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By Juan B. Yianatos

"After almost 100 years, since the first commercial application began in Australia, flotation has shown an extraordinary growth and nearly 2 billion tons of ore per year are presently treated by flotation processes. During this time flotation has promoted a wide scope of research activities ranging from fundamental chemistry and hydrodynamic studies to studies of industrial operations. In general, fundamental studies have been mainly related to ideal situations. In recent years, however, large efforts have been focusing on achieving a better insight into the actual sub-processes provided by the development of new and more sophisticated instrumentation. Since the massive incorporation of flotation columns, around 15 years ago, a renewed interest in flotation fundamental studies, process modelling and new cell designs have been observed worldwide. The key role of the froth has been recognized as an independent and sometimes rate limiting process step. Thus, separation of pulp and froth process stages seems the most appropriate in terms of process modelling, diagnostic, design and scale-up purposes.In relation to flotation equipment development, until the middle of the 1970’s, only the sub-aeration mechanical cells were dominant. Since the 1980’s, the use of pneumatic cells and forced air mechanical cells has emerged strongly. Also, in the last decade, flotation equipment has shown a dramatic increase in size, reaching values of 200m3 in unitary mechanical cells and more than 300m3 in columns. The general feeling, however, is that, despite the great advance observed in terms of process knowledge, the mechanisms and principles of industrial flotation cells design and scale-up are still not fully understood.Advances in process instrumentation and control now in use allow for more efficient operations, both in metallurgical performance and savings in operating costs."

Jan 1, 2003

By G. Belardi

This paper presents the preliminary results of a research programme conducted to assess the feasibility of a flotation technique in the remediation of soils severely affected by heavy metal contamination. The use of flotation in soil remediation is a recent practice. The main difficulties are given by the variety and peculiarity of the heavy metal containing species, and also by the grain size. Most of the studies reported in the literature concern the use of conventional collectors, such as xanthates, after a preliminary chemical modification of the metal bearing species through sulphidization. On the basis of the minera-petrographic characterization and of speciation, some classes of reagents have been selected, capable of acting both on metal-bearing species and all metallic cations to be separated. The design of the synthetic molecules has been based on the coordinative properties of the metallic centres and functionalized in order to act as collectors for a wide range of metals independently on their surrounding atoms. In laboratory experiments a sample of stream sediment has been utilized, whose contamination is caused by the runoff from Sardinia mine waste dumps and overflow from the settling ponds. The material showed contamination mainly from Zn, Pb and Cu and to a lesser extent from Cr, Ni, Cd, and Sb associated in mixed particles of Fe and Mn. Flotation tests on a laboratory scale have been performed on grain sizes less than 355 µm in laboratory cell Minerais & Metaux. The effects of the structure of collectors (functional group, chain configuration) as well as of the principal flotation parameters (such as pH, concentration of reagent) on the grade and recovery of heavy metals in the concentrate and in the tailings (remediated soil) have been investigated. The results of the laboratory tests substantially confirm the theoretical premises, and the most effecive reagents found belong to the classes ATP, MBT, MBO, fat acids and phosphates.

Jan 1, 2014

By S. Sarioglan

The bleaching of edible oils, industrial oils, and some chemicals may be achieved using natural and acid-activated clays. These materials remove impurities and pigments from the oils. In this work, a bentonite clay from Turkey (Somas bentonite) was activated with different concentration of H2SO4 and HCl at 70~90°C and 5~8 hours. Under these conditions several cations were removed from natural bentonite (Al, Mg, and Fe) and DTA-TGA, FT-IR curves of the solids obtained after acid treatment were examined. Treatment time and acid concentration increased the degree of destruction of the bentonite structure which was determined by ICP. Activated samples were tested in order to verify their capacity to bleach soybean oil and compared to standard commercial bleaching clays. The experimental results indicate that treated samples with H2SO4 have the same efficient in bleaching crude soybean oil with the standards and treated sample with HCl is more efficient in bleaching than the commercial products.

