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By Jinjing Dua, Jun Zhua, Kuiren Liub, Bin Wang, Xiaolei Wua

V-Ti-Fe as hydrogen storage alloy was prepared by reducing metal oxides with a metallothermic reduction method. The deoxidation process of the V-Ti-Fe alloy was performed by electro-deoxidation and vacuum induction melting method, respectively. The results showed that the content of oxygen impurity can be controlled at about 0.2wt% after electrolyzing for 240min. Both the maximum values of hydrogen absorption capacity and the effective hydrogen desorption capacity are 2.65wt% and 1.01wt%, respectively. The deoxidization effect of vacuum induction melting process is more remarkable, with Ce as the reducing agent. It is found that Ce addition is beneficial for reducing the componential segregation, promoting the hydrogen absorption activation of V-Ti-Fe alloy. When m(Ce)/m(alloy) is up to 5%, the oxygen content has been reduced to 0.05wt% and the maximum hydrogen absorption capacity and the effective hydrogen desorption capacity are up to 3.36wt% and 1.85wt%, respectively.

Jan 1, 2015

By Larry Joe Linley

The Department of the Interior, Bureau of Mines is reviewing explosion protection methods for use in gassy coal mines. This performance criteria guideline is an evaluation of three explosion protection methods of machines electrically powered with voltages up to 15 000 volts AC. A sufficient amount of basic research has been accomplished to verify that the explosion-proof and pressurized enclosure methods can provide adequate explosion protection with the present state of the art up to 15 000 volts AC. The routine application of the potted enclosure as a stand alone protection method requires further investigation or development in order to clarify performance criteria and verification-certification requirements. An extensive literature search, a series of high voltage tests, and a design evaluation of the three explosion protection methods performed at White Sands Test Facility indicates that the explosion-proof, pressurized, and potted enclosures can all be used to enclose up to 15 000 volts AC, if the performance criteria and verification-certification requirements recommended in this guideline are implemented.

Jan 1, 1982

By Curtis H. Elder

In studies conducted by the Bureau of Mines, two test areas were hydraulically stimulated and exposed by mining: One in the Pittsburgh coalbed at the Vesta No. 5 mine, Washington County, Pa.; and one in the Illinois No. 6 coalbed at the Inland mine, Jefferson County, Ill. Induced fractures were contained totally within the coalbed with no adverse effect on the stability of associated rock strata. Induced fractures were vertical and were propagated normal to the direction of least residual tectonic stress. Gas production was increased fivefold to twentyfold by hydraulic stimulation.

Jan 1, 1977

By H. M. Lawrence, E. Roca

"INTRODUCTION Of the phosphate rock deposits of the United States that are being exploited actively at present, the land-pebble area in Florida is the largest producer. In recent years the land-pebble district, in Polk and Hillsborough Counties, has produced about 80 per cent of the raw phosphate rock that has supplied the requirements of the several national industries based on this essential commodity.In the land-pebble deposits sizes finer than 16 to 22 mesh are below the commercial limit in phosphate content, and washing-plant practice has been directed to the recovery of the coarser material. Recently, more extensive control of the washery plan has resulted in the saving of additional amounts of phosphate, the loss of which had been considered unavoidable. However, strict requirements of the trade regarding the lowest acceptable grade of phosphate rock prevent the inclusion of more than a very small proportion of the low-grade phosphatic sands with the washery output of phosphate roe:. Further advances in practice resulting in larger recoveries of phosphate can only be effected by the application of processes that are based on other principles than merely a difference of particle size. Research is be conducted actively along these lines by the industry and by cooperating agencies.Flotation has been studied for several years by the International Agricultural Corporation and its allied company, the Phosphate Recovery Corporation. J. T. Burrows, vice-president of the International Agricultural Corporation, in a letter dated July 10, 1929, states:"

Aug 1, 1931

By G. R. Hopkins

The average heat requirement per barrel of crude processed in the United states rose from 555,000 B. t. u. in 1939 to 579,000 B. t. u. in 1940, although crude runs increased from 1,237,840,000 barrels to 1,294,162,000 barrels in that period. Thus the almost invariable rule that the average amount of heat needed to refine a barrel of crude oil declines when total crude runs to stills increases was broken. (See fig. 1.) The reasons underlying the apparent loss in fuel efficiency in 1940 are quite obscure. There is little question but that the principle of heat exchange, the most important fuel saver, was used as extensively in 1940, as in 1939. A few companies replaced purchased power with electricity made at their plants, but for the country as a whole purchased electricity increased 7 percent, as compared with a 5-percent gain in crude run to stills. Furthermore, the premise the more complex the products the more fuel required -does not hold, as the yield of ?complex" products, including gasoline, declined in 1940.

