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By Richard Komarek

When limestone (Ca03) is calcined in rotary kilns to produce quicklime (CaO), it is not unusual for 10% to 20% of the stone to abrade and emerge from the kiln as quicklime fines (-6.3 mm or -0.25 in.). While there are various industrial processes that can use fines, handling and shipping is tricky and dangerous. Due to the highly caustic nature of quicklime, airborne dust easily bums eyes and skin. On the other hand, money has already been invested in mining (or buying) the raw material and in the equipment and energy needed for calcining. Discarding the fines will not only waste that investment, but add even more cost in transportation and possibly dumping charges. So the question becomes, how can fines best be turned into a revenue-generating asset? Some plants convert leftover quick-lime fines into calcium hydroxide - Ca(OH)2, also known as hydrated or water-slaked lime - for sale into agricultural applications. For farm uses, hydrated lime fines are preferred over quicklime because they are easier to handle. And they are favored over raw limestone fines for their higher concentration of calcium and greater solubil¬ity. From the producer's viewpoint, quicklime fines are ideal for this use because they go through hydration faster than the larger chunks of quicklime. Those larger chunks, or "pebble lime," are more readily salable and more easily handled, for such uses as steel, copper, aluminum and magnesium production, water waste treatment, chemical, paper, glassmaking and flue gas desulfurization in coal- fired boilers.

Jan 1, 1993

By T. Reed Scollon

Major interrelated factors to be considered in assessing the impact of air pollution control regulations on coal are: (I) the fuel and fuel-related limitations of such regulations; (2) the rate of adoption and areal scope of the regulations; and (3) the availability of fuels and fuel-burning equipment to meet the requirements. A growing number of regulations contain provisions limiting the emissions of sulfur oxides or the sulfur content of fuels or both. With few exceptions, these limitations have not yet become fully effective in those areas which have already adopted regulations, and pertinent details of future regulations or legislation for most other areas are unknown at this time. Sufficient information is not avail- able to determine the availability of low-sulfur fuels at various demand and price levels, and large-scale commercial feasibility of sulfur-oxides removal processes and equipment is believed to be some years away. Accordingly, with the many uncertainties and unknowns, it is possible at best to make only a rough assessment of the impact of such regulations or legislation on coal.

Jan 1, 1969

By R. K. Amankwah, E. K. Asiam

Changes in the thermal-oxidation behavior and other properties of gold-bearing waste activated carbon when milled in both a ball mill and a vibratory mill were investigated. It was found that significant changes occurred in the oxidation temperature of the vibration-milled waste carbon as a result of increases in surface area and mechano-chemical activation. The mechano-chemical action brought about modifications in the crystal structure of the waste carbon. As a result, the vibration-milled sample was completely oxidized at a temperature of 450°C. Thus, the study established that vibration milling is a better way of lowering the temperature of oxidation of the waste carbon. Furthermore, the gold was found to be concentrated in the ash and, when leached with cyanide for 20 hrs, the gold recoveries from a sample having a head grade of 2 kg/t was 99.5% for the vibration-milled sample and 82% for the ball-milled sample. The lower gold recovery for the ball-milled sample was attributed to sintering of the ash, which was caused by the higher temperature required for its oxidation.

Jan 1, 1997

By Chuck R. McLendon

A new face ventilation system was needed at the Allied Chemical Trona mine, near Green River, Wyoming. The development of an exhaust manifold face ventilation system came from a need to reduce the dust and noise concentration level while maintaining methane control at the continuous miner working face. Dust laden air from a heading being driven by a continuous miner was contaminating the intake air in the mine around the roof bolter operator and adjacent headings. Each working heading was exhausted into the last open crosscut by a face fan. A face fan would contaminate the adjacent downstream heading with dust-laden air until a high dust concentration developed in the final entry before the returns. A face ventilation system was needed to give the exhaust of each heading an individual path to the return air. In addition, the system could not interfere with the present room and pillar mining process. A manifold system of rigid duct ventilation tubing was designed using the existing fans in a parallel arrangement. Each system was to consist of the rigid duct tubing in three headings junctioned together at the last open crosscut and exhausted at a common branch in the return air. Each heading was to have its own damper (or valve) so that air could be directed where it was most needed. The system was installed using both round and oval rigid duct ventilation tubing to minimize head loss and to allow proper ground clearance for mining machinery. Two fans in parallel were used to exhaust three headings. By adjusting the valves at each heading, up to 18.0 kcfm (9.36 cu m per sec) could be exhausted from one heading and still keep the methane level controlled in the other two headings. The manifold exhaust system has proven to be an efficient, long lasting ventilation system at the Alchem Mine. It has reduced the dust and noise exposure levels at the working faces while keeping the methane level under control.

