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By Fred N. Kissell, Jon C. Volkwein

In This Chapter [How inert gas works to prevent methane explosions How inert gas is generated and delivered at highwall mines Volume and quality requirements for inert gas at highwall mines How an inert gas system is operated and Precautions to take during mining to prevent methane explosions] This chapter discusses a method, originally developed by Volkwein and Ulery [1993], to prevent methane explosions during highwall mining. In highwall mining, a horizontal auger or a mining machine enters the coal seam from a surface mine pit at the bottom of a highwall, and the coal is mined out from a series of parallel holes. Explosions can be prevented by injecting inert gas into each hole as it is mined. Coal near the surface has lost most of its methane gas over time. However, in recent years, surface mining has been used for deeper reserves of coal. This trend toward mining deeper reserves has increased the chance of encountering methane, and methane explosions at highwall mining operations have resulted in injuries. HOW INERT GAS WORKS TO PREVENT METHANE EXPLOSIONS A methane explosion requires the presence of sufficient amounts of both methane and oxygen, as well as an ignition source. If the methane cannot be reduced and the ignition source cannot be eliminated, then explosions may be prevented by adding an inert gas, which contains little to no oxygen, to the mixture [FWQA 1970]. Just how much inert gas must be added depends on the mining rate, as well as the composition of the inert gas. An explosibility diagram can be used to show whether a methane mixture is explosive after inert gas is added [Zabetakis et al. 1959] (Figure 10–1). This diagram indicates that gas mixtures fall into one of three range categories—explosive, explosive when mixed with air, and nonexplosive—depending on the percentage of methane and percentage of “effective inert.” Effective inert is calculated from the percentage of “excess nitrogen”3 and percentage of carbon dioxide in the mixture.

Jan 6, 2006

By F. D. Osgood, A. C. Fieldner, W. A. Selvig

In connection with investigations being conducted by the Bureau of Mines regarding pulmonary disease which is prevalent among metal miners in certain districts , a large number of rock- dust samples have been collected , and have been examined in the Bureau's laboratories . The earlier work has been described in Bureau of Mines Technical Paper 105 , " Pulmonary disease among miners in the Joplin district , Missouri , and its relation to rock dust in mines " by A. J. Lanza and Edwin Higgins , 1915 , and in Bureau of Mines Bulletin 132 , " Siliceous dust in relation to pulmonary disease among miners in the Joplin district , Missouri , " by Edwin Higgins , A.J. Lanza , F.B.Laney , and Geo . S. Rice , 1919. The methods of collecting and examining dust samples have been greatly improved during the investigation , much valuable information having been made available by similar investigations conducted by the Miners ! Phthisis Prevention Committee , Union of South Africa . The latter are described in the " General report of the Miners ' Phthisis Prevention Committee , Johannesburg, Union of South Africa , 1916 " , and " Final report of the Miners ' Phthisis Prevention Committee , Johannesburg, Union of South Africa , 1919. " The investigations by the Bureau of Mines and the South African committee show that by prolonged inhalation of air containing minute particles of sharp and insoluble rock dust , the lungs retain sufficient dust particles to cause decided injury to the lung tissue , the injured lung becoming very susceptible to the development of tuberculosis .

May 1, 1920

By M. Gottlieb, P. Metes, Charles Sabine, Louis J. Denes, B. Kaminsky, Jami M. Girard, Ronald T. Mayerle

