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By Fathi Habashi

"Hydrochloric acid (HCl), although more expensive than sulfuric, find uses as a leaching agent in reactions involving iron oxide. The reason for this substitution was the discovery that oxyhydrolysis of ferrous chloride by which HCl can be recycled economically. This avoided the pollution of the environment by ferrous sulfate. It was found further that the rate of leaching of sulfides is faster when HCl is used as compared with sulfuric apparently due to the formation of aqueous chlorine. In case of refractory gold ores, HCl leaching under pressure avoids the use of cyanide solution since gold chloride is produced which can be recovered by standard methods. Hydrochloric acid find also uses in the leaching of scheelite and apatite but its use in leaching clay and anorthosite is questionable.INTRODUCTION Sulfuric acid is the cheapest acid and is used as a leaching agent in many hydrometallurgical processes. However, hydrochloric acid (HCl), although more expensive since it is prepared by reaction of sulfuric with sodium chloride, has replaced sulfuric acid in many reactions involving iron oxide. It replaced sulfuric acid for the first time in 1960s in pickling of steel because of pollution problems (Habashi, 2000). Ferrous chloride produced in pickling can be economically decomposed to ferric oxide and HCl according to:2FeCl2 + 2H2O + 1/2O2 ? Fe2O3 + 4HCl (1)which also shows that the acid can be regenerated but ferrous sulfate cannot be economically decomposed to recover sulfuric acid for recycle. Since then, HCl has been used in many leaching processes. Hydrochloric acid is a corrosive acid and is usually handled in rubber-lined equipment. REGENERATION OF HYDROCHLORIC ACID Regeneration of HCl is conducted in fluidized bed or in spray roaster Fluidized bed oxyhydrolysis In a fluidized bed, ferrous chloride solution is introduced onto a bed of hot ferric oxide where heating is provided by the hot fluidizing combustion gases (Figure 1). The solution is fed on top of the bed of oxides. The liquid feed wets the outer layer of the hot oxide particles and is quickly evaporated to form a layer of new solid oxide on top of the existing oxide, thereby producing dense homogeneous particles."

Jan 1, 2017

By A. R. Sheik, A. A. Baba, M. K. Ghosh, K. Sanjay, R. B. Bale, A. G. F. Alabi, F. A. Adekola, L. Ibrahim

"This paper studies the characterization and dissolution of a Nigerian pyrolusite ore, reporting the results of ore physicochemical analyses and detailed ore characterization before and after leaching at optimal conditions. Ore dissolution rate increased proportional to acid concentration and temperature, but decreased with ore particle size. In a 4 M H2SO4 solution at 80°C with a particle size of –90+75 µm and moderate agitation, ore dissolution rate reached 78.7%. Unleached residue produced under optimal leaching conditions consisted of silica with admixtures of cristobalite and stishovite. The calculated activation energy supported the proposed diffusion control mechanism for the process.RÉSUMÉ Le présent article étudie la caractérisation et la dissolution d’un minerai de pyrolusite du Nigeria, il donne les résultats des analyses physicochimiques du minerai et de la caractérisation détaillée du minerai avant et après la lixiviation sous des conditions optimales. Le taux de dissolution du minerai augmentait proportionnellement à la concentration de l’acide mais décroissait avec la taille des particules. Dans une solution 4 M H2SO4 à 80 °C, avec une granulométrie de –90+75 µm et une agitation modérée, le taux de dissolution du minerai a atteint 78,7 %. Les résidus produits sous des conditions optimales de lixiviation étaient constitués de silice avec un mélange de cristobalite et de stishovite. L’énergie calculée d’activation supportait le mécanisme de contrôle de la diffusion proposé pour le procédé."

Jan 1, 2016

By Peter N. Blakey, Jean-Paul Paquette, Barton A. Thomson

"FROM THE BEGINNING OF THE PIT, it was known that the surface mining method had a projected life of about ten years, and that the ore extended to depths recoverable only by underground mining. When serious consideration was given to underground mining in 1968, it was realized that tremendous advantages could be gained by starting the underground mine as early as• poss1ble. These included: 1. The availability of underground ore for grade control, which would become more difficult as the pit deepened. 2. The need to develop new systems, equipment and skills to take full advantage of the technological revolution in underground mining. 3. Early knowledge of rock behaviour through trial mining on a small scale prior to finalizing plans for major blocks. In addition, the pit would be available to guarantee the mill supply if problems were encountered. 4. With sufficient time and early mining experience a much better job could be done on all mine planning. Because ample reserves of economic underground ore were virtually assured, the desired underground mining capability became a function of two restraints: first, the time required to excavate and construct the permanent headframe, shaft and ore-handling facilities necessary to handle large volumes of stope ore; second, the time for lateral and stope development on at least one level which would normally follow shaft sinking. The decision made was to move immediately on the permanent hoisting installations and at the same time embark on the planned ramp from surface, which would allow much stope preparation to be completed prior to .bringing the shaft on stream. Both projects were placed on an urgent basis early in 196S' and the following decisions made shortly thereafter."

