Search Documents

By H. Huang, R. N. Gow

"Previously, Gibbs’ phase rule was applied to mass-balanced EH-pH diagrams for the Cu-As-S-H2O system. Diagrams were generated using the stoichiometry of enargite as a basis. In this study, the calculations were expanded to cover the stoichiometries of three other Cu-As-S minerals (tennantite, sinnerite, and lautite) and compared to enargite. Stability regions within the resulting EH-pH diagrams were found to change with stoichiometry such that a particular mineral would predominate if its stoichiometry was used in the calculation. Solution speciation was also found to vary, with thioarsenate being the best example. This stoichiometric effect helps to explain results reported in the literature and would be difficult to realize if it were not for mass-balanced calculations. INTRODUCTION A comprehensive thermodynamic review has recently been conducted on the aqueous copper-arsenic-sulfur system (Gow et al., 2014a-d). The free energies of over 100 species were collected from various authors and thermodynamic databases to produce mass-balanced EH-pH diagrams, using the thermodynamic equilibrium calculation software, STABCAL (Huang, 2014). The full database was listed and discussed by Gow et al. (2014A). Resulting diagrams were generated for enargite and confirmed with Raman spectroscopy using bulk mineral electrodes in order to identify reactions spectroelectrochemically. Theoretical calculations agreed well with the experimental results under alkaline conditions (Gow et al., 2014a), acid conditions (Gow et al., 2014b), and alkaline sulfide leaching conditions (Gow et al., 2014c). In this study, additional mass-balanced EH-pH diagrams are generated by changing the copper-arsenic-sulfur stoichiometry from enargite (Cu3AsS4) to tennantite (Cu12As4S13), sinnerite (Cu6As4S9) and lautite (CuAsS). Regions for the thermodynamically stable species are shown to change with the four different mineral compositions. Potential leach conditions, both for co-dissolution and selective dissolution techniques, were examined for differences in predominant species according to changing copper-to-arsenic ratios, sulfur compositions, and sulfur oxidation states."

Jan 1, 2015

By Richard C. Holmquist

Some of you may be old enough to remember -- as I do -- the early days of World War II. A highly prepared, well-equipped Japanese striking force had moved like lightning across the South Pacific islands and Southeastern Asia. As the invasion force pushed its way down the Malaysian Peninsula, Singapore stood serene and beautiful, protected by its natural moat of water, busy as ever with its commercial pursuits. One can see its captains of trade and industry now, sitting com¬fortably on the veranda of the "Singapore Country Club", sipping scotch between cricket games, convinced that the weary, logistically extended Japanese force couldn't possibly cross over to their island which had been so secure for a hundred' years or more. No need to remind you what happened. The brave men in their ships at sea and in the gun emplacements ashore were hopelessly out-gunned and out-maneuvered.

Jan 1, 1979

By T. C. Page, P. C. Gibson, M. A. Miller, J. D. Sell

[The Yarnell gold deposit in the Weaver mining district, Yavapai County, Arizona, occurs in a structurally controlled, hydrothermally altered zone in a 1700 Ma granodioritic intrusive. Both potassic and sericitically altered rocks around and above the low-angle, northeast striking Yarnell fault are known to host economic gold mineralization. A wider envelope of weakly-propylitic altered rock also occurs in this area. During mineralization, strong sericitization accompanied several stages of quartz (±adularia) veining, stockwork formation, localized silicification and potassic replacement, in association with deposition of specularite, pyrite (now oxidized) and gold. The footwall of the fault is also sericitically altered but poorly mineralized. Mineralization along the Yarnell fault continues both northeast and southwest from the main deposit, although the thickness of the zone and associated alter avian envelope diminish away from the orebody A sample of undo formed illite taken from the Yarnell fault zone was K/Ar dated at 69 + 1.6 Ma. This date reflects a minimum age for both mineralization and latest movement on the fault. Gold mineralization is accompanied by modest increases in Ag, As. Cu and Mo content. Both CO2- and H2O- rich fluid inclusions were studied and suggest mesothermal pressures and temperatures of formation for the deposit. Ninety-six reverse circulation holes and four diamond drill holes outline a bulk-minable mineral reserve of'4.1 million tons at 0.051 oz of Au per ton. An additional 2.7 million tons at 0.017 oz of Au per ton occurs in a low-grade zone above and subparallel to the main mineralized zone. Total calculated mineral inventory stands at 6.8 million tons at a grade of 0.038 oz of Au per ton, with a waste-to-ore ratio of 1.45:1. Column leach tests indicate that cyanide heap leach gold recoveries should exceed 70%.]

