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By J. J. Taute, N. B. du Preez

"A well-performing solvent-extraction circuit is a key part of producing good quality copper cathode. To ensure consistent operation, a good understanding of the circuit’s operation and an ability to rapidly troubleshoot key parameters is required. This paper briefly discusses the modeling of solventextraction circuits. The paper then goes on to discuss the determination of key performance parameters from plant data and comparing these with the circuit models to quantify circuit performance. The identification and troubleshooting of circuit issues is presented with a worked example. INTRODUCTIONA well-performing solvent-extraction (SX) circuit is a key part of producing good quality copper cathode. To ensure a consistent, high-quality operation, a good understanding of the circuit performance is required. Evaluating the performance of an SX circuit is an extensive topic. The objective of this paper is to focus on the evaluation that the metallurgist should be performing on a regular basis using flow and concentration data. This paper does not cover important topics, such as crud management, phase continuity, or organic management. Some basic SX modeling concepts are first be presented. The calculation of the parameters is then presented with a brief discussion and recommended ranges (where applicable). A worked example is used to provide a basis for further discussion on the evaluation of the calculated parameters and use of data collected.BASIC SOLVENT-EXTRACTION MODELING CONCEPTSThis section presents the basic modeling concepts used in SX simulation packages currently available. SX reagent suppliers have invested significant time and effort into collecting data on the performance of their reagents under different conditions. Based on these data, suppliers have developed packages which they normally make available to their clients for free. These are typically used for process design and plant optimization studies. For example, BASF developed ISOCALCTM and CYTEC Industries developed MINCHEM® and MEUMTM.Chemistry of Copper Solvent ExtractionLiquid–liquid extraction involves the selective transfer of a substance between two immiscible liquid phases by controlling the relative solubility in each phase. In the case of copper SX, the exchange is typically achieved by an oxime-based chelating mechanism. In particular, mixtures of aldoxime and ketoxime are normally used in conjunction with modifiers. More detail on this extensive topic can be found in Schlesinger et al. (2011)."

Jan 1, 2015

By Marthie Kotze, Jacolien Wyethe, Bert Van Hege, Richard Bell

Base metal refinery effluent streams may contain low metal concentrations that cannot be recovered by precipitation. Although the concentration is low, the total mass of unrecovered metal can have significant value because of the volumes of effluent generated. This metal may be recovered with high efficiency using selective ion exchange resins. Three process schemes are considered, viz., fixed bed column ion exchange, continuous countercurrent resin-in pulp, and continuous carousel resin-in-pulp. Each of these has different requirements in terms of equipment, resin inventory, capital and operating costs, and different limitations on feed conditions. Bateman and Mintek recently developed a model which allows an upfront economical evaluation of ion exchange options. The model evaluates the capital and operating costs for each process scheme for various base metals. This provides a general guideline for selecting the appropriate process arrangement for a given process stream.

Jan 1, 2005

By H. M. Dus, D. J. Smith

Resistivity tests indicated that, at temperatures lower than 1450°C, reducing agents alone, as well as burdens consisting of high-carbon ferrochromium and reducing agents, exhibit wide differences in resistivity. These differences are less pronounced at elevated temperatures. The resistivity of a reducing agent and the volume fraction it occupies are important factors controlling the resistivity of burdens of high-carbon ferrochromium. A mathematical model is formulated to describe the dependence of the resistivity of mixtures of conducting and insulating particles on the particle sizes and the volume fraction occupied by the conducting phase. The resistivity of burdens of high-carbon ferrochromium is high if the particle size of the reducing agent is larger than that of the other components of the burden. A number of reducing agents showed small variations in their reactivity towards chromite ore in the solid state. However, with chromite ore in the liquid state, reduction proceeded more rapidly with reducing agents occupying larger volume fractions. During the smelting of manganese ore, high initial rates of reduction were observed for reducing agents that had a high reactivity towards carbon dioxide and a high content of volatile matter, and that occupied a large volume fraction. High liq'uid-state reactivities were observed for reducing agents occupying a large volume fraction and having a Iow degree of graphitization.

Jan 1, 1980

By I. R. M. Chaston

A full and detailed description is given of the dense-medium cyclone plants used in Africa for the recovery of diamonds.

By G. R. Addie

The Hydraulic Institute has completed the task of developing a new ANSI/HI standard 12.1-12.6 (2005) for rotodynamic (centrifugal) slurry pumps covering nomenclature, definitions, applications, and operation. The standard provides examples of the different slurry pump types and contains an extensive section on pump and slurry definitions. The effect of slurry on pump performance is covered along with the pumping of froth. Reference is also made to ANSI/HI standard 9.6.7 (2004), which contains a new method for pump performance correction when handling viscous fluids. Classification of slurry services is established and then is used to determine limitations on velocities and total head per pump in order to obtain acceptable wear performance. The new service class, head per stage and other limits are directly related to capital and other cost considerations that will affect solids transport system economics. The writers review the contents of the new standard, highlight the main points, and discuss the reason for the slurry classification, corresponding limits and expected implications, particularly with respect to operating costs of the pumps in solids transport systems.

