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By L. W. Kesler

Kansas produced 41,966,773 bbl. of oil in the year 1927, thereby taking fourth place among the oil-producing states of the Union. The daily average production decreased from 121,609 bbl. in January to 110,244 bbl. in December. Due to excessive flush production and the resulting decline in the price of crude during the year, operations, both in proved and outlying districts, were reduced materially from those of 1926. There were 2338 completions in 1926, but only a total of 1333 in 1927. Regardless of this decrease in the total number of completions, Kansas made a slight gain in total production for the year, producing 620,262 bbl. more than in 1926. This is accounted for, in part, by the comparative long life of the settled production from the Bartlesville sand areas to the east of the Nemaha granite ridge, and by prolific production in eastern Summer County from horizons new in their importance in the state, productive here at two localities along the axis of the granite ridge (Table 1 and Figs. 1, 2 and 3.) For convenience in further consideration, the state is divided into Eastern and "Western" Kansas. Special emphasis will be placed on those areas in the state of which but little is generally known, and which have not been given detailed consideration in previous publications.

Jan 1, 1928

By Norman B. Pilling

Practical limitations to the usefulness of silicon steels are the hardness and brittleness silicon imparts to iron, making iron-silicon alloys of more than 8 per cent. silicon content unusable except where castings can be employed. In the use of commercial silicon steel, in thin rolled sheets, as in transformer construction, when the silicon content exceeds 4.2 per cent. the sheet is too brittle for satisfactory shaping by punching or similar operations. When such a brittle steel is sheared, it frequently breaks along a haphazard path in advance of the cutting tool. In Fig. 1 is shown a slightly enlarged view of the sheared edge of a 14-mil enameled sheet of nominally 4 per cent. silicon steel. In 5 in. along the sheared edge, only 44 per cent. was actually cut; the rest was torn, with the path of fracture varying widely from the path of travel between the shears. This is probably an extreme case of such brittle-ness, but a shearing or punching test is not necessary to reveal brittle-ness of this order; narrow strips will break when bent between the fingers. In Fig. 2, the proportion of actual cut edge is greater, but secondary fractures branch off at about 30" from the line of shearing in advance of the cut. Deprived of the support of adjacent parts of the sheet, the tips of the angles are bent out of the plane of the sheet by the shears, leaving a peculiar flared effect, like the set of the teeth on a saw. An end-on

Jan 1, 1923

By Edmund M. Wise

NATURE has provided us with many metals, but with few really good ones, and frequently the better metals are the rarer. It is to this circumstance that many physical metallurgists, inventors, and just plain experimenters owe their employment, for much of their work is directed, consciously or otherwise, toward the alleviation of some of the more serious shortcomings of the cheaper, less noble, and weaker metals; by alloying, age-hardening, passivating, cladding, plating, and other useful dodges, which sometimes permit the substitution of one of the less gifted metals for one of the really good ones. As a matter of fact, the varied needs of our complex civilization could be quite well met with only five metals, if they were sufficiently abundant, and one of the five would certainly be platinum, the most noble and versatile that nature provides. Many metals are difficult to handle and seem to take pleasure in defying their investigators to find good uses for them, and finally when a use is found it is frequently quite a specific one; in other words, a hole has to be found--or perhaps made-to fit the peg. It is for this reason that a large amount of research must be con- ducted before the more recalcitrant metals become really useful. In platinum, however, we have a metal that inherently possesses so many valuable attributes that it became useful as soon as methods for producing it in massive ductile form were devised, and once its complicated chemical behavior was understood it became principally an aid to research rather than the subject thereof. In recent years, much research has been done to further improve