Jan 1, 1942

By M. Jayaraman

With the ever increasing demand for commodities, due to changes in lifestyle and increase in population, people are striving to find ways to keep up. Mining is one essential element in the solution. Though being a powerful boost to a country?s economy, mining can have disastrous effects in the absence of waste management practice and technologies; because of the harmful heavy metals and toxic chemical waste that is generated as a by-product in mining operations. It is an established and documented fact that pollution is a major concern for communities having to live with it. Disproportionate water consumption significantly impacts local rivers and ponds thereby reducing freshwater availability and have given rise to social conflict. In light of these misgivings, management and treatment of mine water and waste has gained considerable attention recently. In this paper, we summarize some of the treatment methods that can be adopted by mining companies to reduce their environmental footprint. Appropriate treatment solutions depend on various factors including available space and capital cost for treatment solutions, type of mining waste generated, current state of the mining plant, geographical location, and other location specific issues. Incorporating waste and water management solutions as a priority within mining operations is critical for addressing increasing regulatory requirements and a starting point for initiating other Corporate Social Responsibility (CSR) programs. Collaboration among mining companies, NGOs, local community, and government facilitates successful projects which build trust leading to long term relationships. In this paper we also talk about the benefits of implementing a CSR project that captures the focus of local communities and allows the mining company to focus on operations. Implementing a sustainable business model that incorporates the broader community impacted by projects will continue to benefit even after the mining company ceases operation in that location. The challenges involved with implementing effective CSR projects, which require measuring and reporting effectiveness to create a positive social, economic, and environmental impact is also presented in this paper.

Aug 1, 2013

By Richard C. Rice

Laboratory and field data for wire ropes typical of constructions used in underground mine hoisting were obtained, screened, encoded and analyzed statistically. The statistical analysis of data for hoist ropes retired from service showed that rope remaining strength (or, conversely, strength loss) can be predicted with good accuracy if several nondestructive measures of rope damage are assessed. Found to be most important was the outer-wire corrosion rating, the electromagnetic (EM) nondestructive-inspection technique used for predicting strength loss, and the rope diameter reduction. Signs of rope deterioration such as broken wires or damage were also important indicators of strength loss. Based on the results of this investigation, a number of recommendations are presented that promise to yield better rope inspection and retirement criteria which will in turn lead to improved safety and efficiency in underground mine-hoist systems.

Jan 1, 1983

By Mark R. Pettitt

The development of fire hazard criteria for noise control products in underground coal mines are presented. Qualifying requisites of the criteria include maintaining miners' safety, allowing for maximum use of noise control products, and economic feasibility. The burning process is analyzed for its relationship to fire hazard criteria developed by NASA and the FAA, and the mine environment is analyzed in conjunction with the end-use applications of noise control products. Also, the interim fire hazard specification developed by MSHA is appraised as it applies to end-use applications of noise control products. From these analyses and a literature survey, fire hazard criteria are developed. They include an initial screening procedure that evaluates the level of flammability testing required. Fire tests that may be indicated are the Vertical Flame Test, the Ignition Temperature Test, and the 25-Foot Tunnel Test.

Jan 1, 1983

By R. H. Estrada-Ruiz

This work analyses a new approach to estimates bubble size distribution of froth surfaces using artificial neural networks (ANN).Also, the robustness of ANN to interpret images with illumination perturbations, produced by light problems or dirt attached to the window of the video camera is evaluated. The experimental work was carried out in a laboratory flotation column, instrumented with an image acquisition system. The images were processed making use of a perceptron model with a hidden layer, sigmoidal transfer function and unitary bias, and the ANN trained with a back propagation algorithm. The results of validation show that ANN are reliable for learning and producing generalized predictions of the froth mean bubble diameter and bubble size distribution, when the model is trained using a database that contains information on the illumination intensity. Keywords: image analysis, neural networks, bubble diameter, bubble size distribution.

Jan 1, 2009

By Carl Belser

This report on tungsten in Ouray, San Juan, and San Miguel Counties, Colo., is one of a series describing results of studies on the tungsten potentialities in Region III, Bureau of Mines. The San Juan tungsten deposits occur in an area of 250 square miles, centering near the common corner of Ouray, San Juan, and San Miguel Counties (fig. 1). Field work supporting these studies was done in May 1954. Bureau of Mines reports prepared from investigations made during World War II and under the Defense Production Act of 1950 were reviewed.