Jan 1, 2014

By L. S. Zhou

Germany-made AFX-100 multi-grade fluidized classifier, with exquisite built-in structure and unique novel design, materializes not only advanced and efficient classification, but also precise particle distribution and safe operation, in addition to lower energy consumption and operational cost. It, simultaneously in place of screw grader, water cyclone, and fine mesh sieve, is equipped with multi-function, and indicates superior advantage in comparison with other else grading facilities. As the third-generation equipment, which is efficient and modern, it, in China and therefore all over the world, will find wide application in processing both fine and ultra-fine iron ore resources. Industrial test, carried out in Benxi Steel?s Waitoushan Iron Mine, shows efficient classification, i.e., ?74µm particle contents in coarse, medium and fine products come to 6.09%,11.82% and 82.73%, respectively, while qualitative and quantitative efficiencies end up by 74.38% and 87.66%, respectively. Its separation efficiencies amount to 2.2 times as many as spiral classifiers, 1.8 times as hydrocyclones, and 1.3 times as vibration high-frequency fine screens. Another industrial test, which was practiced in Anshan Steel?s Donganshan Sinter Plant, indicates that classification qualitative efficiency comes to 65.06%, equal to 1.51 times as many as hydrocyclones; yield, 55.79%; -71µm particle contents in medium and coarse products, 42.02%; -71µm content in fine product, 95.42%; and concentration, 12.33%. Estimated separation indexes are as follows: Yield for concentrate at 31.22%, up 0.22% than that from general processing line; concentrate grade at 66.42%, up 1.13%; recovery ratio comes to 65.84%, up 1.28%, which, based on pilot study, results in 20 million yuan of economic return for Donganshan Floatation Plant.

Jan 1, 2014

By Sanjay Agarwal

Polymetallic sea nodule is a good source of manganese having 22.3% Mn, 5.4% Fe, 6.14% Si, 1.1% Cu, 1.15% Ni, 0.076% Co & others. These nodules are available in plenty on the sea beds, generated over thousands of years. Nodules mainly consist of manganese dioxide and iron oxide phases and other metals are entrapped in the complex cage of these Mn-Fe oxides phases.World-wide research is going on sea nodules as an alternative future source of many metals, which has led to intensified efforts to develop practical and economical processes for recovery of these metals. Very little attempt has been made world over on manganese extraction from sea nodules. We at CSIR-NML, India have developed a direct reduction smelting process of nodules to recover manganese as Fe-Si-Mn alloy. This alloy is extensively used in the steel industry as deoxidizer and as an alloying element to make different grades of steel. Lab scale experiments were conducted to study the manganese distribution between Fe-Si-Mn alloy and FeO-SiO2-MnO-CaO-Al2O3-MgO slag at different temperatures by varying the basicity of the slag. The direct reduction smelting of nodules is carried out on 1 kg scale in 50 kVA electric arc furnaces to have Cu, Ni and Co alloy and Mn rich slag. This manganese rich slag is further treated in 50 kVA arc furnace to produce Fe-Si-Mn alloy. The composition of Fe-Si-Mn alloy obtained is in the range of Mn: 60-65%, Si: 14-17%, C: 1- 2%, S: 0.03% and the balance iron which is acceptable grade for industrial use. The equilibrium amount of MnO in the final slag is controlled by the temperature of the final melt and the silica, lime, alumina content of the final slag. Increasing the basicity of the slag plays a major role in minimizing the loss of MnO to slag, increasing the amount of SiO2 of the slag, increases the manganese loss in the slag. Increasing the CaO/ Al2O3 ratio of the slag decreases the manganese loss in the slag. Increasing the MgO/CaO ratio of the slag increases the manganese loss in the slag. Thus by adjusting

Sep 1, 2012

By Kyoungkeun Yoo

A citric acid leaching test after heavy medium separation process was performed to remove the heavy metal contaminat such as Pb, Cu, and Zn from contaminated soil. The lead component was removed from soil by heavy medium separation whereas zinc component shows 0 % - 37.9 % removal ratio with particle size. The citric acid leaching was conducted to remove the remained zinc component. The removal ratio of Zn reached to more than 95 % under the conditions; 10 % in pulp density, 200 rpm in agitation speed, 50 °C, 2 mol/L in citric acid concentration at 2 hrs in leaching time. These results suggest that the heavy medium separation method followed by citric acid leaching is effective for treatment of soil contaminated with various chemical forms of heavy metal. Keywords: metal contaminated soil, citrate, heavy medium separation, zinc