Jan 1, 1953

By A. A. Steel

DUring the summer of 1905 I was employed by the U. S. Geological Survey to investigate the geology, mining, and preparation of barite in most of the fields of the United States. The Eastern districts have been more or less completely described; the Virginia field in detail by Thomas L. Watson, in his paper, Geology of the Virginia Barite-Deposits,' and other fields in abstract, including statistics of production and references to current literature, by various authors.2 There have also been published a few details of the occurrence of barite in the lead-mines of Washington county, Mo.³ The other accounts of this district are erroneous and meager, and since this field is the most important one in the United States at the present time, a detailed description of the local geology seems doubly desirable. Barite-deposits are scattered over nearly the whole of Washington and adjoining counties, but the product is all mined from the areas indicated upon the sketch-map, Fig. 1, and is shipped from the stations of the St. Louis, Iron Mountain & Southern railway, between Blackwell and Potosi, from 45 to 60 miles SW. of St. Louis. The topography is for the most part gently rolling, with slightly graded streams, usually less than 200 ft. below the higher hill-tops. Along Mineral fork and Indian creek are some steep bluffs and cliffs, affording good exposures of the

Jan 1, 1910

By Robert Ammon

THE milling practice at Mascot, at present, consists of dry crushing to 5/8 in., jigging, fine grinding, and flotation. The ore arrives at the mill from two mines, No. 1 mine shaft being located in the mill proper, and No. 2 mine shaft being situated about 2000 ft. east of the mill. No. 2 mine is served by a coarse-crushing plant and aerial tramway to the mill bins. In jigging the No. 2 mine ore, 50 per cent. of the mill feed is rejected by the jigs as a jig tailing ranging from 5/8 in. to 10 mesh; the balance of this ore, after removing a jig concentrate, is ground to flotation feed. In jigging No. 1 mine ore, approximately 80 per. cent. of the mill feed is rejected as a coarse jig tailing, and the balance is ground to flotation feed without the removal of a jig concentrate. The difference in the treatment is due to the fact that No. 2 mine ore carries a higher content of zinc than that from No. 1 mine. Of the total concentrates produced, 30 per cent. are made on jigs and 70 per cent. by flotation. At present, 1350 tons of No. 2 ore and 800 tons of No. 1 ore are treated each 24 hours. The recoveries for a typical week are as follows: Heads 3.55 Jig concentrates 61.30 Jig tails 0.80 Flotation concentrates 60.60 Flotation tails 0.09 Extraction 86.50 The associated minerals are a straw-colored sphalerite, dolomite, calcite, pyrite, quartz, and a small amount of greenockite, which occurs as a stain and sometimes small crystals along with sphalerite, but is comparatively rare. Pyrite is present in small quantities, usually less than 0.5 per cent.; quartz occurs in bands a few inches thick. A complete analysis of the ore is as follows:

Jan 9, 1924

By James E. Berryman

A method is presented for calculating the pressure depletion performance of a gas-condensate reservoir from the original reservoir fluid composition using the laboratory determined pressure-production history and retrograde liquid accumulation as guides. Equilibrium vaporization ratios for this calculation were modified from published data until the calculated dew point pressure and retrograde liquid accumulation agreed with the values observed in the laboratory. The calculated results are compared with the produced gas composition determined by low temperature analysis during constant volume laboratory experiments of pressure depletion behavior. This comparison shows that the calculation procedure is adequate for determination of gas phase composition. Data from field separation tests in low temperature separators are presented which verify the applicability of published equilibrium vaporization ratios for a wide range of separator conditions. INTRODUCTION A reliable prediction of the pressure depletion performance of a gas-condensate reservoir is necessary in determining reserves and evaluating field separation methods. The predicted performance is also used in planning future operations and studying the economics of projects for increasing liquid recovery. Because the flow of fluid in a volumetric gas-condensate reservoir is usually single phase flow, the pressure-depletion per-formake is primarily a function of the phase behavior of the reservoir fluid. The properties of a gas-condensate system of major importance are: (1) compressibility factor at reservoir temperature and pressure; (2) dew point pressure; (3) composition changes of the vapor phase with pressure depletion; (4) recovery of original in-place hydrocarbons at any pressure; and (5) retrograde condensate accumulation. These properties are most generally determined by a pressure depletion-type experiment on recombined separator gas and liquid samples in the laboratory. ldeally the pressure-depletion performance can be calculated from the composition of the original reservoir fluid if the reservoir temperature and initial pressure are known.1,2,3 It has been reported "... comparison of such computations with depletion-type ex-periments on recombined samples in the laboratory have yielded results that appeared to be entirely adequate.". The success of such calculations is determined by the equilibrium vaporization ratios chosen, especially those for the higher boiling point hydrocarbons. It is the purpose of this paper to present a method for computing the change in composition of the vapor phase during pressure depletion by production using laboratory determined properties of the system to guide the calculation and to illustrate the use of the method with data from the Cockfield "D" sand of Washington field, St. Landry Parish, La. Results of field tests and laboratory analysis are included. As a result of this reservoir fluid study, a cycling program has been evaluated, the fidd has been unitized, and the cycling started in July, 1956.

