and oxides (Fe, SiO2 and Al2O3). Iron ore shows a negative correlation between Fe and Al2O3, but in banded iron formation (BIF) there is a positive correlation between these species. Similarly, SiO2 and Al2O3 have a positive correlation in the shales and ore but a negative correlation in the BIF. Correlations obtained within ore-, BIF- and shale-dominated regions are therefore better than those obtained using the entire log and can be used to improve the results obtained when modelling.

Sep 26, 2011

By D Reid, A Fourie, J Ayala

This paper discusses cone penetration test correlations for loose gold tailings that were developed within a critical state soil mechanics framework. The development of a new calibration chamber for cone penetration testing that consists of a modified triaxial cell is described. Some of the early development and commissioning issues that were encountered, as well as the solutions adopted are outlined, including the system to prepare the samples and to acquire high-quality data from the testing. Also, the triaxial laboratory testing required to achieve the critical state line is described, including some of the basic precautions considered necessary as good practice. Additionally, the system adopted for volume tracking of the calibration chamber sample is described, which is essential for ensuring a reliable state parameter comparison against the acquired cone penetration test data. Finally, some laboratory test data from the calibration chamber is plotted against the soil behaviour type charts currently available from various authors.

Jul 1, 2021

By J Naser, M Tuck

This paper reports a computational study using computational fluid dynamics (CFD) in a mine ventilation system. Ambient air is injected to a rectangular mine drive through a circular duct. Moisture evaporates from shaft wall depending on flow properties of air in the drive-duct system. The physical process involves simultaneous momentum, heat and mass transfer. A species transport equation is employed to account for the moisture concentration in air. The momentum equation is solved using standard k- model, while energy and species transport equations are solved using standard expressions for moisture evaporation rate and heat flux from the drive wall. The aim of this paper is to investigate effectiveness of CFD simulation in relation to mine ventilation in a drive where a significant mass transfer phenomenon occurs. Results from simulation are compared with existing data from a site in Victoria.

Jan 1, 2005

By S D. Dessureault

In one of North AmericaÆs largest mines, which contains more than six active coal-producing faces, mine controllers must meet the complex challenge of adhering to the mine plan while also ensuring customer quality. Fleet management systems (FMS) provide many different avenues to control production flows, from the faces to the various pit crushers. Nonetheless, mine controllers must balance a variety of factors such as unplanned downs, differing customer demands, their own daily key performance indicators (KPIs) related to equipment utilisation, among others. Deviating from the short-term mine plan is the most common means of balancing the other factors, since adherence to the plan is traditionally only measured during the weekly variance meeting with engineering staff. However, such deviation may be one of the most costly responses, as long-term scheduling issues may arise such as multi-face dead-heading or insufficient stripping. This paper focuses on the development of a system for real-time adherence to mine plan within a control room environment. This system is part of a larger blending-focused, multi-million dollar project with elements of a centralised remote control room, developed at the University of ArizonaÆs Mining Information Systems and Operations Management (MISOM) Mine Control Center (MC2). The mine plan (MPL) component of the overall blending system integrates both historical and real-time FMS data with mine plan requirements directly sourced from original systems (no additional input required). The measures, displayed largely as graphs, have tools to help controllers manage the production to facilitate adherence to the plan. Some measures are designed to motivate crews to perform by inciting competition between crews, softened through a study of the controller culture. The MPL component was deployed at the mine, and the before and after deployment adherence was measured. This paper discusses the technical development of the new tool, its deployment, and an ethnography (study of culture) to understand controller motivation.