Sep 1, 2012

By Atsushi Shibayama, Toyohisa Fujita, Wan-Tai Yen, Ke-jun Liu

"In this investigation, a sponge gold sample (99.92% pure) has been leached with ammonium thiosulfate solution. The effects of CuSO4, (NH4)2S2O3, (NH4)2SO4, NH4OH and retention time on the gold leaching % (extraction %) and thiosulfate oxidation % (consumption %) have been studied. The copper ion acts as a catalyst in gold dissolution. On the other hand, it also accelerates oxidation of thiosulfate (consumption). It was found in this study that the best gold extraction condition was obtained at 43.2 ks with 0.8 - 1.0x103 mol/m3 (NH4)2S2O3, 30 mol/m3 CuSO4, 2.0 - 3.0x103 mol/m3 NH4OH, 0.4 - 0.5x103 mol/m3 (NH4)2SO4, pH 10±0.2 and 150 rpm. The thiosulfate oxidation was about 15% of the initial concentration.For gold recovery from the pregnant solution, the trioctylmethyl ammonium chloride (TOMAC) was used in this investigation as an extractant to extract gold from thiosulfate solution without pH and other adjustments. The effects of gold concentration, pH, ammonia, thiosulfate and cupric ionic concentrations, extractant and diluent concentrations and retention time on the gold recovery were investigated. It was found that 180 mol/m3 extractant diluted with n-octant at O/A ratio of 1:1 could extracted the 100% of gold in 0.6 ks from the thiosulfate solution at the optimal leaching conditions. The 100% gold stripping could be achieved with 10% thiourea solution."

Jan 1, 2003

By Cheng Xiang, Nan Ye, Xinyuan Ke, Yang. Jiakuan, Huabin Wang

Bayer red mud is a highly alkaline residue produced by the alumina industry through the Bayer process. Its disposal is a worldwide problem. The high alkali content and poor pozzolanic activity is aconstraint for its utilization on construction materials. In this study, the red mud was activated through an alkali-thermal method to improve its activity so that it can be utilized in geopolymerization. The red mud was mixed with different amounts of sodium hydroxide, and calcined under 800 °C to produce geopolymer precursors, and then mixed with water directly to prepare one-part geopolymer. X-ray diffraction was conducted to study the phase transformation of red mud and the mechanism of its geopolymerization. Nitrogen Isothermal Adsorption tests were conducted to analyze the pore structure of the geopolymer binders. The results show that calcinations with alkali would promote the Al in red mud transforming into glassy SiO2 to form the N-A-S phase which is soluble in water. When the red mud was calcined at 800 °C with a Na2O addition more than 10%, the dissolving of Si and Al from red mud was greatly improved. The thermal-alkali activated red mud with 10% Na2O obtaining a compressive strength of 9.77 MPa after it reacted with water and cured for 7 days at 20 °C and 95% RH. But the strength decreased as the curing time extended to 28 days. The reason is suggested to be that the polymerization of Al-O and Si-O is unstable due to the low Si/Al ratio of red mud. The alkali in the structure dissolves again into the pore water and corrupts the pore structure. Therefore, the thermal-alkali red mud should be combined with other reactive aluminosilicate materials such as granulated blast furnace slag to absorb the alkali released by the thermal-alkali red mud at the latter curing days.

Jan 1, 2014

By E. Alldén Öberg

In 2004, LKAB decided to start a basic engineering study in expanding its existing production lines at the Malmberget mine site. It was expected that some of the production lines would become bottlenecks with reference to capacity. In this study, the sorting plant is examined and the results show that several unit operations will be limiting under current operating conditions. An additional purpose with the study was to investigate how replacement of some machines would influence performance and if production plans for the coming years might be achieved. Steady-state simulations using the software Modsim? were extensively used to study process performance for different operating conditions, such as iron content and size distribution in run-of-mine ore. Model parameters were derived from pilot plant data and when possible from ex-isting circuits. A complication for the simulations was the lack of relevant data and therefore some of the initial results were only indicative. The result shows that installation of new screens would give a much better operation, but also new crushers would be an improvement. This, since they can be run with full crusher chamber and tighter CSS. During 2007, most of the proposed remedies were implemented and the result is that the bottle-necks are gone, and the grades and material balances are even better than what was envisioned from the simulations.