Jan 1, 1958

By H. M. Chance

Recent research work has shown that coal can be produced, at reasonable cost, from almost all coal-mining districts containing not more than 3 to 8 per cent. of ash. From coal so produced, an abundant supply of coke, suitable for blast-furnace operation, can be made containing from 12 down to 6 per cent. or less of ash. These statements apply broadly to the Appalachian coal belt, including most of the mining districts in Pennsylvania, Ohio, West Virginia, Kentucky, Tennessee, and Alabama. The exceptions will generally be found among those coals carrying a prohibitive percentage of sulfur. Any gravimetric heavy fluid method of separation will effect a reduction in the percentage of sulfur, but this reduction may not be sufficient to produce, from coal unfit for metallurgic use, a product that can be so used. When a large part of the sulfur is in the form known as "organic sulfur, "or is present as very finely disseminated and homogeneously distributed pyrite, possibly it cannot be eliminated from the low-ash coal produced. When the sulfur exists as pyrite in distinct layers, bands, or nodules, or when it is finely disseminated but is irregularly distributed, often a low-ash coal low enough in sulfur to make good metallurgic coke can be produced from relatively impure coals. It has generally been assumed that the quality of coke on which blast furnaces must be operated depends on the geographic location of the furnace, and that the grade of coke on which a blast furnace must operate is that produced from the best coal obtainable by careful mining; or if the coal is prepared by washing, hand picking, or other means by which the foreign impurities are removed, that the grade of coke on which the furnace must operate depends on what has been termed the "inherent ash" of the particular coal. The term "inherent ash " is generally understood to mean the percentage of ash present after all removable (free) impurities, slate, fireclay, high-ash bony coal, and pyrite have been removed, and is usually applied to the percentage of ash present in run-of-mine coal from any mine after these impurities have been removed. Perfect washing, or perfect preparation, is understood to be attained when the percentage of ash in the washed coal is reduced to the percentage of inherent ash; that is, of ash that cannot be removed by the washing processes in common use. Wash-

Jan 1, 1924

An educated man is distinguished neither by his clothes nor by his knowledge; he is remarkable not for the things he says, but for the way he says them. You cannot even stand with him under an archway in the rain without finding him out. He may talk only of the weather. His words and his phrases alike my be simple. What distinguishes him is the arrangement of his words; however desultory his talk, it will be methodical; he has habituated himself to foreseeing the part to be played by each word he uses and the place to be taken by each sentence he utters. On the other hand, the uneducated man, though shrewd and well-informed, will relate facts and events as they recur to him, generally in disorder; in his effort to recollect and in his attempt to rectify forgetfulness he will pause irregularly, filling the intervals with meaningless phrases, such as "and then", "and so", or "said he to me", "said I to him"; and even the continuous parts of his story will be told confusedly-because he has not learned the proper use of words.* My own experience as an editor of technical manuscripts has taught me that the misuse of 'that' and 'which' is a fruitful cause of obscurity and confusion. The relative pronouns have distinct functions, and no writer can express himself clearly until he has learned to discriminate between these functions. For example : The engineers who refused to submit were discharged. The engineers, who refused to submit, were discharged. The engineers that refused to submit were discharged.

