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By Arne Landsberg

Experiments were made with a batch reactor to determine the effect of gas pressures, temperature, and gamma radiation intensity on the reaction CO + Ch ? COC12. The equation, [dp = 0.0110 (1 - 0.01t) (PCOI)1/2 PC12] where [dP] is the change of pressure of phosgene with time (atm/hr), t is the temperature (°C), PCO and PC12 are the reactant pressures (atm), and I is the radiation intensity (r/hr), was found to best fit the data. Oxygen and a large ratio of reactor surface to volume retarded the reaction, but inert gases had no effect. A low-temperature reactor system is proposed to take advantage of the conditions which give a high reaction rate with gamma radiation and a simple scheme of product purification.

Jan 1, 1970

By Jacqueline A. McClaskey

The U.S. Bureau of Mines Information and Analysis Directorate collects world-wide data on virtually every commercially important nonfuel mineral commodity. These data form the base for tracking and assessing the health of the minerals sector of the U.S. economy. The Bureau's data collection activity was instituted by the 47th Congress in an appropriations act of August 7, 1882 (22 Stat. 329), which placed the collection of mineral statistics on an annual basis. The most recent authority for the U.S. Bureau of Mines survey activity is the National Materials and Minerals Policy, Research and Development Act of 1980 (Public Law 96-479, 96th Congress). This act strengthens protection for proprietary data provided to the U.S. Department of the Interior by persons or firms engaged in any phase of mineral or mineral-material production or consumption.

Jan 1, 1992

By Jacqueline A. McClaskey

The U.S. Bureau of Mines Information and Analysis Directorate collects worldwide data on virtually every commercially important non fuel mineral commodity. These data form the base for tracking and assessing the health of the minerals sector of the U.S. economy. The Bureau's data collection activity was instituted by the 47th Congress in an appropriations act of August 7, 1882 (22 Stat. 329), which placed the collection of mineral statistics on an annual basis. The most recent authority for the U.S. Bureau of Mines survey activity is the National Materials and Minerals Policy, Research and Development Act of 1980 (Public Law 96-479, 96th Congress). This act strengthens protection for proprietary data provided to the U.S. Department of the Interior by persons or firms engaged in any phase of mineral or mineral-material production or consumption.

Jan 1, 1993

By Suresh K. Bhatt, Gary L. Mowrey, Timothy R. Rehak, David K. Ingram

Coal and nonmetal mining used about 4.3 billion pounds of explosives and blasting agents during 2001 in the United States. A major part of this consumption was related to surface mining. Mine Safety and Health Administration accident data indicate that flyrock and lack of blast area security were the primary causes of blasting-related injuries in surface mining. Fatal injuries due to lack of blast area security were primarily caused by failure to clear blast area or inadequate access control to the blast area. At a coal mine, a neighbor walked into the blast area and was fatally injured. The blaster could not see the victim entering the blast area from the firing station. In another case, a passenger in a vehicle was fatally injured by flyrock because highway traffic was not monitored during the blast. In another example, a dozer operator entered a blast area due to lack of access control. Several fatalities resulted from using inadequate or no blasting shelter. A crane operator was fatally injured while standing in the open about 120 ft from the blast site. In another instance, a helper, standing about 150 ft away from the edge of a blast, was fatally injured by flyrock. In a limestone mine an equipment operator was fatally injured while guarding access roads in a pickup truck. This paper briefly describes six representative fatalities due to flyrock and lack of blast area security in coal and nonmetal mines. Several mines were visited to collect information relative to working practices aimed at mitigating blasting hazards. Salient information obtained through these visits is presented.