Jan 1, 1974

By Z. Z. Öztürk, N. Sarica, A. H. Üçisik, C. Bindal

"Titanium oxide films were fabricated on commercially pure titanium surfaces via anodization procedure. Anodization parameters, anodization time and voltage were altered, whereas temperature and chemical composition of anodization bath were kept constant. The main idea in this study is to obtain rough titanium-oxide surfaces. The type and feature of titanium oxide formed were observed via SEM and EDX analyses. What was revealed from SEM and EDX analyses were combined with Ti-O phase diagram in order to make judgment on the type of phases obtained, e.g. solid solution and/or compounds. Studies on the different regions of each sample showed that surfaces consist of different titanium oxide compounds with various O/Ti ratios in nano level and solid solutions varying in terms of chemistry on the same sample. Thus together rough surfaces and inhomogeneous distribution of "titanium oxides" were obtained. It was also found that when anodization time and voltage were increased, more granular surface with higher O/Ti atomic ratio was obtained."

Jan 1, 2015

By P. V. Golde, R. A. Poole, G. R. Baiden

"INCO is committed to proceed into the next century using automation and robotics to achieve safety and productivity goals necessary to enhance its competitive position. Stobie Mine, decades old, is the first of its mines to change from labour-intensive to automationassisted techniques. This paper is a synopsis of the progress made during the transition period including overviews of some of the projects as well as some of the difficulties in the assimilation of the technology. BackgroundThe ObjectiveThis paper is an update on remote control and LHD automation installation at Stobie mine. The communications system installed at the mine and the ability to remotely control underground equipment from surface is reviewed (Poole et al., 1996, 1997). It discusses some of the experiences and processes required to further the concept to consolidate the operation of multiple machines under a single operator. It considers the communications systems requirements and their focuses, particularly on the development of systems for the tele-operation of LHDs and drilling machines from surface."

Jan 1, 1998

By A. Rahimi

Refractory castables based on alumina-silicate aggregates are commonly used in casting wheel components and launders. In this research the recycling process of waste magnesia chrome bricks for production of refractory castable lining for launders and casting wheel ladles at Iranian Sarcheshmeh copper complex (I.S.C.C.) is discussed. The smelting plant of ISCC consumes 4,000 tons refractory materials and produces 2,000 tons waste refractories annually. In order to reduce the environmental pollutions and gain the economical advantages, the recycling of waste refractories proved to be a solution [1]. In ISCC, 800 tons alumina or alumina-silicate refractory castables are used for linings of anode furnace ladles and launders annually [2]. In the present work, the spent bricks from reverberatory, converter and anode furnaces were analyzed in term of microstructural changes from hot zone to the cold end to evaluate the changes in texture and chemical composition. Different formulations based on recycled magnesia chrome aggregates and various particle size distribution and cement content were tested. Economic recycled magnesia chrome refractory mixture was prepared after crushing and sizing the non-deteriorated regions of wasted bricks. After evaluation of physical and mechanical properties of samples, one ton of refractory castable was prepared and successfully installed in the casting wheel ladles.

Jan 1, 2007

By L. K. Daneshmend

Key issues in managing information systems in the minerals industry will likely continue to be those relating to the integration and interoperability of disparate systems. This paper argues that, in order to harness the promised benefits of information technologies, the mining industry should adopt a set of open systems standards to define data formats and protocols for seamless data exchange. This is in direct contrast to the present situation where mining equipment, software and instrument suppliers rigidly adhere to proprietary standards for fear of losing competitive advantage. Benefits to the mining sector resulting from the adoption of such standards would be: the provision of near-time data for executive decision support, and the freedom to choose best technologies. The principal benefits to the leading mining software suppliers will be increased market share as a result of “captive sites” converting to open systems standards. Examples are given of open systems standards developed for related industries such as the Petroleum Open Systems Corporation (POSC) and the Machinery Information Management Open Systems Alliance (MIMOSA).