Jan 1, 1931

By C. D. Keen

In the latter part of the summer of 1913 the Conservation Commission of the State of Louisiana, under presidency of M: L. Alexander, decided to stop the waste of natural gas going on at the "burning gas-well," Located about 2 mile southeast of Oil City, La. On several occasions, both in newspapers and in reports, comment had been made on the condition of this well, its harmful effect on the Caddo gas field, and the considerable loss, estimated at several thousand dollars each month, caused by the escape of the valuable fuel., But nothing had been done to bring the well under control and prevent further waste of gas until the State Conservation Commission took the matter in hand. The gas fields of Louisiana are among the greatest in the country. So far most of the gas has been found in the Caddo field proper, although considerable development has been done in and around the city of Shreveport and near the town of Mansfield in DeSoto parish. To extend the life of the gas fields and to prevent the quick exhaustion of the supply of the natural fuel are matters of vital importance for this section of the country. Four gas companies have entered the Caddo field and supply the surrounding towns and cities With gas. The Arkansas Natural Gas Co. has pipe lines to Little Rock, Ark., and supplies gas to the following cities and towns in that State: Texarkana, Hope, Garland, Emmet, Prescott, Boughton, Beirne, Gurdon, Arkadelphia, Gum Springs, Mal-vern, Dsnaldson, Gifford, Perla, Beaton, Beauxite, Mabelvale, Bryant, Sheridan, Pine Bluff, Little Rock, Argenta, Pulaski Heights, and Hot Springs. The Southwestern Gas & Electric Co. transports gas to Mooringsport, Blanchard, Caddo, Rodessa, Oil City, Vivian, Bloomburg, Hosston, Ida, Dixie, Belcher, and Shreveport. The Marshall Gas Co. supplies gas to the town of Marshall, Texas. The Louisiana Co. has a line to Shreveport. In, the oil field the gas is used for drilling purposes, and the operators either have their own gas system or buy from the gas companies. At the present time the surrounding territory depends for its fuel supply on the Caddo field, and the importance of the conservation of the natural-gas

Jan 1, 1915

By J. W. Marx, R. H. Langenheim

The authors are to he complimented for a timely presentation of useful information concerning application of heat to oil reservoirs to increase the rate and ultimate recovery of oil. The solution for heated area resulting from constant rate injection of a hot fluid, presented by the authors, and the fluid-flow analogy, solved by Carter,' are particularly interesting in that 110 restriction is placed on the direction of development of the heated area. It is not necessary that the heated area grow radially. Thus the solution could provide useful information for heat injection in any type of well pattern with any specified swept area data. However, it was assumed in the development that the heated region would remain at a constant clevatcd temperature. Vertical heat losses were computed on this basis. Physically. the assumption that the heated region will remain at a constant temperature (independent of distance from the injection point) appears to require that the heat injection medium be stcam, or other condensible gases near the boding point at injection pressure. If a hot liquid below the boiling point or a hot gas considerably above saturation temperature were used, the temperature of the heated region would decrease with distance from the injection well. Lauwerier2 has discussed this problem for a linear system. (See also Jenkins and Aronolsky; and McNiel and Nelson.') Thus, the authors' solution applies more nearly to steam injection than to hot water injection or hot, non-condensable gas injection. Assuming steam as the injection medium, it appears that steam would pass through the constant-temperature heated region and condense upon contact with the unheated sand. The tempcrature in the condensing region would probably be governed by the release of heat of vaporization required for phase equilibrium at the existing pressure distribution. Temperatures in the region would also be influenced by vaporization of hydrocarbon. Thus, it is doubtful that an expression for radial temperature distribution based on heat conduction only (such as the authors' Eq. 9) would have practical significance. As pointed out by Marx and Langenheim, the growth of the heated area under constant rate steam drive will eventually be limited economically by vertical heat loss. The possibility of continuing to move heat economically by cold water injection or by increasing the steam injection rate appears to be a very important consideration. (Movement of liquids away from the injection well should increase injectivity.) Fortunately, the solution presented by the authors may be generalized to thc case of a variable heat injection rate. The general solution is:

