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By M I. Pownceby, N A. S Webster, J R. Manuel, J M. F Clout, E Donskoi, N A. Ware

The relative influences of sinter mineralogy, sintering temperature, solid and pore macro- and microstructure on iron ore sinter physical strength are not yet fully understood. Whilst a range of analysis techniques have been used by researchers to evaluate sinter physical properties and sinter mineralogy, none have been able to directly link sinter mineralogy and physical strength under controlled conditions. CSIRO has developed a unique laboratory method to study the fundamental melting properties of fine iron ores in a laboratory furnace under a controlled temperature and gas atmosphere environment designed to simulate the industrial sintering process. Compacted tablet samples for a 0.41 per cent and a 2.5 per cent Al2O3 series were fired in a tube furnace at various temperatures, cooled, then tumbled using a modified Bond abrasion test apparatus to determine a relative tumble index (TI) at each temperature. Quantitative XRD (QXRD) analysis was then carried out on the tumbled samples and optical image analysis (OIA) was conducted on polished sections of a separately fired compact in each case. The amount of total SFCA was found to decrease with increasing firing temperature for both alumina series with the total amount of SFCA higher in the 2.5 per cent Al2O3 series compared to 0.41 per cent Al2O3 series samples. The increase in the amount of magnetite and hematite with increasing firing temperature was largely at the expense of a decrease in total SFCA. Overall, there was good agreement between the quantitative mineralogy determined from QXRD versus OIA for SFCA, hematite and magnetite. Qualitative analysis of high magnification images of the sinter correlated with both the OIA and QXRD results.

Sep 18, 2023

By S Mitra, D O’Dea, N Barrett, T Honeyands, E Copland

This work describes a novel mapping technique that allows the direct overlay of calculated local phase equilibria on micrographs of the physical system. The technique demonstrated integrates FactSage™, ver 8.2 (by Thermfact Ltd. and GTT-Technologies) phase equilibria calculations with mapped compositions determined by Scanning Electron Microscope – Energy Dispersive X-ray Spectroscopy (SEM-EDS) to visually express calculated properties while preserving the spatial information of the sample. The developed methodology is used to analyse interrupted blast furnace softening and melting tests containing mixed burdens of lump and sinter. Tests are interrupted at 1300C and cooled to room temperature for analysis. Phases present at room temperature are analysed to infer the liquid fraction and phases present at high temperature. Analysis of the interface regions between the dissimilar burdens allows insights to be gained into the interaction mechanism. During the transition from solid to liquid, migration and interaction of liquid oxide across the interfaces of the dissimilar burdens has been observed and demonstrated to impact softening and melting performance. Specifically, interaction of the oxides generated by lump (primarily FeO, SiO2 and Al2O3) and sinter (primarily FeO, CaO, SiO2, Al2O3 and MgO) are analysed, and the occurrence of a range of new mineral phases such as merwinite, melilite, olivine and bredigite observed.

Jun 19, 2024

By Mouritz M

Ventilation characteristics and the occurrence of nocturnal surface inversions have been investigated within the Mount Whaleback open cut iron ore mine at Newman in Western Australia. When winds are light and/or nocturnal surface inversions form within the pit, episodes of atmospheric stagnation can occur with resultant accumulation of dust, diesel exhaust fumes, and sulphur dioxide evolved from spontaneous combustion of pyritic shale. Nocturnal surface inversions were recorded outside the mine on more than two-thirds of nights. Inside the pit, inversions were much less frequent - occurring on roughly 20% of nights when they were observed outside - and much weaker - the maximum temperature difference being 5 C¦ over 210 m inside the pit compared with 15 C¦ over 150 m outside.

