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By A. R. Taylor

Low-temperature heat capacities of cesium chloride (7° - 300° K) and cesium iodide (13° - 300°K) were measured with an adiabatic calorimeter. The heat-capacity measurements were analyzed graphically to determine smooth values of heat capacity, entropy, enthalpy function, and free-energy function at 10° K intervals and at 273.15° and 298.15° K.

Jan 1, 1963

By J. Wade Watkins

One potential peaceful application of nuclear explosives is stimulating the production of liquid or gaseous hydrocarbons from essentially nonproductive deposits of petroleum, natural gas, oil shale, and tar sands. Within the United States the appreciable difference between producible proved reserves and ultimate reserves and resources of hydrocarbon deposits is of such magnitude that much petroleum, natural gas, shale oil, and bitumen will not be produced unless significant technological progress is made in production techniques. The shattering effect of contained nuclear explosives and, to a lesser extent, the heat produced, have been considered as stimulative forces when the thickness, depth, and nature of such deposits permit considering the use of nuclear devices. Mechanical production problems would be less in an oil or gas reservoir than in an oil-shale or tar-sands deposit. Also, tar-sands resources in the United States may not be adequate to warrant serious consideration of applying nuclear-explosives stimulation. Gas reservoirs should present the least- radioactive-contamination problem. The technical feasibility of using nuclear explosives cannot be evaluated fully at present. Additional information is needed on the effects of pressure, heat, and radioactivity on the solids and fluids of hydrocarbon deposits, the nature and extent of induced fractures in different rock media, and the possibility of isolating and confining or removing radioactive contaminants. Final technical feasibility can only be determined by a field test. If technical feasibility is established, economic feasibility will depend upon the comparative cost of producing hydrocarbons by nuclear explosives and by conventional means. It is probable that an economic comparison would favor nuclear stimulation only where devices of relatively high yield could be used practicably and safely.

Jan 1, 1964

In this Part, we have included copies of the flip charts and overhead projector viewgraphs used in the two briefings we conducted as part of this seismic detection and location task. The first one was an overview and problem definition briefing given to the seismic consultants on September 7, 1972. The second was a formal oral presentation of study results to technical staff members of the Pittsburgh Mining and Safety Research Center on November 21, 1972.

Jan 1, 1974

By A. A. Campoli

Retreat pillar mining concentrates stresses on workings directly outby gob areas, which can result in coal mine bumps. The development of bump-control design criteria by the U.S. Bureau of Mines was furthered by data from a novel bump control mining method at the Olga Mine, McDowell County, WY. The pillar splitting, retreat mining system induced large pillar pressure increases and roof-to-floor con-vergence. Roof-to-floor convergence monitoring proved to be a valuable tool in evaluating the pillar splitting mining method and localized destressing techniques. Maximum strain energy storage in chain pillars appears to have occurred just prior to the first of four split cuts. At that point a 15-ft-wide, highly fractured perimeter confined the core of the 55-by 70-ft pillars, permitting the pillar core to support tremendous pressures. Splitting the chain pillars into two 17.5-by 70-ft wings removed the confinement load, resulting in pillar yield. Thus, the pillar splitting mining method successfully redistributed the weight of the roof away from the pillar line. Shot fire and auger drilling destressing techniques aug-mented the pillar splitting mining method by redistributing the weight of the roof.

Jan 1, 1989

By A. B. Hooker

Since man first mined underground, there has been need for adequate illumination; this need has never been fully supplied. At first, suitable lamps were not available. Gradually they have been developed, but along with that development the need for better and better lamps has continued owing to the following conditions and factors: 1. Increasing hazards from gas and dust ignitions. 2. The speeding of operations with mechanized mining, which necessitates greater visibility. 3. A demand that cleaner coal be loaded, which requires higher levels of illumination. 4. The cost of compensation for injuries that has created a demand for better illumination and safer lamps. Use of better lamps has been retarded by: 1. Prejudice and resistance to change on the part of the workers in some districts. 2. The cost and upkeep of the lamps. 3. The present types of lamps, while a great improvement over the old lamps, do not entirely fulfill the requirements for a safe and efficient light for underground workers.