By Joseph P. Hodgson

In 1880, mining operations were commenced at the Copper Queen mine. The famous Queen ore body, which extended to the surface, was first quarried from a large open cut in the outcrop. The ore body was followed down to the 300 level with the Queen incline, and stoped. This, we believe, marks the introduction of square setting in the Bisbee district, which is still the method most generally used. Orebodies The orebodies in the Copper Queen mine occur in the limestones, and the main portion of the ore has been mined from the Abrigo, Martin, and Escabrosa limestones. mile the orebodies outcrop in the extreme western end of the mine, the general dip is to the east and south, at an angle of about 20°, although this dip is not by any means regular, being, in fact, very irregular locally. The ore is remarkable for its variableness in character, some of it being very soft, requiring a large amount of timber, and other portions consisting of extremely hard sulphides. The orebodies, in general, while remarkable for their continuity, are very irregular, both as to shape and size. The mine having been in operation so many years, and mining having been prosecuted over such a large area, the operations have caused the shrinkage of the overburden, and there is a constant movement, which is shown by large cracks and interstices in the surface rocks, which largely contribute to the very high deadwork or maintenance cost of the mine. It is surprising that for year 1913 it cost almost $400,000 just for the one item of repairs and dead work in this property. Haulage and Hoisting The underground openings have been extended in the neighborhood of 200 miles. The ore hoisting is performed at a centrally located shaft, the Sacramento, to which all the ores from different parts of the mine are conveyed by electric haulage, of which there was slightly over 9 miles in operation in 1913. The hoisting levels at the Sacramento shaft are placed 200 ft. apart, commencing at the 400 level and continuing down to the 1,600 level, the average hoisting distance being 1,000 ft. The

Jan 1, 1915

By Galen H. Clevenger

Equipment for treating lead ores was added in 1905 to a copper plant which the United States Smelting Refining and Mining Co. had built in 1902 at Midvale, Utah, about 12 miles to the south of Salt Lake City. By 1906 the lead section of the plant had been rounded out and consisted of a 90-ton gravity concentrator, fifteen hand-rabbled reverbera-tory roasting furnaces, six blast furnaces, a briquetting plant for handling flue dust and fine ores, a regulus furnace for concentrating the low-grade matte made in the blast furnaces, and a baghouse. The copper section was later abandoned and the plant has been operated for many years exclusively as a lead smelter. Some 45 years had elapsed at the time this plant was built since the first attempts to smelt lead ores in the West, and lead smelting had become a large and profitable industry but fundamentally little that was really new had been developed, which could be embodied in a plant built in this period. Principles and tools to work with had remained much the same as those borrowed earlier from European practice. Capacities had been increased and there were mechanical improvements but hand charging was still in vogue and there was little attempt to recover suspended particles carried out with the furnace gases, beyond settling in flues, which usually was only partly effective for recovery of the coarser particles. Satisfactory roasting and preparation of the fine components of the charge were still partially solved problems. The Midvale plant of 1906 may be regarded as more or less typical of the smelting plant of this period for treating complex western lead ores as distinguished from the recovery of lead from the simple lead ores to the eastward. The operation of a concentrating mill directly in conjunction with a lead smelter was, however, not common practice. The ores treated in this plant have from the beginning come from mines owned and operated by the company or have been custom ores purchased in the territory tributary to the plant. The treatment of custom ores is an important service to the small producer who does not have sufficient tonnage to warrant a plant, and serves to increase the tonnage of the operator of large properties, thereby helping to reduce