Jan 1, 1988

By S van der Sluijs, M van Ende, Y Tang, A Emami

This paper presents a phenomena-based model for investigating the possibility of scrap melting in an Open Slag Bath Furnace (OSBF) for green ironmaking. The goal of this study is to enhance the circularity of the steelmaking process by utilising scrap as a green source of iron in OSBFs. The model takes into account the fundamental differences between OSBFs and traditional processes such as Electric Arc Furnaces (EAFs) and Basic Oxygen Furnaces (BOFs). The model considers three primary regions where scrap heating and melting occur: the solid feed pile, slag and hot metal. It accounts for factors such as the furnace geometry, scrap charging mechanism and specific heat and mass transfer properties of the reactor. The model was validated using literature data and was used to investigate the heating and melting behaviour of individual scrap particles under various process parameters. The study finds that the scrap melting process in OSBFs involves three stages: shell formation, shell remelting and subsequent melting of the parent scrap. The carbon content of the scrap and the liquid hot metal plays a critical role in determining the melting behaviour. Depending on the carbon concentration and temperature, the melting process can be heat transfer controlled or mass transfer controlled. The paper also examines the scrap feeding methods in OSBFs, including direct charging into the slag or charging through a feed pile. The model provides insights into the melting rate of scrap compared to Direct Reduced Iron (DRI) in OSBFs and highlights the role of carbon in this process. Overall, this phenomena-based model contributes to the understanding of scrap melting behaviour in OSBFs and provides valuable insights for optimising the circularity and efficiency of green ironmaking processes. The findings of this study can inform the design and operation of OSBFs, paving the way for increased utilisation of scrap as a sustainable feedstock in the steel industry.

Jun 19, 2024

IN presenting the following short paper the writer hopes to illustrate some uses of explosives in industrial work under conditions different to those prevailing on mining fields. This paper is based on experience gained at the Newcastle steel works of the Broken Hill Proprietary Company Limited. The management had decided that as soon as No. 2 blast furnace which is of an improved design was ready to be put into commission, No. 1 blast furpace was to be dismantled and reconstructed to a similar design to No. 2 furnace. This reconstruction entailed the removal of the brick lining of the furnace shaft, and, also the removal and disposal of the,"salamander" and hearth-lining. For the information of members who may possibly be unacquainted with the term "salamander," it might be explained that this term is used by iron metallurgists to denote the mass of iron and slag formed at the- bottom of the furnace, whilst in commission.The method of disposal depends upon the size and nature of the salamander, and in the case under review it was decided to bury it below the hearth of the 'furnace' to be reconstructed. A passage-way was made in the concrete walls of the cast house, and the sand-filling of the cast house removed sufficiently to allow of the concrete foundations of the furnace being reached. This passage-way was extended until the hearth was encountered. The next operation was the removal of the hearth-lining below the salamander. The removal of the concrete was not difficult...

Jan 1, 1921

By F Tang, Ö K. Büyükuslu, M Baben, S Petersen

GTT-Technologies’ ChemApp for Python was developed to provide a powerful, easy to use interface to ChemApp for a programming language highly popular with scientists and engineers. It is used, for instance, by GTT to develop program modules such as the CALPHAD Optimiser for the FactSage™ software, by customers to move from interactive FactSage calculations to perform versatile scripting with Python, and by GTT and its partners in research projects in the area of materials informatics. Computational thermochemistry is fundamental for advancing sustainable metallurgy and creating new alloy compositions for engineering applications. Materials informatics involves handling vast amounts of data and complex workflows. GTT’s approach uses ChemApp for Python and the FactSage thermodynamic databases to design recyclable alloys from the start, incorporating a higher percentage of scraps while aiming to simplify the workflows to simulate material design steps. Challenges arise due to recycling scraps, introducing more elements for consideration. CALPHAD-based databases accurately cover materials from primary metallurgy, but additional data for minority and critical elements is crucial for precise computational modelling. GTT combines machine learning-based ab-initio databases with traditional CALPHAD databases to cover the complete chemical space with appropriate accuracy. The design of a hardfacing alloy through a high-throughput materials informatics approach is used as a demonstrator of the current possibilities.