By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

C 2 Complete Hoisting Systems A Above Ground Installations A total of seven companies were identified who supply complete emergency escape hoist units for above ground installations The units have been designed predominately to meet the needs of coal mine operators to satisfy the requirements of the Coal Mine Health and Safety Act of 1969. The seven companies are as follows 1 Dover Conveyor and Equipment Co. 2. Coeur d' Alenes Co. 3. Connellsville Corp. 4. Scott Midland 5. W W Williams Co. 6. Equipment Corporation of America 7. Timberland Ellicott Table VIII contains detailed specifications and price information on each of these units. The units have a number of similarities

Jan 1, 1976

By L. Mallett

The changing demographics of the mining industry make successful passing of knowledge and skills to the next generation critical. Training methods and technologies are being developed to meet this need. Twenty years ago classroom training was largely a one-way transfer of knowledge through instructor lectures. In contrast, instructors today can use virtual reality technologies to guide trainees as they fully participate in learning experiences. Trainees can interact with the virtual work environment, co-workers, and equipment without being exposed to workplace hazards. The speed of advancement in mine safety, health, and production training shows no sign of slowing in the next 20 years. Researchers at the National Institute for Occupational Safety and Health have studied and participated in the evolution of miner training. A look at training materials they have created in the past and those they are currently developing reveals changes in methods and technologies over time and also key characteristics which have remained constant. Possibilities for the future can he discussed in the framework of an implementation of virtual reality in new miner training sessions. The example computer-based training package teaches new miners to read mine maps and provides opportunity to practice navigation skills in a virtual mine. With this 'serious game', trainees experience the look and feel of moving through an underground coal mine while in the safety of their classroom. During field-testing in 2007, trainees and instructors responded very favourably to this new way of learning. The software was usable by mine trainers with even limited computer expertise and could be installed on the affordable computers they were using for their more traditional slide presentations. The Underground Coal Mine Map Reading Training's foundation on past successful development strategies and its acceptance by today's instructors and trainees provide valuable lessons for developing training materials, strategies, and technologies for mining's future.

Jan 1, 2009

By Robert H. Peters, George R. Bockosh, Barbara Fotta

This paper was commissioned by the Japan Technical Cooperation Center for Coal Resources Development. It is to be published in a proceedings following a series of presentations to Japanese coal officials in February 1997. The paper focuses primarily on summarizing the past 20 years of U.S. research on promising techniques for ensuring that underground coal miners work safely. These techniques can be grouped into three major categories: management, workplace design, and training. Each technique is described, and the results of efforts to apply the technique at underground coal mines are summarized. Recent statistics on accidents and productivity in U.S. underground coal mining operations are presented before the overview of research findings is given. Because Japanese coal mines are using the longwall method of coal extraction, separate statistics are given for U.S. longwall versus room-and-pillar coal mining operations.