Sep 26, 2011

By R Castedo, P Segarra, L M. López, J A. Sanchidrián, A P. Santos

The cylinder test allows us to determine the expansion of a copper cylinder by the detonation of an explosive charge inside. This test, originally designed for military explosives, has been adapted for industrial explosives with non-ideal behaviour. From data obtained with this test and known physical relationships, an analytical procedure has been developed to calculate the Jones-Wilkins-Lee (JWL) equation of state parameters for five ammonium nitrate/fuel oil (ANFO) and six emulsion-type explosives. A new radial wall expansion function is proposed considering a non-zero initial velocity with the consequent positive Gurney energy at unit relative volume. A set of equations is established to determine the JWL parameters, three of them obtained at the Chapman-Jouguet (CJ) point and the other three at different relative volumes. These equations, along with some constraints to ensure a physically sound solution, are solved for the JWL parameters by a non-linear least squares scheme. A 2D Lagrangian axisymmetric finite elements (FE) numerical model is developed for each tested explosive to validate the analytical results, in terms of expansion histories, with good agreement. This confirms that the set of conditions, constraints on the parameters and least squares calculation used constitute a robust methodology that fully captures the physics of the detonation products expansion involved in the cylinder test.CITATION:Castedo, R, Sanchidrián, J A, López, L M, Segarra, P and Santos, A P, 2015. Jones-Wilkins-Lee parameters for civil explosives, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 57–64 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By MattelmSki M

Outokumpu Harjavalta Metals Oy has been producing nickel since 1962, based on conventional flash smelting technology followed by electrowinning of nickel. In the 1980s, a research project was initiated to develop a converterless direct smelting process to produce matte for further refining in the then existing refinery. The process was tested on a pilot plant scale at Outokumpu's research centre in Pori and was found to be viable. The process was named the Direct Outokumpu Nickel Smelting Process or the DON Process. At the turn of the 1990s, Outokumpu studied various options to develop its nickel business and the Harjavalta operations. As a result of this work, the DON Process was further developed to produce two mattes: low iron matte in the flash furnace to be leached in the existing leaching circuit and high iron matte in the electric furnace to be leached in the new leaching circuit. In Harjavalta's case, it was essential and important that the process could use the existing flash furnace and electric furnace without converters.

Jan 1, 1996

By D Chalmers

After the sustained use of the GAG (Górniczy Agregat Gaśniczy) engine at a Queensland coalmine, it has raised questions as to its effectiveness as a remote firefighting tool. All firefighting apparatus have advantages and limitations, however the deployment of any apparatus must be based on its likelihood to succeed and effectively extinguish the fire or bring it under control. A recent study conducted for ACARP by researchers at UNSW has highlighted that there is more to be learned about the GAG. As coalmines are mining at greater depths and fan pressures are much greater than they were when the GAG was introduced, deploying the GAG may be a total waste ofresources and may place operators at greater risk. When the GAG unit is positioned on the surface of the mine, the pressure it generates has to overcome buoyancy of the exhaust gases and the frictional resistance of the borehole and part of the mine circuit. Buoyancy in deeper holes can lead to the GAG pressure relief system opening, venting out the products to the atmosphere without delivering any product to the mine workings. Additionally, frictional resistance is a function of distance. Deeper holes will have a greater frictional resistance than shallow holes. Delivering sufficient products from the unit will be limited by the available pressure that has to overcome the buoyancy, and increased mine resistance thatconsumes any residual pressure. By documenting the limitations of this unit it will enable better decisions to combat a fire or spontaneous combustion event.

Oct 12, 2022

The unique chemical and physical properties that can be displayed by polypropylene and its copolymer derivatives are enabling its development as a truly versatile material for water filtration. Well known applications include spiral wound cartridge filters commonly used for household water or the office drinking fountain, to pressure membranes that provide micro, ultra or nano size filtration barriers, whilst needle-felt or woven cloth filter belts or inline pressure bag cloths are well known to the hydro metallurgist and process engineer. A relatively new filtration concept that is generating interest and applications across all industries including the mining sector involves use of a unique fabric type filtering media made from polypropylene fibres. This technology not only has a vastly wider window for potential applications, it delivers an attractive cost saving alternative to the traditional sand media or diatomaceous earth type filters, along with potential benefits for integrated filtration units. This paper discusses the proven potential of the fabric media technology with examples of performance comparisons and confidence gained from full scale operating installations at mine sites and other locations.

