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By Alla D. Mah

The work described in this report is part of a Bureau of Mines research program for obtaining heats of formation of inorganic oxides, carbides, and nitrides by combustion calorimetry. The heats of combustion of molybdenum subnitride (Mo2N) and chromium subnitride (Cr2N) were measured. The data were combined with previous determinations of the heats of formation of molybdenum trioxide and chromium sesquioxide to obtain the heats of formation of the two subnitrides from the elements at 298.15° K. The corresponding free energies of formation were estimated. The heat data were compared with those of nine previously studied nitrides.

Jan 1, 1960

SMCRA contains five principal regulatory provisions that form the basis for its implementation: Performance Standards Performance standard safe intended to ensure that all surface mining is conducted in a way that protects the environment and the public and ensures that the mined land is restored to productive use following mining. Permits Before developing a surface or underground coal mine, an operator must have a permit issued under SMCRA. An application for a permit to conduct a surface coal mining operation is a detailed document that consists of text and numeric data describing the proposed mining and reclamation. Information must be furnished on pre-mining environmental conditions, existing land use, proposed mining and reclamation, how the performance standards will be met, and the post-mining land use. This provides the regulatory authority with the information necessary to determine that the operation can be conducted in accordance with the regulations. Performance Bonds Before a permit can be granted, an operator must post a performance bond sufficient to cover the cost of reclaiming the site in the event the operator fails to complete reclamation. The bond is not fully released until all performance standards have been met and reclamation of the site has been determined to be successful after five years in the East and Midwest, and after 10 years in the arid West. However, the bond can be partially released as various phases of reclamation are completed. Inspection and Enforcement If a violation of SMCRA or of a state surface mining and reclamation law is observed, an inspector issues a notice of violation to the operator. The violation must be corrected within a specific time, and the operator may also have to pay a fine based on the severity of the violation. If the violation is not corrected, acessation order is issued to immediately stop active coal mining, and the operator must pay a fine. If a violation is especially serious (for example, creates an Following reclamation, the land was immediately put back into agricultural production. Today, grain and corn crop yields have continually exceeded targets. 2 imminent danger to public health or safety or causes significant damage to land, air, or water resources) the inspector immediately issues a cessation order. An operator must correct all violations in order to obtain permits for new mines. Lands Unsuitable For Mining Congress recognized that certain coal deposits cannot be mined without permanent damage to unique cultural or natural resources. As a result, SMCRA protects these resources in two ways: It prohibits mining within the boundaries of national parks, forests, wildlife refuges, trails, wild and scenic rivers, wilderness and recreation areas; in areas which will adversely affect sites listed on the National Register of Historic Places; and within a restricted distance of occupied dwellings, public roads, buildings, parks, schools, churches, and cemeteries; and Provides a process that allows anyone whose interests may be adversely affected by proposed mining to petition to have specific lands designated unsuitable for mining.

Jan 1, 1992

By R. L. Grayson, S. S. Peng

"Abstract. Sampling of respirable dust and analyses of samples have been partially completed for a longwall panel. Physical and compositional properties which have been characterized include:l. Respirable mass concentration, 2. Mineral composition,3. Particle size distribution by mineral,4. Particle shape distribution by mineral,5. Particle angularity distribution by mineral, and6. Respirable size distribution.Analytical techniques used in the characterization of samples are described, and results are reported with emphasis placed on relationships between the various characteristics and worker locations. Details of existing mining conditions, equipment arrangements, dust control methods and operating system parameters are presented.INTRODUCTIONThrough the work of many researchers worldwide, the health of coal miners in modern societies is now protected from dangerous exposure to respirable coal mine dust. A vast amount of research culminated in the exposure-response model of Jacobsen, et al. (1971) whi3h has been used to establish the 2mg/m exposure limit in the United States. According to the model, exposure to respirable dust for 35 years at this level or less would prevent the occurrence of a clinically significant case of coal workers' pneumoconiosis (CWP). The exposure limit, of course, must be adjusted whenever greater than five percent free silica exists in the respirable dust.The Jacobsen model was built around a mass concentration exposure, which showed the highest correlation with incidence and progression of CWP. As Morgan; et al. (1973) noted, howev.er, the quantity of respirable dust inhaled is not the only significant factor. It is noted that although mass of respirable dust correlates highest with the incidence of CWP, it is not a causal factor. Indeed, the insidious processes causing the disease occur on the cell-particle scale, requiring microscopic investigation."