This Information Circular from the National Institute for Occupational Safety and Health (NIOSH) documents and supplements the information presented in a series of workshops held during 2002 and 2003. The primary intended audience consists of all who are involved in developing and conducting miners' training. According to the Mine Safety and Health Administration (MSHA), mine operators reported 240,000 full-time equivalent workers and independent contractors reported 42,000 full-time equivalent workers working on mine property during the year 2000. Unfortunately, these workers have a relatively high risk of suffering serious work-related injuries and illnesses. The mining industry has the highest rate of occupational fatalities among all U.S. industries. The fatality rate is 30 deaths per 100,000 workers compared to 4.6 for all private industry (Morbidity and Mortality Week Report, 2001; NIOSH, 2002). Compared to workers in other industries, miners also have a relatively high rate of nonfatal lost-time injuries, and their injuries tend to be more severe (Bureau of Labor Statistics, 1999). Many miners are also exposed to significant health hazards, including coal and silica dust, diesel exhaust, and noise. More than 1000 U.S. miners die of lung disease each year (NIOSH, 1999). Mine safety and health professionals have long recognized training as a critical element of an effective safety and health program. Federal regulations (30 CFR, Parts 46 and 48) require mine operators to provide initial safety and health training to all new miners, as well as a minimum of 8 hours of refresher training each year. The time and money being spent to train U.S. miners is substantial, and so there is a strong and steady demand for new and better mine training materials and methods. A growing concern among mine safety professionals regards the training of new workers. A major change in the mining workforce is anticipated within the next decade. In major segments of mining, especially coal, relatively few workers have been hired since the 1970's. Thus, as an entire cohort of miners in the current workforce nears retirement, the replacement of these employees will require an influx of new workers. New miners may be young people who lack the ability to recognize and respond to mining hazards in an appropriate manner. They may also have had different educational experiences than their older counterparts. Many safety professionals believe that these two cohorts require different approaches to training. The papers in this report should help prepare mine trainers for the changes about to occur in the workforce and acquaint them with strategies they can use to enhance the effectiveness of their training. The first three papers present basic principles for teaching adults. The five remaining papers are intended to illustrate how these principles can be applied to the development and imple¬mentation of effective training for miners. Below is an overview of these papers. 1. Kowalski and Vaught review the process and principles of adult learning. The learning model they present includes a discussion of goals, content, delivery, assessment, and remediation. Adults are viewed as active learners, experienced-based, expert in their own right in specific areas, independent, real-life centered, task-centered, problem-centered, solution-driven, skill-seeking, self-directing, and internally and externally motivated. Basic aspects of curriculum development are briefly reviewed. For further information about adult learning, see Camm and Cullen's paper. 2. Mallett and Reinke's first paper discusses issues related to training new miners who have recently or will soon be entering the mining workforce. These new generations of miners have different learning style preferences and training needs than Baby Boomers and other older miners. Even trainers who have been highly effective in the past should reassess their training styles and their classroom materials to determine if they are prepared to meet the needs of these young new workers. This paper provides information that will help mine trainers communicate across the generation gap. 3. Mallett and Reinke's second paper provide an overview of training evaluation. Trainers and decision-makers are given a framework for planning and assessing training evaluation strategies. The authors present Kirkpatrick's (2001) model of evaluation categories and discuss how to start an evaluation plan and various ways to collect data. They do not provide detailed instruction in evaluation methodologies, but give trainers a review of the things they need to consider when developing an evaluation plan. A good evaluation plan can inform revisions to a training course, assess trainee learning, and/or answer managers' questions about program effectiveness. 4. Brnich, Derick, Mallett, and Vaught discuss a technique for incorporating worker participation into fire prevention and safe equipment operation training. This technique involves development of short (5 to 7 minutes) videotapes coupled with toolbox talks that ground the content of the videos within the context of a miner's workplace. An example of one of these training modules is presented, along with the results of an evaluation performed on its effectiveness at improving miners' understanding of what types of information they should be sure to communicate during a mine emergency. 5. Wiehagen, Conrad, Friend, and Rethi discuss on-the-job training (OJT) as a method for teaching miners safety and production skills. Much of the training is done by experienced workers. This paper describes how small investments can help improve the effectiveness of on-the-job training. Effective on-the-job training involves some structure and planning in the transfer of responsibility for task performance from the trainer to the novice. Assisting the trainer could involve helping develop up-to-date job analyses and offering strategies for teaching and evaluating job skills. This paper addresses organizational considerations supporting structured on-the-job

Jan 1, 2002

By E. G. King

Heats of formation of three crystalline oxides of rhenium (Re02, ReO3 and Re207) have been determined by the method of solution calorimetry, using an aqueous perchloric acid--ceric perchlorate solvent. Copper metal and cupric oxide were utilized as auxiliary substances. Heats were determined at 298' K for the reactions Re + 2CuO = Re02 + 2Cu, Re + 3CuO = ReO3 + 3Cu, and 2Re + 7CuO = Re207 + 7Cu. Standard heats of formation were derived using the value of -37.23 ±0,15 kcal/mole as the heat of formation of CuO. The standard molal heats of formation of the rhenium oxides were determined: Re02, -107.3 ±0.8 kcal; ReO3, -140.8 ±0.9 kcal; and Re207, -301.9 ±1.8 kcal.