A significant risk factor in assessing and modeling potential catastrophic slope movement in open-pit mines is the presence of argillic alteration in host rocks. High-resolution hyperspectral imagery operating in the visible to shortwave infrared can be a useful tool for identifying and mapping potentially dangerous argillic zones. We have conducted preliminary experiments with a new type of hyperspectral imager that employs an acousto-optic tunable filter, a variable retardation plate and a standard digital camera. The instrument we tested operates in the .5-1.0 micrometer range. A shortwave infrared instrument is planned, and mid-infrared instruments have been designed. An AOTF consists of an acoustic transducer that generates an acoustic wave that propagates through an attached crystalline substance. The wave sinusoidally modulates the refractive index of the crystal, selectively diffracting incident light according to its wavelength. The instrument also measures polarization signatures of reflecting surfaces as well as their spectral properties, opening up new areas of possible research. Images can be acquired and processed at 30 frames/second. The AOTF camera system offers numerous advantages to geologists. It can be used as an airborne imager or as a portable field device to image pit walls, outcrops, rock specimens or drill core. It can be adapted to image polished sections under a microscope, and it could be used in underground workings. Algorithms can produce processed images in real time (e.g., ratio images), and, because it is a camera system, aerial images can be orthorectified.

By Richard J. Bielicki

The possibility of replacing the brattice cloth closest to the coal mine working face with an air curtain mounted on top of a continuous-mining machine or with a diffuser fan was explored by the Bureau of Mines. Preliminary tests conducted at a full-scale model working face with the brattice end set at 18 feet showed that the air curtain improved face ventilation only slightly and was not nearly as effective as placing the brattice at 10 feet. A 2,000-ft3/min diffuser was more effective than the air curtain. It is concluded that the air curtain probably could not function as a line brattice extension, although the diffuser fan may have some potential.

Jan 1, 1975

By J. E. Zeilinger

This Bureau of Mines report describes the preparation characteristics of three samples collected from the Kidney seam, in the Northern Field of the anthracite region. Removal of the sink 1.70 specific gravity material from the samples collected would result in greatly reduced ash contents at yields in excess of 90 percent. The Kidney seam, in the locations sampled, proved to be a low-ash anthracite containing an unusually high percentage of float 1.45 specific gravity material.

Jan 1, 1970

By Martin Berman

The Bureau of Mines has investigated the mineral matter content of 38 American coals using X-ray fluorescence. Measurements of the Ka intensity for magnesium, aluminum, silicon, sulfur, calcium, and iron permit the determination of those elements as well as an indirect determination of the ash con-tent of the coals. The percentage of each of the six elements was corrected for absorption by all six elements as well as by hydrogen, carbon, nitrogen, and oxygen. It made little difference whether the values used for hydrogen, carbon, and nitrogen were obtained from chemical analysis or whether average values for all coals were used. In all cases, oxygen was obtained by difference. The correction for absorption by all these elements involved the inversion of a 6 X 6 matrix and was performed by computer. Assuming that the elements magnesium, aluminum, silicon, calcium, and iron were present in the ash as oxides, the quantity of ash was determined. The results for the mineral elements as well as for ash and oxygen were in good agreement with chemical results. Particle size was found to have a significant effect on fluorescence intensities. A study of size effects was made for pyrite particles, since the sulfur content of coals is of particular interest. Theoretical equations were derived and verified relating the intensity to particle size. It was found that the coal samples must be ground to less than 2 microns. Sulfur appears in several forms in coal, and the effect of sulfur form on intensity was investigated. It was found that the Ka intensity was independent of sulfur form but the Kß intensity varied with the type of sulfur. Thus, the Ka intensity was used for determination of the quantity of sulfur present. Utilization of the sulfur KB intensity did not permit a determination of the proportions of sulfur forms present in coal. However, for synthetic mixtures of cystine and pyrite in carbon black, measurement of sulfur Ka and Kß permit determination of each constituents from measurements of sulfur intensities alone.

Jan 1, 1968

By Kenneth B. Higbie

Expenditures to advance scientific technology in general reached an all time high in 1965 with some $22.2 billion estimated to have been allocated by government and industry. Federal Government expenditures were estimated at $15.4 billion, with almost 90 percent of the funds devoted to programs involving defense, atomic energy, and outer space efforts. With this massive effort in the United States and a very impressive effort elsewhere in the world, there is little wonder that many new metallurgical developments were announced in the technical press during the year. No effort has been made to cover all aspects of the industry, but a few of the developments are described in this chapter.

