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By M. Frenzel, D. Ebert, K. Bachmann, A. D. Renno, R. Möckel, J. Gutzmer, J. Krause

With the increasing demand for metalliferous and mineral raw materials, and consequent depletion of the global natural resource base, the possible utilization of secondary raw material sources is receiving more and more attention. In the present study, we present results from a detailed vanadium deportment study of three basic oxygen furnace slag (BOS) samples known to containing elevated bulk concentrations of vanadium (V). Complementary analytical methods that were used to quantify the abundance and composition of V-containing phases include SEM-based automated mineralogy, Xray fluorescence (XRF) analysis, and X-ray powder diffraction as well as electron probe microanalysis. The vanadium deportment was quantified using Monte-Carlo simulations of the data obtained from automated mineralogy and electron microprobe analysis. The total V concentrations identified by XRF are between 1.7 and 2.2 weight percent V. The most important hosts of vanadium are larnite-, brownmillerite- and portlandite-solid solutions. In two samples, calcium carbonates also significantly contribute to the V deportment, while wuestite, lime and native iron do not contribute significantly to the vanadium deportment. A thorough consistency check identifies considerable uncertainties in the density of the Vbearing phases as the most likely reason to explain remaining discrepancies between measured and calculated V values.

Aug 1, 2024

By Xinyang Yu

The flotation of diaspore, kaolinite, pyrophyllite, illite and the diaspore-kaolinite mixture were studied with a new cationic organosilicon quaternary ammonium collector entitled QAS222. The acting mechanism of the collector with the four minerals was analyzed by Zeta potential measurement and FT-IR spectrum analysis. The results indicate that the QAS222 was effective in the reverse flotation of the diaspore-bauxite mixture of different Al2O3 -to-SiO2 mass ratios (A/S ratio) at an optimum pulp pH of 11. The potentials of the four minerals increased when they were conditioned in the QAS222 solution; however, the potentials of the three aluminosilicate minerals increased faster than that of the diaspore, especially at pH>9. Furthermore, they were positive in a wide pH range, indicating that QAS222 has a strong adsorption on the surface of the aluminosilicate minerals and thus that these minerals can be floated. The FT-IR spectra analysis further indicates that, besides electrostatic adsorp-tions, formation of the hydrogen bond and ammonium absorptions, chemical adsorptions occur between QAS222 and the aluminosilicate minerals, which allow for the QAS222 to be strongly adsorbed on the aluminosilicate minerals. However, these reactions between QAS222 and diaspore at pulp pH=11 are weaker than those of the aluminosilicate minerals. Thus, surface adsorptions cannot be formed effectively, resulting in reduced floatability.

Jan 1, 2010

By N. Zouridakis

Radon is an established lung carcinogen and remains the most important environmental radiation exposure. It was estimated that inhalation of radon and its short-lived decay products accounts on average for about one half of the effective dose equivalent from all natural sources of radiation. Radon contained in household water can transferred into room air as a result of agitation or heating. An indoor air concentration of 400 Bq/m3 is obtained if the radon concentration in household water is 4 kBq/L. A typical concentration of radon in ground water is about 1000 times lower than this concentration but sometime elevated concentrations of some kBq/L in ground water are reported. In this work a Liquid Scintillation counting system is used to obtain fast and accurate measurements of radon (222Rn) in water samples from Argolida, Greece.

Jan 1, 2007

By W. F. Visser

The growing availability of information and data analysis capabilities provides new opportunities for improving the performance of operations. By using real-time measurements and artificial intelligence, it is possible to respond faster to changing conditions, while accurate and timely information permits the rapid evaluation of changes and fast business improvement decisions. This paper presents a blueprint for system alignment, organizational design and management practices to leverage these developments in performance-driven operations management in mining and mineral processing.

Information Technology has addressed those problems unique to senior management in the mineral industry. In general, these problems are those concerned with decision-making. Peter Drucker in his discussion of making effective decisions identifies five phases: (1) define the problem, (2) analyze the problem, (3) develop alternate solutions, (4) decide the best solution, and (5) convert the decision into effective action. The scope of the chapter by Guernsey addresses the first three phases which provide input to the decision-maker. The decisions to be made relate, in most instances, to the economics related to a mineral property or process. Computer models have been designed to generate these economic and financial evaluations. No one model is appropriate to the solution of all management's problems. In this chapter several applications are identified and summarized; a model for the economic evaluation of a mineral property is described in greater detail. The implementation of such models is dependent on the unique needs of management.