Jan 1, 2014

Considerable attention has been, and is being, given to the physics of water-films associated with bubble interactions at surfaces. In contrast, little information on the chemistry of such films has been reported. This communication reports a method using sum frequency vibrational spectroscopy (SFVS) to describe hydrogen bonding of interfacial water molecules in water films created with bubbles at hydrophilic and hydrophobic surfaces. The SFVS spectra of water films at hydrophilic silica surfaces differ significantly from the spectra of water at a hydrophobic silica surface. The SFVS spectra indicate that a very ordered water structure exists in water films at the hydrophilic silica surface during contact with a bubble and that the extent of hydrogen bonding increases with an increase in contact pressure. Such structural considerations as well as repulsive electrostatic and Van der Waals forces account for film stability for a bubble at the hydrophilic silica surface. In contrast, the SFVS spectra of water at a hydrophobic silica surface show a lack of hydrogen bonding and are characterized by a distinct absorption at about 3700 cm-1 similar to the spectrum of the air/water interface. These results suggest the presence of a water void, or water exclusion zone, at the hydrophobic surface, as supported by X-ray reflectivity measurements reported in the literature, by atomic force microscopy, and by the results from molecular dynamics simulations. Of course the water film at the hydrophobic surface is unstable with film thinning and rupture upon bubble contact. Under these circumstances it is shown that an attractive Van der Waals force between the bubble and the hydrophobic surface can be expected when the water exclusion zone is taken into consideration. As the thickness of the water exclusion zone increases to a thickness corresponding to the size of nano bubbles, the calculated attractive Van der Waals force increases. This analysis may help to explain the so-called ?short range? and ?long range? hydrophobic forces. Keywords: SFVS spectra, hydrophilic silica surface, hydrophobic silica surface

Sep 1, 2012

By F. K. Ikumapayi

An approach to environmental sustainability and improved process economy, in sulphide minerals production is recycling of process water in flotation of complex sulphide ores, although the chemistry of process water may be a critical issue to flotation efficiency. The influence of major components of calcium and sulphate ions in process water on xanthate collector adsorption and flotation response using pure chalcopyrite, galena and sphalerite minerals were investigated by Hallimond flotation, zeta-potential measurement, FTIR and XPS spectroscopy studies, while bench scale flotation tests were also carried out using complex sulphide ores. The impact of the species in flotation was comprehended using deionised water, tap water, process water and simulated water containing equivalent amount of calcium and sulphate species in process water. Hallimond flotation results showed a decrease of chalcopyrite and galena recovery in process water and also in the presence of calcium and sulphate ions in both deionised and process waters, whereas sphalerite does not respond to flotation. The adsorption of calcium and metal ions but not sulphate ions on the minerals is evidenced by zeta-potential data. FTIR and XPS studies revealed the presence of surface oxidized sulfoxy species and surface calcium carbonates on chalcopyrite in the presence of process water and water containing calcium ions, surface oxidized sulfoxy and carbonate species on galena in the presence of deionised water, process water and water containing calcium and sulphate ions, all at flotation pH 10.5, and these surface species influenced xanthate adsorption. The presence of surface oxidized sulfoxy and carbonate species at the sphalerite flotation pH 11.5 were seen in the presence of deionised water, process water and water containing calcium and sulphate ions, but the surface species does not influence xanthate adsorption. Bench scale flotation using two different complex sulphide ores showed that chalcopyrite, galena and sphalerite recoveries are better in process water than tap water. The studies showed that the process water can be recycled in flotation with no detrimental effect on grade and recovery of sulphide minerals. Keywords: sulphide minerals, flotation, zeta-potential, FTIR, XPS

Sep 1, 2012

Poor floatability of fine particles is known to be the main cause of the low recovery of ilmenite in Panzhihua, which is the largest titanium mine of China. To get an optimum ilmenite recovery, selective flocculation, and flotation of fine ilmenite was investigated through flotation tests, particle size analysis, zeta potential tests and scanning electron microscopy. The results indicate that carboxymethyl cellulose (CMC) shows flocculation effect for both ilmenite and titanaugite without selectivity, while selective flocculation could be realized by the combination of water glass and CMC. It is because that competitive adsorption would take place on these two kinds of mineral when water glass and CMC are used together. On the surface of ilmenite, the adsorption ability of CMC is stronger than that of water glass, so that CMC can absorb to the same extent irrespective of the presence of a pre-adsorbed layer of water glass and ilmenite particles is flocculated by CMC. The same cannot be said of the titanaugite phase as water glass strongly adsorbs onto the titanaugite, and the adsorption of CMC is hindered. Therefore, the titanaugite particles keep dispersion. Furthermore, the flotation of fine ilmenite particles is feasible as the ilmenite floccules could react with sodium oleate. In the flotation separation of Panzhihua ilmenite ore, the recovery of TiO2 increased from 52.63% to 68.28% by selective flotation. Keywords: ilmenite, flotation, selective flocculation, adsorption