Jan 1, 1994

By D. A. Robbins

Remote sensing for environmental measurements is already being used. Aircraft-mounted imaging spectroscopy has been used to evaluate historical mining operations, as well as active mine sites. To the extent that remote sensing can provide more sensitive, cost effective and timely monitoring potential, the technology is of interest to the industry. Questions, however, remain about the application and validation of the data and concerning the availability of the technology in the private sector. This paper discusses some of the potential uses, benefits and concerns related to remote sensing. And it discusses efforts to monitor the technology's development.

Jan 1, 2000

By T. J. Cox

The Red River is located within the Sangre De Cristo Mountain Range in northern New Mexico. An approximate 12-mile segment of the river from the town of Red River to the village of Questa (Questa) includes several hydrothermal alteration zones. Alteration ?scars? formed as a result of rapid chemical weathering and physical erosion of pyrite-rich hydrothermally altered rocks. Storm water runoff from the scar drainages contributes metal-laden, acidic water to the river and creates a visible plume of discolored water in the river. Acidic runoff reduces the river pH from 7 to the mid 3s for at least 2 hours during large storms and the low pH water continues downstream. Runoff from scar drainages increases some metal concentrations in the river from below chronic ecological criteria to as much as two orders of magnitude greater than acute ecological criteria, and results in acutely toxic conditions for macro-invertebrates. A general improvement in the river?s water quality occurs downstream due to dilution from tributary inflow from non-mineralized watersheds, the natural buffering capacity of the river, and storm water controls at the Chevron Mining Inc. Questa mine.

Jan 1, 2011

By F. N. Earll

4.1 – DEFINITIONS 4.1.1-MINERALS, ROCKS, ORES AND NONMETALLIC MINERALS F. N. EARLL A mineral is a naturally occurring inorganic element or compound. Most minerals are distinctly crystalline in habit, and many commonly occur in well-formed crystals or crystalline aggregates, but a few species are characteristically amorphous or noncrystalline. Nearly 2,000 mineral species are now recognized but, perhaps fortun¬ately, a rather large proportion are rarely encountered. Even so, the application of modern mineral-detection and identification techniques reveals the presence of surprising numbers of mineral species, even in deposits of outwardly simple mineralogy. A rock is an aggregate of grains or crystals of one or more minerals. Some rocks are essentially monomineralic. Thus, limestone consists largely of the mineral calcite, and many sandstones are dominantly quartz. Most rock varieties, however, contain a number of mineral species, and their classification or identification depends upon the minerals present, their relative abundance, and such factors as rock tex¬ture and origin. Ore is defined as an accumulation or deposit of one or more minerals that can be exploited at a profit. The profit criterion commonly is taken somewhat liberally, however, for, although always present, the specific mineral content that constitutes a viable product is transitory. The term ore, usually, but no longer consistently, is restricted to the description of mineral deposits that are of value for their metal content. Nonmetallic deposits, although similar to metallic ores in many respects, generally are valued for the minerals or compounds present, as with rock salt (halite), rather than for individual contained elements, though such minerals as elemental sulfur are of much value. 4.1.2-ROCK TYPES F. N. EARLL Rocks arc grouped tinder three broad headings: (1) igneous rocks formed by the crystallization of magma; (2) sedimentary rocks formed by surface processes of weathering and deposition; and (3) metamorphic rocks, which may have been derived from either of the foregoing, but have undergone important physical and/or chemical changes through the application of heat or pressure, or both. The three groups can he further subdivided for convenient reference. Thus, igneous rocks are described as being abyssal or plutonic if formed at great depth, hypabyssal if formed at intermediate depth, and extrusive or effusive if formed at or on the earth's surface. The sedimentary rock group is similarly subdivided into clastic sediments and chemical precipitates. The clastic sediments form by deposition of preexisting minerals that were released from their place of origin by weathering and were transported to their point of deposition as discrete grains

Jan 1, 1973

By J. L. Arola

Since start-up of fluxed pellet production in August: 1987, the Minorca Mine has made a number of process changes to improve pellet quality and productivity. Quality improvements include: 1. Installation of a contraction t:ester. 2. Installation of on-line calcium and silica analyzers. 3. Process autocation changes. Productivity improvements include: 1. A second fluxstone storage bin and feeder. 2. A new vacuum pump and disc filter. 3. A filter aid addition system. 4. Enclosing the filter cake reclaim feeder. 5. A new grate bar cleaner.

