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Clinoptilolite as a Low-Cost Solution to Remove Heavy Metals from Water in Mining and Mineral Processing Industry

Sep 13, 2010

By R. W. Baldwin

On page 309, column 1, the second equation should read: Ma-M1 = dlog_Pa M2-M1 d log P2

Jan 1, 1961

By Peter G. Kovalchik, Lawrence W. Scott, Thomas H. Dubaniewicz, Mark A. Fuller

Mine trailing cables operated above safe thermal limits can cause premature insulation failure, increasing electrocution and fire hazards. Previous U.S. Bureau of Mines Pittsburgh Research Center research showed that, under static test conditions, electrical current levels permitted under present regulations may not limit cable temperatures to less than the 90 °C rating of reeled trailing cable. Continuing research under the National Institute for Occupational Safety and Health (NIOSH) addresses thermal characteristics of reeled trailing cable under dynamic test conditions more representative of field conditions, where operators constantly reel in and pay out cable. This research is in support of efforts by industry associations and the Mine Safety and Health Administration to establish safety guidelines for cyclically rated reeled machines. This paper describes a unique approach to measuring temperatures within reeled cable under dynamic test conditions. Fiber-optic sensors embedded within the metallic conductors measure temperatures at 1-m intervals along the entire length of cable. Temperature measurements are reported to be accurate to within 1±° C. The test setup requires access to only one end of the trailing cable, allowing researchers to freely reel in and pay out cable while temperature measurements are made, simulating field conditions. Manufacture of a fiberoptic-embedded trailing cable is described, along with initial test results that indicate the fiber-optic approach is viable.

By Nikhil Dhawan, Shrey Agrawal

India’s most extensive renewable energy expansion program targets 280 GW of solar energy by 2030. Due to the massive generation of photovoltaic waste (expected 34,600 T by 2030), stringent recycling effort to recover metal resources from endof- life PVs is required for resource recovery, circular economy, and subsequent reduction in the environmental impact. The present study investigates the recycling potential of end-of-life silicon solar modules. The feed characterization reveals that most of the values in PV modules are concentrated in the frame (pure Al), Si wafer (72–84% Si, 9–12% Al, and 0.13–0.71% Ag), and electrical connections (Cu wire coated with Sn). The Si and Ag values in the feed were beneficiated using water fluidization, and concentrate with 90% Si and 2% Ag was attained in the underflow concentrate. Ag values were recovered in the form of AgCl by leaching in nitric acid and precipitation. After the purification step, the residue containing 99% Si can be further utilized to fabricate Si wafer and Al-Si alloy. The preliminary cost estimations suggest that the proposed process is economically viable for the recycling of solar panels with the maximum value generated from the AgCl precipitate followed by Al panels and Si wafers.

Nov 14, 2022

By F. Bonnet, J. Lehmann, H. Gaye

A review of thermodynamic information and models of slags, including associated software when available, is presented. The pertinence and accuracy of these models is discussed by comparison of their predictions for various slag thermodynamic properties with the available experimental data. Practical industrial applications will be illustrated by a literature review of the dephosphorization process of ferromanganese alloys and by the description of Ti behavior during silico-manganese alloys production. This latter example will show how the thermodynamic models have been used to propose a flotation treatment at low temperature to enhance TiC removal.

Jan 1, 2004

By Elli Nurminen

Keywords: Thermal conductivity of sulphates, flash smelting, heat recovery boiler, flue dust Accretions and build-ups in metallurgical heat recovery boilers decrease the efficiency of the heat transfer and may cause process shut downs. Transient plane source method (Hot Disk) has been applied to measure the thermal conductivities of the Copper Flash Smelting flue dusts. Thermal conductivities of copper, iron and zinc sulphates, and process flue dusts were measured. The results indicate that all the components are effective thermal insulators, having a thermal conductivity of less than 1 W/mK. Decreasing dust layer porosity has an increasing effect on thermal conductivity. Insulating layers on the boiler walls decrease greatly the heat transfer efficiency of the boiler. The gathered information will be used in CFD-modelling of the process, and in the process control.

Jan 1, 2005

By Padmavathi V. Sagi

In this paper, effect of cyclic loading on the behavior of a long, flexible, unrestrained vertical pile loaded laterally in soft clay is examined. For cyclic loading, the analysis is carried out using a new method for the construction of p-y curves and for static loading conditions, p-y curves proposed by Dewaikar and Poonam (2005) are used. An iterative analysis is employed with secant modulus approach using a matrix method known as moment area method developed by Sawant et al. (1994). For pile top deflection of 20% of pile diameter, the load values are computed for both static and cyclic conditions. The comparison of results with the field test results reported by Matlock (1970) shows a good agreement. A parametric study is further carried out to examine the effect of load eccentricity, pile embedment length, diameter and the number of cycles on the pile response. The results of this study are discussed in the paper.