Jan 1, 2004

By Y Tang, G Si

The analysis of rock fragment sizes plays a pivotal role in various stages of geotechnical and mining engineering. Traditional case-based methods often falter in addressing the variability in rock fragment images due to fluctuating geological conditions and imaging environments. To counter this challenge, AI-based models necessitate training on expansive and diverse data sets, encompassing a wide range of conditions and fragment types. However, the creation of such data sets is often hampered by financial and environmental constraints. This paper introduces a novel approach for rock fragment recognition, which leverages the power of AI for data augmentation, automated annotation and prediction. The methodology integrates three key components: Style-Based Generator Architecture for Generative Adversarial Networks (StyleGAN) for data augmentation, the Segment Anything Model (SAM) for automated annotation, and the multiscale version of you only look once (YOLO-MS) real-time instance segmentation model. The proposed method begins by training a new StyleGAN model using the original data set. It then delves into exploring the latent vectors of different rock fragment images to generate specific ‘style representations’. These latent vectors form the foundational elements of each image in a high-dimensional space, encapsulating critical features such as size, shape, texture, and colour variations. The next step involves conducting quality checks on the generated images to ensure their realism and suitability as training data. Subsequently, the augmented image set is annotated using modified SAM module, followed by training the YOLO-MS real-time instance segmentation model. The performance of this model, trained on the augmented data set, is compared with a model trained on the original data set, particularly in terms of generalisation abilities in new scenarios. The results exhibit a significant enhancement in accuracy, robustness, and generalisability of the model trained on the augmented data set, underscoring the potential of StyleGAN as a powerful tool for data augmentation in geotechnical engineering image analysis.

Sep 1, 2024

By L Xiong, W J Shi, J H. Wei

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. The Baizhangzi gold deposit is located in the northern North China Craton. The structural and lithological controls on the location and geometry of orebodies were studied through geologic survey, ore spatial configuration analysis and structural analysis. The orebodies of the deposit comprise auriferous quartz-sulfide veins and disseminated gold-bearing sulfides. The auriferous quartz-sulfide veins are dominantly hosted by the NNE- (and NE- and NW-) trending faults, which are subsidiary structures of the regional NNE-trending F2 fault. The subsidiary NNE-trending faults, having sinistral reverse kinematics, are associated with the sinistral reverse kinematics event of the F2 fault, which happened under a regional S–N-oriented compression stress field. The subsidiary NE- and NW-trending faults appear to be compressive and extensional respectively. These NE- (and NW-) trending faults are restricted to the granite intrusion and are associated with a sinistral strike-slip event of the F2 fault, which reactivated under a NW–SE-oriented compression stress field. It makes significant influence on geological evolution and distribution of different ore types that the strike of the F2 fault presents significant transition from NNE- to NE-trending in vertical. The ore-bearing disseminated host rocks, with widespread silicification and pyritisation, distribute in the lower inner contact zone of the granite intrusion, especially in the lower wavelike boundary of granite intrusion.CITATION:Xiong, L, Wei, J H and Shi, W J, 2015. Structural and lithological controls on the location of orebodies in the Baizhangzi lode gold deposit in western Liaoning Province, China, in Proceedings PACRIM 2015 Congress, pp 193–200 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

Titanium tetrachloride may be reduced to trichloride with hydrogen on a hot tungsten filament and other hot: surfaces. The effect of temperature, time and size of t.he filament on the rate of reaction has been studied. A laboratory unit for preparing a few pounds of trichloride at a time is described. The yield of trichloride is 2·2 - 2·4 gm/sq. cm. of hot surface/hour at 1,000°C. and the energy requirement 3'5-4 kWh/pound of trichloride produced.'INTRODUCTIONThe lower chlorides of titanium (titanium tri- and dichlorides) are amenable to electrolysis, being electrovalent in nature. Furthermore, relative to other oxygen-free titanium salts, they are easy to prepare in a pure state and their use has been investigated to prepare titanium. The experimentaJ work described in this paper deals with the preparation of titanium trichloride by reduction of titanium tetrachloride with hydrogen on hot surfaces.REDUCING AGENTS FOR TITANIUM TETRACHLORIDEThe free energy diagram (Fig. 1) for the formation of chlorides suggests that titanium' tetrachloride may be reduced to trichloride by various reducing agents such as aluminium, zinc, arsenic, antimony, tin, mercury, silver, hydrogen, sodium, potassium and magnesium. Ruff and Neumann (1923), Thorpe (1885) , Billy and Brasseur (1935) and Seurbert and Schmidt (1892) used various metals to reduce tetrachloride to trichloride and found that the yields were invariably low and the products difficult to separate.Besides the metallic reducing agents, hydrogen may also be used to reduce titanium tetrachloride to trichloride.Goerges and Stahler (1909) obtained a deposit of violet...

Jan 1, 1956