Jan 1, 1966

By N. A. Caspero, W. E. Eckard, W. T. Wertman

A thermal oil-recovery experiment was conducted in the Venango First sand, Goodwill Hill oilfield, Warren County, Pa., about 10 miles northeast of Titusville. The Quaker State Oil Refining Corp., Bradford, Pa., performed the experiment with assistance from Sinclair Research, Inc., Tulsa, Okla., and the Federal Bureau of Mines. The Goodwill Hill field was discovered in 1885. Primary-production oper- ations continued until 1930 when an air-gas injection project, which is still in operation, was started. At the location of the combustion experiment, the reservoir is 400 feet deep and 30 feet thick, with wide permeability and porosity variations. The crude oil is typical Pennsylvania Grade paraffin- base oil with a gravity of 43.9° API and a viscosity of 4.55 cp at 60° F. The well pattern for the experiment consisted of 5 producing wells, enclosing an area of 1.28 acres, and a central ignition-injection well. An air-natural gas mixture was ignited in the ignition well on July 29, 1961. Ignition was followed by injection of air and natural gas at various rates. The experiment was suspended January 5, 1962, when it became evident that economic oil production could not be achieved. There was no conclusive evidence that self-sustained combustion was achieved or that combustion increased oil and water production. A slight increase in liquid production was attributed to stripping action caused by the air-injection rates, which were higher than those normally used during air-gas injection.

Dec 1, 1963

By C. E. Jordan

The Bureau of Mines conducted laboratory studies on methods to increase the recovery of brine from slime produced by operating potash plants. The slime was comprised of 80 percent brine saturated with KCl and NaCl, and 20 percent solids. A variety of settling techniques, filtration methods, continuous centrifugation, and novel processing techniques were investigated. Vacuum filtration recovered 6S percent of the brine at 47 gallons of brine per square foot per day. Pressure filtration, on the other hand, recovered 74 percent of the brine at 40.9 gallons of brine per square foot per day. Centrifugation in a 6-inch-diameter continuous decanter-type separator resulted in 42 percent recovery of the brine at a treatment rate of 542 gallons of brine per day. Vertical drains proved to be the most promising novel debrining technique investigated. With this method, 45 percent of the brine was recovered in 3 days.

Jan 1, 1977

By G. E. McElroy, D. Harrington

The use of shall electrically- driven fans , in conjunction with air- pipe of various diameters is becoming of increasing importance for the ventilation of working places in metal mines through which the general ventilating currents can not be coursed . It will probably continue to increase in importance since the concept that air motion is the most important factor in maintaining comfort in hot ( above 80° F . ) working places is more generally accepted , and as the inefficiency and greater expense of attempting to ventilate such places with compressed air is recognized . Managers of large properties can afford to experiment with fan- pipe installations until types are found that meet their conditions , but managers of shall properties , unless forced to it by extreme conditions , prefer to wait until they can obtain data sufficient to guarantee at least a measure of success from such installations . At present , such data , even in part , are available to only a few (mainly fan manufacturer's representatives , consulting ventilation engineers , and ventilatin engineers employed by large companies ) , and important recent developments are mostly of a confidential nature . One large metal - mining company cooperated with a fan manufacturer in some extensive experimental work on small blowers and found that instead of using stock fans , considerable power economy could be effected and equal quantities of air delivered by use of or 2/3 width fans with small motors rather than using stock fans and larger motors ; it was also found advisable to adopt certain sizes of tubing for certain lengths of run . In fact , many important facts were ascertained in this study , and it is now promised that they will soon be given to the public . It is true that a certain amount of data on industrial installations are available , but such data are only in part applicable to metal -mine conditions , because , until recently , little attention has been given to ventilation in metalmines , and the conditions encountered usually require a greater length of pipe , a more temporary type of construction , and closer attention to temperature control than the ordinary run of industrial installations demands ..