Jan 1, 1979

By D. B. Desai, J. T. Waggoner, J. S. Hill, R. R. Redd, S. J. Klein

The 13 km (8 mile) long Riverside Badlands Tunnel is planned for construction starting in 1998. Extensive geotechnical investigations indicate that the 3.7 m (12 ft) finished diameter tunnel will be excavated through soft ground, weak sedimentary rocks, and heavily fractured metamorphic rocks. Nearly 80 percent of the tunnel will be excavated beneath the groundwater level. Tunneling conditions are expected to range from raveling and over-stressed in the sedimentary rocks, to blocky and seamy/crushed with some squeezing in the metamorphic rocks. Two alluvium reaches will require dewatering. The variable and interspersed ground conditions are expected to be a key factor in selection of tunneling methods, equipment, and initial support.

Jan 1, 1997

By Albert L. St. Peter

The "Old Reliable" four million pound blast in March of 1972 marked the opening, as far as is known, of serious efforts to commercialize the In Situ concept. That was a coyote shot, and it was followed by three blasts at McAlester Fuel's "Zonia" operation which were surface hole shots. As the only individual who had a principal part in all four shots, it seems to be appropriate to present experiences in the developments and evolutions of the in Situ method of ore extraction. Some of the problems will be described, along with proposals for management of such projects in the future.

Jan 1, 1976

By W. Hu

Gravity concentration has been the main method for tin ore beneficiation, based on the significant difference of density between cassiterite and gangue in the tin ore. However, with the exhaustion of rich and coarse reserves, the proportion of tin distribution in slime be-comes as high as 50 to 70% and has a size range of -19 urn. In some sulfide tin ore, most of the tin is of the minus 10-urn size fraction, and thus slime processing has gained importance in tin ore processing. Some innovations are being developed, such as the centrifugal cone separator, belt concentrator, slime table, B-M separator, and slime flotation. Direct flotation with tolyl arsonic acid has been practiced with success.

Jan 1, 1989

By D. A. Newman

A longwall chain pillar is comprised of two distinct zones, a solid elastic core enclosed by an exterior of failed or yielded coal. For the purpose of pillar design, the ability to delineate the extent of pillar yielding and correlate the yielding with the applied pillar load is of fundamental importance. A study was initiated on a longwall section of a West Virginia mine to: (1) delineate the location of the elastic core-yield zone boundary, (2) examine the stress distribution within the pillar, and (3) quantify pillar stability as the longwall face retreated toward an instrumented pillar. A US Bureau of Mines sonic velocity probe was used in conjunction with vibrating wire stress meters to define the elastic core-yield zone boundary and the migration of vertical stress toward the pillar core. The extent of the yield zone as determined by field results is compared with the extent of the failed zone as predicted using a series of equations developed by Wilson.

Jan 1, 1988

By J. P. Sieverson

The Comprehensive Environmental Response, compensation, and Liability Act (CERCLA -commonly referred to as Superfund) was passed into law in December 1980 in the wake of such incidents as Love Canal and the Valley of the Drums. Superfund was originally perceived as a way of cleaning up spills of hazardous substances and/or cleaning up abandoned hazardous waste dumpsites. In February 1981, Michael Cook, EPA deputy assistant administrator for hazardous emergency response, called Superfund "a tremendously powerful law. It could revolutionize the way the environment is protected, but we certainly don't intend to realize the full potential of the law for some time." These words have proven prophetic for Asarco's East Helena Smelter.

Jan 1, 1988

By Joel Lööw, Jan Johansson, Lena Abrahamsson

In this study, we try to illustrate what new technology can mean for the individual miner. We formulate the notion of Mining 4.0, where we attempt to create an image of how the future might look from a miner’s perspective and how mining companies might navigate their way to a future that works for all miners. 