Jan 1, 2006

By Carlos Del Castillo Whittembury

El presente texto señala el uso de la bioRemediación como principal técnica que permite la digestión de residuos orgánicos contaminantes de aguas, suelos y aires. En el caso del agua, su limitación está en el tiempo de mantenimiento (5 días) donde se necesita contar con tanques o pozas acordes con los flujos a tratar, así como el control periódico del sistema. sistema. En el caso de suelos contaminados, es una de las opciones más convenientes por la facilidad de aplicación y la capacidad del tratamiento para remediar. Finalmente, en el uso del aire, los sopladores con membranas porosas mejoran los niveles de oxígeno disuelto, empleando menor energía eléctrica, cuyo aspecto redunda en un menor costo de los tratamientos. En este sentido, se busca mostrar nuevas tendencias de tratamientos a fin de regresar a las condiciones originales las aguas, suelos y aires contaminados por residuos orgánicos, inorgánicos e incluso por hidrocarburos, las cuales están disponibles en el Perú.

Sep 12, 2005

By Wen Songlin

This paper presents an experimental program to investigate the behavior of a pile with wings under horizontal loads in sand at laboratory. The work focused on evaluating the lateral resistance behavior and the geometric effect of wing board on the horizontal resistance. Based on the measured data and observed phenomenon, the following behaviors have been observed: 1) A pile with wings is not only a powerful means to improve the horizontal bearing capacity of a pile foundation but also economy and feasibility; 2) The horizontal bearing capacity of a pile with wings increases with increasing of it?s wing board?s area; 3) The pile lateral capacity is also influenced by the wing board?s geometric shape. Under a certain soil and pile condition, there is a critical embedment depth of the wing board, which will yield the maximum horizontal bearing capacity. It was further observed that when the displacement of the pile head increases, part of the horizontal bearing capacity of the pile is developed by the so-called shaft?s anti-pulling capacity.

Jan 1, 2007

By V. T. McLemore

The mining industry is at a crossroad. To sustain our technically based society, demands for commodities are increasing, and exploration for these commodities is a must. The debate is between sustainable development and the status quo and begins with exploration, where it is determined if a mineralized area contains enough potential ore to be mined economically. Mineral deposits are relatively rare and depend upon certain natural geologic conditions to form and may not always occur in locations that are most suitable to society. Exploration can be compatible with environmental protection and social responsibility, but difficult challenges face the industry to develop a property that is environmentally, economically, and socially responsible.

Jan 1, 2004

By Y. P. Chugh

During late 2010, a scientifically founded water spray system was developed for continuous miners (CM) (Patent Pending) that reduces respirable dust exposure for miner operator by about 30%. It includes engineered sprays around the cutting drum, outer bit-ring sprays, chassis sprays and side cutter boom sprays. About 3.6 ? 4.5m (12-15 ft) behind these sprays is additional sprays that spatially cover the area between the CM chassis and the mine roof and ribs. The spray system uses approximately the same volume of water as currently used on CMs with similar operating pressures. An Illinois mine decided to implement these concepts on a CM during rebuild stage. Dust control performance of the rebuilt CM was evaluated using gravimetric sampling and real-time monitoring using multiple personal dust monitors (PDMs). The average results based on about 105 cuts show about 30% and 20% reduction in dust exposure for the miner operator, and the haulage unit operator. Visibility in the mining areas was also significantly improved. The coal company has already decided to implement the system on all their CMs.

Jan 1, 2012

By C. P. Mangelsdorf

Introduction The use of frequency of vibration measurements to determine tension has long been accepted by industries that use electrical or stranded cables of wire ropes in their operations. In contemplating how to determine the tension in chords of a roof truss, it seems almost inevitable that a similar approach should be investigated even though there are some important dissimilarities in physical behavior between a chord of a rod-type Birmingham truss and a stretched wire rope. While the dominant feature of both types of behavior is the existence of tension, the bending resistance of the vibrating truss chord cannot be ignored. And it is common to have attached to the chord, pieces of hardware (turnbuckles, extension sleeves, wedge boxes) that represent concentrations of mass not usually found in a vibrating wire rope. Analytical solutions to the problem of vibrating wires or beams can be found in the literature on vibrations (Timoshensko, 1955; Den Hartog, 1956). But in every case, at least one of the ingredients of the vibrating truss chord is missing. The presence of axial tension, or bending resistance, of concentrated masses and of end conditions peculiar to truss chords is a combination that appears not to have been dealt with before, although the techniques for dealing with it are commonly known. The purpose of this note is to report the results of a project to measure and calibrate such frequencies. The work was conducted by the University of Pittsburgh under the sponsorship of the US Bureau of Mines. Field observations Tests were conducted on 24 different truss installations. The first 18 trusses were installed in shale roofs above Kentucky No. 9 seam and Illinois No. 6 seam. The remaining six were placed against the competent sandstone over the Pocahontas No. 3 seam in West Virginia. Chord tension was determined by two electrical resistance strain gages, in series, applied diametrically opposite to one another on the rod before tensioning. Due to the combined effects of inexact gage placement, rod bending and residual torsion in the chord due to tightening, errors in tension as high as 1780 N (400 lb) were reasonably possible. Due to faulty soldering or damage, three of the first 18 trusses and one of the final six were rendered completely unreliable. In addition to strain, the first natural frequency of vibration was observed to the nearest 0.1 Hz. Dimensions recorded included the span between contact points at the bearing blocks (Fig. 1) and the locations and amount of excess rod and rod gap at the wedge box and turnbuckle, respectively.

