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By A. Pawelczyk, D. Hreniak, E. Zych, W. Strek, K. Grabas, A. Ostrowski

"Mongolia is a country rich in rare earth resources. In the experiments carried out samples of the Mongolian ore were processed to obtain a lanthanide concentrate. The concentrate underwent hydrometallurgical processing. At the same time radioactive elements were removed. The lanthanides were obtained in the form of hydroxides that were further processed in order to get concentrated products. As a result cerium, lanthanum and neodymium-praseodymium concentrates were separated in the process. Also a concentrate of remaining elements: samarium, europium, gadolinium, terbium, dysprosium, holmium and erbium was obtained. INTRODUCTIONAccording to the assessment of the US Geological Survey, Mongolia possesses 16.77 % of the world total rare earth (RE) resources (Daly, 2011); that is the second largest RE reserve in the world, estimated to be 31 million tonnes in terms of rare earth oxides (REO). In the face of Chinese RE trade restrictions, Mongolia emerged as an important economical partner in mining and exploitation of these critical raw materials. This country is recognized as having more than five large RE deposits in the southern provinces. The most important are Lugeengol (Lugin Gol), Mushgia Khudag, Khotgor and Khalzan Buregtei (Eurasia, 2010). The Mongolian government has taken measures to facilitate western investments, nevertheless the country is economically dependent on China, the basic trading partner, particularly where exports are concerned.In the late 1970s Hydromet Kowary Enterprise, Poland, took up, along with the Wroclaw University of Technology, research and technological study on lanthanides recovery from raw materials of Vietnamese and Mongolian origin and from Indian monazite sands (Kowalczyk, 1990; Kowalczyk & Mazanek, 1987; 1990). For that purpose, a rare earth processing plant had been constructed with the capacity of about 10 t/year of hydroxide concentrate. The facility included several technological operations like grinding, flotation, hydroxide concentrate production in the hydrometallurgical processing, particular RE separation, and production of commercial products in form of CeO2, La2O3, Nd2O3, Pr2O3, and misch metal. Additionally work had been carried out in Kowary on the manufacture of yttrium and europium oxides of high purity, which were intended for color TV picture tube production in Poland."

Jan 1, 2012

By G. Goodall, M. Muinonen, R. Pandher, R. Jabbar, S. J. Muinonen

"The implementation of a new and highly efficient converting practice at the Glencore Sudbury Integrated Nickel Operations Smelter has opened the possibility to further capacity increases by using larger ladles. To quantify the impact of increasing ladle sizes from 200 to 300 ft3, XPS constructed a detailed discrete event simulation using the commercial software package Rockwell Arena®. The challenges associated with implementing a model on an intricate and tightly scheduled process, and the solutions needed to derive meaningful results will be presented. The aisle capacity is predicted to increase by approximately 17 %, with a reduction in furnace tapping demand of 8 %. Arena modeling capabilities and the key factors contributing to the overall capacity increase at the Sudbury INO Smelter will be reviewed and presented.INTRODUCTION The Glencore Sudbury Integrated Nickel Operations (INO) comprises two Ni-Cu-PGM mines, Strathcona Mill, and the Sudbury Smelter. The Smelter has operated continuously since 1929 using different processes to produce nickel-copper Bessemer matte. Feeds to the Sudbury INO Smelter are a blend of concentrate from Strathcona Mill, Raglan concentrate produced at the mine-mill complex in Raglan, Quebec, as well as third party concentrate feeds shipped to Sudbury from around the world. In 2016, the Sudbury INO Smelter produced 75,900 tonnes of nickel and 20,000 tonnes of copper in Bessemer matte. The product matte is shipped to Glencore’s Nikkelverk refinery in Kristiansand, Norway where it is refined to produce nickel and copper cathode. A schematic of the Sudbury INO Smelter’s flowsheet is shown in Figure 1."

Jan 1, 2017

By R. D. Browns

In his Budget Speech on March 31, 1 977, the Honourable Donald S. Macdonald expressed concern about the financing of investments through new equity issues. He mentioned the need to render more attractive participation in the equity market by investors in all in come brackets. One of the measures introduced in the budget to accomplish this goal is the proposal to increase the dividend gross-up and tax credit in respect of most dividends received by an individual from Canadian companies. The following comments and tables serve to illustrate the impact of this particular proposal.