Jan 1, 1938

By D. B. Gawthrop

"In connection with the proposed use of Cordeau-Bickford to fire L.O.X. (liquid oxygen explosives) in well drill holes, the question has arisen as to the effect of very low temperatures on (1) the rate of detonation of Cordeau-Bickford; (2) the sensitiveness to detonation of its TNT filling; and (3) the lead covering of Cordeau-Bickford.The Cordeau-Bickford used in this investigation was the standard 6 mm. size, such as is regularly used in blasting, and was manufactured and furnished by the Ensign-Bickford Company, Simsbury, Conn. All pieces tested were taken from rolls, all of which were from the same melted batch of TNT in order that all the pieces tested might be as nearly identical as possible.Different portions of this Cordeau-Bickford were tested plain (not countered), countered, and double countered. The countering and double countering was carried out by the manufacturer prior to shipment.The determination of the temperature at the instant of making a test was accomplished by the use of a Leeds and Northrup potentiometer and copper constantan thermocouples. Each couple was made from No. 28 B & S gage wire with short junctions. One junction was inserted in a hole drilled by a No. 60 drill through one lead wall of the Cordeau-Bickford to approximately the opposite wall, so that this junction was in the center of the TNT filling while the other junction was immersed in ice water. The potentiometer readings in millivolts were converted to °C. from the calibration curve of the thermocouple wire,"

Jun 1, 1924

By R. V. Ramani, R. Stefanko, G. W. Luxbacher

MINE VENTILATION NETWORK ANALYSIS

Jan 1, 1977

By Maria I. De Rosa

Table 1 and figure 1 show the number of fires and fire injuries that occurred in underground metal/nonmetal and stone mines by state during 1990-2001. Table 1 also shows the injury risk rates, employees' working hours, and lost workdays. Overall, 65 fires occurred in 20 states; these include 2 fires and no injuries for contractors. Six of the fires caused nine injuries. The yearly average was 5.4 fires and 0.75 injury. Forty-one fires with 2 injuries occurred in metal mines, 14 fires with 7 injuries occurred in nonmetal mines, and 10 fires with no injuries occurred in stone mines. The underground mine fires required 25 mine rescue team interventions and 30 mine/section evacuations. The Ewhr value was 260 x 10° hr (Irr = 0.007), and the LWD value was 83. Idaho had the most fires (eight fires and no injuries), followed by Louisiana (seven fires and two injuries), Michigan (six fires and six injuries), and Missouri (six fires and no injuries). Of these states, Michigan had the highest injury risk rate value (Irr = 0.146). Table 2, partly illustrated in figure 2, shows the number of fires, fire injuries, risk rates, employees' working hours, and lost workdays by time period. The number of fires during the six time periods show an increase during the fourth period followed by a sharp decrease during the fifth period and a sharp increase in the last period. The number of fire injuries show an increase followed by a decrease during most of the periods, accompanied by a decline in employees' working hours during most of the periods; an increase is seen during the third and fourth periods. The In values follow patterns similar to those shown by the injury values. Tables 3-8 show the number of fires by ignition source, method of detection and suppression, equipment involved, location, and burning material by time period. Figure 3 shows the major variables related to fires for 1990-2001. Table 9 shows the number of fire injuries per number of fires causing injuries and total fires by year, ignition source, equipment involved, and location.