Jun 19, 2024

By A S. Derrington

This paper describes a hybrid ventilation system, which uses secondary fans that also act as de-facto primary fans to extract fresh airflow from the mine intake raise system. Also discussed are the associated problems such as uncontrolled recirculation, inadequate decline airflow, fire safety issues, prolonged blast fume clearance times, high air temperatures in main access routes, neutralisation of mine air cooling by heat from secondary distribution fans, increased ventilation system complexity, reduced flexibility and high pressure differentials (which cause safety issues with personnel access and reduce secondary ventilation system performance).Practical suggestions are provided on options to avoid these problems listed.CITATION:Derrington, A S, 2013. A critique of the push-pull hybrid ventilation system, in Proceedings The Australian Mine Ventilation Conference , pp 73-78 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 1, 2013

By T M. Campos, H A. Petit, L M. Tavares, R Olympio

Much practical experience has been gathered in the last 30 years of application of high-pressure grinding rolls (HPGR) integrated with ball milling in size reduction of fine iron ore concentrates. The company Vale S.A, in Complexo de Tubarão (Brazil), was one of the pioneers applying the technology prior to pelletisation with an outstanding size reduction energy efficiency in the circuit and a significant increment in the specific surface area of the product. Recent studies by the authors demonstrated benefits of modelling and simulation to improve the performance of HPGRs in this particular application, with the model being able to describe HPGR performance under different operating conditions and under variations of feed size distribution. Despite these important advances, this modelling approach has only been used offline and under steady-state conditions. The present work applies the modified Torres and Casali model proposed by the authors in pseudodynamic simulations. The ability of the model to predict the characteristics of the product in real-time is evaluated using data available online for the pellet feed preparation circuit. Results demonstrated the model capabilities to map the physical operation and give a realistic representation of the process. Additionally, the model is demonstrated to be able to support the pellet feed production by providing extended real-time information of the process, making it a useful tool for improvement of the operational strategies and process stability.

Aug 24, 2022

A laboratory investigation was carried out to obtain data on the explosive character- istics of selected coals mined in New South Wales. Seven coal seams were sampled and the volatile matter content of the coals tested varied between 28 and 37 percent. A mod- ified Hartmann apparatus with a volume of 1250 ml was used in the investigation. Dust clou' generation was produced by an air blast delivered radially through a mushroom type valve and the ignition source was a-continuous A.C. spark produced by a 20 000 V, 50 mA transformer. The coal dust parameters invest- igated were the maximum pressure developed, the average and maximum rates of pressure rise at dust concentrations between 200 and 1500 3 g/m.

Jan 1, 1981

By D Chalmers, C C. Harb

The detection and control of gas levels in mining is a continuing challenge for the industry. Standard detectors have many problems that could be overcome with laser based spectroscopic instruments, but to date these systems have not been suitable for mining conditions. This paper reports the development of a new digital data extraction scheme to modernise traditional cavity ring down spectroscopy (CRDS). CRDS is a direct cavity enhanced laser based absorption technique, which is used to allow the identification of an unknown substance by their molecular fingerprint; this unknown substance is identified by analysing the ring downtime of the light exiting the optical cavity. Traditional CRDS has many issues when analysing substances in hostile environments, or when multiple species may be present. This presents an alternative approach, called real-time CRDS (rtCRDS) that has the potential to overcome many of these issues and produces systems that could be used in the mining industry. The system utilises newly developed widely tuning quantum cascade lasers combined with improved optical cavities and novel digital data extraction to produce spectra over a 1500 nm range in a few seconds. The ring downtime measurements produced are accurate and have high sensitivity and maximum signal to noise ratio. This paper discusses the technique, illustrating the advantages compared to traditional systems and show real-time spectra for a set of molecules of interest to the mining industry. This paper also provided an analogy between this approach and that used in digital communications systems, and shows that this scheme is ideally suited to provide a network of sensors in hostile environments.CITATION:Harb, C C and Chalmers, D, 2015. Real-time methane detection – modern digital laser spectroscopy for hostile environments, in Proceedings The Australian Mine Ventilation Conference, pp 161–166 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 31, 2015