Sep 1, 2012

By Graeme Lamson, Rene Dobbe, Merle Kalstrom, Janice Baron, Robert Thorpe, Chris Martin, Snezana Bajic, Amanda Palko

"This paper presents early results from a case study at the Mount Polley porphyry copper mine in British Columbia, Canada. Daily mineralogical data was acquired and reconciled with daily plant assay and recovery balances to interrogate the mineralogical controls on plant performance. After commissioning, the Minesite machine operated smoothly and reliably, creating daily data to generate mineralogical balances around the circuit for a period of several weeks. The key data, on final products were produced within 13 hours of the end of the respective operating period. The resulting information allowed for a greater understanding of the opportunities and limitations of the Mount Polley metallurgy. In this paper, how this information can be used to help long term strategic planning for the operation, as well as mine planning and production forecasting and the fine tuning of day to day mill operations is described. Early data available at the time of preparing this paper indicated that roughly 40% of the sulphide losses, or 32% of total copper losses existed as low grade inclusions in +75 micron tails. This represented the dominant form of long term copper losses, demonstrated repeatedly in the routine analytical data. However, on a day-to-day basis, the amount of copper present as chrysocolla is the major driver behind variations in total copper recovery. The degree to which this influences mill recovery is valuable to the geologist or mine planner. As they are armed with mineral speciation information for future ores, this will allow for improved mine planning, prediction of copper recoveries and production forecasting. The data was also started to find value in the mill by showing what caused sulphide losses. In the roughers, for example, the data showed poor recovery was the result of poor flotation performance and not any changes the speciation of copper sulphides or their liberation characteristics."

Jan 1, 2014

By Shounak Banerjee, Suresh Babu Dasari, Dharmendr Kumar, Shashank Pardhikar, Beena Rai, Venugopal Tammishetti

Recent increase in steel demand has led to the increased usage of high grade iron ores. During the mining, crushing and washing of ore, huge quantities of fines and slimes (<150 µm) are generated, majority of which is dumped into tailing ponds owing to their high alumina contents (~10-15%). Due to rapid depletion of high grade iron ore, it is the need of the hour to utilize low grade iron ore fines and slimes. These fines and slimes contain high iron values assaying 45-60% Fe. Dumping these valuable resources in ponds locks enormous land space and causes environmental hazards. The constituent minerals present in Indian iron ores comprise of hematite, goethite, gibbsite, kaolinite and quartz. Our research is focused on beneficiation of iron ore slimes through selective flocculation. We use density functional theory simulations to screen the reagents and perform experiments with screened reagents to determine the experimental conditions for effective performance of the reagents. Our studies revealed that reagents like starch, guar gum and carboxymethyl cellulose exhibit excellent selectivity in high alkaline pH range. However, the higher cost of alkali makes the process economically less attractive. In the present study, a commercial reagent from NALCO Water (Hi-Tex 83570) has been explored as selective flocculant for beneficiation of iron ore slimes in wide pH range (4-11). However, the reagent was also found to be the most selective in alkaline pH range only. Full factorial design of experiments was done considering three parameters namely, pulp density, flocculant dosage and settling time. Regression models were developed for yield, iron grade, alumina grade and iron recovery in the concentrate, using experimental results. Further parameter optimization was done to achieve high Fe recoveries and low alumina recoveries. The optimal parameters thus arrived at were validated with the experiments. We were able to achieve a concentrate grade of 60.0% Fe and 5.1% Al2O3 with 68.8% Fe recovery from a feed containing of 53.1% Fe and 8.9% Al2O3. The performance of flocculant Hi-Tex 83570 was also compared with reagents starch and guar gum.