Jan 1, 1989

By C. D. Kuchera

Ore crushing facilities at the Phelps Dodge Morenci Reduction Works became operational in January of 1942. This plant, with a capacity of 25,000 tons per day, was part of a project started some five years earlier with development of the Morenci Open Pit Copper Mine. In the following year, World War II's heavy copper demands prompted an 80% expansion in concentrating capacity to 45,000 tons per day resulting in a doubling of the secondary crushing plant. In the late 1950s and early 1960s, grinding capacity was again expanded to the present 60,000 TPD. This time the then 20 year old crushing plant was obliged to meet a 20% increase in production demand with no additional equipment. The ore, principally a medium hard monzonite porphyry, is dumped from 40 yard rail cars into an ore pocket over the primary crusher at a rate of approximately one car per minute. The primary crushing flowsheet, Figure 1, has remained essentially unchanged over the years. Equipment consists of a 40 by 16 foot grizzly set on a 40° incline and having 6" openings, a 60" gyratory crusher nomin¬ally set at 62" + 1" on the closed side and two 72" by 38' panfeeders which load crushed ore and grizzly undersize at a rate of 4,000 tons per hour onto a twin 54" belt conveyor system for delivery to the coarse ore bin. Ore is distributed across the bin by two single side discharge tripper cars. Bin capacity is extremely limited at 23,000 tons of which only 12,000 is available or "live".

Jan 1, 1975

By N. Duru

"Gravity concentration is still a challenging area in the mineral industry. This is mainly because of the fine size valuable mineral losses to the tailings during its application. But the recent developments in centrifugal separation methods and their mutual application with conventional separation techniques has increased mineral recoveries. In this paper, field application of conventional gravity separation methods with the combination of 2” diameter hydrocyclone cluster unit and a multi gravity separator (MGS) was discussed. Additionally, particle size distribution and chromite content of the plant streams is presented and initial laboratory test results were compared with the actual plant data throughout the paper. As expected, field data showed derivations from the laboratory tests but the combination of MGS and conventional gravity separation techniques resulted in gravity separation of -0.1 mm chromite particles. INTRODUCTION The purpose of this mineral processing plant project was to investigate the possibility of upgrading chromite ore from 12% to 48% Cr2O3 and having final tailings assay as 2% Cr2O3. For this reason, initially a set of laboratory gravity separation studies were conducted to evaluate the performance of combination of 2” diameter hydrocyclone cluster and multigravity separator. After obtaining successful results from the laboratory work, a feasibility study was initiated. Economical results of the feasibility study showed that an achievable high net present and return on investment values. Following the investment decision; engineering, equipment procurement, construction of the processing plant was completed in eighteen months. This paper focuses on the initial laboratory test work results, operational data of the 2” diameter hydrocyclones and MGS units; resulted chromite recoveries. Processed ore has the chromite associated with serpentine and olivine minerals. The chromite particles are generally in round shapes with sizes between 50 µm to 1600 µm and average size of 450 µm. The microscope images of the chromite and associated formations are presented on Figure 1.Chromite is formed in mixture with iron oxides, with varying amounts of magnesium, aluminum. The average chemical composition of the representative drill core samples of the ore deposit is given on Table 1."

Jan 1, 2017

By Dae S. Young, Steven F. Hoerger

The geostatistical method of indicator kriging (IK) was extended to analyze two-dimensional distributions of rock joint orientations. The IK method provides a non-parametric approach for spatial analysis of local probability distribu- tions. By taking into account the spatial correlation of rock joint outcomes and the relative geometry between estimation unit and samples, the IK method provides optimum, spatially conditioned estimates. The estimation method was tested by comparing distributions of actual mapped rock joint orientations with their corresponding kriged estimates. The comparisons show the unbiasedness and accuracy of the non-parametric approach for estimating local probability distributions.