Jan 1, 1969

By Maria I. De Rosa

Table 1 and figure 1 show the number of fires and fire in¬juries that occurred in underground coal mines by state during 1990-1999. Table 1 also shows by state the risk rates, employ¬ees' working hours, lost workdays, and coal production. Over¬all, 87 fires occurred in 12 states. Twenty-seven of those fires caused 34 injuries (the yearly average was 8.7 fires and 3.4 injuries). One fire and one injury involved a contractor. The underground mine fires required 25 mine rescue team interventions and 30 mine/section evacuations followed by 13 mine/section sealing/flooding/CO2/N2, gas injections. The Ewhr value was 1,003 x 106 hr (In = 0.007), the CP value was 4,008 x 106 st (Frr = 0.022), and the LWD value was 208. Virginia had the most fires (15 fires and 7 injuries). Pennsyl¬vania had the most fire injuries (12 fires and 9 injuries), fol¬lowed by Kentucky (12 fires and 6 injuries), and Alabama (12 fires and 4 injuries). Among these states, Alabama had the highest fire risk rate value (Frr = 0.073), whereas Pennsylvania had the highest injury risk rate value (In = 0.016). Table 2, partly illustrated in figure 2, shows by time period the number of fires, fire injuries, risk rates, employees' working hours, lost workdays, and coal production. The number of fires and fire injuries show a decrease followed by an increase during the five time periods (see table 2 and figure 2). This was ac¬companied by a decline in employees' working hours throughout the periods and an overall small decrease in coal production. The In and Frr values follow patterns similar to those shown by the fire and injury values. By comparison, data from Pomroy and Carigiet [1995] show that during 1978-1992 a total of 11 states were involved in 164 underground coal mine fires (yearly average, 10.8) with 43 injuries (yearly average, 2.9) and 27 fatalities (yearly average, 2; however, the 27 deaths occurred during a single fire caused by an overheated air compressor [MSHA 1984]). The CP value was 5,340 x 106 st (yearly average, 356 x 106 st) (Fn = 0.031). Data on employees' working hours and injury risk rates were not available. Tables 3-8 show the number of fires by ignition source, method of detection and suppression, equipment involved, location, and burning material by time period. Figure 3 shows the major variables during 1990-1999. Table 9 shows the number of fire injuries per number of fires causing injuries and total fires by year, ignition source, equipment involved, and location.

Jan 1, 2004

By Richard L. Sayrs

"The Stiner zinc prospect near the north boundary of Union Tennessee, and the Bunch Hollow property 5 miles northeast in Claiborne County, Tennessee, were diamond-drilled by the Bureau of Mines during the period .September 1, 1944, to February 22, 1945. Seventeen holes totaling 5,687 feet were completed, 13 of which, totaling, 5.083 feet, were on the Stiner property and the remainder, totaling 604 feet, at Bunch Hollow.The Stiner prospect is about 1 mile east of the old workings known as ""New Prospect"" or ""Lead Mine Bend."" The Federal Geological Survey made a study' of the area early in 1944. The prospect was first visited in August 1944 by Bureau of' Mines engineers3/ accompanied by members of the Federal Geological Survey.4/ The locality is reached by traveling State Road 33 north-about 9 miles from Maynardsville, Tenn., thence northwest about 7 miles by an improved county road that leads to the mine (fig. 1). The tract comprises an area of about 181 acres held by G. S. Stiner of Sharps Chapel, Tenn.; it is now under option to the Universal-Exploration Co. of Jefferson City, Tenn.The Bunch Hollow property, about 5 miles northeast of the Stiller prospect, was also studied by the Federal Geological Survey previous to being;Visited by Bureau of Mines engineers in August 1944. It is reached by traveling north from Maynardsville, Tenn., on State Road 33 about 13 miles, thence northwest by county road 6 miles to the property (fig. 1). The last 3 miles of the county road are in poor repair but are passable during the entire year. The property comprises an area of approximately 300 acres and is held by the imperial Mining Co., Pressman's Home, Tenn.Few reliable data are available as to the history of the Stiner prospects themselves. However, the New Prospect mine, 1 mile west, has had a colorful past, This mine was opened in 1883 and was worked intermittently until 1918, by which time more than 65,000 tons of concentrates had been shipped. No further work was done until 1942, when the mine pillars were robbed and 1,900 tons of ore averaging 25 percent zinc was shipped to the New Jersey Zinc Co., Austinville, Va."

