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By Jolanta Olkowska-Oetzel

Reactions of gold?phosphino complexes [(AuX)(PR3)] (X= Cl, Br, I; R = organic rest) with Se(SiMe3)2 lead to the formation of gold complexes with chalcogenide bridges. The reaction of the complex Ph3PAuCl and tBuSe(SiMe3) gives the cluster [Au5Se2(PPh3)4]Cl 1. The in situ preparation of the complex [(AuCl)2dpph] (dpph = Ph2P(CH2)6PPh2) by reaction of dpph with Me2SAuCl, and subsequent reaction with Se(SiMe3)2 leads to the formation of [(Au3Se)2(dpph)3]Cl2 2. Reactions of the gold(I) complex [(AuCl)2dpppe], (dpppe = Ph2P(CH2)5PPh2) with Se(SiMe3)2 and InCl3 in different molar ratios lead to the formation of [Au10Se4(dpppe)4]InCl5 3 and [Au4(SeInCl3)2(dpppe)2] 4. The reaction of [(AuCl)2dpph] with Te(SiMe3)2 and GaCl3 produces the isostructural cluster compound [Au4(TeGaCl3)2(dpph)2] 5. From the reaction of Se(SiMe3)2 with [(AuCl)2dppe] (dppe = Ph2P(CH2)2PPh2) and InCl3 [Au8Se4In(dppe)4](InCl4)3 6 can be isolated. The structures of 1 - 6 were determined by X?ray diffraction.

Oct 1, 2003

By P. R. Stephenson

"The Australasian Code for Reporting of Mineral Resources and Ore Reserves (JORC Code) has been operating successfully for 14 years, and has an ancestry dating back over 30 years. Together with complementary developments in stock exchange listing rules, the Code has brought about substantially improved standards of public reporting by Australasian mining and exploration companies. The Code is regarded as a world leader in its field, and has been used as a basis for the development of resource/reserve reporting standards in other countries. The reasons for its success are varied, foremost among them being its adoption in full by the Australian and New Zealand stock exchanges, and the ability and willingness of mining industry organizations to bring Competent Persons to account when necessary.The latest revision of the JORC Code was undertaken in 2002-2003, based in part on releases of upgraded reporting standards in Canada, the United Kingdom/Western Europe, and South Africa, and the 2003 edition is expected to be released mid-year. Two of the more significant changes are: the introduction of a requirement for a Competent Person to be responsible for the documentation upon which Exploration Results are reported; and inclusion in the definition of a Competent Person of a reference to “Recognized Overseas Professional Organizations” being overseas professional organizations to which Competent Persons may belong for the purpose of preparing documentation for the submission of reports to the Australian Stock Exchange."

Jan 1, 2004

By Hyung Sup Choi

The preparation of high-purity zirconyl compounds was studied in order to develop an economical process for obtaining pure zirconium via the caustic fritting of zircon sand. The direct dissolution of caustic frits with concentrated hydrochloric or nitric acid at 80c. followed by the addition of a small amount of acidified gelatin, gave high-purity zirconyl chloride or nitrate. The addition of a small amount of gelatin caused a mutual flocculation between colloidal silica and gelatin. The precipitation of this silica floc markedly lowered the content of silica in the product. The silica content of the compounds (or solution) so produced, generally less than 100 ppm., was sufficiently low for tributyl phosphate extraction for nitrate solutions. It was found that the degree of purification de-pends not only on the procedures employed but also on the nature of the frit itself. Silica was more effectively eliminated from the fritted product produced at higher temperatures, and less silica was present in the com-pound prepared from the frit produced in a shorter heating time. In order to ascertain the nature of the

Jan 1, 1965

CORPORATE SOCIAL RESPONSIBILITY CSR is about how companies manage the business processes to produce an overall positive impact on society. - Indentured work, sexual slavery, fair trade, organic growing, business ethics, environmental issues, ?Right to know -Right to decide?, AIDS activism, civil society - Balancing stakeholder issues - Government responses Who are the bad guys? Where are the threats?