Jan 1, 2007

By A E. Paterson

General aluminium corrosion charts based on 1100 alloy listing product and temperature have been developed by AFSA, mainly from available sources. The categories of corrosion expectation are fairly wide. As a result the charts are more useful in indicating what is not suited as distinct from what is. The question of how to develop useful information is assessed. Having discarded improbable options one is left with the need to refine the possible. Within each alloy group corrosion potential differs. From an engineering application point of view, the corrosion resisting marine alloys, the 5xxx series show increasing corrosion as the percentage of Magnesium increases. An important issue is that as the welding filler used for 5xxx series is Mg rich (to avoid hot cracking), the filler is likely to show the weakest resistance. In addition, when subjected to fatigue loading, the preference for critical joints is to dress the joint to the level of the base material. Overheating of the weld extends the HAZ zone and weakens the material as Mg moves to the grain boundaries. Indicator chart refinement approaches suited to aluminium use in commercial transport are discussed.

Jan 1, 2006

By L. S. Belyayeva, A. S. Chumak, N. N. Boyko, A. V. Bondarenko

Analysis of results of many years concerned study of the fire hazard parameters of the material of the mine conveyor belts come in for use at the mines of the Ukraine in 1984-2002 that was carried out in the laboratories of the Scientific-Research Institute of Mine-Rescue Work is adduced in the paper. The basic tendencies on raising the fire safety of the conveyor belts that are retraced in their world production are shown.

Jan 1, 2003

By A. W. Bryson, J. D. le Roux, B. D. Young

Several rate models for the adsorption of gold cyanide from aqueous solution onto activated carbon are given in the literature. The purpose of this study is to critically examine their ability to simulate the adsorption process over a wide range of conditions. An account is given of a comprehensive set of experimental work on the kinetics of gold adsorption onto a coconut shell- based activated carbon. Equilibrium isotherms were also determined. It is concluded that the homogeneous surface-diffusion model fits the experimental data reasonably well and provides a good balance between simplicity and descriptive accuracy. The model contains two parameters: the extra-particle mass-transfer coefficient and an effective intraparticle surface-diffusion coefficient. Both can be evaluated readily from simple adsorption experiments.

Jan 1, 1991

By D. G. Krige

The scope and salient features of a general risk-analysis model for the main types of new mining ventures are covered in brief outline. The following special features and their effects on the investment criteria are discussed: - various criteria for viability, - the maximum shortfall of funds, - correlations between the grades of up to five ore constituents and between the corresponding product prices. differential inflation and escalation rates for costs and prices, - the estimation, if relevant, of a pay limit based either on the major product only, or on the two major products jointly, - the likely recovery grades of all the products to be obtained when the ore-body is mined to any such pay limit. - an option to take account of the effect on the pay limit of any negative taxation on marginal ore, - investment analyses in current and real terms for individual groups of investors subscribing for equity and any loan capital on differential terms.

Jan 1, 1979

By G. R. Addie, A. S. Roudnev

The Hydraulic Institute has completed the task of developing a new ANSI/HI standard 12.1-12.6 (2005) for rotodynamic (centrifugal) slurry pumps covering nomenclature, definitions, applications, and operation. The standard provides examples of the different slurry pump types and contains an extensive section on pump and slurry definitions. The effect of slurry on pump performance is covered along with the pumping of froth. Reference is also made to ANSI/HI standard 9.6.7 (2004), which contains anew method for pump performance correction when handling viscous fluids. Classification of slurry services is established and then is used to determine limitations on velocities and total head per pump in order to obtain acceptable wear performance. The new service class, head per stage and other limits are directly related to capital and other cost considerations that will affect solids transport system economics. The writers review the contents of the new standard, highlight the main points, and discuss the reason for the slurry classification, corresponding limits and expected implications, particularly with respect to operating costs of the pumps in solids transport systems.

Jan 1, 2007

By N. von Stade, G. du Plessis, W. van Niekerk, H. Bosman

Exploration, and other, boreholes are drilled to obtain information about the geological environment. Knowledge of the exact position (dip and direction) of the holes is important to ensure compatibility between the hole and the geological information. Kumba Resources traditionally used mechanical methods to determine the hole characteristics. These are cumbersome and expensive, and as a consequence a new method, the IVEC (Iscor Video Exploration Camera), was developed which utilizes a charged coupled device (CCD) image sensor focused on a three-dimensional compass. This system is rugged, relatively inexpensive and gives real-time results during borehole logging. Keyword: Borehole inclination, deviation, dip and direction, geophysics, exploration.