Jan 1, 1980

By Fathi Habashi

A LARGE number of metals are found in nature, in rich deposits, in the form of sulfides as shown in Table 4.1. Treatment of sulfide ores is done mostly by pyrometallurgical operations; it is only recently that hydrometallurgical processing started to compete with pyrometallurgical methods.

Jan 1, 1970

By Finn E. Bronner

HISTORICAL PERSPECTIVE "Blessed be the Lord my strength, which teacheth my hands to war and my fingers to fight." Thus sang David three thousand years ago, in tacit acceptance of the condition of war, and in praise of the exceptional military skills with which this warrior king of Israel was endowed. He had cause to exult, for he had consolidated King Saul's conquests and added new ones of his own, not least of which was the capture of Jerusalem. David revealed in this operation that his mastery of the military arts embraced not only the weaponry and tactics of his day, but also strategy and that oldest of intelligence techniques: spies. The Jebusites, who built Jerusalem, had encompassed the city with the first of its many walls, but had neglected to incorporate the sole reliable water supply within its perimeter. This was Ain Gihon, today called the Fountain of the Virgin, which bubbled out on the east slope of Mount Ophel, one of the ridges on which Jerusalem was built, and drained eastward into the Kidron Valley. Water was brought into the city in the traditional manner: by women descending the stony trail outside the wall to fill their jars at the spring. But this essential daily activity was vulnerable to interruption by a hostile force outside the walls. To remedy this weakness, the Jebusites had driven a gallery from the spring a short distance into the water-bearing limestone under the city, and there cut a small collecting basin in the rock, a common way to develop springs throughout this arid region. But then the Jebusites dug a small vertical shaft from the roof of the gallery above the cistern upward about 15 m. From the upper end of this shaft, they constructed a narrow inclined tunnel with rock-cut steps leading up to the city streets. Thus the water supply could be reached even in time of siege.

Jan 1, 1979

By W. Addy Majewski, Kenneth L. Bickel

The U.S. Bureau of Mines (USBM) and Diesel Controls Limited evaluated a new diesel emission control system on an underground mine vehicle. The system was a catalyzed ceramic wall-flow diesel particulate filter (CDPF) combined with an catalytic converter, or diesel oxidation catalyst (DOC). This paper describes the design and installation of the system on a load-haul-dump (LHD). The results of screening tests conducted by the USBM are also given. The screening tests were conducted to determine if the device's particulate collection efficiency, regeneration temperature, and effect on gaseous hydrocarbon (HC) and carbon monoxide (CO) emissions changed over the period it was being used. The system was removed from the LHD and evaluated in the laboratory after operating for 308 and 1200 hours. After 308 hours of operation, laboratory testing revealed its particulate collection efficiency varied from 41.0 to 93.5 percent, depending on engine operating conditions. Its regeneration temperature was about 415° C. It reduced HC emissions by up to 97.6 percent, and CO by up to 95.0 percent. When tested in the laboratory after operating for 1200 hours on the vehicle, no significant change in performance was observed.