May 1, 2010

By G. Auld

"A simple method is presented whereby the additional quantity and static pressure necessary to compensate for ventilation duct leakage may be estimated using the circular reference functions of modern spreadsheets. Favourable comparisons have been made to the National Coal Board (United Kingdom) design charts and to a case study analysis. IntroductionIn mining, most ducted systems are applied to the development of access tunnels, and most of these systems leak to some extent. When the ventilation duct fails to deliver the required quantity of air to the work place, there is a significant contribution to the development costs, either directly or indirectly.Directly — More air and more pressure are required to compensate for the leakage, more capital development (ventilation shafts, parallel drives) are required because ventilation systems cannot push the fresh air far enough, and longer re-entry times to ensure toxic blast fumes to be diluted.Indirectly — There is a reduction in productivity because of the inclement atmospheric conditions, and/or closure of development ends because of unacceptable atmospheric conditions at the working place. This has been exacerbated over the last few decades because of the increased use of diesel equipment of ever increasing power, and the more stringent Occupational Health and Safety requirements demanding more air flow per kilowatt of diesel power.The leakage from a duct must, therefore, be reliably estimated in order to assess the effectiveness and construction of the system; assess the effectiveness of the maintenance or repair of the duct; appreciate the cost of the leakage, and therefore apply effective maintenance and installation procedures; and engineer safer, healthier and more cost-effective ventilation systems."

Jan 1, 2002

By I. Ruiz Bustinza, L. F. Verdeja, Daniel Sbarbaro, R. Parra, J. Mochón

The oxidation of sulfides is a complex process involving gaseous products and intermediate species given rise to emission and absorption spectra which carry out important information about the reaction process. This information could be used for on line monitoring of pyrometallurgical reactor if the appropriate sensors were available. We present in this paper an analysis of the concept that has been successfully applied in iron and steel making industry, as well on fuel combustion control, where the spectra measurement gives the possibility for online monitoring and automatic control of high temperature processes. This concept has not been widely applied in the nonferrous pyrometallurgical primary production. The design of new sensors is discussed from the analysis of spectra measurements during flash combustion of copper concentrates at laboratory scale.

Jan 1, 2015

By J. W. Austin

"Introduction The Brenda dust collection system was originally designed to handle air at the 5000 ft. elevation with less than 1 grain of dust per cubic feet of air handled. The temperature variation is from 32°C in the summer to -20°C in the winter.DUST COLLECTIONOriginal Equipment 1. Primary Crusher 2 compartment baghouse, shaker type design capacity - 17,000 cfm2. Primary Screening 3 compartment baghouse, shaker type design capacity - 30,000 cfm3. Secondary Crusher 4 compartment baghouse, shaker type design capacity - 45,000 cfm4. Secondary Screening 4 compartment baghouse, shaker typedesign capacity - 60,000 cfmThe original dust collecting equipment was designed using a napped terylene fabric at an air to cloth ratio of 5:1. The ducting was designed to handle the dust laden air at 3200 ft. per minute with all elbows and blast gate sections rubber lined. The hoods and the pickup velocities were designed to handle the anticipated low dust counts."

Jan 1, 1976

By A. F. Banks

"Potash processing has much in common in terms of unit operations and plant operating strategy with other mineral processing plants. As it is a rather large topic the processes will be broad brushed to give you some background and then I will go into a little detail on the things we do in the Cominco plant that may be of interest to the group as a whole. In particular the centrallized computer control system and associated instrumentation and the operator training programs will be covered as well as the mill fire, something that could happen in any plant. THE ORE AND PRODUCTSThere are differences in potash ores as you would expect. It is my intention to deal with the ores processed in the Saskatoon area. These are mined from the beds in the Patience Lake Member and have a mineralogical description as follows:Sylvite (Potassium Chloride) 40%Halite (Sodium Chloride) 55%Insolubles (Slimes) 5%A number of products are made from this ore. It is characteristic of a potash plant that you put as much effort into grading and converting the sylvite to meet market requirements as you do in recovering it."