Jan 1, 2004

By Martin Harper

This paper concludes a five year program on research into the use of a portable X ray fluorescence (XRF) analyzer for analyzing lead in air sampling filters from different industrial environments, including mining, manufacturing and recycling. The results from four of these environments have already been reported. The results from two additional metal processes are presented here. At both of these sites, lead was a minor component of the total airborne metals and interferences from other elements were minimal. Nevertheless, only results from the three sites where lead was the most abundant metal were used in the overall calculation of method accuracy. The XRF analyzer was used to interrogate the filters, which were then subjected to acid digestion and analysis by inductively coupled plasma optical emission spectroscopy (ICP OES). The filter samples were collected using different filter holders or "samplers" where the size (diameter), depth and homogeneity of aerosol deposit varied from sampler to sampler. The aerosol collection efficiencies of the samplers were expected to differ, especially for larger particles. The distribution of particles once having entered the sampler was also expected to differ between samplers. Samplers were paired to allow the between sampler variability to be addressed, and, in some cases, internal sampler wall deposits were evaluated and compared to the filter catch. It was found, rather surprisingly, that analysis of the filter deposits (by ICP OES) of all the samplers gave equivalent results. It was also found that deposits on some of the sampler walls, which in some protocols are considered part of the sample, could be significant in comparison to the filter deposit. If it is concluded that wall deposits should be analyzed, then XRF analysis of the filter can only give a minimum estimate of the concentration. Techniques for the statistical analysis of field data were also developed as part of this program and have been reported elsewhere. The results, based on data from the three workplaces where lead was the major element present in the samples, are summarized here. A limit of detection and a limit of quantitation are provided. Analysis of some samples using a second analyzer with a different X ray source technology indicated reasonable agreement for some metals (but this was not evaluated for lead). Provided it is only necessary to analyze the filters, most personal samplers will provide acceptable results when used with portable XRF analysis for lead around applicable limit values.

Jan 1, 2007

By Lynn L. Rethi, Barbara Fotta

Recent employment figures (taken from the Mine Safety and Health Administration's database) indicate that the number of independent contractor' employees working in the coal mining industry has doubled over the past ten years. As their numbers increase, they become a more visible segment of the industry. [ ] Increased exposure to mining hazards has also brought an increase in the number of fatalities involving independent contractor workers. One gauge that is traditionally used to evaluate the overall safety of an entity is the "number of fatalities." Over the five-year period from 1985-89, 27 independent contractor employees were fatally injured while working on coal mine property. This number increased to 45 fatalities during the subsequent five-year period from 1990-94. Nearly half of these fatalities (47%) were due to accidents involving powered haulage (See Table); 13% were electrical accidents; and 9% were machinery accidents. Combined, these three accident classifications accounted for 69% of all coal nine independent contractor fatalities. Information taken from fatality data is an important piece of the safety puzzle; however, other variables need to he examined in order to better define contributing factors associated with accidents. More specifically, information on trends in fatal and nonfatal accident and injury data is necessary before deciding what approach should be used to improve safety. In order to implement appropriate safety strategies, it is important for safety practitioners to examine all available lost time accident and injury information. The following coal industry data sites specific and present trends of independent contractor employees working in underground locations at coal mines, surface areas of underground coal mines, surface coal mines, and preparation plants. The data compares employment and accidents for time periods at the beginning and the end of a ten-year span from 1985 to 1994. Because the number of incidents involving independent contractors in certain accident categories during any one year may be small, three-year totals are used; the first three years (1985-87) of the ten-year period are compared with the last three years (1992-94). [ ]

By F. W. Hoertel

The Bureau of Mines investigated the use of depleted uranium as a sacrificial anode for the cathodic protection of submerged and underground structures of iron , steel , and copper . Uranium-metal couples were tested in simulated marine environments of varying oxygen contents at pH values between 5.5 and 8.5 and under simulated boiler service condition in Rolla , Mo. , city water . Similar couples were tested in samples of Missouri soils to simulate underground service . Uranium remained anodic to iron , steel , and copper in the simulated marine environments and under simulated boiler service if the electrolyte was oxygen- free city water . Uranium appeared to offer limited protection to iron , low- carbon steel , stainless steel , copper , and zinc in the simulated underground tests . Uranium anodes offer a space advantage because 1 cubic inch of uranium gives approximately the same protection as 2 cubic inches of magnesium or 1-1 /2 cubic inches of zinc .