Jan 1, 1977

By R. L. Bruening, R. M. Izatt, N. E. Izatt, K. E. Krakowiak, S. R. Izatt

The need for selective metal separations has increased as the mining industry encounters more complex ore bodies and the demand for higher performance end products expands. Molecular Recognition Technology (MRT) is a green chemistry process that involves use of SuperLig® resins to selectively remove desired metals from a variety of solutions in mining and metals processing industries. Recoverable metal concentrations can range from multiple g/L to mg/L or less. The MRT separation process is based on green chemistry principles and can efficiently produce high purity metal products with minimal waste generation and energy usage. In this paper, applications of MRT to metal recovery and purification in the minor and specialty metals industry will be presented and discussed. Examples will be described involving cobalt, nickel, zinc, rhenium, iridium, indium, germanium, bismuth, and cadmium, as well as removal of lead and iron from process streams.

Jan 1, 2015

The Project ? $1.4 billion project ? 59,000 tonnes of nickel and cobalt ? Large resource base ? First production end of 2004 The Place ? Half the size of Vancouver Island ? Population 210,000 ? 43% Melanesian, 37% European, 12% other South Pacific groups, 8% other nationalities ? Tourism principal industry ? 1/3 of world?s nickel resources The Politics ? French Overseas Territory ?1998 Noumea Accord: increased local control over domestic policy ? Referendum on independence in 2014 ? Seeking more economic autonomy, less dependence on French support

May 1, 2002

By M. A. Halim, V. I. Lakshmanan, Z. Jankovic

An innovative mixed-chloride process for the separation of iron from lateritic ore is described. The separation of Fe(III) from leach liquor is an important process step for the recovery of nickel and cobalt. The patented process of Process Research ORTECH Inc. uses a lixiviant containing hydrochloric acid (HCl) and magnesium chloride (MgCl2) for the leaching of lateritic ores/concentrates followed by the selective solvent extraction step of Fe(III) over other value metals such as Ni and Co. The use of MgCl2 increases the activity of the hydrogen ion in the lixiviant, which reduces the consumption of HCl in the leaching stage and enhances the formation of HFeCl4-, thereby increasing the solvent extraction efficiency of Fe(III) with ketone. The process produces high purity iron oxide (Fe2O3) and regenerates HCl by the pyrohydrolysis of the FeCl3 rich pregnant strip solution. The developed process flowsheet is in closed loop, economically attractive and environmentally friendly.

Jan 1, 2015

By A. J. Williams, W. H. A. Timm

"Lake Dufault Mines, Limited, is located north of Noranda, Quebec, and is a producer of copper and zinc concentrates. Various papers have been given on the mill design, construction and operation. 1, 2This paper is intended to describe the application of computer control to the Lake Dufault milling process. A brief history and description of the plant flowsheet will be given, followed by the reasons for installing the computer and the development of the program up to its present use. The success attained to date, comments on economic justification and future plans will also be given.HISTORY AND FLOWSHEETThe Lake Dufault ore body was discovered in September, 1961, and the mill commenced production during August, 1964. The rated capacity of 1,300 tons per day was reached by October 1, 1964. In milling the Lake Dufault ore, many metallurgical problems have been encountered, mainly due to wide and rapid variations in mill heads and oxidation of the massive sulphide ore. However, flexibility in plant layout and the incorporation of up-to-date instrumentation have facilitated its processing."

Jan 1, 1969

By V. G. Papangelakis, T. Clark, G. Kolliopoulos

Sustainability of the hydrometallurgical industry requires the development of processes for effective water recovery; if process water is recovered and recycled, fresh water intakes will be reduced. Forward osmosis (FO) is an innovative membrane process that promises to recover water from industrial process aqueous streams or seawater with less energy input compared to reverse osmosis (RO) and evaporation; the energy efficiency relies on the spontaneity of the process (no energy input required). The driving force of the process is the osmotic pressure gradient between a dilute feed solution (process water) and a concentrated draw solution. The draw solution is an engineered aqueous solution that contains a highly soluble chemical reagent that is able to osmotically "draw" only water from the dilute stream, through a semi-permeable membrane, leaving behind a small volume of concentrated brine. The draw solute is separated and recovered for reuse, leaving behind water. The main energy requirements of the FO process arise from the separation and the regeneration of the solute chemicals from the diluted draw solution. This work focuses on the evaluation of aqueous carbonated trimethylamine (TMAH:HCO3) as the draw solution and reports recent findings on the separation efficiency of TMA and CO2 from the solution.

