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By S. D. Hill

To help insure the continued viability of the minerals and materials sector of the U.S. economy, the Bureau of Mines is conducting research and disseminating technology that will result in more efficient minerals extraction. As part of this effort, a process is being investigated that involves an aqueous chlorine-oxygen leaching procedure to treat complex sulfide concentrates to produce ZnCl2. Subsequent fused-salt electrolysis of the ZnCI2 produces high-purity zinc metal. Previous reports described preliminary, small-scale research on the chlorine-oxygen leaching system and fused-salt electrolysis of ZnCl2. This report discusses the details of design, construction, and longterm, continuous operation of both monopolar and bipolar fused-salt cells. The effects of temperature, electrode gap, current density, electrolyte composition, and electrode configuration on current efficiency and energy consumption were determined for a ZnCl2-KC1-NaCl electrolyte system. Zinc metal was produced at the rate of about 50 lb/day in a monopolar cell which was operated continuously for 60 days with current efficiencies from 85.8 to 98.6 pct and an average power consumption of 2.1 kwhr/lb. Bipolar cells with several different electrode configurations were operated for 90 days. A current efficiency of about 70 pct and power consumption of about 1.7 kwhr/lb of zinc were achieved using a three-electrode-pair, bipolar assembly with a chlorine gas lift pump to circulate electrolyte.

Jan 1, 1981

This Bureau of Mines publication summarizes the industrial minerals industry of Idaho. It contains information on 119 principal deposits of 21 commodities in the State and describes the institutional and infrastructural factors affecting mineral development.

Jan 1, 1991

By Edward A. Barrett, Roberta A. Calhoun

Introduction This Instructor’s Copy contains most of the information needed to use the Wearing Hearing Protection Properly 3-D training reel. It offers practical suggestions on how to use the reel as a training aid, performance objectives for deciding if the training is appropriate for your needs, and discussion notes that provide additional information to the user. The 3-D reel was designed as a self-teaching aid that drillers and others who work at a drill site can use wherever the opportunity for such training presents itself. The latter could be a company preshift requirement or a tailgate session where workers would have an opportunity to view and discuss the reel. It could also be an individual looking at the reel in a pickup truck prior to beginning work at a drill site. The 3-D training reel is versatile in that it can be used for a small group of persons or for a single worker. For any of these situations, information is transferred to the individual by viewing each of the seven colorful, in-depth 3-D scenes and relating the words that appear in each scene to what is depicted in the visual. Acknowledgment The authors thank Linda J. McWilliams, Statistician, NIOSH Pittsburgh Research Laboratory, for her assistance in analyzing the experimental data in this document.

Jan 11, 2004

By James F. Neill, O&apos

Brown iron ore resources in Barbour, Butler, Crenshaw, and Pike Counties were investigated in a drilling program and geological study by the Federal Bureau of Mines in cooperation with the Alabama Geological Survey and the University of Alabama. The aggregate footage drilled was 18,010 linear feet. When developed, reserves of 12,664,000 long tons of crude ore were indicated, containing from 26.9 to 29.0 percent iron and 0.2 to 1.6 percent manganese under a maximum overburden of 40 feet. Total inferred crude ore for the four counties was calculated to be 827,700,000 long tons. Beneficiation of samples by simulated log washing and use of a 118-inch screen yielded from 46.8 to 51.7 percent iron and 0.2 to 2.6 percent manganese. Screen-test studies indicated no appreciable interlocking between the iron and manganese minerals and the waste particles of materials retained on a 200-mesh screen. Clay was prominent in micron-size slimes. Silica was deleterious in the minus 20-mesh size. While an indicated 2,198,000 dry long tons of usable iron ore can be recovered, sink-and-float tests show that it may be possible for 4,654,000 dry long tons to be recovered by other than log washing. However, applicable commercial processes have not been demonstrated.

Jan 1, 1965

By Staff

This U.S. Bureau of Mines publication presents the results of investigations into the fire and explosion hazards of oil shale rocks and dust. Three areas have been examined: the explosibility and ignitability of oil shale dust clouds, the fire hazards of oil shale dust layers on hot surfaces, and the ignitability and extinguishment of oil shale rubble piles.