Feb 1, 1922

By Stephen C. Brown

THE expansion of the world economy which has been in process since 1958 continued in 1963 and both production and consumption of minerals rose. Gross national product (GNP) rose sharply in the United Kingdom and Japan, continued to expand in the United States and Canada, and maintained a high though slightly declining rate of growth in the European Economic Community (EEC) despite the appearance of excess capacity in certain lines and inflationary pressures in Italy and France. The steel and motor vehicle industries both increased output in North America, Western Europe, and Japan. The less developed areas benefited substantially from an improvement in their terms of trade, and their export earnings increased some 8 percent in 1963; although estimates of GNP for the majority of them are 110t yet available, it is probable that this increase was partly reflected in a substantial rise of GNP.2 In the United States the expansion was steady and extended through all sectors of the economy producing no distortions likely to disturb its continuing growth; at yearend with unemployment still at about 5.5 percent of the labor force and operating rates of industry estimated at about 87 percent of capacity, there was a substantial margin for further expansion. Though the balance of payments was still in heavy deficit for the year, in the last half it was moving rapidly toward equalibrium as net exports rose and capital outflows declined; prices were relatively stable, inventories increased only slightly and the activity of mineral-consuming industries remained high, steel output rising by 11 percent to highest level since 1957 and the auto industry output equalling the 1955 record.3

Jan 1, 1964

By K. Rubow, Z. Zhlqun, V. Marple

A theoretical technique has been developed and verified experimentally for determining the aerodynamic diameter of irregular shaped particles. The aerodynamic diameter of a particle is a very important property in determining where that particle deposits in the respiratory tract. Many instruments, such as impactors and cyclones, will determine the aerodynamic size distributions of aerosol particles but few analyze the particles individually. The theoretical approach of our technique is to solve, by use of high speed computers, the three dimensional Navier-Stokes equations to obtain the flow field around an irregular shaped particle of any contour. The computer program will then determine the drag on the particle, and thus the aerodynamic diameter of the particle can be calculated. The experimental approach has been to pass the particles through a centrifuge and collect the particles upon a collection foil. The position of a particle on the foil is an indication of its aerodynamic diameter. These particles were then shadowed in two orthogonal directions and inspected under an SEM. The top view of the particle in the SEM plus the views of the two orthogonal shadows allows one to determine the three dimensional shape of the particle. Studies have been performed on silica, coal and talc particles with aerodynamic diameters in the 1 to 4 um size range. The three dimensional shape, as is determined from SEM analysis was used in the theoretical computer program and the results compared. It was found that in most 'cases the agreement between the experimentally and theoretically determined aerodynamic diameters was within 5%.

Jan 1, 1988

By Maria I. De Rosa

Table 37 and figure 13 show the number of fires and fire injuries for surface stone mines by state during 1990-2001. Table 37 also shows the injury risk rates, employees' working hours, and lost workdays. In all, 96 fires occurred in 31 states and 1 fire occurred in Puerto Rico. Sixty-eight of the fires caused 67 injuries and 1 fatality (including 6 fires and 5 injuries involving contractors). The yearly average was eight fires and 5.6 injuries. The Ewhr value was 689 x 106 hr (Irr = 0.02), and the LWD value was 7,399. Indiana had the most fires (eight fires and four injuries), followed by Georgia (seven fires and seven injuries) and Pennsylvania (seven fires and five injuries). Of these states, Georgia had the highest injury risk rate value (Irr = 0.058). Table 38, partly illustrated in figure 14, shows the number of fires, fire injuries, fire fatalities, risk rates, employees' working hours, and lost workdays by time period. The number of fires and fire injuries show an increase during the second period followed by a decrease during most of the remaining periods. Employees' working hours increased during most of the periods. The In values follow patterns similar to those shown by the injury values. Tables 39-44 show the number of fires by ignition source, method of detection and suppression, equipment involved, location, and burning material by time period. Figure 15 shows the major variables related to fires for 1990-2001. Table 45 shows the number of fire injuries per number of fires causing injuries and total fires by year, ignition source, equipment involved, and location.