Jan 1, 1937

By J. E. Johnson

OF the many items of information necessary to the successful management of the blast-furnace, few are more important than knowledge of the location and movement of the stock: line:—whether the furnace is full and has been kept so; whether the stock is settling regularly or slipping; and, if slipping, how often it has slipped, at what times, and how far at each time. To obtain these data, a man is sometimes stationed at the top of a pair of mechanically-filled furnaces, sim-ply to watch and gauge them by hand in the old-fashioned way. A more recent practice is the suspension of test-rods from ropes leading over pulleys to the ground-level, where the ropes are mound on small drums with graduated peripheries and provided with crank-handles, whereby the skip-man or some other person can quickly and conveniently gauge the position of the stock-line in the furnace. I believe the credit for this great improvement belongs to Messrs. McClure $ Phillips of Sharon, Pa., who were, as far as I know, the first to apply it, and who have a patent for it. The valuable indications gained by application of the Uehling pyrometer to the down-comer are not to be ignorcd; but the information thus furnished is somewhat indirect, and there is no scale for the translation of " top-temperatures " into " feet down." Moreover, this apparatus, as a whole, is delicate, and the cost of installation and maintenance is high. If the record furnished by the Uehling pyrometer is not in the most desirable form, the test-rods, on the other hand, give no record at all, except through the memory or notes of a man who, to say the least, is not gauging continuously, and who may omit to report an improperly low stock-line, if it be due to a fault of his own.

Jan 1, 1906

By Dorsey Lyon

I. INTRODUCTION THE utilization of hydro-electric power in electro-metallurgical indus¬tries, aside from purely mechanical operations, may he of two kinds. The electric energy may be used to supply the heat necessary for the per¬formance of the chemical reactions of a metallurgical process, or the elec¬trolytic action of a direct current may be employed for extraction of metals, either in a reduction process or a refining process. In discussing this subject, it is well to distinguish between established industries, which are producing metals and alloys at a profit by use of the electric current, and the many processes which are either still in the experimental stage or have not even passed the paper stage of development of a patent. That is, we consider electro-metallurgical industries as commercial operations which are now consuming large blocks of electric energy, while processes which are not in commercial operation are only prospective consumers. Also, owing to the difficulty and risk of any attempt to foresee the effect of the European war upon electro-metallurgical industries, we have felt obliged to disregard the war entirely, and state our opinions regardless of its existence.

Jan 8, 1915

By R. S. McFarland

OKLAHOMA, in 1924, recorded the largest single increase of any state; the total oil production for the year being 176,206,397 bbl. (Oil & Gas Jnl.), which gives an increase over 1923 of about 9 per cent. Oklahoma ranked second in total amount, California being first, and produced almost 25 per cent. of the total production of the United States. This gain in production is accounted for entirely by the rapid development, deeper drilling, and efficient management of productive areas known at the beginning of the year, for, due to the small number of wells drilled, few new pools were discovered and developed up to any important stage during the year. Three major pools, Burbank, Tonkawa and Cromwell, furnished 37 per cent. of the total production. Burbank led by a wide margin, having the largest production of any single pool; there was a steady increase in production until September. The close. development of the pools in Okfuskee, Seminole, and Hughes Counties, together with the new deep-sand production at Tonkawa and increased drilling operations in Osage County, accounted for the big increase shown during the year. In January, 1924, the shutdown movement and curtailment of production in Hewitt and Tonkawa, which had been effective during the year of 1923, were stopped. The shutdown movement and curtailment of operations in 1923 does not give a fair comparison with 1924, as undoubtedly a great deal more oil would have been produced in 1923 had it not been for these measures. The sensational developments during the year, which were certainly beyond the prediction of the oil industry, were the Cromwell field, which started the year with 10,478 bbl. for January and increased rapidly to 1,267,032 bbl. for. December, and the discovery of the Wilcox productions below 4000 ft. in the Tonkawa field in May, which by the end of the year had produced 11,650,000 bbl. In this connection, it can be safely said that 1924 was a banner year for the Wilcox sand series; it has been estimated that between 40,000,000 and 50,000,000 bbl. of the production for the year came from this sand. Although numerous Wilcox pools were opened throughout the state, the big Wilcox production came from. the Tonkawa and Stroud pools. Oklahoma's deepest well, the Kingwood Oil Co. No. 1 Barnett in the northwest corner of the northeast quarter of the southeast quarter of Sec. 7 T. 7 N. R. 10 E., Hughes County, was abandoned in January, at 5281 ft. with numerous good shows recorded, which have stimulated-further drilling in the locality.