Sep 1, 2001

A banquet, attended by 467 members and visitors, was held at the Wanderers Club, Johannesburg, at 8 p.m. on Friday, 21st March, 1969, to celebrate the 75th Anniversary of the founding of the Institute. Introduction of Dr Carel de Wet R. C. J. Goode (President) Dames en here: Ons het 'n aantal vooraanstaande gaste in ons midde vanaand en mnr Maxwell sal u later meer van hulle vertel. Dit is my aangename plig om u voor te stel aan sy Edele, die Minister van Mynwese, van Beplanning, en van Gesondheid, Dr de Wet en sy gade, mev de Wet. Sy Edele Dr de Wet het geen bekendstelling nodig nie-alhoewel hy ons minister vir slegs die afgelope twee jaar is, het hy reeds talle funksies van ons Mynbedryf bygewoon en het baie vriende gemaak onder ons. Hy het homself baie bemind onder ons gemaak toe hy Wes-Driefontein onlangs besoek het om hulle ondersteuning en aanmoediging aan te bied in hulle uur van nood. The Honourable Dr de Wet was born in the Free State. He is a grandson of that very famous general Christiaan de Wet, who caused so much pain to the British forces and for so many months so successfully eluded them in the Transvaal and Orange Free State. He was educated at both the Pretoria and Witwatersrand Universities. He first practised medicine at Boksburg and then moved to Vanderbijlpark, so you see he has an early association with gold mining on the Witwatersrand, and in moving to the Vereeniging-Vanderbijlpark district he became closely involved in our coal mining and metallurgical industries. South Africa's first steel was poured from a l0-ton open hearth furnace belonging to the Union Steel Corporation in Vereeniging in 1913. Dr de Wet has been mayor of Vanderbijlpark and for several years has been their member of parliament. More recently, the Honourable Dr de Wet has filled with great honour that most important office of Ambassador for the Republic of South Africa in London. At present he wears two hats, in that he is Minister of Planning and of Health, but more important is his cloak, that of Minister of Mines, which I trust offers him the greatest comfort. To fulfill these three arduous tasks must demand of him a terrific devotion to duty, and in doing this he carries on that loyal tradition of service to his fatherland so evident in his grandfather. Dames en here, dit is vir my 'n groot genoeë om Sy Edele Dr de Wette vra om 'n heildronk in te stel op die Instituut vir Mynwese en Metallurgie. Toast to the Institute of Mining and Metallurgy Dr the Honourable C. de Wet (Minister of Mines): Mr President, ladies and gentlemen, Mr President you have introduced me gracefully to this distinguished company and I am appreciative of your remarks. I am fully conscious of the responsibilities that devolve upon me as Minister of Mines in a country where mining makes so vital a contribution to economic progress and development and has, in fact, laid much of the foundation on which our present proud edifice is built. The achievements of the mining and metallurgical industry in its diversified activities arouse feelings equivalent to paternal pride, but let me speedily add that in considering any family relationship that may exist, the Minister of Mines should not be regarded in the role either of a fairy godmother or an indulgent father.

By F. P. Agterberg, A. G. Fabbri

"A statistical analysis was done on the locations of 718 copper and 1 257 gold deposits in Abitibi. This area of about 20 000 square miles is one of the better-explored metal-producing areas of Canada.Patterns of clusters were studied by harmonic analysis. Several two-dimensional power spectra showed a number of distinct peaks. Sets of crest lines for patterns of interfering waves were constructed on the basis of these peaks. They pass through elongated clusters of deposits which are spaced more or less equally. For copper these periodic regularities in location may coincide with geological structures largely of Archean age (major fractures and sedimentary belts indicating synclinal structures). A directional relationship with swarms of diabase dykes of known ages and distinct attitudes indicates that the gold mineralization is, in part, younger than the copper mineralization."

Jan 1, 2014

Contribution by W.D. Ortlepp In the Journal of May 1994, the authors first presented the concept and analysis that formed the basis for a design approach for deep tunnels, now expressed more explicitly in the present paper (March/April 1996). In a contribution in the Journal of March/April 1995, I expressed a certain disquiet about the validity of their original approach. The authors responded to these criticisms in the same issue. It is apparent to me now that both the contribution and its rebuttals were written, probably for different reasons, in such an obscure and pedantic way as to further confuse the reader rather than provide enlightenment. My concern still persists. But in order to avoid further confusion I will attempt to pose my uncertainties and difficulties in a much more direct way. On page 98 (top of 2nd column) in the earlier paper, an important statement concluded as follows: '. . . the horizontal ellipse requires 140 per cent less force for equivalent stability'.