Jan 1, 1976

By E. De Souza

Two comprehensive surveys, which focus upon backfill practices and the economics of backfilling in underground mines in Canada, have been conducted. The two surveys were designed to assess operational practices and costs associated with the wide scope of filling operations that must be met by individual mines, ranging from raw material feed to the preparation plant, through underground backfill transportation, to in-stope product placement. This paper presents the current state of backfill usage in Canada, identifies trends in minefill practices and provides mine operators with an updated database of information upon which they might compare their own practices and costs with present trends throughout the industry.

May 1, 2003

By C. Campero, C. Nicolau, L. Pagliero

The Chilean Congress has recently promoted desalination as a solution to meet the mining industry’s growing water demand. However, this rapid expansion of desalination infrastructure comes with trade-offs. This includes a significant energy cost for treatment, as well as socio-environmental impacts on indigenous communities, tourism, fisheries, and the marine ecosystem. This paper advances a regional-scale model for analyzing competing trade-offs through a case study in the Antofagasta mining region of Chile. Through geospatial data analysis in ArcGIS, new desalination infrastructure investments supplying water to mines are overlain with features of concern raised by communities during the environmental impact assessment (EIA) process, such as national parks, fisheries and exploitation areas for benthonic resources. The resultant model provides a test-bed for analyzing the cumulative effects associated with desalination expansion and for investigating scenarios to mitigate negative social-environmental impacts. The model simulates alternative scenarios for desalination locations and pipeline routes according to competing constraints (i.e. to minimize cost and energy constraints while also avoiding ecological and social hotspots). The ultimate contribution of the work is a demonstration of how the proactive adoption of a regional-scale infrastructure planning might have led to different desalination investment decisions. INTRODUCTION Chile represents the largest producer of copper globally, and holds approximately a third of the world’s estimated copper reserves. However, access to water represents a major constraint to industry expansion and creates conflicts with competing water users (Aitken et al., 2016; Côte et al., 2010). Recently, the Chilean Congress has promoted desalination as a solution to meeting the industry’s growing water demand, which is likely to lead to significant growth in desalination infrastructure to support large-scale mining projects that extract freshwater over a rate of 150 l/s1. By most recent projections, the Chilean copper mining sector is set to increase seawater use by 230% by 2029 (Faversham House Group Ltd, 2019). By the year 2015, Chile had 11 projects serving the mining industry and there are at least other 12 planned plants (Cochilco, 2015). While the use of seawater allows continued expansion of the sector without depletion of scarce underground aquifers, it is nonetheless accompanied with important socio-environmental drawbacks. One such challenge with desalination is the associated energy costs, expressed, both economic and environmental (e.g., CO2 emissions). This includes the energy required for reverse osmosis treatment facilities, as well as to pump water to inland regions at high elevations around 3.100 m.a.s.l in Chile. (Dixon, 2013; Knops et al., 2013). Additionally, the impacts of desalinated water use on flotation chemistry are generally poorly understood, necessitating the need for further research into the impacts, both positive and negative (Cisternas and Gálvez, 2018; Liu et al., 2011).

Jan 1, 2019

By Jean-François Lessard

The performance of rock pass systems has a significant contribution to the economics of underground mines. Operational concerns include hang-ups due to arching of material, blockage and degradation of the rock pass. This papers presents the preliminary results of a comprehensive rock pass database on the engineering and operation of rock pass systems in Quebec underground mines.

May 1, 2002

By J. Flemming, R. O. Burt

"The Tanco pegmatite is located in the Bird River greenstone belt of southeastern Manitoba approximately 160 km northeast of Winnipeg (Figure 1). This pegmatite body was discovered in 1929 and subsequently attempts were made to exploit it for tin by Jack Nutt Mines Ltd. and later in the middle 1950's by Montgary Oil Ltd., who extensively developed but did not produce from, its lithium deposits. In 1966 systematic investigation of the pegmatite as a potential source of tantalum led to the founding of Tantalum Mining Corporation of Canada Ltd. (TANGO) in 1967 and production of tantalum concentrates from the Bernie Lake mine commenced in 1969. Tanco is currently jointly owned by Hudson Bay Mining and Smelting Co., Cabot Beryl co Inc. of Boston, and the Province of Manitoba. (Williams and others 1978, Burt 1979, Burt and others 1982), continued until the end of 1982, when, due to falling demand and prices, operations were suspended.During the 1970's Tanco had investigated the potential of the lithium orebody; carrying our research into both the concentration of the ore and into the production of lithium chemicals. However lithium chemicals were in an over-supply situation, due in part to the production from Chilean brine deposits (Buckley, 1983), and Tanco' s own plans were put into abeyance. The potential alternative market, the direct use of concentrates in the glass and ceramics industry, did not at the time justify the cost of constructing a new plant."