Jan 1, 2015

By N. Manopulo, J. Maier, L. Tong, C. Becker, P. Hora

The contribution presents a new finite element approach in which the common updated Lagrangian formulation is replaced by a spatial flow formulation applying a special arbitrary Lagrangian-Eulerian for-mulation (ALE). The description separates spatially the process in a die inside zone and in a profile zone. For the description of the inside zone, where the filling process occurs, a special Euler time independent mesh is applied. By this formulation the mesh has to be generated only once, which simplifies the generation of spatially optimized meshes. For mapping of the material flow during the filling process the method uses a flow surface traction method as applied in casting simulations. A further strength of the new method is the computational efficiency which allows the modelling of extrusion process with the highest complexity with a response time of 12 hours, which is important for the industrial optimization process.

Jan 1, 2015

By A. McLean, L. Gao, Z. Shi, Y. D. Yang, K. Chattopadhyay, G. F. Zhang

Levitation melting of metals is one of the emerging applications of magnetic and electric fields in liquid metal refining. The varying magnetic field generates induced current inside the metal droplet and leads to the Joule heating effect and Lorentz force against gravity. This contactless process can avoid contamination from the crucible and can be used to produce high-purity materials. Visualization of the levitation melting process is difficult, and thus generally investigated by mathematical modeling. In the present study, a three-dimensional mathematical model of metal levitation was developed using finite element method for proper understanding of the levitation process. The effects of harmonic magnetic field frequency, coils power input, and sample size on levitation nickel droplet were investigated. Temporal evolution of temperature fields were predicted directly though the model. Levitation and balance condition of the droplet were investigated as well.

Jan 1, 2015

By K. J. Daun, C. J. Shi

UsiborThrough the second step heating at 900 °C, the spectral emissivity shows a gradually decreasing trend with increasing soak time, caused by the surface phase transformation from Al® 1500P coupons are austenitized in a Gleeble 3500 thermomechanical simulator using a two-step heating procedure in an argon atmosphere. Variations in spectral emissivity are measured in-situ using a near infrared spectrometer and ex-situ with a Fourier transform infrared reflectometer. Microstructural evolution and surface roughness are investigated using optical microscopy, FE-scanning electron microscopy, and a surface profilometer. A series of phase transformations of Al-Fe-Si intermetallic phases at the coating/steel substrate interface cause the surface phase and surface roughness to change, which in turn influences the spectral emissivity. At the beginning of the first heating step, the coupons have very low spectral emissivity, due to the molten Al-Si coating. Spectral emissivity increases significantly with increasing soak time from 5 to 12 minutes, associated with the surface phase transformation of the coating into Al7Fe2Si intermetallic phase and an increase in surface roughness. 5Fe2 into AlFe intermetallic phase with a decrease in surface roughness.

Jan 1, 2015

By W. Yang, R. Rajasingam, B. Tadesse, K. Mohanarangam

Copper electrowinning is a complex electrochemical process that involves the production of LME grade copper from copper rich electrolyte. The process involves the deposition of the copper ions onto the cathode from copper rich electrolyte with the production of oxygen bubbles at the anode. Acid mist is produced by these oxygen bubbles bursting at the electrolyte free surface. It is an undesired by-product of the Electrowinning process which unchecked could result in mist generation higher than the recommended time-weight-average exposure limit. Various approaches to alleviate the problem have been adopted by companies, all with varying degrees of success. All of these have been attempts to treat the symptom acid mist rather than the inherent problem, often proving expensive and, in some cases, ineffectual. In this paper, a new method was developed for acid mist quantification based on ‘total acid mist’ capture above the EW cell under well controlled conditions. With the use of sophisticated diagnostic analytical tools and measurement techniques it was possible to study all the operating variables including current density, flow rate, temperature, etc. independently and their effect on bubble size, bubble velocity, gas hold-up as well as acid mist generation and its droplet size. Results show that total acid mist capture increases with an increase in current density but remains more or less constant between 300–500 A m-2. Total acid mist also shows an increase with increasing electrolyte temperature. These findings are substantiated with the aid of bubble size and gas hold-up measurements with the transparent EW cell.