Jan 1, 1995

By Anthony J. Peach

With the new generation of so called "Super TBM", we would all expect to witness the implied super-performance. In some instances this is occurring, but one must ask why is it not occurring in the majority of applications? For hard rock TBM related projects, we are observing a decrease in the volume of projects in the previously traditional areas such as North America and Western Europe and an increase in Asia (Hong Kong, Indonesia, China, Korea etc). As a consequence less experienced contractors are acquiring the latest ultra high power equipment, without the knowledge necessary to achieve optimum performance. The interdependence of TBM and muck removal systems has been assessed with emphasis on the emergence of the continuously extending conveyor technology, as a means of achieving dramatic productivity increases. The Australian system assessed here at the time of drafting this paper holds the world record tunnel excavation production of 2,166 metres. A little considered aspect of the adoption of conveyors is the associated improvement in safety.

Jan 1, 1995

By D. P. Patil, T. C. Rao, J. P. Barnwal

Factorial design of column flotation experiments was used to understand the main and interactional effects of the column parameters. In the experiments, the air flog rate, the wash-water, flow rate and the froth depth were varied at two levels. Analysis of the results showed that an increase in airflow rate had a deleterious effect on the grade of the concentrate, whereas, an increase in froth height increased the grade. The interactions between airflow and wash water and between airflow and froth height were significant with respect to grade of the concentrate. These results demonstrated that, from an ore containing 12.76% P2O5, it is possible in a single-stage flotation column to obtain a concentrate containing 31 % P2O5 (10.6% Si02) with a recovery of 94%, thus reducing the number of cleaning stages that would be required if conventional flotation cells were used.

Jan 1, 1997

Development of process control in the metallurgical industry over the past ten years has been highly influenced by technical advances centered on use of computers as well as on measurement and associated equipment. The discussion in this section reviews advances in computer technology, measurement devices, data input-output techniques, and their use in mineral processing for the objective of guiding application of process control principles. Advances in the next ten-year period through the 1980's can be foreseen in the cost and application of data handling facilities in the coincident fields of data processing equipment, interface and control devices, and computer programming systems. These will lead to greater acceptance in a widely expanding range of mineral processing fields. It can be predicted that process control methods now known to be effective will become more re- fined. Costs of on-stream analyzers for assays and particle data will be reduced. Continued innovation can be anticipated in measurement devices required for effecting control. Control techniques developed over the last decade in key process operations such as crushing, grinding, flotation, smelting, and hydrometallurgical processes are described in the following chapters. The general forms taken by computer process control are first outlined briefly.

Jan 1, 1979

By John C. Balla

The Spar Lake deposit is located in northwestern Montana, approximately 27 km (17 miles) south of Troy, MT, under Mt. Vernon. The deposit is a stratiform, stratabound copper-silver deposit occurring in the Revett Formation of the Proterozoic Belt Supergroup. Distribution of known sandstone-type deposits in the Revett Formation is shown in Fig. 1.

Jan 1, 1991

By J. W. Rains

Arizona Portland Cement Company's limestone deposit (called Twin Peaks) is approximately 4 miles southeast of the cement plant. The pant is adjacent to both the Southern Pacific Railroad and Interstate 10, about 17 miles northwest of Tucson. Placer claims were filed on the Twin Peaks deposits in 1923. From that time until the present, geologic data have been accumulated and evaluated to define more closely the quantity and quality of the limestones. The cement plant at Rillito was originally constructed as a one-kiln plant in 1949. Capacity was increased in 1952 and 1956, bringing the plant to an annual capacity of 44,000 tons of cement. In 1972 anther expansion program was completed, bringing annual cement capacity to 1.1 million tons. Geologically, the Twin Peaks contain formations ranging from the Precambrian Pinal Schist to the Pennsylvanian Naco Formation. Within this sequence, other exposed formations include the Cambrian Bolsa Quartzite and Abrigo Formation, Devonian Martin Limestone, Mississippian Escabrosa Limestone, and Pennsylvanian Naco Formation. Generally, the Escabrosa, Naco, and Martin Formation are the primary sources of limestone for manufacturing cement. The Martin Formation is basically a dolomite with bands of limestone, quartzite, and siltstone. These limestones are blended with outside source materials (clay and iron ore) to make a raw mix that will make specification cements. Several drilling programs were initiated between June 1946 and March 1982. Information derived from these programs provided the means to develop cross sections, geologic blocks, and grade blocks. The configurations of the geologic and grade blocks are the same. Block boundaries delineate the various formations on any particular level. Cursory inspection of the structure would indicate a broad syncline elevated on the west side. A more detailed examination shows that the structure has been complicated by several periods of faulting and intrusion of igneous rocks.