By S Ravn

Under platform exhaust (UPE) systems are often designed into metro stations as a means of removing heat generated by trains as they come to a halt in the platform. These systems are designed to extract heat from the brakes and brake resistors directly at the source in order to capture as much heat as possible before it can enter the public areas of the station, or contribute to the temperature build-up in the tunnels. Due to space requirements for the associated duct and air handling units, the UPE plays a significant role in the geometric design of the platform and station as a whole.In recent years questions have arisen as to the effectiveness of UPE systems. However, very little data is available for designers to use when making important decisions on the station designs for new metro systems. This is important as significant savings could be achieved by omitting or re-designing these systems for new build stations; not only due to the capital costs of space provision for the duct itself but also due to the associated operation and maintenance cost of the UPE system.This paper will present recent measurements of the UPE system of the Copenhagen metro together with one-dimensional (1D) simulations, looking at typical dispersion of heat into the station plenum box and air exchange through draught relief shafts as the train enters the station in order to evaluate the effectiveness of the UPE system. The aim of this paper is to disseminate the results of measurements and analysis to increase awareness of the issue and to provide discussion relevant to designers in their evaluation of heat removal systems in new build station designs.

Mar 8, 2011

By A Melkumyan, F Ramos

This paper addresses the problem of prediction of grade variables over volumes (block estimation) for an autonomous mine. Resource estimation is usually concerned with the prediction of the quality of material over volumes (blocks in resource models). This problem is tackled by developing Bayesian block estimation with the Gaussian processes (GPs) framework. GPs are commonly used for nonparametric regression and classification and offer an elegant solution to deal with incomplete knowledge and information. A GP is defined by its mean and covariance function. The parameters of the covariance function can be learnt by maximising the marginal likelihood of the data. This offers a way of automating the covariance fitting process, while at the same time allowing for an assessment of how well the covariance function fits the data. Within the GP framework the calculation of the average grade over a volume can be performed using Bayesian quadrature, which treats an integral as a random variable. First, it is demonstrated that the block kriging equations in geostatistics are the same as Bayesian quadrature. Then, it is determined when closed form analytical solutions for the integrals are possible and quadrature approaches for approximations are briefly discussed.

Sep 26, 2011

By S Moradi

The thickener overflow of zinc concentrate, obtained from flotation process in the Angouran plant located in Iran, contains a large quantity of slimes which were transferred to the tailing ponds. These slimes have caused problems of storing and environmental aspects in the Angouran area. The objective of this research is to describe the extraction of zinc from these slimes by leaching method using sulfuric acid in pilot plant scale.Chemical analyses showed that these tailing materials contain 35 per cent of zinc. By XRD analysis, smithsonite is identified as the major constituent. Calcite, dolomite, and cerussite are found as carbonate minerals. A minimal amount of Zn occurs as hemimorphite. Quartz, kaolinite, clinochlore and muscovite are other silicate minerals in the slimes.In the optimal conditions, ie acid leach at pH of 1, temperature of 55¦C, reaction time of 120 minutes and solid-liquid ratio of 1:3 and neutralisation with Ca(OH)2 at pH = 4.5, temperature = 70¦C, time = 90 minutes, the total recovery of zinc obtained was 95 per cent.