Jan 1, 2000

By Amin Saravari, Jamal Jafari, Abbas Sam

"The fourth concentrate production plant includes the comminution systems and the medium-low intensity magnetic separators (LIMS). Based on different conditions, two types of materials are fed into the plant. Type A: 70% of mine ore and 30% of reject materials from magnetite plant and type B: 100% of mine ore. The goal of the present study was to increase the iron grade and the blain number with low sulfur content in final concentrate as the pellet feed. An appropriate pellet feed should have more than 67% of iron, less than 0.1% of sulfur and a Blain number of more than 1800 cm2/g. The Fe, S and Blain no. amounts for the present concentrate are 66.6%, 0.95%, and 500 cm2/g (feed type:A) and 67.8%, 2.3%, and 450 cm2/g (feed type: B), respectively. In this research, the plant improvement efficiency was evaluated by changing the feed particle size distribution and using the flotation system. Laboratory experiments were designed based on the three circuits:1) LIMS (Low Intensity Grinding Rolls) feed grinding-LIMS test-flotation test2) LIMS feed grinding-flotation test-LIMS test3) LIMS concentrate grinding-flotation testThe best results were obtained using the first circuit at the LIMS feed size (d80) of 132 ?m. The processing results using the circuit no. 1 (feed type: A), showed a LIMS concentrate with 69.8% of Fe and 0.36% of sulfur. In this case, the final concentrate (after flotation) with Fe grade of 70.3%, sulfur content of 0.07% and Blain no. of 1571 cm2/g were obtained. In case of the feed type of B, the LIMS concentrate with Fe grade of 68.7%, and sulfur grade of 1.6% was achieved. Also, the Fe and sulfur contents were 69.3%, and 0.4% respectively with a Blain number of 1112 cm2/g. According to the obtained results, it was suggested that a LIMS feed comminution along with a LIMS and flotation systems are necessary to achieve an appropriate iron and sulfur grades with an acceptable blain number. To reach a concentrate Blain number as a pelletizing feed, a High Pressure Grinding Rolls (HPGR) system at the end of the processing line was recommended."

Jan 1, 2016

By Martin Bergeron

Producteur d?or de taille intermédiaire Mines Aurizon Ltée Bureau-chef àVancouverMine et projets localisés au Québec2

May 1, 2011

"An innovative concept is proposed whereby the operating power for haul trucks in certain areas of an underground mine are reduced in order to lower ventilation costs. Airflow that must be provided for diesel-powered equipment in most jurisdictions are regulated based on engine peak power capability and engine emissions, both of which can be lowered by artificially reducing the capacity of the engine through the engine control unit. Advances in asset tracking and ventilation on demand enable this methodology and this study demonstrates that it could represent significant value for mine operators. An examination of haul truck duty cycle indicates that de-rating of engine operating power based on the truck’s location in the mine can enable a step change in ventilation rates, often with no material impact on working conditions. Methods for implementation and estimate of cost savings will be defined.INTRODUCTION Ventilation of underground workings remains a significant operating cost burden for modern mine operators. In particular, ventilation rates for underground diesel mining equipment are often defined by local regulatory bodies and are assumed to present minimal opportunity for optimization or savings, at least until battery propulsion systems can be adopted. Commonly, the quantity of air flow required is defined by the peak rated engine output power of diesel equipment. For example, Ontario Regulation 854 SS 183.1 (3) states that “The flow of air must be at least 0.06 cubic metres per second for each kilowatt of power of the diesel-powered equipment operating in the workplace”. Jurisdictions that define air flow using the prescribed CANMET or MSHA ratings use peak engine emissions to calculate air flow required for dilution ventilation. These approaches are similar in that the maximum power capability of a vehicle’s engine is used to define the ventilation rate in all areas where it travels, regardless of what power output is actually used in any of those areas. Examination of the duty cycle of a typical underground haul truck identifies a large variance in the power output of the vehicle depending on its location in the mine and the activities undertaken at these locations. For example, travel on a mining sub-level requires a fraction of the truck’s peak power due to the minimal grade and significantly reduced travel speed. So if we can reliably reduce the peak engine power capacity and engine emissions in areas where peak power is not required, we can logically cut the ventilation rates for those areas."