Jan 1, 1987

By F. A. Renninger

Limestone and dolomite are the most common rock types mined and quarried as industrial minerals in the United States. In 1993 over 720 million tons of limestone and dolomite valued at over 3.1 billion dollars were extracted and consumed throughout the nation. While the greatest volume of this vast production is used as aggregate for construction purposes, few people realize how critical limestone and dolomite are to our food chain and our national goals of clean air and water. Limestone, including dolomite, can truly be called nature's gift to the environment. Without a reliable, economical source of limestone the quality of our environment would be severely comprised and the standard of living of our citizens dramatically reduced.

Jan 1, 1995

By T. W. Eddy

Research was conducted in which elemental mercury and its sulfide mineral (cinnabar) are removed from a copper sulfide concentrate by low temperature thermal applications. The goal of this research was to reduce, volatilize, and collect mercury vapor from concentrated smelter feed in a simulated drying environment while maintaining the chemical integrity of the residual. The study used synthesized concentrates composed of copper sulfide and mercury bearing minerals (such as cinnabar (HgS) or elemental mercury) to determine optimal residence times and temperature ranges.

Jan 1, 1996

By Stephen D. Hill, C. R. Ferguson, T. H. Jeffers, P. G. Bennett

The U.S. Bureau of Mines' Salt Lake City Research Center has developed porous polymeric beads containing immobilized non-living biological materials for extracting metal contaminants from waste waters. Immobilized biological materials include peat moss, algae, biological polymers, and other materials that demonstrate high affinities for heavy metals. The beads, designated as BIO-FIX beads, have distinct advantages over traditional methods of utilizing biological materials in that they have excellent handling characteristics and can be used in conventional processing equipment or low-maintenance systems. Toxic metals such as copper, cadmium, zinc, lead, and mercury are several of the many heavy metals effectively removed from mine waste waters using BIO-FIX beads, Continuous cyclic testing indicated that the beads continued to produce treated effluents which met National Drinking Water Standards (NOWS) after 150 loading-elution cycles. Adsorbed metals were removed from the beads using dilute mineral acids. In many cases, the extracted metals were further concentrated to enable processors to reclaim the metals, thus minimizing the generation of a hazardous sludge, Tests indicated that use of the beads in a low­maintenance system was particularly effective for treating remote acid mine drainage waters and small toxic seeps from hard-rock mining districts.

Jan 1, 1991

By R. Woods, O. A. Kiehn, C. A. Born, F. N. Bender

Development of the flotation reagent scheme at Climax Molybdenum Company's mine at Climax Colorado is reviewed. Features of the mineralogy, milling practice and background of reagent changes are outlined. Special attention is given to the hitherto unpublished details of the application of depressants for copper and lead impurities. The present rougher flotation reagent scheme utilizes a neutral hydrocarbon oil, low in unsaturates and wax, as collector with a sulfated coconut oil emulsifier and pine oil frother. Lime and sodium silicate are used as rougher conditioning and slime dispersant agents. Chalcopyrite and galena impurities are de- pressed in both rougher and cleaner plants by stage addition of Nokes reagent and sodium cyanide to yield a metallurgical grade molybdenite concentrate containing greater than 90% molybdenite and less than 0.5%, 0.1% and 0.05% iron, copper and lead impurities, respectively.