Jan 1, 2004

By S Doyle

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. The Macraes gold mine in Otago, New Zealand, is developed along the central portion of the Hyde-Macraes Shear Zone (HMSZ), which dips gently to the NE, and is traceable over 30 km of strike, before disappearing under tertiary cover. Mineralisation is most intensely developed along the hanging wall shear, which defines the upper limit of the shear zone, although significant packages of quartz vein arrays and mineralised shears occur sporadically beneath the hanging wall shear.The Macraes gold mine is now in its 25th year of operation, well beyond the projected mine life at the time of commissioning in 1990, and currently contains over triple the measured and indicated resource inventory that was defined at start up. The extended mine life and resource growth has been driven by exploration and resource development success, efficient low-cost mining and processing, improving gold price, as well as an ethos of continuous improvement.The emphasis of Oceanagold’s exploration and resource development has shifted over time; from hanging-wall-focused mapping, soil sampling and step-out drilling, through exploitation of previously drilled stockwork mineralisation, to the pursuit of blind, higher-grade underground targets.Mineralisation within the HMSZ remains open at depth, and the regional potential has not been fully tested. Given the relatively low-grade of gold mineralisation at Macraes, the consideration of tungsten as a supplementary co-product provides an exciting opportunity.CITATION:Moore, J and Doyle, S, 2015. Resource definition in the world-class Macraes gold mine, New Zealand, in Proceedings PACRIM 2015 Congress, pp 557–564 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By Thomas E. G

In the economic evaluation of any Australian mining project, changes in taxation can significantly affect viability. Australian tax laws, particularly in the period since early 1973, have undergone many changes which have led to shifts in the profitability of mining companies. This paper examines the sensitivity of a selected, broadly based sample of Australian mining companies to the changes that have occurred, or are reasonably likely to occur, in taxation legislation. In the past, tax systems have been altered for a variety of reasons, such as 1. reduction'in the impact of inflation 2. neutralization of incidence between different sections of the economy 3. as an incentive to encourage expansion and growth in a particular industry or area, and 4. increase in the real "take" of government. In this paper, conventional rate of return analyses are applied in a study of how profitability is affected under various taxation systems.

Jan 1, 1977

The purpose of this study was to investigate the effectiveness of froth fl otation for the recovery of gold from the gravity tailing stream of the former Lihir Gold Limited (LGL) operation in Ballarat. The P80 of the tailings was determined by screen analysis as 1 mm, with test work conducted on as received material along with samples ground to P80 sizes of 47, 78 and 134 microns. Laboratory scale batch flotation tests were conducted at both natural and elevated pH to investigate the impact of pyrite depression on gold recovery. Results indicated that although an increase in grade from approximately 0.7 g/t to 3 g/t was achievable at a natural pH and a P80 of 134 micron, gold recovery was low at just 35 per cent. Finer grind sizes were found to have an adverse effect on both grade and recovery. Future efforts will be focused on the sub 310 micron size fraction of the tailings, which was revealed to contain approximately 85 per cent of the available gold and may be amenable to cyanidation or ultra-fine gravity treatment.

Aug 1, 2010

By R A. Anand, N N. Viswanathan, M M. Pande

Slags are the most voluminous solid by-products generated in pyrometallurgical operations, and, as such, finding an application for these oxidic materials is pertinent to maintaining resource efficiency. In particular, pyrometallurgical copper production is associated with high slag rates, typically ranging from 2.2 to 3.0 tons of slag per ton produced copper, which necessitates slag valourisation. A possible application for these iron silicate slags is as supplementary cementitious materials (SCMs), which effectively lowers the CO2 emissions per ton of cementitious material. Although utilising iron silicate slags as SCMs has been studied in previous work, the scientific literature has limited data on the effect of composition on the inherent reactivity in cementitious systems. More specifically, no reports on the impact of FeO/SiO2 ratio have been presented in previous publications. Therefore, the present study aimed to isolate this parameter in a synthetic FeO-SiO2-Al2O3-CaO-MgO-Cr2O3 system. Since the amorphous content is a pertinent parameter for SCMs, a high-temperature confocal laser scanning microscope (HT-CLSM) was utilised to assess the crystallisation behaviour at continuous cooling conditions. Furthermore, high-temperature rheological experiments were conducted to measure the viscosities of the slags in relation to the crystallisation behaviour. The experiments showed that depolymerising the slag by increasing the FeO/SiO2 ratio generated a less viscous slag, which showed higher tendencies for crystallisation. Furthermore, experiments assessing the inherent reactivity as an SCM showed that depolymerising the slag by increasing the FeO/SiO2 ratio as the sole independent parameter generated an initially more reactive slag. However, replacing SiO2 with FeO was found to negatively affect the reactivity as measured over seven days within the tested compositional range.