Jan 1, 1963

By B. W. Jong

The U.S. Bureau of Mines investigated anhydrous chlorination and caustic-acid leaching processes to recover Ni, Co, Mo, and W from waste hydroprocessing catalysts. In batch laboratory-scale equipment, the chlorination process extracted 61 to 99 pet of the metals. Final recovery was 65 to 99 pct. The caustic-acid leaching process extracted 81 to 98 pct of the metals. Final recovery was 36 to 99 pct. Chlorination processing included roasting, chlorination, hydrolysis of metal chlorides for recovering Mo or W, water leaching of Ni or Co from the spent charge, purification, and solvent extraction or precipitation of Ni or Co from the purified solutions. Caustic-acid leach processing included NaOH leaching, solvent extraction of Mo or W from the NaOH leach liquor, H2S04 leaching of the NaOH leach residue, purification, and solvent extraction or precipitation of Ni or Co from the purified solution. The estimated fixed capital cost for a commercial-scale plant processing 39,000 Ibid of waste Ni-Mo-AI catalyst was $8 million for the chlorination process and $9.6 million for the caustic-acid leaching process. The estimated operating cost was about $0.20 and $0.40 per pound of the waste catalyst, respectively, for the two processes.

Jan 1, 1989

By James C. Cawley

A summary is presented of existing leaky feeder communications systems currently in operation in North America. Background information pertaining to previous use of leaky feeder technology is discussed along with the survey methodology. A review of some pertinent facts concerning propagation in tunnels and specific reference to mine tunnel propagation is presented. A summary of the characteristics of each mine visited is presented in tabular form, and methods of procurement and maintenance are discussed. The role of user training in efficient system use is presented. Seven sites representing eight mines are included in the survey. Economic and technical topics are considered.

Three types of communication systems have become popular in solving communication requirements underground: Loud-speaking pager phones, carrier current phones, and magneto ringing phones. Basically, all three are simply single-channel party line systems. Although these systems are quite reliable, the single channel creates a variety of problems. For example- 1. Since no call is confidential, messages are sometimes purposely made vague, especially if accidents or safety topics are being discussed. 2. A potential user must literally "wait in line" until the channel becomes clear for his use; thus, when foremen have to wait to call in reports or supply requests, this single chan-nel creates a serious productivity bottleneck. 3. In many large mines, there are independent branch lines that must be tied together by a dispatcher, adding further delays to the system. To solve these problems, some mines have installed other phone systems-mostly commercial dial phones in industrial enclosures that offer extra channel capacity and private line features. Others have installed a system that combines both dial- and page-phone features in a single unit. Although these do represent improvements, they do not truly solve the overall problems that face modern mines. Besides extra channels, a communication system should have the following features to enhance productivity and safety: 1. A means of paging a roving miner to alert him that he is wanted on the phone. 2. Wireless-to-wired system interconnects by which a miner can talk on the wired phone system by using a remote portable radio. 3. Remote monitors that alert personnel when there is a toxic or explosive gas buildup. 4. Control interfaces that allow remote control of fans, pumps, or other devices. 5. Transmitters and receivers that can serve as emergency links. 6. Loopback that allows an alternate path of communications if the main path is cut. This chapter focuses on equipment and methods to meet the special communication needs of individuals in various places of the underground mine. The communication requirements can be broken down into four categories: 1. The mine entrance (shaft communication). 2. Permanent and semipermanent locations (shop areas, lunchroom, crusher stations, etc.). 3. Mining areas (the room-and-pillar sections, longwall faces, block caving areas, etc.). 4. Haulageways (tracked trolley haulage, diesel, belt haulage). Methods of implementing systems to meet the communication needs of these areas are described in sections 3.2 through 3.5. Section 3.6 discusses methods of satisfying special communication requirements that exist. Major topics in this category include communications with roving personnel, the isolated miner, and motorman-to-snapper communications. Emergency communication systems are described in section 3.7.Detecting and

Jan 1, 1984

1. In 2002, a total of 2,065 coal mining operations reported employment to the Mine Safety and Health Administration (MSHA). Coal mines comprised 14.2% of all mining operations. • Bituminous mines comprised 92.5% (n = 1,910) and anthracite mines 7.5% (n = 155) of coal mining operations. • More than 70% of all coal mines were located in three states: Kentucky (28.7%), West Virginia (21.7%), and Pennsylvania (20.1%).

Jan 1, 2004

By J. M. Gomes

The Bureau of Mines has investigated the occurrence and recovery of by-product heavy minerals from sand and gravel operations as a means of assessing the Nation's resources. Sand samples from 63 locations in central and southern California were treated to yield heavy-mineral concentrates. The mineral compositions of the concentrates were characterized by chemical and mineralogical examinations. Additional large quantities of concentrates were prepared from selected deposits that contained significant quantities. Beneficiation studies were performed on these concentrates to recover individual mineral products. Gold was recovered by amalgamation; platinum-group metals and radioactive minerals by flotation; magnetite, ilmenite, and chromite by magnetic and high-tension separation techniques.