Jan 1, 2018

By Å Sandström

Loussavaara-KiirunavaaraAB?s (LKAB) iron ore mine, Kiirunavaara, is of magnetite type and associated with apatite, a calcium phosphate mineral. Rare earth elements (REE) have been found in connection with the apatite but also in other minerals. An apatite concentrate was produced by flotation, in order to investigate the possibilities to extract REE from the apatite by hydrometallurgical means. The content of rare earth elements calculated as oxides (REO) was 0.44% in the concentrate. Initially, leaching was done with large excess of sulfuric acid, hydrochloric acid, and nitric acid to study the REE solubility with different acids. In sulfuric acid, the leaching recoveries of the different REE varied between 35% and 69%. The reasons for the relative low recoveries, were that the rare earth elements precipitated together with huge amounts of gypsum, that was formed during leaching. However, both hydrochloric- and nitric acid gave almost complete extraction of the REE into solution. Analysis of the small leaching residue obtained, revealed, that mainly the light REE remained in the residue indicating that a small part of the light REE were present in the concentrate, in some acid, insoluble mineral other than apatite. With the aim to separate the REE from the phosphoric acid, the solutions from hydrochloric- and nitric acid leaching were neutralized to a pH of approximately 2 with ammonia. During neutralization, REE were precipitated as phosphates with good recoveries and a concentrate of 10.5% REO suitable for further upgrading was obtained, while the remaining solution can be used for fertilizer production. In further solvent extraction studies, it was shown, that after re-dissolution the REE could be effectively extracted by Cyanex 923, thus allowing for purification from calcium and phosphate ions. The REE were finally stripped from the organic phase and a REE nitrate solution was produced. Keywords: apatite, rare earth elements, REE, leaching, solvent extraction, cyanex 923

Sep 1, 2012

By Ying Gu

Automated mineralogy methods and tools, such as the Mineral Liberation Analyzer (MLA) and the QEMSCAN, are now widely used for ore characterization, process design and optimization. Several case studies published recently demonstrate that large gains can be obtained through grinding and flotation optimization guided by automated mineralogy data. However, since automated mineralogy can only provide the information pointing to where the process gains can be made, it does not directly impact the production gain. Thus, a question is often asked: how to value the contribution of automated mineralogy to process improvement of a particular plant. This appears to be a difficult question. On close examination however, it is found that this is essentially a question of the value of information and it is reasonably well documented in various other industries. Hubbard (2010), in chapter 7 ?Measuring the Value of Information?, dealt with exactly this type of problem. The value of information is the reduced risk of an investment and opportunity loss. The methods Hubbard developed can be applied to estimate the value of automated mineralogy, as well as metallurgical test work, which also produces information that reduces the risk of investment. This paper first introduces Hubbard?s theory on the value of information and how to measure it. It then applies his methods to estimate the value of automated mineralogy, using Anglo Platinum?s fine grinding project as an example. In this case, the value of automated mineralogy includes the reduction in investment risk worth US$ 62.5million, in project rejection worth US$197 million and in opportunity loss worth US$320 million. In the end, a general model is developed to allow the simulation of the value of automated mineralogy in different mining operations constrained by different parameters.

Sep 1, 2012

As a kind of collector, Xanthates are generally used to make sulfide minerals hydrophobic in flotation process. Xanthate adsorption on a galena surface has been widely studied experimentally. In this paper, DFT methods were employed to investigate the local adsorption interactions about the collectors,such as ethyl xanthate (CH3CH2OCS2?, EO) and ethyl trithiocarbonate (CH3CH2SCS2?, ES), absorbing on two different PbS clusters. From the results, it can be easily found that, on the edge or at the apex, both collectors, with two S atoms bidentate coordinating on the clusters, have surprising interaction energies, while on the surface, its interaction is relatively weak in the form of monodentate ligand. NBO analysis results reveal that there is at least a covalence bond with sulfur atom about 10% and lead atom about 90% when the absorbed lead is on the lattice edge or at apex, but, if the absorbed lead is on the lattice surface, no covalence band would be found. Meanwhile, the S-Pb bond, formed by the absorbed Xanthate and galena lattice, seems to have much more covalence characteristic than that formed in the PbS lattice inner. Furthermore, those data also imply that the difference of the collecting effect between the EO and the ES may be not notable, because of the similar distance and the interaction energy for the same interaction mode.