Jan 9, 1985

By Roy Jennings

The Discovery Expedition of St. Charles, MO chose to build its two-story museum in the flood plain of the Missouri River, near the starting point of the Lewis and Clark Expedition. Should the lower level be inundated at flood stage, plans call for the replica riverboats to be moved by trailer to higher ground. The museum's design required an open span structure with heavily loaded footing or piles. Spread footings could not be used due to the compressible soil profile. The location, in a historical district, precluded dynamically driven piles. Sixty-three uncased Helical Pulldown Micropiles were driven to the bearing stratum to support the museum with minimum disturbance. There were no spoils to dispose of during construction and the piles were completed in eight working days with minimum impact to the environment and neighborhood. The maximum working load required was 84,000 pounds (374kN). Test results are given in the form of installing torque.

Jan 1, 2003

By Benjamin Smith Lyman

THE importance of topography to geology is so commonly underrated as to deserve to be pointed out again and again. The relation of topography to the different branches of geology may be seen best by a glance at them all. Geology is well understood to consist of the observation of facts about rocks as materials of the earth (geognosy), and the explanation of those facts (geognosy). The facts to observe are : I. GEOMETRICAL, as (1) structure, including the dip and strike at different points, the size, shape, and position of basins and saddles; (2) vertical section, that is, the thickness of rock groups and of their parts ; (3) horizontal or geographical position. 11. PHYSICAL, such as texture, whether sedimentary or crystalline ; and, if crystalline, whether granitic, porphyritic, amygdaloidal, globular, or concretionary ; whether compact or granular; coarse or fine; pervious or impervious; hard or soft; firm or tender; with cleavage or without ; massive or thin ; the microscopic structure ; also whether magnetic or not ; soluble or insoluble ; fusible or infusible ; and the constituent minerals. 111. CHEMICAL that is, the composition of the rocks and of their minerals and their affinities. IV. PALAENTOLOGICAL, as what kind of fossils are in the rocks,

By C. Navalkar

Systematic drilling & blasting techniques are currently being viewed in the mining & construction industry as a correct 8z scientific approach for optimization process in rock excavation, as drill & blast costs usually represent major share in total cost of production and also the environmental impacts plays an important role in designing of the operations. Designing a blast is a complex planning task, which for optimization, includes deciding the bench geometry with respect to the rock properties & geology of the area, capacity of the excavators, choice of explosives & detonation method, tiring sequence, etc. Optimization of blast design needs a detailed comprehensive study of all the above intersecting elements. Preblast & Post blast surveys are required for further improvements in blast designs. However, the choice of blast design depends upon the the requisite blasting results opted for and the cost you are ready to pay for the same. The blasting operation, in general, also involves numerous side effects namely, ground vibrations, fly rocks, dust, noise & gas pollution, air blast effect etc. Again these effects can be made tolerable up to a certain extent depending upon the limitations of the environmental obligations as may be specified by the concerned authorities.

Jan 1, 2001

By Donald P. Tuchman, Robert P. Vinson, Jon C. Volkwein

Research by the National Institute for Occupational Safety and Health (NIOSH) has pursued quartz analysis for the specialized ?lter assemblies of a new worker-wearable personal dust monitor (PDM). The PDM is a real-time instrument utilizing a tapered element oscillating microbalance (TEOM®). Standard ?berglass TEOM ?lters cannot accommodate the desired P-7 infrared analytical method used by the Mine Safety and Health Administration (MSHA). Novel ?lter materials were tested with the objective of demonstrating this type of analysis. Low temperature ashing and spectrometric examination were employed, revealing that nylon ?ber candidate ?lters left minimal residual ash and produced no signi?cant spectral interference. Avoiding titanium dioxide in all ?lter materials proved to be a key requirement. Fine quartz particulates were collected on prototype ?lters in a Marple chamber, either open-faced or through PDMs during test runs. The ?lters were then subjected to MSHA P-7 analysis and the spectrometrically based analytical results for quartz mass were compared to reference measurements. Also, PDM instrumental mass readings were compared to ?lter gravimetric measurements. Results suggest that the P-7 method is adaptable to variations in ?lter materials and that quartz dust analysis by the P-7 method when utilizing the new ashable PDM ?lters can have accuracy and precision within 10% and 4%, respectively. This is within the declared 13% accuracy and 7–10% precision of the P-7 method itself. Instrument mass readings had modest positive bias but met NIOSH accuracy criteria. Continued work with specialized PDM ?lters is merited, as they are a new type of TEOM sample amenable to ashing analysis of particulates.