Jan 1, 1956

By Roe-Hoan Yoon, Kaiwu Huang

Derjaguin and Dukhin (1961) were the first to develop a model for bubble-particle interaction in flotation from first principles by considering the surface forces in wetting (or flotation) films. The model predicted that the energy barriers to bubble-particle attachment arise from the ζ-potentials of fine particles, which corroborates well with an earlier work of Fuerstenau (1957) reported for the flotation of quartz using dodecyl ammonium acetate (DAA) as collector. In the present work, a series of surface force measurements have been conducted by accurately monitoring the changes in bubble curvature during bubble-silica surface interactions. The curvature changes are then used to determine the capillary force, which is the sum of the hydrodynamic and surface forces. By subtracting the former that can also be determined from the curvature changes, one obtains the surface forces (or disjoining pressure). The results obtained as functions of pH and collector concentrations show that control of the ζ-potentials of bubbles relative to those of the silica surfaces is critical for maximizing the negative disjoining pressure, which is conducive to promoting bubble-particle attachment in flotation.

By John H. Johnson

This report covers the third and final year of work conducted under U. S. Bureau of Mines Grant G0166027, "Monitoring of Mine Air Pollutants". The report discusses work performed in three areas. These are the White Pine Mine (WPM) Experimental Unit, diesel mine-vehicle tailpipe emissions monitoring, and mine ambient air concentration data analysis. The WPM experimental unit was used to study diesel exhaust stratification in an 80 foot long dead-end heading while loading ore with a Wagner ST-5D scoop train LHD. The MTU Mine Air Monitoring Laboratory (MAML) was used to gather temperature and CO2 concentration data at 10 locations. Three different ventilation conditions were compared. The data substantiate the presence of strong buoyant forces of the hot exhaust gases which result in temperature stratification in dead-end headings. The diesel mine-vehicle tailpipe emissions monitoring study involved laboratory measurements of diesel undiluted exhaust pollutant concentrations by the portable tailpipe emissions measurement apparatus (EMA) assembled for in-mine use. The results were compared with simultaneous measurements by standard laboratory exhaust monitoring instruments. These results indicate that accurate field source quality control measurements can be obtained for CO2, CO and NO but NO2 results were low for all engine conditions. The mine ambient air concentration data analysis study included analysis of diesel pollutant concentration data in the Orchard Valley Mine air and comparison of the results with data collected earlier in the White Pine and Brushy Creek mines. The analysis included preparation of lognormal frequency distributions and calculations of C02-based concentration ratios and correlations. In the three mines compared, pollutant concentrations are distributed quite similarly, and the concentrations appear to be controlled to present standards.

Jan 1, 1979

By G. R. Hopkins

The average heat requirement per barrel of crude processed in the United states rose from 555,000 B. t. u. in 1939 to 579,000 B. t. u. in 1940, although crude runs increased from 1,237,840,000 barrels to 1,294,162,000 barrels in that period. Thus the almost invariable rule that the average amount of heat needed to refine a barrel of crude oil declines when total crude runs to stills increases was broken. (See fig. 1.) The reasons underlying the apparent loss in fuel efficiency in 1940 are quite obscure. There is little question but that the principle of heat exchange, the most important fuel saver, was used as extensively in 1940, as in 1939. A few companies replaced purchased power with electricity made at their plants, but for the country as a whole purchased electricity increased 7 percent, as compared with a 5-percent gain in crude runs to stills. Furthermore, the premise -the more complex the products the more fuel required -does not hold, as the yield of ?complex" products, including gasoline, declined in 1940.

Jan 1, 1942

By D. C. Bailey, D. I. Hodson

Paper presented at the annual joint meeting of the IMM and IMinE held in Harrogate, 31 January 1991. The Neves-Corvo copper-tin mine is the highest-grade large-tonnage copper operation in the world and is now arguably the most significant producing base-metal mine in Europe, rating in the top ten world producers of both copper and tin. A description is given of the initial exploration work and the development of the project from the orebody discovery in the Iberian Pyrite Belt of southern Portugal in 1977 to full operating capacity in 1990. The chronological account includes discussion of the main organisational, financial, technical and environmental decisions and of the various difficulties encountered, and the challenges of the future are identified. The project was brought in on schedule and within budget

Jan 1, 1991

By E. P. Youngman

This paper presents one of a series of digests of foreign mining legislation and court decisions that is being prepared in advance of a general report relative, to the rights of American citizens to explore for minerals and to own and operate mines in various foreign countries. This interpretation of the mining laws of British Guiana has been prepared from the best available sources in Washington and is, released subject to amplification and correction, if necessary, by United States foreign-service officials. INTRODUCTION The sources of information available in the preparation of this paper are the following: 1. The Crown lands ordinance, No. 32 of 1903, September 26, 1903.