By James Warren Andrews, Philip C. Nyberg

The regulation of exposure of underground personnel to radon and its daughter products has significantly changed since the 1950's. The U.S. Bureau of Mines - Mining Enforcement and Safety Administration (MESA) - Mine Safety and Health Administration (MSHA) sequence of standards and regulations have lowered the maximum allowable occupational exposure and now the new Environmental Protection Agency (EPA) National Emission Standards for Hazardous Air Pollutants, effective in 1990, have further regulated uranium mine emissions. Under the authority of Section 112 of the Clean Air Act (42 U.S.C. 7401), the EPA has set regulations for the control of radon (Rn-222) emissions from underground uranium mines as well as other sources. Since the venting of radon from the mine atmosphere to the outside air is a major component of the miner's protection, and since this is the first quantitative effort to limit gaseous mine emissions to the environment, it was felt that it would be useful to examine the implementation of the EPA regulation at working mines. The concern was not only for determining compliance with the regulation but also for observing what effect the rule might have on mine air quality and thus on worker exposure. The regulation is stated in terms of the maximum permitted radiation dose to the closest potentially exposed individual, which is calculated from a computer program supplied by EPA and radon emission rates measured by the mine operator. Relative proximity to nearby populations determines the allowable magnitude of mine exhaust ventilation emissions. For some mines this is a serious operational constraint.

Jan 1, 1991

By V. F. Swanson

M&MP, Volume 6, No. 4, November 1989, pp. 190-196

Jan 1, 1990

By D. C. Sisti

A paper was presented during the 1970 SME Fall Meeting on the Stinson Preparation Facilities by representatives of Beaver Creek Consolidated Cool Company and Heyl & Patterson, Inc. This paper summarized a combined approach to development of a flow diagram and selection of cleaning equipment required to produce a uniform metallurgical coal at maximum recovery with special emphasis on sulphur reduction. These facilities were located in the Elkhorn. Coal Fields of eastern Kentucky and, in particular, the area of Wayland, Knott County, Kentucky, where approximately forty-five- million tons of Elkhorn No. 3 coal could he recovered. The facilities incorporated a Bradford Breaker for reduction of the ROM coal to minus 1-1/2 x 0, 6000 ton-raw coal storage, preparation plant, water clarification and thermal drying facilities, clean coal storage and a 4000 TPH unit train loading facility.

Jan 1, 1973

By Hans W. Brodbeck

The Advisory Conference on Tunnelling of the OECD, held in Washington, D.C. in June 1970, has established the following definition: "Tunnelling refers to the construction by any method of a covered cavity of predesigned geometry whose final location and use are under the surface, whose cross-sectional area is greater than 2 square metres". (1) The definition makes clear that the term includes all types of underground construction, be it in hard rock, soft ground, under mixed conditions, underwater, etc. Small-sized tunnels in rock therefore constitute but one part of the tunnelling scene. With an ever-growing urbanisation taking place in industrialized as well as developing countries, the demand for small-sized tunnels is, however, rapidly increasing and requires a far-reaching mechanization of excavation and support functions. This trend is accentuated by the fact that small-sized tunnels are far more labor-intensive than large ones, and, with wages raising at a much faster rate than costs for plant and equipment, this will accelerate the introduction of new tunnelling systems. SMALL-SIZED ROCK TUNNELS The main field of application for a tunnelling system for small sized hardrock bores is thus defined. It is in fact the numerous relatively short tunnels required under cities and other populated

Jan 1, 1974

By Karl P. Norrena, Clayton V. Deutsch

Ore and waste cannot always be visually separated. The distinction between ore and waste may need to be made on the basis of blasthole sampling. Hand drawn dig limits or computer-generated contour lines do not account for uncertainty, economics or equipment. Geometric methods for interpreting grade information such as the polygonal or triangulation methods share the same limitations as contouring. Geostatistical techniques exist for the realistic modeling of grade variations and uncertainty. Decision analysis techniques exist for the binary classification of ore, and waste blocks in the presence of this uncertainty. Block-by-block classification is not enough; mining equipment cannot exercise free selection of blocks. There is a need for procedures to determine optimal dig limits that account for (1) the uncertainty in the grades, (2) the economics of risk-qualified decision-making, and (3) the ability of the mining equipment to dig to specific limits. This paper presents a procedure for optimal determination of dig limits that account for these constraints. Simulated annealing (SA) is used with modest computational requirements because the number of variables is relatively small. The solution of the optimization problem is dig limits that maximize profit under multiple constraints. The method is illustrated with different constraints and tested against hand drawn dig limits in a "Dig Limit Challenge," which illustrates the efficacy of the new method.