Jan 1, 1986

By J. F. Archibald

This paper reviews the formation of the Canadian Mining Education Council (CMEC) and its terms of reference. CMEC considers that Canada?s mining schools represent a distinct competitive advantage to the Canadian Mining Industry. The core objective of CMEC is to reinforce the links between the constituent schools and their individual Industry Advisory Committees. The latter traditionally provide the schools with a great deal of guidance on a range of planning issues, including recruitment, curriculum, research and infrastructure. Beyond those bounds CMEC intends to improve its ability to network with the industry and government. It is concerned overall with the objective to raise the quality and level of its educational and research contributions to meet the needs of industry and society.

May 1, 2002

By M. Bélanger, H. -L. Jacob

"The province of Quebec has a strong tradition in industrial minerals. Ten commodities are produced and the annual total shipments have exceeded $600 million in recent years. Quebec is a world renowned producer of chrysotile, titanium slag, graphite, and ilmenite. Quebec is an important North American producer of mica, talc, and peat moss. This paper reviews the main minerals and commodities that have been the object of exploration or development in recent years, namely graphite, wollastonite, dolomite, and silica. Some of the leading projects concerning magnesium minerals and apatite-ilmenite are described. IntroductionQuebec has a strong tradition in industrial minerals. It goes back to the second half of the 19th century when the first graphite and apatite mines in the Gatineau area and asbestos mines in the Eastern Townships were opened. Since then, more than 25 commodities have been produced in Quebec, making industrial minerals an integral part of the Quebec mineral industry. Today, industrial minerals and building materials count for one third of the total mineral production in Quebec.Present industrial mineral production includes 10 commodities (Table 1). In the last five years, the value of industrial mineral shipments has varied between 500 and 700 millions dollars annually, which represents 20% to 25% of Quebec’s total mineral production. For many years, Quebec has been a major producer of chrysotile and titanium slag, the only producer in eastern North America of mica, graphite and ilmenite, and a leading Canadian producer of talc and peat moss. Quebec also produces, mainly for domestic markets, dolomite, limestone, salt and silica.Quebec’s industrial mineral sector has been quite active in the recent years. Exploration by government geologists and companies has led to the outlining of new deposits, some of which are now in production; others are currently being evaluated. Technical and economic studies are also underway to determine the feasibility of various development projects."

Jan 1, 1999

By J. Stiksma, R. Kalanchey, M. J. Collins, G. Owusu, R. Raudsepp, K. R. Buban, L. A. Barta, I. M. Masters

This paper describes the results of testwork for the treatment of Ambatovy laterite ore by a pressure acid leach process, with recovery of the soluble nickel and cobalt values as mixed sulphide intermediate by precipitation with hydrogen sulphide, and subsequent refining of the mixed sulphide to nickel and cobalt metals. These process development studies were carried out primarily in 2004, as part of a bankable feasibility study for the Ambatovy Nickel Project. The Ambatovy orebody is located in Madagascar. The mini pilot plant testwork was carried out in the Dynatec metallurgical laboratory in Fort Saskatchewan, Alberta. The results of the testwork were very encouraging, including nickel and cobalt extractions in the range of 95.5% to 97.0%, and 94.0% to 97.0%, respectively, in the ore leach step with sulphuric acid. High recoveries of nickel and cobalt were achieved throughout the remaining process steps, yielding separate nickel and cobalt metal powders with better than acceptable purity.