Jan 3, 1925

By Frank E. Shepard

Electric power in mining-operations is now successfully applied to haulage, hoisting, lighting and pumping; and until lately, drilling was the one department of mining in which an electric source of energy had not been introduced. Drilling by electric power has been the field for much investigation and several forms of electric-drills have been tried; but in the severe service of rock-drilling many dieculties have been encountered, and the heavy cost of repairs has caused a deep prejudice against this system of drilling. In the majority of electric rock-drills previously placed on the market, two principal factors have been considered; first, a portable electric motor usually of heavy pattern, coupled to the driving-mechanism of the drill proper by means of a flexible shaft; and second, the coupling of some form of reciprocating cross-head to a piston by means of a spiral spring, the drill-bit being fastened to the piston-rod by some suitable form of chuck with fastening bolts and nuts. In this latter form of drill, the cross-head has a fixed stroke, while the piston with drill-bit attached is allowed a variable stroke through the

Jan 1, 1904

By Ancel St. John

At the New York meeting of the Institute of Metals Division in February, 1927, Jeffries and Tarasov presented a paper on Tungsten and Thoria,' in which the experimental facts were interpreted in accordance with the prevailing point of view that the thorium is present as the oxide, thoria. In discussing that paper the writer of this article stated that his own investigations, which had been unavailable to Messrs. Jeffries and Tarasov, showed that the so-called "thoriated" tungsten filament failed to disclose any sign of the oxide when subjected to X-ray diffraction analysis, but did give plenty of evidence of the presence of metallic thorium and, in certain cases, of a material believed to be an alloy of tungsten in thorium. Since these results were completely at variance with the results reported in the paper under discussion and with other papcrs which had preceded it from time to time in the past, it was felt that further discussion should be withheld until the new evidence could be presented adequately. Arrangc-mcnts were therefore made to present that evidence at this meeting. Material Examined The material exalllined was high-ernission filament such as is used in radio tubes, supposed to contain about 0.75 per cent. thoria. The actual analysis was not stated. Scope of the Investigation The investigation was undertaken because of a feeling that the thorium present in filamentary material of this type exists as metallic thorium or as an alloy of thorium and tungsten and not as the oxide. Attention was therefore directed to determining: 1. The minimum amount of thoria detectible in a mechanical mixture of thoria powder and finely divided tungsten. 2. The amount of t.horia detectible in the filament. 3. The condition of any thorium present in other form than as thoria. 4. The amount of thorium dissolved in the tungsten.