Jan 1, 1980

By Maria I. De Rosa

The major fire and fire injury findings for all coal mining categories for 1990-1999 are reported in tables 37-38. Table 39 and figure 13 show the number of fires. fire injuries, risk rates, employees' working hours, and coal production (under- ground and surface coal mines only) by time period for all coal mining categories. Table 40 shows major findings (for under- ground coal mines only) for 1978-1992. For all coal mining categories, 458 fires occurred during 1990- 1999; 157 of those fires caused 164 injuries and 2 fatalities (Ewhr = 2,070 x l0%r, Irr = 0.016: C'P (for underground and surface coal mimes only) - 10,363 x l0\t, Frr = 0.044, LWD = 14,753). Twenty-nine fires and 17 injuries involved contractors. Sixty-six fires required firefighting interventions by mine rescue teams (25 times in underground mines) and fire brigades and fire departments (at least 41 times at surface coal operations). In all, 51 fires destroyed or heavily damaged equipment (including 16 pieces of mobile equipment) because of failure of other firefighting methods, late fire detection, undetected fires, or fire size. A total of 114 fires were detected late, and 42 fires were undetected. The greatest number of fires and fire injuries occurred at surface coal mines; the highest risk rate values were also calculated for this category. For all coal operations, the ignition sources that caused the greatest number of fires were flame cutting/welding spark/slag/flames (1 03 fires or 23% with 69 injuries), hydraulic fluid/fuel sprayed onto equipment hot surfaces (98 fires or 2 1 % with 29 injuries), spontaneous combustion/hot coal (62 fires or 14%), electrical short/arcing (49 fires or 11% with 18 injuries), and conveyor belt friction (3 1 fires or 7% with 6 injuries).

Jan 1, 2004

1. In 2003, a total of 4,357 stone mining operations reported employment to the Mine Safety and Health Administration (MSHA). The major industrial classifications in stone mining are dimension stone (used for construction purposes), crushed and broken stone (aggregates), cement, and lime. • Stone mines comprised 30.3% of all mining operations. • Mines producing crushed and broken stone (n = 3,412) comprised 78.3% of all stone mining operations.

Feb 1, 2005

By P. R. Bremner

In keeping with its mission to maximize mineral and metal recovery from domestic sources, the Bureau of Mines investigated a method to extract silver from tailings not amenable to cyanidation. Results of a laboratory study on the recovery of silver from cyanide tailings containing 1.7 ounces of silver per ton by leaching with an acidic ferrous chloride-sodium chloride solution are presented. The effects of reagent concentration and reaction time on the leaching of silver were investigated. A leaching solution containing 5 wt-pct NaCI, 2.5 wt-pct FeCI2, and 1.2 wt-pct HCI (for acidity) extracted 82 pct of the silver from the tailings during a 24-hour leach. The amount of HCI consumed during the leach was 46 pounds of HCI per ton of feed. Only 23 pct of the silver was extracted by conventional cyanidation. Ninety-nine percent of the silver was recovered from the pregnant solution by cementation onto iron powder.

Jan 1, 1982

By Willard L. Hunter

The separation of tantalum and columbium by solvent extraction was under-taken as part of the Bureau of Mines research program to improve methods for extracting, separating, and reducing these elements to metal. The diethyl ketone aqueous HCl-HF system was one of several systems studied to determine the effect of metal and acid concentrations in aqueous solutions upon the transfer of tantalum and columbium into selected ketones. The tantalum-columbium oxide mixture used in this investigation was obtained by chemical extraction from Geomines slag. The investigation showed that tantalum 99.4 percent pure and columbium 97.2 percent pure can be produced by the selective transfer of tantalum into diethyl ketone from a solution of 2-N HF and 1-N HC1. The relatively low acid concentration necessary for tantalum transfer and the excellent selectivity of the system recommend its use for the separation of tantalum and columbium.

Jan 1, 1961