Mar 1, 1989

By Potter G. M.

Ore-dressing tests were conducted on a sample of ore submitted by the Richmond Hill Mining Co. of Lead, S. Dak. as a part of the Bureau of Mines program for investigating potential domestic sources of manganese. Half of the sample was taken from the 300-foot level and half from surface cuts. The problems involved were liberation and rejection of silica and iron and removal of lead, Silver, and gold from the manganese concentrates. Although a portion of the silica and iron oxides was too intimately associated with manganese minerals for rejection by ore-dressing methods, thus limiting recovery of high-grade concentrates, the Richmond Hill ore was found amenable to simple gravity methods of concentration for producing intermediate-grade products. By jigging and tabling, 73.8 percent of the total manganese was recovered in a product that, when sintered, assayed plus 40 percent Mn. Lead, silver, and gold were successfully removed from gravity concentrates by a chloridizing roasting treatment.

Jan 1, 1948

By H. D. Jacobs

The Bureau of Mines undertook a research program to insure an adequate supply of iron raw materials for future iron and steel making needs. A sample was obtained of oxidized taconite from the western Mesabi Range in Minnesota, and the metallurgical response of the taconite to beneficiation by a process that included selective flocculation-desliming-cationic flotation was evaluated. The sample contained 35.3 pct iron and represented approximately 2 billion tons of crude material. Selective flocculation and flotation were evaluated in a pilot plant with a feed rate of 900 Ib/hr. Concentrates averaging 61.7 pet iron and 5.1 pet silica were obtained, with an accompanying iron recovery of 67.2 pet. About 83 pct of the process water requirements were reclaimed from the slime and froth tailing and then recycled.

Jan 1, 1980

By David J. Kusler

This report describes a rapid, reliable, and relatively simple method developed by the Bureau of Mines Pyrometallurgy Laboratory at Bruceton, Pa., for determining lime (calcium oxide) and magnesia (magnesium oxide) in various materials containing these constituents in greater than trace amounts. Optionally, titania (titanium dioxide) may be determined for the same sample. The accuracy of the method, suitable for most purposes, is shown by comparing the Bureau results with those obtained by accepted procedures. The method has been applied satisfactorily to the routine analysis of blast-furnace slags, for which purpose it was primarily developed, and to other calcareous compositions. In the Pyrometallurgy Laboratory it has replaced the standard methods previously used to determine lime and magnesia, and has been in general use by that laboratory for the past several years. The analysis time, generally under 3 hours, is considerably less than required by standard methods.

Jan 1, 1960

By Irving Hartmann

1. Under the conditions of the tests described herein, the proper use of an incombustible stemming plug of the type discussed prevented ignitions of gas in all tests during the firing of 21 single shots of permissible explosive in cool. In two tests with multiple blasting (four and five shots each) no ignitions resulted. 2. The results of a few tests in this investigation and of numerous tests made previously indicate that fire-clay stemming of the same weight as an incombustible plug provides about the same degree of protection as the plug against gas ignitions during blasting of coal by permissible explosives. 3. The hazard of gas ignition on firing charges of non-permissible 40-percent gelatin dynamite in coal was reduced but not eliminated when the shot holes were stemmed with one or two incombustible plugs or with an equivalent weight of fire clay. 4. On the basis of this investigation, the Bureau of Mines considers the proper use of incombustible stemming plugs of the design tested, under the conditions of the tests described in this paper, to be of equivalent safety as the same weight of fire-clay stemming. This report does not constitute approval or disapproval of the incombustible stemming plugs by the Bureau of Mines. 5. The test data indicate that misfired charges in shot holes stemmed with the incombustible stemming plug cannot be disposed of with certainty by the procedure recommended by the manufacturer. In this investigation the misfired charges failed to detonate in 30 percent of the trials.