Jan 1, 1989

By A. D. Hahn

This report describes and gives the results of an examination by the Federal Bureau of Mines of ilmenite-bearing placer sand deposits in the 24-mile long valley of Otter Creek, Kiowa and Tillman Counties, Okla. Drilling and sampling was completed in three periods between October 1956 and September 1957. Mineralogic studies and mineral-dressing tests on recovery of ilmenite and other heavy minerals from composited samples of the sands were made in Bureau of Mines laboratories at Rolla, Mo., in 1957 and early 1958. Otter Creek rises in and drains the southwestern extremity of the Wichita Mountains, which are represented locally by knolls and ridges of gabbro and granite surrounded by plains floored with flat-lying Permian red beds. The valley fill consists of a basal sand-clay component, derived from weathering of the igneous rocks, and an overlying silt-clay alluvium. Ilmenite is present in significant quantity and recoverable grain size only in the basal sand-clay.

Jan 1, 1960

By S. M. Shelton, A. L. Engel

"This report presents the results of investigations of ore-testing projects assigned to the Ore-Dressing Section, Metallurgical Division, Bureau of Mines, at the Mississippi Valley Experiment Station, Rolla Mo. During the fiscal year ended June 30, 1941.The manner of approving ore-testing projects has been explained in a previous reports. 4/ The testing procedures likewise have been described. 5/The treatment methods described are based upon laboratory experiments with small amounts of sample and naturally are subject to the inherent, normal, limiting conditions of such procedure. It is not intended to describe treatments in detail, but rather to indicate applicable methods. Local operating conditions, when the laboratory results are applied to plant operations, may require further study. Large-scale pilot-plant tests should be made before commercial operations are begun, so that translation from the experimental stage will yield satisfactory results."

Mar 1, 1942

By Whitman E. Brown

"As part of a Nation-wide program of the United States Government to develop natural resources, funds were made available to the Bureau of Mines for the investigation of the ""Reduction of Iron Ores by Solid and Gaseous Fuels."" These investigations are concerned with the direct production of iron from its ores without the use of a blast furnace. Many processes have been proposed for the low-temperature reduction of iron oxides, but few have been developed to commercial use. High-quality sponge iron is produced com-mercially only in Sweden.The cost of iron production depends in part on the grade of the ore and increases with decrease in grade. The substitution of cheap natural gas in a sponge-iron process for expensive coke in smelting in the blast fry pace would partly compensate for the use of low-grade ores. If a process can be developed in which inexpensive natural gas can be used as fuel and reducing agent, the large deposits of low-grade iron ore and the natural-gas resources of east Texas may be utilized in the commercial production of sponge iron.Sponge iron may possibly be used to supplement scrap iron, pig iron, or, in special instances, wrought iron. Sponge iron will vary but slightly in composition and will contain little or no nickel, cobalt, manganese, copper, and other allowying metals. It is becoming increasingly difficult to obtain choice scrap iron of nonalloy composition. Pig iron contains 1.5 to 3.0 percent silicon and 3.0 to 4.5 percent carbon. Sponge iron generally contains less carbon than pig iron.The Madaras Steel Corp. in Longview, Tex., built a set commercial-scale sponge-iron plant which was intended to be operated in connection with a steel foundry. The process is based upon the reduction of preheated iron ore, with hot reducing gases under pulsating pressure. Although the Madaras Corp. had previously experimented with the production of sponge iron by reducing the ore with pure hydrogen, several attempts to use a re-formed natural gas as the reducing agent in this pilot plant were unsuccessful. The Bureau of Mines leased this plant and conducted an extensive investigation of the Madaras process on a semicommercial scale.The experiments were not entirely satisfactory, partly because of mechanical difficulties and partly because the reducing gas was not of the best quality. However, much information on the production of reducing gas by re-forming natural gas and on the reduction of iron ore with re-formed natural gas was obtained.The sponge iron produced contained approximately 0.1 percent phosphorus; and, after melting in an electric furnace, the iron contained approximately 0.15 percent phosphorus. The results of attempts to improve the ore by ore-dressing methods were not encouraging."