Jan 1, 2005

By Michael G. Nelson

Control of the feed provided to mineral processing facilities is a continuing challenge. Much effort is currently being devoted to overcoming these problems. These projects are usually described under the general headings of Mine-to-Mill Integration or Mine-Mill Optimization. It should be possible to combine the knowledge of ore type, mineralogy, and other characteristics (located in the mine modelling system), with the advanced capabilities of state-of-the-art mill control systems, to achieve an improved level of control in mineral processing, allowing optimization of the mill processes on an almost realtime basis. This is not happening because mill feed it is often treated as a uniform material, when in reality it varies in composition and characteristics. The University of Utah is investigating the use of odor sensors for maintaining traceability in ore production and processing. Odor sensors now used in food processing, environmental monitoring, and other applications can detect the presence of very small amounts (0.1 - 500 ppm) of some molecules. An assortment of such molecules could be used to ?tag? blocks of ore as they are mined, according to their respective characteristics. Then, as the ore came into the mill, an array of ?electronic noses? could be used to assess its characteristics in real time.

May 1, 2004

By L. Frost

"Since the late 1990s, increased prevalence of severe lung disease among US coal miners has been observed, particularly in central Appalachia where thin-seam mining is prevalent. While respirable silica exposures have been implicated in many cases, the available dust monitoring data from mines shows no explanatory trends. One possible factor could be differences in the relative toxicity of silica particles based on their surface condition. Previous research has indicated that particles with occluded surfaces (e.g., by a thin layer of clay) may be less toxic than those with non-occluded surfaces. However, this dust characteristic has not been investigated before now in central Appalachian mines. In the present study, 18 respirable dust samples from seven central Appalachian mines and two northern Appalachian mines were analyzed to assess the relative occurrence of surface-occluded silica. Results showed that the dust from central Appalachian mines actually had higher fractions of occluded silica, which may be due to extraction of large amounts of rock strata along with the coal. However, the central Appalachian mines also more silica particles overall (i.e., occluded + non-occluded) in terms of total number percentage of respirable particles.INTRODUCTIONResurgence of occupational lung disease among US coal miners, especially in the central Appalachian region, has been observed since the late 1990’s (Gibson, 2016; Zosky et al., 2016; Suarthana et al., 2011; Gamble et al., 2011; Antao et al., 2005; Attfield & Sexias, 1995). In addition to increased prevalence of simple Coal Workers’ Pneumoconiosis (CWP, or “black lung”), the prevalence of severe and rapidly progressive disease has risen dramatically (Almberg et al., 2018; Blackley et al., 2018a, 2018b, 2016, 2014; Graber et al., 2017; Cohen et al., 2016). While exposures to respirable silica have long been known to cause or play a role in diseases such as silicosis or progressive massive fibrosis (PMF), which is conventionally considered as the most advanced form of CWP, it is unclear whether silica is the only culprit in the recent outbreak of severe disease. Indeed, as disease rates have risen, both total respirable dust and silica concentrations generally appear to have declined since the late 1980s, based on regulatory monitoring data in the most affected mining districts (i.e., MSHA coal Districts 4, 5 and 12, which cover central WV, eastern KY and southwestern VA, and southern WV, respectively) (Figure 1). Of course, the latency of disease can vary and may be or more 10 years, but many of the most recent cases are likely to have resulted from exposures that occurred since the late 1980s."