Jan 1, 1950

By H. E. Powell

This Bureau of Mines study describes two processes for recovering zinc, copper, silver, and iron from the magnetic fraction of a waste generated by the primary smelting of zinc in horizontal retort distillation furnaces. The laboratory-scale procedures include reduction melting to produce a high-copper iron and matte smelting to produce a copper-silver-iron matte and metallic iron. Zinc is fumed in each process and recovered as the oxide. Direct reduction melting yields a metallic iron high in copper and a small rich matte from the sulfur contained in the waste. The products of the second process are a matte containing essentially all of the silver, about 80 pct of the copper and 37 pet of the iron, and an iron-copper alloy containing all of the remaining copper. Extraction with metallic lead or sodium sulfate recovers essentially all of the copper from the molten high-copper iron and yields an acceptable foundry iron.

Jan 1, 1973

By Aner W. Erickson

Magnetite iron deposits on Tolstoi Mountain were examined as part of the investigations by the Bureau of Mines of iron and copper ores on Prince of Wales Island. The Tolstoi Mountain project was a part of a program for investigating mineral deposits in Alaska, under the general supervision of R. S. Sanford, acting branch chief.

Jan 1, 1948

By Thomas J. Peters

In 1987, at the request of the U.S. Bureau of Land Management, the Bureau of Mines studied the 350-acre Henry?s Lake Wilderness Study Area (ID-035-077) in order to evaluate its identified mineral resources. The Wilderness Study Area is located in northern Fremont County, ID, approximately 140 air miles north-northeast of Pocatello and 3 miles south of the Montana border. The Wilderness Study Area is near the north shore of Henry's Lake at the foot of the southwest-facing slope of Black Mountain. Archean hornblende gneiss, the main rock type present, crops out northeast of the Madison Range Fault, which trends northwest across the southwest corner of the Wilderness Study Area.

Jan 1, 1988

By W. H. Ode

An investigation of standard methods for determining ash in low-rank* coals showed that generally 60 to 95 percent of the total sulfur in the coal is retained in the ash as SO3. This large sulfur retention causes a positive error in the determined mount of ash of as much as 6 percentage points for the coals examined, although it usually is 2 to 3 percentage points for lignites and about 1 for subbituminous coals. Unless the sulfur content is low or unless a correction is made for the SO3 retained, the fixed carbon and oxygen have an equivalent negative error when determined by difference; also other inaccurate analytical values occur when the data are calculated on an ash- free bas is. No simple modification of the ashing procedure was found that would reduce the sulfur retention to a point where its effect on the ash determination would not be significant, Therefore, for accurate analytical work on law-rank coals, the SO3 should be deducted from the determined ash to obtain a "corrected" ash value.

Jan 1, 1962

By Roger J. Morrell

Disk-cutter experiments were performed on five rock types ranging in compressive strength from 9,000 psi to 27,000 psi. A specially constructed testing machine called a linear-cutter apparatus (LCA) was designed to load and traverse a free-rolling disk cutter across a sawed rock surface. The LCA was instrumented to measure the vertical and horizontal forces acting on the cutter during the run.. The ability of disk cutters to fragment rock was determined for both 60--degree and 90-degree cutting-edge angles, and relationships and regression equations were developed to predict cutter performance based on rock physical properties and applied forces,

Jan 1, 1970

By C. F. Swab

A relatively innocuous halocarbon was investigated as a substitute for the highly toxic carbon tetrachloride in the approval testing of chemical cartridges. The vapor effluent of 1,1,2-trichloro-1,2,2-trifluoroethane from chemical cartridges is continuously monitored by a nondispersive infrared analyzer. Breakthrough times for the cartridges, using the halocarbon, can be equated to those of carbon tetrachloride, if multiplied by the factor, 1.49.