Jan 1, 2002

By Frank E. Dalton

The Metropolitan Sanitary District of Greater Chicago (MSDGC) serves an area of approximately 860 square miles and collects and processes used water from the city of Chicago and 116 surrounding communities. As a public agency, the MSDGC -Serves a population equivalent to 10 million people which is composed of 5.5 million people and an industrial wasteload equivalent to an additional 4-1/2 million people. -Provides 400 miles of intercepting sewers and tunnels ranging in diameter from 12 inches to 24 feet. -Operates 71 miles of navigable waterways and channels conncecting the Atlantic Ocean and the Great Lakes with the Gulf of Mexico and 6,000 miles of inland waterways. -Maintains the largest water reclamation plant in the world. -Processes 1,380,000,000 of used water daily and removes approximately 1,000 dry tons of organic solids each day. -Has spent approximately 700 million dollars in capital improvements to date, and will require expenditures in excess of 3 billion dollars (including over one-half billion dollars in tunnels) to meet existing federal and state water quality standards.

Jan 1, 1974

By Shosei Serata

In the past, salt cavities for storage of liquid and gaseous fuels have been developed and operated using practical experience as a guide rather than rock mechanics principles and practices. Although many salt cavities are still operating satisfactorily. some of them are beginning to show various problems associated with long-term deterioration of the cavities. This paper describes a major breakthrough in the rock mechanics design of solution cavities which is the development and application of the REM computer simulation system. From the computer simulation analysis, the long-term deterioration process of cavities can be related to the basic parameters of rock mechanics design and the storage operations. The computer simulation system is also used for optimizing cavity design and operational specifications. This optimization technique is explained by its application to the three basic storage systems: 1) open dry storage system for liquids and solids 2) open wet storage system for liquids 3) pressurized storage system for gases, liquids and solids The effectiveness of the optimization technique is illustrated with some field examples by showing the direct interaction between the computer simulation system and field data of a test well including tectonic stress conditions, material property coefficients and geological anomalies.

Jan 1, 1974

By E. Kurt

The field of percussion rock drilling is subdivided into two areas of application; that which takes place on the surface and that which takes place underground. Surface drills are used in quarrying, highway construction, and maintenance work; underground equipment in mining and tunneling work. Two basic principles are involved in the operation of all percussion drills. First, the principle that reciprocates the impacting piston and second, the principle that causes the drill steel and bit to rotate. The back and forth motion of the piston is accomplished by a self-acting automatic valve that admits air alternately to each end of the piston (Figure 1). Drill steel and bit rotation is imparted by an integral ratchet mechanism (Figure 2) in the so-called "rifle bar" machines (Figure 1) or by a separate pneumatic motor in "independent rotation" drills (Figure 3). While rock drills are subject to all kinds of physical and operational abuse, they are most sensitive to faulty lubrication. Proper lubrication is the single most important factor in the longevity of a percussion drill.

Jan 1, 1970

By Peter W. Harben

Once considered the dowdy country cousins of the glamorous metallics, industrial minerals are shedding their old image. They are neither common nor easy and their time has come in an age of increasing specialization. Consider that of the 45 or so industrial minerals and rocks listed in [Table 1], almost three-quarters have ten or fewer significant suppliers (i.e., those individual countries contributing 2% or more of total world production); in more than half the cases, 85% of world production is accounted for by only five countries or fewer. Curiously, even materials that appear to be virtually ubiquitous like crushed rock and common salt have significant production vacuums. For example, there is a severe lack of sound aggregates along the US Gulf Coast and common salt production on a large scale is virtually absent in central Africa. These examples all underline the obvious, but acute truism that "The single most important fact about mineral resources is that they are not distributed equally over the world" (Flawn, 1966). Just as significant today is that human resources are not distributed equally over the world, and so arise some interesting commercial incongruities. In certain regions raw materials are plentiful but consumers are not, and without a market a mineral deposit is merely a geological curiosity. Elsewhere, there may be a market but no local raw material supply. For example, despite a huge market there is no or virtually no commercial production of chromite, diamonds, and manganese in the United States and Canada, nor phosphate rock, diamonds, rutile, and zirconium minerals in western Europe. In contrast, Australia with its small domestic market is the world's largest supplier of bauxite, diamonds, ilmenite, natural and synthetic rutile, and zircon; the same is true for South Africa which is a leading producer of chromite, manganese, diamonds, andalusite, ilmenite, rutile, and zircon (Table 2). In the commercial world, Nature's uneven distribution is counterbalanced by deep sea international trade.

Jan 1, 1994