Jan 1, 2004

By G. R. Hopkins

"A new record in fuel efficiency at petroleum refineries was achieved in 1935, when an average of only 615,000 B. t. u. was needed to refine a barrel of crude oil, compared with an average of 638,000 B. t. u. in 1934 and 829,000 B. t. u. In 1925. (See fig. 1.)Refiners have made almost uninterrupted progress in firing efficiency during the last decade although much of this gain was brought about by improved technique and greater use of heat exchangers and pipe stills, the determining factor was the trend in crude runs to stills. Most plants can increase their crude throughput materially with but small increase in fuel consumption. Consequently, in years in which crude runs have increased substantially, average requirements have declined; but in years in which crude runs have decreased, the average has tended upward. This conclusion is confirmed by figure 1, which shows that there has been but one minor exception to this rule in the last 10 years.Technical progress in fuel efficiency may be illustrated by comparing crude runs and total B. t, u. consumed. Between 1925 and 1935 crude runs to stills increased 31 percent, but the total quantity of heat required did not increase; in fact, it declined slightly.The trend of modern still construction is from shell stills, in which a large body of oil is heated, to tube stills, in which the heat comes into much closer contact with the oil. In 1935 the total capacity of operating pipe stills increased about 4 percent; this increase, though small, probably was related to the gain in average efficiency.The Increased use of heat exchangers and their role as fuel savers have been discussed in previous reports of this series. It is sufficient to say that refiners with insufficient exchange capacity added as much in 1935 as their budgets would permit."

Jan 1, 1937

Objective Develop field measurement and computer modeling methods to predict the potential for hang-ups and structural failures in underground mine ore paws. Background Analysis of Mine Safety and Health Administration (MSHA) accident statistics has identified ore pass hazards as a significant safety problem in underground metal mines in the United Stales. Recent ore pass failures have underlined the lack or ore pass design methods ant1 standards available to both MSHA and mine engineers. Injury and fatality data for the 20-ycar period between 1975 and 1095 show that nearly 75% of the injuries were directly or indirectly related to pulling or freeing ore pass chutes, the use of hand tools, falls or broken rock, and structural failures or chutes or gates and ore pass walls.

Feb 1, 1998

By W. C. Phalen

"The term ""manjak"" is applied to a variety of bitumen or solid hydrocarbon occuring on the Island of Barbados, West Indies, and in Utah, Cuba, and Trinidad. The deposits on the latter island are found within a distance of three miles of San Fernando, the second largest town on the Island, and within three miles of the famous asphalt lake.In chemical composition, manjak is like asphalt. It is almost pure bitumen. Its melting point is, however, more than 4000F. whereas asphalt melts at 1000F. In composition, it consists of 80 to 90 per cent carbon, the balance being chief¬ly hydrogen, with a small quantity of sulfur. It resembles coal in appearance, is odorless, hard, and brittle. It is found in thin beds between layers of clay.The island of Trinidad is rich in this mineral resource. Its development has as yet hardly begun, and the exportations already made have been with the view of testing out the ma-terial. During 1918, exports to the United States were valued at about $3100, and in 1919, up to October 1, they totaled 41 tons, valued at $1900. Prior to 1900, manjak was mined on a small scale in Trinidad, but for various reasons, very little was done between 1900 and 1913. In the latter year, mining operations were resumed by the Trinidad-Tarouba Oil Development Company, of San Fernando. At the present time, there are five shafts, one of which has reached a 37 foot bed of manjak at a depth of 400 feet. Operations could be greatly extended if there were a greater demand for the material.It has not been found profitable to export manjak from Trinidad in the crude state as the price received, namely $35 per ton, hardly covers mining expenses. These are increased by the necessity for careful and thoro timbering on account of the clay formation.Compounds, made by combining manjak with mineral oil command fair local prices which have enabled mine operations to proceed at a profit. Experimentation is still in progress with different mixtures of manjak and oil for various purposes. The manjak, recently sent to the United States was for the purpose of ascertaining whether American oils would be more economical and useful for mixing with the manjak than the Trini¬dad oils. It is the plan to erect a plant very soon for the manufacture of a variety of manjak paints and compounds.Manjak is rapidly increasing in use, particularly in connection with the oil industry. It is produced in close proximity to the oil wells in Trinidad. It is boiled with oils at high temperatures and converted into compounds and paints for nearly every purpose where a preservative is needed, for example, on pipe lines, boilers, chimneys, and miscellaneous iron ware, machinery, etc. It is usually applied in the liquid state, hardening into a tough, rubberlike coating. It has low viscosity, and is not affected by ordinary heat. It makes an excellent insulating material and is impervious to both air and water. In hot and damp climates, like that of Trinidad where pipe lines quickly deteriorate, their life has been pro-longed for extended periods when painted with this material."