Jan 1, 1970

By Philip C. Tully

This Bureau of Mines report contains experimentally determined vapor-liquid equilibria data for a helium-nitrogen-methane mixture with a nominal composition of 15, 60, and 25 mole-percent, respectively. Measurements of the equilibrium phase compositions were obtained by means of a windowed cell, in conjunction with an automated chromatograph and a special analyzer for low helium concentrations. The data presented include a comprehensive table and eight graphs depicting phase compositions, vaporization ratios, and correlations with a previous study of two helium-nitrogen-methane mixtures of different compositions.

Jan 1, 1976

By P. C. Good

This Bureau of Mines report describes the preparation of phosphoric acid directly from phosphate ore, without prior beneficiation, in a small-scale, continuous process research unit, as part of an effort to improve minerals and metals recovery from domestic resources while minimizing environmental effects. Three phosphate-matrix samples, ranging in grade from 18.2 pct P20S5to 11.9 pct P205, were dry-fed at a rate of 1.82 kg/hr (4 lb/hr) to a continuous-circuit, 12-liter, single-tank digester to yield phosphoric acid and byproduct gypsum filter cake. Comparison with earlier data shows that a significantly improved filtration rate was attained in a single-tank reactor compared with that attained in a five-tank reactor train processing the same ore. Iron and aluminum impurities in the product phosphoric acid averaged about 60 pct higher than amounts reported in commercially prepared, concentrate-derived acid. All gypsum filter cakes prepared had a firm, sandy texture, rendering them physically suitable for stacking or landfill use. Introduction of dry attritioning and air classification approximately doubled the attainable filtration rate when the dry-beneficiated product was digested. In air classification, there was a 12-to 14-pct P205 loss. Depending on the technique used and the matrix grade, overall P205 recovery ranged from about 72 to 89 pct.

Jan 1, 1979

By G. R. Hopkins, A. B. Coons

A survey of the petroleum pipe lines by the Bureau of Mines as of May 1, 1923, shows that on that date there was a total of slightly more than 90,000 miles of pipe lines in the United States, having a capacity of approximately 15,750,000 barrels, which is equivalent to one-fourth of the nation's average production for one month. These lines varied in diameter from 2 to 16 inches, the weighted average being 6 inches. The total pipe-line milenge was about equally divided between trunk lines and gathering lines, though the capacity of the former was about four times that of the latter. This was due, of course, to the difference in average diameter, that for the former being 7.4 inches as compared with 3.7 inches for the latter. The common size for trunk lines was 8 inches, and for gathering lines 2 inches. Oklahora, with 19,180 miles of pipe lines, is the leading State in total mileage, with Texas second and Pennsylvania third. From point of trunk lines alone Texas is considerably ahead of any of the other States, a position which it owes to its size and to the growth in the rovement to its Gulf ports. Cali- fornia, though the leading State from point of production, ranks only seventh in pipe-line mileage. This is due to the fortunate location of the Los Angeles Basin fields, some of which are within sight of the refineries to which their oil is delivered or of the port of San Pedro through which their oil is shipped. The last survey of this nature, made in the spring of 1924 by the U. S. Geological Survey, recorded a total mileage of nearly 83,000 with a capacity of approximately 14,450,000 barrels. This indicates an increase of 9 per cent in both mileage and capacity during the two years.