Aug 1, 1946

By Bobby B. Gillenwater

This report presents recommended guidelines and regulatory changes applicable to electrical installations in underground oil shale mines. These recommendations are based on information gathered from oil shale operators, government agencies, and other knowledgeable sources familiar with existing plans for mining systems and electrical installations, and on present understanding of the problems and hazards associated with oil shale mining. Additional discussions of specific electrical problems related to oil shale mining are also presented. These specific problems include: ? Ground fault current levels ? Permissible electric wheel motors ? Permissible batteries and electric starting systems ? Intrinsically safe instrumentation and applicability of existing test standards.

Jan 1, 1983

By J. R. Thoenen

"The curtailment of imports of foreign potash during the World War directed attention to the necessity of establishing a domestic source of potash for fertilizer, and considerable study has been given to the subject by Government bureaus, research organizations, and private individuals. These studies have covered all known sources of potash, and among them the extensive greensand deposits of New Jersey in which the potash content is found in the mineral glauconite have been investigated.Several hundred patents have been obtained covering processes for the extraction of potash from siliceous minerals, but up to the present time none have proved successful on a large commercial scale.When the investigation of the potash deposits of Texas was started by the Federal Government, the laboratory study of the drill cores was assigned to the Nonmetallic Minerals Experiment Station at New Brunswick, New Jersey, with the object of ascertaining a possible commercial method of utilization.The purpose of this preliminary study was to investigate existing literature and previous investigations to ascertain the extent and availability of the deposits, the extent of commercial success so far attained in potash extraction, the most promising known methods and by-products obtained from them, probable markets, and possibility of competition with foreign potash, and by a study of these data to determine whether further chemical engineering analysis and laboratory investigation were warranted.As the study advanced it became evident that adequate reserves of green-sand were available for many years supply. and that whereas many processes had been patented few had been tried commercially. In collaboration with former private and Government investigators these patents were first divided into two"

Feb 1, 1929

By Michael A. Trevits

Since the promulgation of the MINER Act and the follow-up changes to the regulations governing mine seal construction and maintenance, mine operators must be acutely aware of the atmosphere in sealed mine areas and prepared to deploy control technologies when the conditions are warranted. On Site Gas Systems1 in Newington, Connecticut was awarded a contract by the National Institute for Occupational Safety and Health (NIOSH) to construct a novel in-mine nitrogen (N2) generation plant using pressure swing adsorption (PSA) technology. PSA technology utilizes carbon molecular sieve material and pressure to adsorb oxygen (O2) molecules while allowing N2 molecules to pass through the sieve material. The prototype PSA unit was tested at the NIOSH Safety Research Coal Mine (SRCM) where a 62,000 ft3 area of the mine was rendered inert during a series of two tests. The resultant data were then used to construct a CFD simulation of both injection tests. In addition, O2 depletion and gas leakage rates were quantified in the model and were compared to actual values. Once the model was calibrated, the sealed mine area was doubled and simulations were made with various injection rates and injection site locations to determine the impact on the time needed to render this area inert. This paper presents an overview of the PSA plant, the details of the gas injection tests and CFD modeling work.

Jan 1, 2010

By Sally A. Shoop

Thirty-seven blasts have been monitored using either three or four seismographs, at four coal strip mines and at a limestone quarry. Statistical analysis of the data shows that square-root, cube-root, and site-specific scaling methods predict peak particle velocities with about the same (low) degree of reliability. Some mines have peak particle velocities that are significantly lower or higher than the U.S. Bureau of Mines averages (Siskind et al., 1980). This suggests that the option provided by the proposed regulations (Office of Surface Mining, 1983), to adjust blast designs based on site-specific measurements could be highly beneficial both to operators and to the public. The frequency spectra reveal that the predominant frequencies were generally less than 50 Hz but several blasts had a significant amount of energy up to 125 Hz. In some cases the vibration energy was concentrated at frequencies corresponding to the delay intervals.