Jan 1, 1986

By Philip Antunes, A. E. (Tony) Reschke

"INTRODUCTION Tunnel Boring Machine (TBM) operations require the injection of material into the annular tail voids as the machine advances ahead of the segmental concrete lining. This annular gap is created because the cutting diameter of the TBM has to be larger than the outer diameter of the concrete segments of the tunnel lining. Fundamentally, the two basic types of annular grout are thick, concrete like mortars and thin, mobile, two-component grouts. While some European countries seem to still favor the concrete like mortars, from a global perspective it is now the two-component type grouts that dominate the industry. Two-component type grouts are comprised of an “A” component grout (typically cement, flyash, bentonite and a retarder/stabilizer) and a “B” component accelerator (sodium silicate or water glass as it is sometimes known). They are thus sometimes referred to as A/B type or bi-component grouts and were pioneered by the Japanese over 30 years ago. They offer a host of operational benefits over thick mortars, such as reduced settlement (Feddema et. al., 2001), effective penetration of the void space, with less energy, and reduced strain on the segmented linings (Robinson et. al., 2007). Two-component grouts are highly mobile and can be pumped many kilometers. The use of a retarder/stabilizer can also extend the shelf life of the “A” component grout for several days while the early strength of the accelerated grout stabilizes the ground and supports the segmental liner almost immediately. The batch plants that prepare the two-component grouts use one of two possible mixing methods for preparing the “A” component grout. The simplest plants use paddle type mixers and numerous tunnels worldwide have been successfully grouted using this technology. However, a superior type of mixer is available, namely the high shear colloidal mixer. Keller Colcrete successfully pioneered the development of the colloidal mixer back in 1937 and for over 75 years colloidal mixers have been internationally recognised as the most efficient method of mixing cement based grouts (Houlsby, 1990). These mixers are used in grout preparation for radioactive waste encapsulation, hydro dam grout curtains, soilcrete jet grouting, soil nailing, and numerous other geotechnical applications. In tunnelling, these mixers are also used for ground treatment, compensation grouting and for the preparation of bentonite lubrication for pipejacking. It has been only within the last decade however that these high-shear colloidal mixers have been adapted for use in the preparation of two-component grouts."

Jan 1, 2016

By Jim Morris

This paper will describe the excavation of a 5.4 percent decline at the Montanore Project for Noranda Minerals Corporation. The 5.3 m by 4.9 m tunnel was driven to provide access for the exploration of a major copper-silver deposit. Soft ground and conventional drill-blast mining were used on the 4,270 m tunnel. Ground support consisted of steel sets and concrete in the soft ground and pattern rockbolts providing the majority of the rock support. A special feature of the project was the use of conveyor haulage in conjunction with the drill-blast excavation.

Jan 1, 1993

By Madeline Mello, Michael Low, Nick Karlin, Bryce Scofield

The LA Effluent Outfall Tunnel is the first tunnel in the United States to incorporate post- tensioning into the precast segmental lining. Several unique components were integrated to ensure that the post tensioning could be carried out successfully in the tunnel, even concurrently with the TBM excavation. This also required the development of new processes both in the casting facility and in the TBM to ensure that the almost 3,700 rings could be successfully manufactured, threaded, stressed, and grouted. This paper will discuss the material selection, fabrication, and installation of, as well as lessons learned from, this first in country tunnel lining.

Jun 23, 2024

By R. F. Pearce

The paper in based on laboratory and pilot plant investigations which led to the development of a series of processes for production of high purity metals from nickel-copper-cobalt mattes of a wide range of composition. The selection of ammonia pressure leaching or acid pressure leaching for various mattes is discussed. This is followed by discussion of various methods for leach solution purification and metal separation. The metals of high purity are produced by reduction with hydrogen from purified solutions. Examples are given of complete flowsheets for a number of mattes. Drawing upon those examples, general principles for the selection of the most suitable treatment process for particular material are outlined. Under certain circumstances, those processes may replace part of the pyrometallurgical treatment and all of the electrolytic refining steps which are customary in the treatment of nickel-copper-cobalt mattes.