By Richard H. Rein, John Chipman

The activity of SiO2, in the entire liquid system SiO2-CaO-Mg0-A12O3 at 1600°C is calculated from the distribution of silicon between these slags and Fe-Si-C alloys saturated with either graphite or silicon carbide, the activity coefficient of silicon in these alloys, and the requisite thermodynamic data. The activities of the other components in the ternary systems SiO2-CaO-A12O3, SiO2-MgO-CaO, SiO2-MgO -A12O3 are computed from these data by the IrON blast-furnace slags can be regarded as consisting of the four major oxide components, SO2, CaO, MgO, and A12O3 along with minor proportions of other oxides and of sulfur. The purpose of this study is to measure the activity of silica in the liquid solutions of these four oxides at iron-making Gibbs-Duhem equation with the aid of the known free energies of several of the interoxide compounds and the accepted phase diagrams. Based on these activities, new data are Presented for the free energy of formation of a number of the interoxide compounds. The free energy of mixing the liquid metasilicates of CaO and MgO shows slight positive deviations from the ideal. temperatures and to obtain activities of the other components by application of the Gibbs-Duhem equation and the properties of several interoxide compounds. Recent investigations on the activity of silica in the SiO2-CaO-A12O3 system1-3 and recogntion of a serious error in older data for the free energy of formation of SiO2 (Ref. 4) have succeeded in bringing a fair degree of concordance into the results of different investigators. In the present study, the activity of silica is obtained from the silicon-distribution experiments described in a previous paper,' the revised activity coefficient of silicon

Jan 1, 1965

By G. S. Scott, H. G. Turner, W. L. Kleene

It is well known that different forms of carbon show differences in chemical behavior under apparently identical conditions. It is fairly well known that these differences persist, although to a lesser degree, in a single group of carbons, such as the anthracites of Pennsylvania. It is the purpose of this paper to show the extent of these variations for Pennsylvania anthracites from actual quantitative measurements of the amount of carbon dioxide reduced under the standardized test conditions employed. As the amount of carbon dioxide reduced to the monoxide (under comparative conditions termed, for convenience, the "reactivity") is important in combustion, gas production and metallurgy, it is hoped that this paper will be a useful contribution to the store of knowledge on these subjects. In carrying out the investigation, considerable time and thought were spent in obtaining what seemed to be the best possible design of apparatus. The next step consisted in making a number of trial runs on the same sample, varying temperature, particle diameter, etc. and then outlining a standardized procedure to be followed in testing all samples. Fifty anthracites were tested. As a matter of interest, some 10 miscellaneous samples were also tested. The data show initial reaction temperatures (abbreviated I.R.T.), reaction velocity constants at 900" and 950" C., some effects of added substances, and a few additional tests designed to throw some light on the causes of differences in reactivity. The sample of charcoal, as was anticipated, proved to be easily the most reactive of any sample tested. The anthracites as a group came second. The five samples of gas and by-product cokes, obtained from five different coke manufacturers, came third, and a single sample of Rhode Island anthracite ranked fourth, with respect to reactivity as above defined. Although the five coke samples do not necessarily represent the average market coke, and five samples constitute a rather small number of samples to serve as a basis for comparisons, the fact that none

Jan 1, 1934

By Irwin Roman, Thomas C. Serman

It has been known for many years that when a wire is moved in a magnetic field, an electromotive force is developed which is proportional to the rate at which the wire is moved in a direction perpendicular to the magnetic intensity and to the magnetic intensity itself. If the ends of the wire are connected to a current indicator, the current behaves exactly as though the source of electromotive force were a galvanic cell. If a wire is wound circularly and rotated uniformly around a diameter not parallel to the intensity, the current flowing through the wire will be alternating of sinusoidal shape. If, instead of a single loop, there are several turns wound in a short helix, the electromotive force developed will be approximately proportional to the number of turns, the area of the helix and to the speed of rotation. The maximum electromotive force will be developed when the axis of rotation is perpendicular to the field; if this is not so, only the component of the intensity that is perpendicular to the axis of rotation is effective. This is the principle of the usual earth inductor. With a few turns of wire and comparatively slow rotation, it is possible to produce a considerable deflection of a galvanometer. If two similar coils are rotated together at two different points for which the magnetic field intensities perpendicular to the axes of rotation are different, the electromotive forces developed will each depend on its corresponding intensity and be a measure of that intensity. If the intensities are sufficiently different so that the electromotive forces may be compared, the two intensities may be compared. This is the principle

Jan 1, 1934