Jan 1, 1983

By Joseph Grumer

About a century ago Bunsen and his associates invented the famous burner that bears his name and was to become the ancestor of today's gas appliances. Over the years, Bunsen's invention became the starting point of a highly developed, practical technology that culminated in the gas industry as we now know it. However, it did not occur to the early workers to investigate the scientific potentialities of the new device, and as a result the science of gas-burner performance did not keep pace with the growing industry. It was with the objective of closing the rapidly widening gap between science and technology that the present research was undertaken Its immediate purpose was to provide basic information on the combustion characteristics of .fuel gases, in particular as they affect flashback, blowoff, and yellow tipping. Information obtained in the present research and contained within this report consists of the following: (1) Fundamental flashback and blowoff characteristics have been determined, it is believed, for all fuel-gas mixtures in which the gas industry may be interested. These are critical boundary velocity gradients for flames in free air, on burners with ports at room temperature and pressure. Burner aeration is characterized by the parameter, fraction of stoichiometric. These basic limits are explained, values are presented, and calculation procedure is given for deriving corresponding values of port loading and percent primary air (chs. I and II).

Jan 1, 1956

By Richard L. Rains

The Bureau of Mines made a study of mines and prospects of the Benton Range RARE II area (No. 5056), Mono County, California in October and November 1980. The study area is west of Owens Valley and 30 mi (40 km) north of Bishop, California. The mineral deposits were evaluated by examination of mines, prospects, and mining claims by the Bureau of Mines. Geological, geochemical, and geophysical studies were conducted by the Geological Survey. The principal mineral commodities of the Benton Range RARE II area are gold and silver but tungsten deposits may also extend into the area. Properties with resources are listed in table 1; their locations are shown on figure 1.

Jan 1, 1982

By J. D. Ramsdell

To obtain information on the effects of cobalt on microstructure and tensile properties of titanium-vanadium-cobalt alloys, the composition ranges of 4 to 16 percent vanadium with 1 to 4 percent cobalt have been studied. The beta phase was not completely retained with vanadium additions up to 16 weight-percent or in the same alloys containing up to 4 percent cobalt.

Jan 1, 1960

By E. O. RHODES

This report is one of a series written by members of the Solid Fuels Mission to Germany describing wartime developments in the mining, prepara- tion, and utilization of coal. This mission was organized early in 1945 under the auspices of the Technical Industrial Intelligence Committee, which cooperated with a counterpart British Committee. In some instances; engi- neers from other allied countries cooperated. The Solid Fuels Mission operated under the direction of a steering committee headed by Dr. C. J. Potter, Deputy Solid Fuels Administrator. The personnel of the mission consisted of H. F. Yancey, in charge, J. W. Buch, Thomas Fraser, L. L. Newman, and L. D. Schmidt of the Bureau of Minos; H. H. Lowry, Director of the Coal Research Laboratory, Carnegie Institute of Technology; H. J. Rose, Vice-President and Director of Research, Bituminous Coal Research, Inc.; and F. H. Reed, Chief Chemist, Illinois Geological Survey. E. 0. Rhodes, Manager, Development Section, Tar Products Division, Koppers Co., Inc., served on the mission for the Chemical Subcommittee of 1.I.I.C. in Europe. His assignment was the investigation of the coal-tar industry. In this connection he prepared this report on the German Low- Temperature Tar Industry as a companion to his provious report on the German High-Temperature Tar Industry (Bureau of Mines Information Circular 7409). Because of Mr. Rhodes' extensive experience in these fields and the impor- tance of the subject material to the coal producers and those utilizing coal-tar products, both reports are issued by the Bureau of Mines. Over fifty reports were written by the members of the Solid Fuels Mis- elon. These, together with microfilms of supporting data obtained in the course of the investigations, are on file at the Foreign Documents Group, Technical Reports Section, Bureau of Mines, Pittsburgh, Pa., where they are available for examination. Copies of reports available in printed form may be ordered from the Department of Commerce, Office of Technical Services, Washington 25, D. C. Check or money order accompanying order for printed reports should be made payable to the Treasurer of the United States. A Bibliography of Scientific and Industrial Reports, covering all ma- terials and subjects and giving instructions for obtaining the desired items, has been published weekly by the Office of Technical Services. Effective July 1, 1948, the Bibliography of Scientific and Industrial Reports will be prepared monthly instead of weekly and on a more selective basis. issue, which will be the first monthly issue, will be available about July The July month thereafter through June 1949. Annual subscriptions and orders for individual copies starting with the July 1948 issue should be addressed to the Department of Commerce, Office of Technical Servicos, Washington 25, ur, and be accompanied by chock or money order made payable to the Troas- Bibliof the United States. Annual subscriptions for monthly issues of the Bibliography of Scientific and Industrial Roports will be $10. Individual issues will cost $1 per copy. Foreign subscriptions will be $14 per year and $1.50 por copy. tions listed in the Bibliography of Scientific and Industrial Reports should All orders for reports in microfilm or photostatic type of reproduc- ורי