Jan 1, 2014

By Vinay Jain

Beneficiation of alumina rich iron ore slimes is a major challenge for the Indian iron ore industry. One of the methods by which this problem might be addressed is by design/screening of suitable reagents (flocculants/depressants/collectors) which act selectively towards either aluminum containing minerals (gibbsite and kaolinite) or iron bearing minerals (hematite and goethite) in order to separate them. Our earlier work indicates that separation of iron oxide minerals from gibbsite is relatively more difficult than from kaolinite. Accordingly, our research work has been focused on finding selective reagents for iron oxide ? gibbsite separation. We have performed density functional theory (DFT) computations to evaluate the interaction energies of seven different reagent groups - carboxylic acid, flotol, hydroxamic acid, phosphonic acid, iminobismethyl phosphoric acid, xanthate and starch with hematite and gibbsite surfaces. The objective was to identify if any of these groups show selective adsorption towards one of the mineral surfaces. Among all these reagents, starch exhibits the highest selectivity towards the hematite surface with a difference in interaction energy of ~63 kcal/mol between hematite and gibbsite surfaces. This is consistent with experimental findings at our laboratories on slime samples from Noamundi mines wherein it is being observed that usage of starch as a flocculant does lead to an improvement in the final grade of the ore with significant reduction in the Al-content. A binuclear complexation mechanism based on affinity between Fe and Ostarch atoms combined with a geometrical templating effect, arising out of a close correspondence between Fe-Fe distance on the hematite surface and O-O distance in starch, is proposed to explain the strong adsorption of starch on hematite surface. Keywords: slimes, iron ore, alumina, hematite, gibbsite, DFT, adsorption, flocculants

Sep 1, 2012

By G. Demi

The biggest chromium mineral processing plant in Albania is Bulqiza plant. It has been in operation for more than 20 years, treating low-grade chromium ores grade 20 ? 26 % Cr2O3 and producing chromium concentrates grade 48 ? 50 % Cr2O3. About 2 million tons of tailings with 13 % Cr2O3 content are stocked in a dam close to the plant. Mineral processing of low-grade chromium ores with less than 16% Cr2O3 content is unprofitable because the mining expenses are high comparing with the current market prices of chromium concentrate. Recycle and enrichment of existing tailings is profitable, because there are no underground mining expenses in this case and because that this kind of raw material does not need expenses operation of crushing and grinding. The existing plant is in operation for more than 8 years treating existing tailings as raw material. Grade of concentrate in the value 40 % Cr2O3 and Cr2O3 recovery in the value 30-35% in the plant are considered low. The main reason of low concentrate grade and recovery is high content of particles under 100 microns, the slimes, in raw material. In the paper is described the study carried out to improve enrichment of the tailings, as well as analyses of existing process, raw material and products. It is concluded that majority of lost is present in the slimes which are not separated in existing spiral separators and shaking tables. Basing in the study is composed the new flow sheet of recycling and concentration of the tailings to produce chromium concentrate grade 41 ? 42 % Cr2O3 and recovery 60 %, decreasing in this way the concentrate production cost two times. In the paper are presented the tests and results of concentration of particle size fraction under 100 microns, using gravimetric, magnetic and flotation methods, as well as equipment and machines suitable for slimes treatment and concentration.

Sep 1, 2012

By Gulsen Tozsin, Ekrem Kalkan, Taskin Oztas, Elif Agirman Akturk, Ercument Koc, Ali Ihsan Arol

Marble wastes are generated by quarries (marble quarry waste-MQW) and processing plants (marble cutting waste-MCW). The large amount of marble wastes is becoming serious problem for industry and environment because of discarded into rivers and lagoons, without any treatment. Marble wastes can cause environmental problem and economic loss if the waste is not used. However, this type of wastes has a good potential to be used as an amendment for the neutralization of acid soils. In this study, MQW and MCW were applied to an acid soil at different rates and their effectiveness on neutralization was evaluated by a laboratory incubation test. The results showed that soil pH increased from 4.71 to 6.36 and 6.84 by applications of MCW and MQW, respectively. It was suggested that MQW and MCW could be used as soil amendments for the neutralization of acid soils, and thus the negative impact of marble wastes on the environment could be reduced.

Jan 1, 2014