Jan 1, 1996

By E. M. W. Skinner

Various models of near-surface kimberlite pipe emplacement have been proposed over the years. These include a top-down, phreatomagmatic model, a bottom-up, embryonic pipe model and three top-down explosive dyke models. AU of these models consider kimberlites as essentially the same rock type. However, different kimberlites have different pipe shapes and contain different rock types with very specific mineral assemblages and textures and therefore are likely to have been emplaced by different processes. Some authors have considered local geological differences as the principal reason for the contrasting geology but others argue that, while geological differences might contribute locally the petrographic peculiarities of particular kimberlites may be due mainly to inherent compositional differences specifically in the ratios of juvenile CO2 and H2O.

Jan 1, 2010

By C. P. S. Barnard, D. G. Krige

Objective justification on economic grounds for expenditure aimed at improving the quality of the underground working environment requires a suitable measure of any improvement in productivity that would result under routine working conditions. For this purpose, a composite production criterion is suggested, as well as its correlation under actual operating conditions with various factors directly affecting productivity and the environment. Of the environmental factors, wet-bulb temperature appears to be the major factor affecting productivity. The production data given indicate that a decrease in the wet-bulb temperature of 1OC can be expected to result, on average, in some 3 to 4 per cent increase in productivity; in the higher temperature ranges, this percentage could be much higher.

Jan 1, 1981

By R. M. Falcon

The paper opens with a summary of the major factors responsible for spontaneous combustion in coal discards. These include heat arising from the oxidation of coal and pyrite, and from the weting of dry or oxidized coal and pyrite; and certain petrographic conditions leading to self-ignition of the coal such as low rank, the presence of a high proportion of reactive constituents, and the occurence of highly porous and botanicaly structured inertinite macerals, The analyses of 6 samples from 2 discard dumps in the Witbank coalfield are included, which show that, according to a three-grade classification of liability to spontaneous combustion, one dump is 'reasonably liable' and the other is 'most liable', It is pointed out that factors other than liability to self-ignition determine the possible utilization of such discards, and that the prevention of oxidation is of great importance if they are to be utilized and spontaneous combustion to be prevented,

Jan 1, 1986

By R. T. White

The usual figures quoted for water usage in South African gold mines are 1 ton of water used per ton of rock broken, which represents a consumption of 4000 litres of water every second. Owing to the limited sources under ground water, the high cost of surface-water supplies, and the environmental problems of effluent disposal, water IS recycled continuously for underground use. This paper reviews the various types of water treatment and why water needs to be treated. The uses of lime and some flocculants are considered, since much of the mine service water requires only simple neutralization and clarification. Where mining depths necessitate the installation of underground refrigeration plant, more stringent water requirements must be met, and where plant performance is to be maintained, the prevention of system scaling and corrosion is necessary. The families of chemicals added to provide such protection are outlined, together with a description of the mechanisms of control.

Jan 1, 1985

By C. P. Smyth

Large volumes of quantitative geochemical data, presenting a formidable interpretation task to geologists, are generated in the course of exploration drilling for new ore deposits. The incorporation of geological expertise into computer programs developed for the interpretation of this data would improve the speed and accuracy with which it is interpreted. A detailed analysis of the geochemical log interpretation problem, together with a survey of relevant research in Artificial Intelligence and petroleum well- logging techniques, confirms, that artificial intelligence, particularly as developed in the fields of expert systems and pattern recognition, provides techniques for implementing such data interpretation programs. In addition, it provides data analysis techniques significantly more powerful than those currently applied to geochemical data, and very appropriate to the hypothesise and test' character of mineral exploration problem-solving. The conversion of raw borehole log data to meaningful higher level geochemical entities, in terms of which geological reasoning may take place, is a critical step in applying these techniques to log data analysis. A method of achieving this conversion as an exercise in signal-to-symbol transformation is presented.1

Jan 1, 1987

By C. E. Dohm

The paper serves to show the importance of both a geological model and geostatistical model that support one another in mineral resource evaluation. It highlights the advantage of reference models for the geometry, the geological, statistical and geostatistical models of various orebody types and introduces a method for quantifying the combined uncertainty in these models. The example presented reveals how the above levels of information can be applied to add value to a resource evaluation process. It is a generic example in that it is the technique of combining uncertainty in the geological model (boundaries) as well as the grade model to assess the overall risk in the estimation of the resource. Data from the coal industry is used to illustrate the techniques. The geological uncertainty is considered via categorical simulations and these are combined with simulations of the variables (grades, thickness,) being estimated in the resource. The simulation techniques used are based on the application of GSLIB software1and a general discussion of the two simulation processes is included. In conclusion the paper demonstrates how the results of two types of conditional sequential simulation can be combined to produce confidence limits that take both uncertainties into consideration. This technique does not replace the resource estimation; it serves as an additional tool to quantify confidence in the resource evaluation model. The topics considered in this contribution are in terms of continuous improvement of mineral resource evaluation.

Jan 1, 2003