Jan 1, 1959

By Wayne Wride, Amy Lamb, Debra Sonntag

In today's "information age", we have the ability to collect volumes of data about a company's performance. The challenge is to turn that data into information employees can understand and use to fine-tune equipment, modify work processes, and ultimately manage production. Software programs have increasingly given end users control over what data is used and how it is presented. Kennecott has implemented an information system capable of collecting and storing data at the primary level. This enables plant personnel to transform historical data into information for action. Kennecott plans to expand its data collection and use trending and reporting capabilities to move toward a fully optimized operation.

Jan 1, 2000

By J. G. Groppo

Laboratory settling and filtration testing was conducted on wet processed fly ash in order to determine the applicability of conventional dewatering techniques to reduce the moisture content prior to drying. Settling tests showed that acceptable clarity (<1.5 g/l suspended solids) could be achieved after as little as 6 minutes of settling. After settling to a consistency of 40 weight % solids, continuous laboratory vacuum filtration testing produced a cake containing below 20% moisture with throughput exceeding 150 lb/ft2/hr.

Jan 1, 1997

By D. Park, V. Gall

The three-dimensional finite element technique combined with a progressive failure approach were used to simulate stress distributions in a complete mine section that occur in response to a longwall mining operation. Due to the availability of a Cray supercomputer, a large-scale, three-dimensional, finite-element model was developed for the analysis. The Hoek-Brown failure criterion, which describes a realistic behavior of rock masses, was used for the simulation of progressive failure. A comparison of calculated and monitored stresses in the mine has shown that the model gives a good representation of stresses in the mine structure.

Jan 1, 1992

By Yuting Xue, Xin Li, Ihsan Berk Tulu, Gaobo Zhao, Deniz Tuncay, Mindi Ruan

Most coal mine roofs in the Appalachian region consist of laminated shale, which is prone to brittle failure. Accurate modeling of shale roofs is vital for studying cutter failures of these shale roofs, and ordinary and formational bedding planes play a significant role in the response off the shale roof to mining-induced stresses. This paper presents a robust method for constructing three-dimensional shale roof models using limited borehole cores and leveraging image processing techniques. The approach begins with image extraction from shale cores. Then, we extract the portions that feature the core and employ image-stitching techniques to merge them seamlessly. Once the images are stitched, they are duplicated horizontally and merged to create a cross-sectional plane image representing a shale roof. This roof cross-sectional plane image serves as an input to our proprietary Digital Image Processing (DIP) algorithm, which is adept at extracting ordinary bedding planes (interfaces that represent color transitions between a single shale unit). The extraction process involves transforming discrete core points (ordinary bedding plane pixels) into continuous lines representing ordinary bedding planes. Finally, extending this method into the third dimension, the model is further extrapolated to form a comprehensive three-dimensional shale roof. Through this process, the geometry information of ordinary bedding planes can be extracted for each type of shale in cores, including sandy shale, gray shale, dark shale, etc. This work bridges the gap between limited core data and comprehensive 3D geological modeling, offering valuable insights into identifying and quantifying the variations in different shale roof geologies.

Jun 25, 2024

By R. J. Mirville

Flocculation is an important step in the treatment of coal preparation waste waters. The effects of polymer charge and molecular weight and solution pH and ionic strength on the adsorption and flocculation characteristics of a series of polymeric flocculants on some typical waste water constituents have been studied experimentally. The results indicate that the nature and extent of flocculation are strongly system-dependent. For the case of coal, both adsorption and flocculation behavior can be correlated with the polymer conformation in solution. For the mineral constituents, on the other hand, adsorption and flocculation depend also on the surface properties of the solid.

Jan 1, 1979

By James M. Baylor

Ladies and geltlemen, it is indeed a privilege and a pleasure to be here in Denver with you. I want you to know too I&apos;m not a stranger out here. Golden, Colorado is the headquarters of A. T. Massey Coal Company&apos;s Western Division, headed by Vice President, Gregory H. Hoyl. I also have a very close friend and fraternity brother who works and lives in Denver so I could talk on and on about this area and our western coal properties, but it&apos;s Massey&apos;s coal terminal business I&apos;m to focus in on today, and that&apos;s a horse of a different color. So on to the subject of my address: MASSEY COAL TERMINAL INVOLVEMENT As I have stated on other occasions, A. T. Massey Coal Company, for better or for worse, is in the coal terminal business.

Jan 1, 1981