Jan 1, 2019

By L. Tafaghodi, A. Hosseinpour

"Silicon is considered as the most appropriate semiconductor material for manufacturing solar cells because of its natural abundance and being nontoxic. The transferable knowledge and technology from the electronics industry and the long history of silicon-based semiconductors are also assisting the domination of silicon as the most common semiconductor material. Developing an environmentally and economically viable process for producing solar grade silicon has been one of the main challenges in the silicon industry in the past few years. Metallurgical refining processes have received significant attention because of their high productivity and low cost. Slag refining is one of the purification methods which is based on oxidation of the impurity elements, followed by its dissolution into a slag phase. This article presents a review of various slag refining processes that have been employed for purification of silicon and silicon alloys. SiO2, CaO, CaF2, CaCl2, Al2O3, MgO and Na2O are the major components of the slags used for silicon refining. These slags can be classified into three main categories including binary, ternary and quaternary slags.INTRODUCTION Silicon can be categorized into three different grades based on its application or purity: metallurgical grade silicon (MG-Si) with purity of ~98 %, solar grade silicon (SoG-Si) with purity of ~99.99999 % and semiconductor grade silicon (SeG-Si) which has the purity of 99.9999999 % (Johnston & Barati, 2010; Krystad, Tang, & Tranell, 2012; Tang, Øvrelid, Tranell, & Tangstad, 2009). Producing SeG-Si is carried out through an energy-intensive and complicated process named Siemens. This purification process is relatively slow and involves using toxic and corrosive reagents (e.g. Trichlorosilane). At present the majority of SoG-Si is produced via Siemens or Siemens-like processes and there is very limited production via processes dedicated to SoG-Si. Because of the difference in silicon specifications required in microelectronics and photovoltaic industry, and the cost and energy associated with the Siemens process, an interest has emerged to develop technologies dedicated to producing low cost SoG-Si (Istratov et al., 2003; Johnston, Khajavi, Li, Sokhanvaran, & Barati, 2012; Mitrašinovic, D'Souza, & Utigard, 2012; Wu et al., 2012)."

Jan 1, 2017

By Sandeep Singh Sandhu, Karanvir Singh Ghuman, Manjit Singh

"Cobalt based super alloy stellite 6 was weld cladded on AISI 304 L stainless steel using SMAW process in order to improve the wear resistance for tyre crusher blades. Microstructure characterization and micro hardness testing was performed on stellite 6 cladding. The suitable parameters viz. 80 Amp current with arc weaving technique was selected by performing bead on plate experiment were further used for depositing multipass multilayer cladding to achieve full filler chemistry at the top surface. Further GTAW process was used for re-melting the top surface of the cladding. Comparative evaluation of the claddings showed that TIG re-melting resulted in increased microhardness and wear resistance in comparison to as cladded specimens even with lesser deposition of material. It was observed that TIG re-melting improved the hardness from 603 HV0.5 kg to 712 HV0.5 kg. Micro structures of stellite 6 contained cobalt solid solution matrix along with inter dendrite chromium carbides which resulted in the increased micro hardness values. Pin on disc abrasion tests were carried out at room temperature and the worn out surfaces were characterized using SEM and EDS.INTRODUCTIONThe crusher blades are used in many industries for crushing various types of material and its wider applications in tyre rubber crushing mills, metal-powder crushers industries etc. Most of the crusher blades are damaged by the wear and impact loading conditions. It is because of metal to metal abrasion and the temperature also plays a vital role in blunting the cutting edges of these blades. The wear is the major cause which leads to loss of material and thus the productivity that can never be recovered (Kotechi et al., 1992). The wear can be reduced by coating of various super alloys which could reduce the behavior of metal degradation even in aggressive environments. Cladding of cheaper low alloyed material with expensive superalloys to enhance the performance of components at low cost has been investigated by many scholars (Deng et al., 2010, Kennametal, 2007, Lolla et al., 2014, Singhet al., 2014, J.N et al., 2003, Ramkumar et al., 2012). Many researchers have reported that cladding is an application of build-up deposits of specialized alloys to resist abrasion, high temperature corrosion and impact loadings. Cladding is used for providing required mechanical strength properties as well as inhibition of oxidation and other corrosive degradation. Coatings are used to protect the heat affected areas like tubes of fluidized bed combustor etc. (Kirchbner et al., 2008, Wang et al., 1994, Hocking et al., 1993, Ananthapadmanabhan et al., 1991, Staia et al., 2001). Coating techniques are widely used for the protection of turbine engine and boiler tubes against high temperature corrosion attack, power generation equipment, chemical process equipment, aircraft engines, pulp and paper processing equipment, bridges, rollers and concrete reinforcements, orthopedics and dental, land-based and marine turbines, ships. Coatings of stellite 6 are widely used in steam turbine blades and boiler tubes for power generation because of an excellent combination of impact, wear and other properties. It can maintain its properties even at high temperature and in harsh environments (Kobayashiet al., 1999, Alam et al., 2009, Munehru et al., 2009). The loading and unloading conditions experienced by the material may induce the surface cracks which lead to its breakage and leaving large pits in the surface (Meng et al., 1995). Many researchers have reported that the properties of cladded layers can be increased by various techniques such as controlling the current variations, dilution, heat input, laser and other re-melting processes, addition of special alloying elements, speed of weldingetc(C.M Anaet al., 2002, Kumaret al., 1999, Luo et al., 2012, et al., Madadi et al., 2011, Shin et al., 2003, Kuzucu et al., 1997, Sudha et al., 2008, Sawant et al., 2017, Houdkova et al., 2016, Ciubo"