Jan 1, 2017

By Han Xing, Cui Jianzhong, Qin Ke, Shao Bo, Zhang Haitao

In this paper, a new approach that uses hot-top DC casting process to producing multi-alloy ingots is present. The different type and size of composite and coated ingots (4045/3004/4045 three-layer composite ingots with section 630mm by 1500mm and 4045/3003 coasted ingot with F140mm/F110mm in diameter) are cast by this approach. The macro-morphologies and microstructures of the composite ingots, the temperature distribution and the element distribution in the interface zone were investigated, also and the interface bonding strength was measured. Results show that the solid supporting layer formed on the cooling plates plays a key role in the casting process of composite ingots. The solid supporting layer can prevent the blending of two melts by resisting the impact of alloy melt, which ensures the stable casting process and casting high quality composite ingots, because the contact height is increased using hot-top DC casting. In addition, fabrication and properties of 4045/3004/4045 three-layer composite ingots with section 630mm by 1500mm are reported in detail.

Jan 1, 2015

By A. J. Williams

"IntroductionAN EXCELLENT paper entitled Potash Discoveries in Western Canada (l) was presented to the 1948 Annual Meeting of the C.l.M. by L. Heber Cole, of the Department of Mines and Resources, Ottawa. In the intervening three and a half years, the search for oil and gas in Saskatchewan has added considerably to the information available on the occurrence of potash. It is the purpose of this paper to summarize the additional data. For greater clarity, it may be useful, first, to recapitulate some of the highlights of Mr. Cole's paper.Underlying the western plains of Canada there is a large deposit of sodium chloride, believed to be of early Devonian age. Associated with the sodium chloride are certain potash salts, primarily 'sylvinite,' a mechanical mixture of sodium chloride (halite) and potassium chloride (sylvite) crystals. The potash salts, when present, are usually near the top of the salt formation, though in at least one well they were found near the central part of the deposit. Cole reported on some seven wells in Saskatchewan which had encountered appreciable amounts of potash; these were the Ogema, Radville, Davidson Nos. 1 and 2, Prairie Salt Nos. 1 and 2, and Verbata wells. Depth of potash from surface ranged from 7,653 feet in the Radville well to a minimum of 3,466 feet in the Verbata well. Such depths do not compare favourably with those at which the potash is found in mines in the United States, France, and Germany, where about 1,000 feet is the average. The greatest concentration of sylvite encountered was in the Verbata well, where a bed 11 feet thick carried the equivalent of 21.64 per cent K20."

Jan 1, 1952

By J. Grignon, C. Fleming

It is possible to reproduce the performance of an operating CIP or CIL plant in the laboratory, in small scale batch kinetic tests, coupled with mathematical models that translate kinetic data into predicted steady state gold profiles across multi-stage adsorption circuits. Once the performance of the commercial plant has been mimicked by the model, the plant operating parameters can be varied systematically in the model, and the likely response of the plant to the step wise change can be determined. In this way it is possible to inexpensively optimize the operating conditions of an existing plant, with no disruption to plant operations and no economic risk to the mining company. This approach had been adopted by IAMGOLD to optimize the performance of their Rosebel CIL plant following several major expansions in mill capacity since 2004.

Jan 1, 2011

By A. S. Knight

THE breaking and handling of ore is obviously the most important consideration when the layout of a new mine is contemplated. The problem must be attacked with due regard to the claim area of the property, the dip of the orebody, the anticipated percentage of payability, the width of the reef, and the amount of dislocation anticipated by dykes, faults, or sills. Among these, as far as East Geduld is concerned, the three most important items are: Area. 2,640.5 claims. Average dip 12° (from flat to 35°) Average channel width 36 inches. We are fortunate on the Witwatersrand in 'chat there is usually sufficient information available from surrounding properties to determine, within narrow limits, the factors mentioned above. With this information avail-able, the choice of layout is not limited, and it will be found that on the Witwatersrand each group has developed its own technique to suit its individual requirements. On East Geduld, the layout of the property for handling ore is known as the endless-rope haulage system. Following is a brief description of the general principles followed.