Jan 1, 1934

By G. F. Kuncir

The analysis summarized herein evaluates the Bureau of Mines Program for Advancing Mining Technology Oil Shale in terms of the economic benefits which may be derived for the Nation as a result of its successful research and development efforts. On the basis of postulated oil shale production scenarios, benefit-cost ratio indicators are computed for the program elements as they apply to surface, underground, and modified in situ oil shale mining systems. Eight value indicators are used to measure the Program's beneficial impact on the future oil shale industry in relation to planned research and development costs. These are: capital cost savings, operating cost savings, labor savings, environmental quality maintenance cost reduction, reduction in production costs, byproduct production benefits, total production benefits, and additions to recoverable reserves. Program costs are aggregated from 1974 through 1987 and major benefits are accrued from 1982 through 2040. Both cost and benefit streams are discounted to mid-1975 present value.

Jan 1, 1977

By Kim B. Shedd

The U.S. Bureau of Mines Particulate Mineralogy Unit examined the habits of six zeolite minerals commonly occurring in domestic zeolite deposits. Mineral habit is of interest because current theory on the potential for sarcoma production in test animals emphasizes the size and shape of mineral particles, without regard to composition or structure. A scanning electron microscopic study revealed that, of these six minerals, only mordenite and erionite crystallized in acicular to fibrous habits, The fibrous varieties of these two minerals were characterized by size and shape on the transmission electron microscope, and their dimensions were compared with those of asbestos and amphibole cleavage fragments. When comminuted, these two minerals possess "fibrosity indices" similar to those of amphibole cleavage fragments. One sample, a rare woolly erionite, has uniform widths, large aspect ratios, and a "fibrosity index" similar to those of asbestos.

Jan 1, 1982

By Oluwasegun Samuel Odebiyi, Shaona Wang, Feng Gao, Biao Liu, Hao Du

Recovering vanadium from vanadium titanium-magnetite (VTM) ore using ( NH4)2C2O4 is a clean hydrometallurgical process, but the drawback is the low recovery and slow kinetics due to the formation of inhibitor. A novel energy-efficient mathematical model was derived for green leaching of VTM in which the mechanical activation (MA) removed the inhibitor “δ” (formation of impermeable product layer of CaC2O4) covering the reacting core of the CaV2O6 leaching process in ( NH4)2C2O4 solution. Before the MA processing, the formation of the CaC2O4 layer affects the kinetics (slow) and NH4VO3 leachability (low recovery). The dissolution rate enhancement and economic importance (in terms of leaching kinetic/recovery) of mechanical activation (MA) pretreatment in hydrometallurgical processing cannot be overemphasized. It is shown from the experimental and developed mathematical model results that the rotating speed of the ball mill (ωb) has a significant effect on the NH4VO3 recovery. At 360 rpm, the experimental result gave an 82% optimum recovery rate and a reaction rate constant of 0.01889s−1 with close correlation with the present models at 82.8% and 81% for liquid-to-solid layer diffusion and chemical reaction controls, respectively, with a reaction rate constant of 0.018883s−1. The close correlation between the experimental recovery rate results and the diffusion recovery rate model result justifies that the leaching process is diffusion control shrinking core kinetic with experimentally measured activation energy (Ea) value of 19.502 kJ/mol . This present model proved that MA enhances the dissolution rate regardless of the formation of a passivation layer on the material and best describes the kinetics of the MA hydrometallurgical processes compared to the shrinking core model.

Nov 3, 2023

By Thomas A. Davidson

The Bureau of Mines Helium Field Operations has developed a simple and accurate method for calculating the viscosity of gas mixtures. Only the composition of the mixture and the molecular weights and viscosities of the pure components in the mixture are required. The momentum fraction of a mixture is calculated from the composition. The fluidity is calculated as a quadratic function of the momentum fractions. The efficiency factor for transfer of momentum in collisions between bodies of different masses is derived and used with one empirical constant. The viscosity is the reciprocal of the fluidity. Results of the method are compared with 752 reported viscosities for 40 dilute binary systems at temperatures from -78 to 276.9°C. Using this method the average absolute deviation is 1.29%, the root-mean-square deviation is 1.99%, and the average deviation is -0.84%.

Jan 1, 2010

By M. D. Flavel

Research programs conducted by Allis-Chalmers Corporation are showing that the most efficient energy use in crushers is achieved when the forces applied to particles undergoing breakage are increased. Laboratory bench scale tests have been developed to confirm this phenomena, which was first observed in the field using HYDROCOME crushers with automatic setting controls. A new testing machine is described and methods of maximizing such benefits are postulated. FOREWORD Allis-Chalmers Corporation was founded in Milwaukee, Wisconsin, in 1847 as the E. P. Allis Company, which had an initial interest in manufacturing components in the grinding of flour. As such, its roots were started in reducing material size, which is covered by the generic term, comminution.

Jan 1, 1981