Jan 1, 2017

By T. R. Skerry, H. P. Hudson, T. E. Warren

"ALTHOUGH coal is generally the cheapest fuel on the basis of heating value it has been at a disadvantage in competition with other fuels because means have not been available for efficient •Conversion of its thermal energy to mechanical work. Taking the •railway application •as an example, the cost of Diesel oil is about three times that of its thermal equivalent in coal, but the overall efficiency of a Diesel locomotive is about five times that of a coal-fired steam locomotive. Accordingly, the Canadian railways are replacing all coal-fired steam Locomotives, as they are retired from service, with Diesel units. This conversion in itself represents a major loss to the coal industry because the value of railway fuel is approximately 130 million dollars per year, and there are other applications in the medium power range where oil is displacing coal. There is, therefore, a strong incentive to attempt development of an efficient coal-burning engine.Coal has never been a promising fuel for reciprocating internal combustion engines because of the time required for its combustion in pulverized form . This is not less than one-tenth of a second so that the speed of such an engine would have to be very slow. There are also serious difficulties of a mechanical nature arising from the necessity for intermittent combustion and the use of close-fitting pistons."

Jan 1, 1952

By J. E. Danoczi, J. A. Herbst

"Shore Gold Inc. (Shore) is presently designing a diamond processing plant for the Star and the Orion South kimberlite deposits in the Fort à la Corne (FalC) area in central Saskatchewan. The first step in the plant is diamond liberation and occurs in the comminution section. Diamond liberation is the process of breaking up the kimberlite rock, as gently as possible so as not to damage the diamonds.Autogenous grinding mills (AG mills) use a combination of impact crushing, abrasion and attrition to break up the kimberlite. The forces that occur during the actions of abrasion and attrition cause the kimberlites to break up preferentially along lines of weaknesses which offers a “diamond friendly” method of comminution.Hard competent kimberlite is commonly found in the diatreme zone as well as the root zone of the volcanic pipe and is the source of kimberlite for most of the Southern African diamond mines. Softer kimberlite is typically found in and around the crater area of a volcanic pipe and it is this kimberlite that makes up the majority of kimberlite for both the Star and Orion South deposits. These softer kimberlites can be readily broken up using abrasion and attrition imparted by AG mills. In order for Shore to benefit from the softer kimberlite found in the Star - Orion South diamond project, two large (10.97 m diameter x 7.10 m long) AG mills were designed for the comminution section based on extensive test work and simulations by Metso Minerals (Metso)."