Jan 1, 1976

By Thomas M. Hanna, John W. Anthony, Lee C. Atkinson

Ground water can pose major engineering and environmental problems to the new generation of large, deep gold mines currently being developed throughout the world. It is important that the potential magnitude of these problems be assessed early in the planning of such projects and that any necessary dewatering and environmental remediation programs be designed at least preliminarily in the feasibility stage. The assessment should begin with acquisition of hydrogeologic data during exploration drilling and be followed by carefully designed and analyzed aquifer tests. Once a sufficiently detailed conceptual hydrogeologic model has been defined, state-of-the-art numerical models should be used to estimate ground-water inflows to proposed pits and underground openings, to design and evaluate the potential effects of various dewatering schemes, to define specific environmental impacts, and to predict pore pressures in highwalls relative to slope stability. The modeling results will indicate which method(s) of dewatering will be most effective both technically and economically. If wells are used, it is imperative that they be as hydraulically efficient as possible. There are new methods of drilling and completing dewatering wells that can help assure maximum efficiency.

Jan 1, 1989

By C. A. Fleming, C. J. Ferron, E. S. Makande, P. Mason

Several small mines are producing refractory gold concentrates in Zimbabwe and, owing to the small scale of most of these operations, their output is processed in a central custom roaster in Kwekwe. Owing to the wide variations in the feed to the roaster, the efficiency of the old Edwards roaster is deemed unsatisfactory with gold recovery from concentrate as low as 70%, and alternative processes were evaluated to improve this situation. Various processes for oxidizing refractory arsenopyrite/pyrite concentrates to liberate gold prior to cyanidation are known. In practice, only two have to date met with wide industrial acceptance, pressure oxidation and roasting. Owing to the ·high arsenic and antimony levels of some concentrates in Zimbabwe, the only viable roasting alternative would be two-stage air-roasting of concentrates in two reactors, as practiced at Giant Yellowknife, Campbell Red Lake and New Consort. This process, however, creates an arsenic disposal problem, and produces gas of fairly low SO2 content, requiring a large gas handling system for acid production. On the other hand, there are currently four commercial pressure oxidation plants treating refractory gold ores (McLaughlin, Mercur, Getchell and Goldstrike) and three treating concentrates (Sao Bento, Porgera, Campbell). One other concentrate oxidation plant is being constructed (Con), and several more are being considered.

Jan 1, 1992

By David Martin Menne

In a small tank, slurry is passed through the high shear impeller zone with small time intervals, and a large proportion is regularly exposed to air at the surface, and at relatively high shear rates. This accounts for significant differences in the performance of large and small tanks. It is preferable to derive data where possible directly from an operating plant rather than applying data generated in small tanks where allowances must be estimated for the above differences [and where slurry aging and often substantial cooling compared to hot freshly milled ore further distorts results]. Various measurements have shown that many gold slurries can suffer extreme variability, as streamers of bypassing material or boules of hold-up periodically condstitute the instantaneous discharge from a tank - the relatively high Yield stress of slurries [around 1 to 10 Pa] causes very incomplete homogenization of slurry in any tank, the worse the larger the tank and the more viscous the slurry. To provide a background for this subject, this monograph presents leach and adsorption models based on the fundamental physics and chemistry of these processes, and includes quantitative discussions of factors which can lead to deviations on scale-up. The Throughflow model which avoids the need for such alowances is then presented, as well as a Computer Programme applying this model, and which allows direct calculation of the effects of:

Jan 1, 1995

By Kenneth S. Johnson

Western Oklahoma, with an estimated 48 billion tons of minable gypsum, has one of the largest reserves of high-purity stone in the United States (Figure 1). Gypsum beds of the Permian Blaine Forma¬tion are 10 to 30 feet thick in the southwest and northwest regions, and the Permian Cloud Chief Gypsum is 20 to 90 feet thick in the west-central region (Ham, 1962; Ham and Curtis, 1958; Scott and Ham, 1957). Republic Gypsum Company, in the southwest part of the State, is Oklahoma's second-largest gypsum producer. Since opening its plant in 1964, the company has steadily increased production and now accounts for about 15 percent of the State's annual output. The plant and quarry are 15 miles west of Altus at Duke, a small commu¬nity on the Hollis and Eastern Railroad in northwestern Jackson County.

Jan 1, 1970