Apr 1, 1946

By John M. Devine

The oxygen bomb-is used extensively for determining sulphur in petroleum, although it has been suspected that the results obtained with this method are somewhat lower than the true varies. In this paper are compared the results given by the oxygen-bomb and Carius methods, the latter being generally accepted as the standard procedure for the determination of sulphur in organic compounds. The Carius determinations given hero were made in connection with a special study of this method.4 Only petroleum oils of the less-volatile type are covered in the present work. Summary and Conclusions. When used with oils containing 2.3 to 0.15 per cent of sulphur the oxygen-bomb method gives results that are consistenly if slightly lower than those obtained with the Carius method. This variation, for the oils used, amounts to 3.1 per cent (on tae basis of sulphur present) for the sample containing 2.47 per cent of sulphur, and gradually increases (as the percentage of sulphur in the oils decreases) to 7.3 per cent for the oil containing 0.15 per cent of sulphur. With the oils studied the presence of ammonium nitrate in the bomb does not influence the results materially.

Jan 1, 1928

By Sathit Tandanand

Geological differences among various coalfields restrain the applicability of subsidence prediction using empirical approaches previously developed. The Bureau of Mines assessed data collected from 16 longwall panels in the Northern Appalachian basin. Attention was focused on the effects of rock lithology, excavation width, and panel depth on the subsidence factor. The results show that the subsidence factor can be expressed in terms of the width-to-depth ratio by a simple exponential equation, which has a coefficient tentatively considered as the subsidence index. This index varies with the lithology of a particular site, and can be expressed in terms of percent distribution of weak and strong rocks in the overburden.

Jan 1, 1982

By P. G. Pigott

This investigation by the Bureau of Mines demonstrated that building bricks can be produced by the steam-curing process from various types of industrial mineral wastes. Wastes, utilized to produce bricks, consisted of copper mill tailings, roofing granule fines, asbestos fines, and zinc mill tailings. Bonding of the wastes with either Ca(OH)2 or portland cement resulted in building bricks that met ASTM specification C73-67 for grade SW and MW bricks when evaluated in accordance with ASTM designation C67-66 on sampling and testing of brick. An economic evaluation of the process indicates the total operating cost per 1,000 bricks is about $36.

Jan 1, 1974

By Alex C. Smith, Thomas P. Mucho, John B. Walsh, Alden Ozment, Michael R. Thibou, Michael A. Trevits

The National Institute for Occupational Safety and Health (NIOSH), with US Foam Technologies, Inc. and On Site Gas Systems, Inc., conducted research on the remote application of extinguishing agents with the intent of improving deployment strategies to limit miner exposure and to help ensure the best possible outcome during a mine fire. Full-scale in-mine were conducted at the NIOSH Lake Lynn Experimental Mine to determine the flow characteristics, stability and fire-suppression capability of gas-enhanced foam. The in-mine experimental work was designed to evaluate movement of gas-enhanced foam through mine workings closely simulating an underground coal mine environment and how long gas-enhanced foam would remain stable. This paper presents results of the experiments and provides valuable insight into mine fire deployment strategies for gas-enhanced foam technology.