Jun 19, 2024

By G Reynolds, N A. Ware, L Lu

Queensland Pacific Metals (QPM) is progressing its Townsville Energy Chemicals Hub (TECH) project to produce nickel and cobalt sulfates for advanced battery materials. Apart from the nickel and cobalt sulfates, the process also generates a hematite by-product (~640 ktpa). The hematite byproduct precipitated from the process, hereafter ‘hematite precipitate’, is high in Fe and particularly low in impurities. However, it is a fine <20 μm crystalline, hydrometallurgical precipitate and is produced as a filter cake containing a high moisture content of about 15 per cent. This is considerably different from natural hematite ore and is expected to change its performance during sintering. In the present study, laboratory scale sintering tests were undertaken to evaluate the potential impacts of substitution of the hematite precipitate for traditional magnetite concentrates and further for Australian hematite-goethite ores in a simulated industry base blend. Substitution of hematite precipitate for magnetite concentrates was found to slightly increase the sintering temperature required to achieve the strength of laboratory sinters. However, further substitution of hematite precipitate for Australian hematite-goethite ores slightly reduced the sintering temperature required to achieve the laboratory sinter strength. These results reflect the reduction in Al2O3 contents of the blends and are consistent with the trend observed in industry and pilot scale facilities. The reduction in sintering temperature generally correlates to a reduction in fuel rate in the larger scale sintering process. The pore structure of selected laboratory sinters was further examined and discussed in conjunction with sinter strength. The pore structure images highlighted the relative difference between the blends with the most obvious difference being seen at 1290°C which correlates well with the laboratory tumble index (TI). The laboratory sinter samples showed an increase in porosity and irregularity of pore shape, as hematite substitution increased demonstrating the correlation between a more porous structure and a lower TI.

Sep 18, 2023

By P McCarthy

The relatively new field of geo-metallurgy promises to improve the predictability of mill feed quality and enhance processing outcomes. However, it is subject to the same limitations as the prediction of grade using geostatistics and has additional limitations due to the spatial distribution of the variations being measured and the sample sizes required. Schedules based on geo-metallurgical models will, in turn, be subject to variations arising from geological control and practical mining constraints.This paper discusses the key drivers of variations in mill feed quality and quantity from a mining perspective. It concludes that geo-metallurgical modelling addresses only one aspect of the problem. A case study is provided to illustrate poor predictability of metallurgical performance even with very detailed geological data.

Aug 8, 2011

By J de Vries

Arthur Page, a past President of AT&T said:All businesses in a democratic society begin with public permission, and exist by public approval. Product stewardship in its most basic form is simply risk management applied to the products we produce. Conceptually it may be considered as a more expansive approach to many existing safety, heath and environmental programs. Key differences include the extension of responsibility beyond the direct control of management, and consideration of the implications your products and processes have on the broader community, as opposed to the confines of an individual mine site or operation. This paper reviews the processes used by Orica Ltd to manage its product stewardship program. OricaÆs product stewardship program is expansive and supports activities and business that range from manufacture and delivery of commercial explosives and sodium cyanide to mines throughout the world, supply and operation of municipal water facilities, and manufacture and distribution of consumer products such as household paints and adhesives. We highlight the development of the program through experience both good and bad, and by use of case studies to illustrate how an active product stewardship program is an effective business risk mitigation strategy.

Jan 1, 2006