Feb 1, 1949

By P. A. Cox

The purpose of the initial research performed under this contract was to determine the margins of safety in explosion-proof (XP) enclosures, which were designed and certified according to the current schedule (Schedule 2G). Results from this work provide baseline data on the current schedule, from which a new schedule can be formulated to give equal or greater levels of safety. Results and discoveries in the initial work led to an expansion of the contract to cover, additionally, weld quality in enclosure fabrication, reliability of enclosures with windows and lenses, and performance tests for enclosure qualification. Finite element calculations and hydrostatic tests revealed wide variations in the margins of safety in the enclosures studied; however, only one enclosure had a safety factor which was less than one. Results from a weld quality survey led to the recommendation of AWS Welding Standard D14.4 for the fabrication of XP enclosures. Based on other work, accelerated aging tests were recommended for qualifying plastics and adhesives that are used in some enclosures, and a Structural Performance Test was developed to test enclosure strength for a minimum static pressure of 150 psig.

Jan 1, 1982

1. Domestic Production and Use: In 1982, 13 companies operated 30 primary aluminum reduction plants, with 3 firms accounting for 55% of production. Washington, Oregon, and Montana accounted for 34% of the production; Texas, Louisiana, Missouri, and Arkansas 18%; Tennessee, Alabama, South Carolina, and North Carolina 14%; other central and eastern States 34%. Based on published producer prices, output of primary metal in 1982 was valued at over $5.5 billion. Aluminum consumption by 25,000 firms was centered in the East Central United States. Packaging accounted for an estimated 39% of domestic consumption in 1982, transportation 20%, building 14%, electrical 8%, consumer durables 8%, and other uses 11%.

Jan 1, 1983

This report is the 22d in a series summarizing Bureau of Mines research and technologic work on coal and related investigations.2 3/ A summary of work published during 1957 and of work in progress is presented. Details regarding the subjects treated in the publications may be found by referring to articles cited in the footnotes. The objective of the coal work of the Bureau of Mines is to obtain information that will lead to improved production and utilization of coal, thus conserving a most important national asset.4 5/ Though studies of mining methods and exploration of various coalfields ma; contribute directly to improved production, no less so does the work in health and safety. The many problems relating to chemical and physical properties of coal reflect the need for an understanding of these properties for the most effective use of coal in its various fields of application and for the development of new methods of processing coal. Studies of existing and proposed processes of combustion, carbonization, gasification and hydrogenation of coal are necessary for increased efficiency in its use. Engineering service provided by the Bureau is of direct value in the conservation program in preventing waste. Stations where the main coal activities of the Bureau are carried out are shown in the following list:

Jan 1, 1959

By G. W. Reimers

Conditions in the underground mine environment can cause self-heating of sulfide ores as a result of exothermic oxidation reactions, which may result in mine fires. This Bureau of Mines report describes thermal analyses of finely ground chalcopyrite, chalcocite, galena, pyrrhotite, marcasite, and arsenopyrite, to characterize their responses under oxidizing conditions. Thermal gravimetric analysis (TGA) and differential thermal analysis (DTA) were used, in the temperature range 1000 to 5000 C. Chalcopyrite showed an initial weight gain, due to formation of sul-fates, a weight loss, caused by ignition of iron sulfide to iron oxide, and a final weight gain, indicating the conversion of copper sulfide to sulfate. Chalcocite did not ignite in the temperature range studied but exhibited a rapid weight gain, because of the rapid conversion of copper sulfide to sulfate. Likewise, galena failed to ignite but underwent a steady weight gain when oxidized in a moist atmosphere, showing conver-sion of lead sulfide to sulfate below the ignition point. Marcasite underwent a rapid weight loss, indicating ignition, at 2000 C. Moisture in the oxidizing atmosphere lowered the ignition point of marcasite and arsenopyrite but not that of pyrrhotite. All the sulfides exhibited exothermic behavior at temperatures below the ignition point.

Jan 1, 1987