By Jack Wasserman, Don Wasserman, Gretchen Hinton, Logan Mullinix, Shekar Khanal

Human testing has always been a needed way to provide information on the effects of vehicle vibration, however, the manner of testing has not reflected the real situations of driver’s hands on a steering wheel and a seat with back support and driving tasks. The typical system have used a standard sinusoidal excitation rather than the typical types of road – truck excitations The new truck driver training simulators provide the combination of road roughness, speed effects, cab environment and individual tasks. The system has a full six axis simulation potential. The simulators have the protection of the individual by a combination of two ways for the individual to stop the motion as well as an operator with visual capability who can stop the testing. The closed simulator, shown in Figure 1, has the potential for providing motion during the operation.

Jan 6, 2006

By Gary W. Kramer

The Bureau of Mines has developed a rapid analytical method for the determination of anions by ion chromatography (IC) in phosphate rock mining materials and cement kiln dust (CKD). The procedure employs an Na2C03 fusion of the sample, followed by a water extraction that allows direct injection of the sample into an ion chromatograph without separator column poisoning by the transition metal ions. Fluoride (F-) and phosphate (P043-) were determined in 24 phosphate rock processing and waste material samples by the IC method. The results were compared with a pyrohydrolytic distillation-titration method for F-and a colorimetric procedure for P043-. Excellent analytical agreement was obtained for F-and p043-values determined by IC and the comparable wet chemical methods. Fluoride values ranged from 0.3 wt-pct in the filter cake to 3.6 wt-pct in phosphate rock concentrate. Phosphate values ranged from 1.2 wt-pct in the filter cake to 33.8 wt-pct in the rock concentrate. Fluoride, chloride, phosphate, nitrate, and sulfate in several CKD samples were determined by the IC method and standard wet chemical techniques. Excellent agreement was obtained between the two methods for all anions. A total of 113 CKD samples from all areas of the United States was analyzed by the IC method. Fluoride values ranged from <0.01 to 0.36 wt-pct. Chloride values ranged from <0.01 to 12.5 wt-pct. Sulfate values ranged from 0.41 to 31.6 wt-pct. Phosphate and nitrate were detected in only about 25 pct of the samples at >0.02 wt-pct. Maximum phosphate and nitrate values were 1.0 and 1.6 wt-pct, respectively.

Jan 1, 1982

Great strides have been made in recent years to reduce the disaster potential of underground mine fires. However, mines can still be caught unprepared for a fire emergency. Fires can grow too large before they are detected, warning systems can be too slow and uncertain to reliably signal the danger, and suppression systems can be inadequate to extinguish the flames. New mining systems and equipment may create unanticipated fire hazards, and new materials may generate highly toxic combustion products. This report contains papers that summarize recent significant developments from the Bureau of Mines mine fire protection research program relating to these problems. Certain of these findings are also applicable to surface mining operations. The papers fall into the general categories of fire detection and instrumentation, fire warning, fire suppression, diesel equipment, spontaneous combustion, and toxicity analysis of combustion products.

Jan 1, 1988

By Rudolf E. Greuer, Linneas W. Laage, Xinton Chang

The program MFIRE consists of four files MFIRE0 EXE, MFIRE1 EXE, MFIRE2 EXE, and MFIRE BAT The batch file, MFIRE BAT, controls the operation and cooperation of the three executable pro¬gram files and the output Networks of up to 500 air¬ways and 350 junctions can be modeled in the PC version of MFIRE Larger data sets can be accommodated by increasing array dimensions and compiling the program again. Input for MFIRE is in the form of a data file The data file contains fines of numerical data describing the physical mine, the ventilation parameters present, the fans, and the proposed thermal or mechanical disturbances

Jan 1, 1990

By R. R. Schehl

The Bureau of Mines has developed a quantitative Analysis for pyrite in coal by X-ray diffraction that can be accomplished in little more than 1 hour. To minimize the sample analysis time, data processing has been completely computerized with pertinent output information displayed on a VR12 cathode-ray tube display. Use of this computerized system is not only advantageous during the experimental stages of the pyrite analysis project but would also be essential if the X-ray diffraction procedure is accepted as a standard method of analysis.

Jan 1, 1973