Nov 1, 1919

By Parviz F. Rad

The Bureau of Mines conducted groove cutting experiments in marble, lime-stone, granite, and quartzite with a 7-inch disk cutter under a normal thrust of 7,000 lb. The values of muck weight per unit length, specific energy, cutting coefficient, and groove depth for each of these rocks were determined for groove spacings ranging from 0.1 to 4 inches, and from these results the values of optimum and critical spacing were computed" The results indicate that compressive strength may be used to predict some of the cutting characteristics of the independent grooves. Considering all the cutting characteristics, particularly those for the interacting grooves, Shore hardness, coefficient of rock strength, and torsional velocity correlate with cutting characteristics better than do other physical properties. Some of the field applications of the principles established in this report are identified.

Jan 1, 1974

By John C. Edwards

Chapman-Jouguet detonation calculations were carried out for pentaerythri-tol tetranitrate (PETN), TNT, and ammonium nitrate-fuel oil (AN-FO) explosives using the compressibility form of an equation of state of hard spheres based upon Percus-Yevick (PY) theory, and a chemical equilibrium detonation code called TIGER. Similar calculations were also carried out with the Becker-Kistiakowsky-Wilson (BKW) equation of state. For PETN, the BKW equation gives somewhat better agreement with experimental values of detonation velocity and pressure. However, in terms of experimental temperatures and concentrations of the minor product species (NO), the predictions of the PY equation are shown to be more satisfactory. Similar comparisons of experimental and theoretical results for TNT and AN-FO indicate that the PY equation has general utility in predicting the detonation properties of condensed explosives at moderate loading densities (Po < 1.3 g/cm3).

Jan 1, 1974

By Richard J. Mainiero, Harry C. Verakis

The Bureau of Mines has conducted research to determine whether the total elapsed delay time for blasting bituminous coal in underground mines could be safely expanded beyond the present 500-ms limitation without igniting a methane or methane-coal dust atmosphere. The results indicated that the increase of total delay from 500 to 1,000 ms had no detectable effect on safety relative to incendivity as long as permissible practices were observed in all other aspects. Research was also conducted to evaluate the safety of 18-in hole spacing for delay blasting in coal relative to misfires. For a variety of permissible explosives, misfires were observed for about 50 pct of the holes at 18-in spacing. Based on this observation, the Bureau has recommended that the new regulations prohibit hole spacings of less than 24 inches in underground coal mines. Misfires were also observed for 24-in spacing, but the number of misfires and test shots was too small to sup- port any firm conclusions.

By A. T. Coumbe

The Bureau of Mines has compiled pipeline mileage every 5 years since 1926, with the exception of the war period 1941 to 1949. The present survey has been made to reflect the progress under mobilization of the petroleum pipeline industry where efforts have been made by the government to stimulate construction of those facilities that would best equip the nation for a possible major emergency. This report summarizes the total mileage change 1n petroleum pipelines for 1950 through 1952. In order to increase the value of the information gathered the reporting companies were requested for the first time to report not only the net change in mileage as formerly, but also all new and used pipe laid and the total taken up. This new information permits effective appraisal of the construction effort of the industry and relates it to steel requirements.

Jan 1, 1953