By Z. Sun

Magnetic fields have been used for inclusions removal from melt and preparation of materials with gradient compositions. Fundamental in these applications is that the induced magnetic forces on the particles/melt can enhance migration and change the interaction behavior. In the present paper, migration and interaction behavior of electrical-insulating particles in a conductive melt under strong magnetic field are theoretically analyzed. It is found that the migration can be considerably enhanced for micrometer sized particles by applying a strong magnetic field. In addition, two forces are involved in the interaction between two particles: the interparticle magnetic dipole-dipole attractive force due to magnetization and the repulsive force induced by flow of the melt. This theoretical analysis renders a better understanding of recent experimental results. Additionally, a new method by using strong magnetic field can be proposed to control the particle size distribution for the preparation of metal-matrix composites.

Jan 1, 2009

By G K. Jorkenson

The SABREX Blast Modelling Program was developed joinlly by the companies of the ICI Explosives Group. of which C-I-L Inc. is a member. SABREX (Scientific Approach to Breaking Rock with Explosives) is a modular computer program which incorporates new technology with a number of tested programs that have been in use world wide.

Jan 1, 1989

By John Hoelle

Coal mines in southern West Virginia, south-western Virginia and eastern Kentucky have experienced coal bumps at least since 1933. Most of the bumps have occurred due to high cover, strong roof and floor strata and stress concentrations due to the mining sequence. A longwall mine in eastern Kentucky first experienced coal bumps on the tailgate side of the longwall face in 1989. The bumps continued until 1996. The bumps were the result of: Thick overburden up to 2200 feet Strong roof and floor (strata strengths up to 25,600 psi UCS and elasticity modulus up to 4,800,000 psi Previous over-mining in places Sandstone channels Not all characteristics occurred simultaneously. The bumps produced seismic events recorded up to 4.3 (Richter scale magnitude), and damaged pillars that were up to 147 by 152 feet in size.

Jan 1, 2008

By L. C. IlsLey

"During the last eight years there has been a noticeable increase in the use of permissible equipment in gassy and dusty coal mines. This trend has undoubtedly been toward greater safety in mining, but in spite of this all is not well ""along the front.""In many mines those in charge, either through ignorance or supposed economy, have neglected to install sufficient copper and maintain good bonding on the rails used for return circuits to have a safe working voltage for the permissible equipment which is intended to afford them safety.Low voltage, when properly analyzed, is not economy but frequently is an expensive oversight. Burned-out armatures, controllers, rheostats, and switches are costly in themselves to repair or replace, but the greatest cost in many instances is the loss of production resulting from idle and broken-down equipment.From a safety standpoint, excessive low voltage where permissible equipment is necessary is almost criminal negligence. A burn-out of any kind is liable to cause an arc that may burn its way through a casing wall and bring about a hazardous condition if gas or dust in explosive proportions should be present. Again, all wiring, both interior and exterior to the apparatus, is subject to the extra heating consequent upon low voltage. It should be remembered that if the voltage drops the current must increase a corresponding amount in order that the same work may be accomplished; and as the heating effect is as the square of the current, an enormous overheating of the electrical parts and wiring often takes place. This heating effect is especially detrimental to trailing cables used on portable equipment, because under the most favorable conditions the size of cable selected is only barely sufficient to do its work properly at a safe working temperature; therefore, when the extra current load is added because of poor voltage, overheating is sure to result, with consequent deterioration of the insulation, This effect greatly increases the liability of cable failures in service, and in turn adds to the hazards incident to the use of portable equipment of the permissible type involving the use of trailing cables.Some manufacturers have tried -to protect their equipment from low voltage, especially below a certain point, by -installing low-voltage relays which will trip when the voltage falls to a predetermined value. It is understood that some operators have hesitated or refused to install such low-voltage protection because they were aware that the voltage conditions were so poor that the equipment could not operate under the safe limits set. It is difficult to understand how any progressive company that is willing to go to the ex-pense of installing permissible equipment could be so shortsighted in this phase of common sense, safety, and economy."

Dec 1, 1929