Jan 1, 1927

By Victor E. Kral

"SUMMARYFollowing a magnetometer survey on the McCoy iron deposit, a trenching and drilling program was carried out by the Bureau of Mines in August 1944.This deposit is 32.3 miles southwest of Battle Mountain in the McCoy Mining District, Lander County, Nevada, and lies on the east flank of the Fish Creek Mountains at an altitude of 5,400 feet, about 1 1/2 miles south of the gold camp of McCoy.Total production from the deposit has been 400 tons of magnetite, mined by hand and shipped to the west coast for ship's ballast.Bureau drilled two holes to a total depth of 92 feet and excavated 12 feet of trenches. Both holes were drilled in the same ore body and engineered magnetite ore 14 and 11 feet thick. Trenching was used successfully to show the lateral limits of the ore.Magnetite ore bodies were found to occur as replacements of a limestone bed in quartzite. They outcrop near and parallel to the exposure of a diorite entrusting that forms a long westward-trending ridge. Although magnetic outcrops can be traced for 5,000 feet trenching definitely proved the ore bodies to be disconnected to have little or no lateral extent beyond their outcrops. Only two ore bodies more than 10 feet thick were found; one of these is the inaccessible to and the other was drilled by the Bureau."

Jan 1, 1947

By F. N. Kissell, R. J. Bielicki, J. H. Perkins

A sorption apparatus for measuring the equilibrium sorption isotherm and the rate of diffusion of methane from fine-sized coal was designed and constructed. Preliminary work that used Pittsburgh and Pocahontas No. 3 coal shows that the diffusion coefficient varies with pressure and that the fracture spacing in these two coals is substantially different.

Jan 1, 1972

By G. R. Hopkins

The petroleum-refining industry established a. new record in fuel effieciency at refineries in 1936, when 597,000 B. t. u. of heat mere required to refine a barrel of crude oil, compared with an average of 615,000 B. t. u. in 1935 (see fig. 1). The principal factor in the 'indicated gain in fuel efficiency at refineries in 1936 was an increase in crude runs of 11 percent over 1935. A large part of the heat utilized at refineries is consumed elsewhere than under stills, or in ways quite independent of crude-oil distillation. In other words, as the operating ratio ( crude runs divided by capacity) for re- fineries increases toward tine maximum of 100 percent, the fuel requirements show progressively smaller increases and the average B. t. u. consumption per barrel of crude refined declines.

Jan 1, 1938

By John Gross

In connection with some investigations being made at '!'he Ra.re uid Precious 1ets.ls Station of the U, S. Bu.rea.u of Mines, at Reno, Nev., on the precipitation of gol'i and silver from cyanide solutions, it wa.s sug­ gested tnat the use of acetylene for this purpose be investigated, A pa.tent was iss·.ied to Fre<!.erick W. Martin and Frederick Stl1.bbs in 1900 covering the precipitation of precious metals from cyanide solu­tions by acetylene, The acetylene used in the tests described below wa3 made f'rom a. corr.:nercial cal ci \'!Z:l carbid.e, A r..umber of exper:me11. +,s rezul ted in more or lP.ss ccmplete pree;p1tatien of silver, -but 1n no case was a11Y gold precipitated. As silver acetylide, obtained by precipitatir.g the silver from an ar:::ncni'i\.Ca.l so1ut1on of silver n,. tra.te by acetylene, is yellowish white, esn:, solu'.)le in cyanide and hlghly explosive, and the pr9cip1tate ob­tain£ frcvm the cy'31lide sclutions was black, not tlubla L., cyanide and not explooive, it 'Na.s deid-,d. to ir.·.restigate the na.tur.e of the slJ.ver pre­cipit.te !rem the cy;r:iide solu·t:i.i,ns, !n prepa;.•i::lg a lge (!\,wrttity ,:f the preci-pi tte 1 t. wa, fo·und that a.fter c,:.\i;:1 ete prEc"'.pi tat ion cf the eil ver the !IOl ution con ta.ined soluble eulphic.e • Thia p:!:'O'lided a el f!W "lt·d. a.ft er apr,ropri-9.te tests the preeipita.te VIO,I proved to 'be ailver sulphide.

Apr 1, 1922