Jan 1, 1942

By Matt Manson

Renard?1-10 kimberlite pipes and ?Lynx-Hibou?kimberlite dyke system within ?Foxtrot?property 50/50 JV with SOQUEM, Stornoway operator 2001: Discovery of the Renard kimberlite pipes 2003: Discovery of the Lynx-Hibou kimberlite dykes 2006-2007: Bulk sample program 2008: First 43-101 Resource and Preliminary Assessment 2009/2010: Updated 43-101 Resource

May 1, 2010

By M. J. Bunyard, I. Mullany

"The pressures on mine operators are varied and constantly increasing, declining ore grades, more remote locations and increasing environmental concerns. The challenge facing the mining industry is to find new ways to process ores which are more efficient and less costly and to control them better. This requires a fundamental rethink in the way in which projects are developed, it is no longer good enough to just copy what has been done before. The process starts with the surfacing of the primary underlying constraints for the project and the establishment of new design principles to address these. The generation of new design criteria and processing options follows the well-established path of brainstorm, focus, brainstorm, refocus and economic evaluation. The aim is process intensification, doing more with less, as early as possible and better use of plant data. The methodology requires a complete geometallurgical understanding of the orebody to facilitate the evaluation of viable processing options. Examples of early stage processing considered are blast optimization and ore sorting to reject waste and reduce processing costs. Mine to mill integration, which starts with the optimization of blasting for separation, offers another way to significantly reduce operating costs and increase efficiencies.VALUE MODEL The mining industry has, over the past decade, experienced an unprecedented cycle of increased commodity prices and investments in new mining and processing capacity followed by a market collapse and fall in prices and confidence. Whilst there are now some signs of a return to investment in new capacity, the metals and mining industry is still wrestling with eroding margins and investor demand that companies achieve the full value of their assets. Metals and mining companies must work on all available levers to deflate their costs back to more manageable levels and capture the full value for their products. Levers include optimizing external spending, re-thinking make vs buy trade-offs, debottlenecking, improving availability and operating time of key equipment, more accurate and agile planning processes, value-in-use optimization, and tighter performance management. Figure 1 is a diagrammatic representation of a company’s value model. The three goals of a successful mining enterprise are social acceptance, environmental acceptance and sound financial returns to shareholders. Some of the KPI’s used to measure the success or not of achieving these goals are shown in the translation layer."

Jan 1, 2017

By H. G. Warrington

Abstract As part of the active development programme pursued by Dominion Magnesium Limited since 1945, a modern extrusion plant was erected and has been in operation for about twelve months. The only source of nigh purity magnesium in the world, Canadian metal is produced by metallurgical processes within the frame-work of the mining industry, which gives a different viewpoint to every phase of production from other world suppliers of commercial grade metal whose operations are based on chemical industries and techniques. The superior properties of corrosion resistance and grain refinement have aided a programme of standardization, reducing the number of alloys supplied in extruded form from seven to four as an aid to economic production. The first big step was the development of a general purpose alloy known as AZ?21x covering all decorative and medium stressed applications, which will supersede two older alloys. Sales approaching a million feet in this alloy show that it bids fair to become the 'mild steel' of the magnesium industry, its applications ranging from terrazzo floor strip to textile machinery and television mast components. In the high stressed field, metallurgical features preclude low-cost extrusion of the older high-strength alloys, but recent development of a magnesium alloy containing zirconium promises an easily workable metal. Hitherto produced by expensive chemical additions, research now shows that the alloy can be produced by metallurgical means, which may make this alloy available for a wide range of commercial applications. Thus the future development programme for extruded products in the form of tube, bars, shapes, and structural angles and channels may evolve two alloys to cover all applications for strengths up to 52,000 lb. per sq. in. Such standardization is the result of taking advantage of the physical and metallurgical properties of high-purity magnesium instead of accepting techniques based on metal produced by older processes.

Jan 1, 1951

By G. J. McTeer, D. L. Verhelst, D. J. Rioux

Teck Metals Ltd. operates an integrated zinc-lead complex at Trail, British Columbia, Canada. Since 1997, KIVCETTM flash smelting technology has been utilized for the treatment of zinc plant residues and lead concentrates. Trail Operations’ furnace uses four water-cooled jackets for bullion tapping. This paper provides an overview of KIVCET bullion tapping for the past 16 years, and discusses successes and challenges encountered with respect to operations, training and monitoring.

Jan 1, 2015

By Brian G. Pewsey

Located in the northern part of the Province of British Columbia, the Cassiar Mine started development of its asbestos orebody in 1952, and is currently producing 105.000 tons of asbestos fibre annually. The townsite is nestled in a beautiful valley and supplies more than average facilities. The fibre is shipped to more than 40 countries and is used in many industrial products.

Jan 1, 1978

By Pieter van Nierop

Outline ? What is gasification? ? Gasification Technologies ? Gasification ?The early years ? Gasification ? The last decade ? The Alberta Situation ? The Importance of Gasification in Alberta ? Polygeneration ? Development ? Conclusion

May 1, 2004