Jan 1, 2019

By Arthur. H. Winckers, Stephan L. Chryssoulis

"The deportment of gold in residue samples of cyanide leach tests of David Bell ore from level 6A block 13 was established using a comprehensive quantitative mineralogical approach. In every test the feed was first pre-aerated for 4 hours, followed by 48h cyanidation. Test no. 2 was done without lead nitrate and yielded a residue assaying 3.03g Au/t. In test nos. 4 and 9 lead nitrate was added before pre-aeration at 0.03kg/t and 0.3kg/t respectively yielding residues of 1.04 and 0.81 g Au/t.The mineralogical approach employed to establish the deportment of gold involved superpanning, to preconcentrate the free gold and assaying of the tailing fraction to determine the gold associated with quartz. It was thus determined that without lead nitrate added 47.2% of the lost gold is in the form of residual free gold particles less than 20 µm in size. It is this form of gold which is under represented in the residues of leach tests with lead nitrate added.Having eliminated coarseness of gold particles as a factor for lower recovery, it was determined that the residual gold particles have extensively contaminated surfaces. Amongst the deleterious surface contaminants identified: S, As, Ag, Sb and Hg, the two most harmful are S and Hg because of their concentration on the surface and rate of accumulation.Mercury and Ag are minor constituents of native gold at David Bell (average composition Au: 78.9 wt%, Hg: 18.5 wt% and Ag: 2.6 wt%) and they become enriched on the surface of residual gold particles because of their slower rate of dissolution in cyanide. The other elements absorb onto the gold particles from solution.The beneficial effect of lead nitrate was documented by comparative surface analysis of gold from residue samples of 48 hour leach testing with and without lead nitrate added and from time dependent (0-2 hour) leach tests in the presence and absence of lead nitrate. Lead nitrate accelerates the dissolution of gold by performing the following functions: (i) catalytic effect on the cyanidation of gold by accepting electrons; (ii) reaction with surface sulphur to form PbS which is then removed by oxidation; (iii) catalytic reaction on amalgam and Ag facilitating the cyanidation of Hg and Ag thus slowing down their build up onto the dissolving gold particles and (iv) the precipitation of sulphide sulphur from solution thus minimizing its build up on the surface of dissolving gold particles which is believed to facilitate the access of cyanide ions."

Jan 1, 1996

The importance of understanding the behaviour of cemented paste backfill (CPB) within the framework of the effective stress concept is highlighted in this paper. Only through an understanding built on this concept can problems such as barricade loads, the rate of consolidation and arching, be fully understood. The critical importance of the development of stiffness during the hydration process, and its impact on factors such as barricade loads, is used to illustrate why conventional approaches that implicitly ignore the effective stress principle are incapable of capturing the essential components of CPB behaviour.

May 1, 2007

By H. A. Halupka, I. A. Mozer

"At its plant in San Juan, Peru, Marcona Mining Company operates two grate pelletizing furnaces for the agglomeration of 3.5 million long tons of magnetic concentrates annually. Line One, installed in 1963, was built by Lurgi as a downdraft process furnace utilizing a furnace fan for the recuperation of hot gases from the cooling zone. This line was modified in 1966 to include both updraft drying and downdraft drying, and the original roof burners were converted to side-wall burners. Line Two, a Dravo-Lurgi furnace with an annual capacity of 2.4 million long tons, was built in 1966. This line, in contrast to the modified Lurgi furnace, employs direct recuperation of hot gases from the cooling zone and utilization of process gases from the firing zone for updraft drying.At its plant in San Juan, Peru, Marcona Mining Compa-ny operates two grate pelletizing furnaces for the agglo-meration of 3.5 million long tons of magnetic concentrates annually. Line One, installed in 1963, was built by Lurgi as a downdraft process furnace utilizing a furnace fan for the recuperation of hot gases from the cooling zone. This line was modified in 1966 to include both updraft drying and downdraft drying, and the original roof burners were converted to side-wall burners. Line Two, a Dravo-Lurgi furnace with an annual capacity of 2.4 million long tons, was built in 1966. This line, in contrast to the modified Lurgi furnace, employs direct recuperation of hot gases from the cooling zone and utilization of process gases from the firing zone for updraft drying. 5 per cent increased capacity, 30 per cent lower fuel oil consumption, and approximately 400 per cent reduction in grate bar and pallet corrosion. Firing of the pellet bed was improved by conversion from roof to side-wall burners. This modification also permitted utilization of monolithic refractory in place of pre-fired shapes, thereby improving over-all furnace availability and reducing refractory stock requirements from 154 different shapes to 18.Data are presented to compare operating performance of the Dravo-Lurgi furnace and the modified Lurgi furnace. These data show 30 per cent lower fuel oil consumption and 10 per cent higher capacity per unit grate area for the Dravo-Lurgi furnace, which also averages higher availability due to greater operating flexibility."

Jan 1, 1970