Jan 1, 2012

By R. O. Suzuki, S. Natsui, R. Nashimoto, T. Kumagai, T. Kikuchi, H. Takai

A newly developed computational fluid dynamics model based on a multi-phase particle simulation is presented for predicting the entrainment behavior of liquid metal into slag due to rising single bubble. By comparing results calculated using this model against experimental data, it was found that the transient behavior of bubbles and the two immiscible liquids can be accurately estimated by this method. The rupturing of the thin water film surrounding the bubble was less reliably predicted, but this 3-dimensional unsteady numerical model still nevertheless provides valuable new information for directly predicting the change in the liquid-liquid interface over time. This model predicted the Young-Laplace pressure, and the interface shape was simulated with volume conservation using this model as opposed to the conventional particle method. This simulation model can calculate both of dispersed phase and continuous phase seamlessly.

Jan 1, 2015

By Q. Chen, J. H. Zhang, M. Zhang, F. M. Zheng, Y. J. Zhang

The characteristics of air bubbles and gas dispersion in KYF flotation cell are studied using the method of the point conductivity probe and CFD simulation. With increasing of speed, the velocities of air bubbles increase slowly and the distribution of diameters exhibits little change. With increasing of aeration rate, the gas holdup is increased. However, the velocities and diameters of bubbles have no great change. The CFD predictions on gas holdup have good agreement with the experiment results. The gas holdup distribution in the center section is revealed. The gas dispersion in the middle and upper part of flotation cell is uniform. It would be helpful for bubbles and solid particles collision. The gas holdup of the lower part of flotation cell is scarce, and it agrees with the observation in experiment. The gas would accumulate at the suction side of impeller blades, and it would decrease the power consumption. The rotating speed and aeration rate have great effect on gas dispersion. With increasing of aeration rate, the gas holdup of flotation cell will increase. The increasing of speed would improve gas dispersion. The results are expected to help to optimize the performances of KYF flotation cell.

Jan 1, 2015

By Pura Alfonso, Teresa Escobet, Hernan Anticoi, Eduard Guasch, Josep Oliva, Sarbast A. Hamid

"The liberation modelling of mineral particles using mineral liberation analysis have been used in the past to model comminution and concentration processes. In this work this concept has been taken a little further, using comminution and concentration for applying the mineralogical characteristics of particles. This approach is shown using the image analysis, mineral liberation analysis and the distribution density functions for liberation modelling. The work focused on the effect of comminution on mineral liberation for liberation modelling. To model this, effect the mineral liberation of the particles using distribution density and the cumulative distribution was linked to the image analysis of the ore particles. These properties have been estimated by statistical measures such as the distribution density and liberation grade, which were extracted from MLA data and images analysis, using proper image analysis and techniques based on MATLAB software. A comparison of different tungsten ores of liberated particles, has been introduced and evaluated by estimated results and image analysis.INTRODUCTION The chief economic minerals of tungsten are wolframite [(Fe,Mn) WO4] and scheelite(CaWO4), and approximately two-thirds of the world tungsten reserves consist of scheelite deposits (Lassner and Schubert, 1999). Tungsten has unique properties and is widely used in various industrial high strength and high temperature applications. It occurs coarsely aggregated in low grade ores. Most of tungsten ores, particularly scheelite, wolframite and ferberite, occur in deposits with very low content of WO3 (0.1–2.5%) that is not economically viable to apply directly metallurgical methods to extract tungsten (Martins, 2014). Tungsten is considered as a critical metal by the European Union by the economic importance and also the high supply risk (European Commission, 2014; Chakhmouradian et al., 2015).Currently, scheelite is playing an increasingly important role in tungsten industry because the mineral reserve of wolframite is getting depleted after gradual exploitation and utilization (Min et al., 2016). In mineral processing, the liberation of valuable mineral from the gangue determines the efficiency of subsequent separation processes. The liberation characteristics of an ore are primarily dependent on its texture, the association of mineral in the host matrix of gangue minerals, and to some extent on the grinding process (Zhang and Subasinghe; 2013)."

Jan 1, 2017

By Jamie N. Burdeski, Susan E. Hartfield-Wünsch

Aluminum sheet use has been steadily increasing in the automotive industry to achieve mass reduction and improve fuel economy. One significant manufacturing challenge for aluminum sheet implementation is the reduced formability compared to the steel alloys it replaces. This paper includes friction results from the draw bead simulator (DBS), twist compression (TCT) and strip draw (SDT) tests, for two oil based lubricants and four hot melt lubricants. Formability testing was done with the same lubricants and materials, testing in pure stretch with a hemispherical punch, and in draw with a breadpan shaped die.

Jan 1, 2015