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By G. L. Kulcinski, R. D. Leggett

Irradiated uranium containing 635 ppm of carbon, mostly in the form of UC precipitates, was annealed at temperatures from 650" to 900°C under hydrostatic pressures of 0 to 1000 bars. Postirradiation examination revealed that the carbide particles are not stable in the r phase of irradiated material but are stable in unirradiated material annealed under identical conditions. The degree of carbide dissolution appears to be connected with the fission product concentration and independent of annealing pressure. THIS paper describes the change in appearance of carbide particles in irradiated uranium after the uranium has been postirradiation-annealed. It has been proposed by several investigators&apos;-5 that fission gas-induced swelling in irradiated uranium may be reduced by incorporating a fine dispersion of second-phase particles into the metal. Because of the low solubility of carbon in uranium6 and the apparent stability of UC precipitates at high temperatures,6-8 this system has received some attention. The stability of UC particles to low-temperature irradiation has been demonstrated many times, as well as their stability during postirradiation anneals in the high a or B phases.9 Unirradiated uranium containing UC particles has been annealed high in the r phase, and the solubility of carbon was found to be only -115 ppm at 1050ºC.6 Vacuum annealing of irradiated uranium to the same temperature produces a spongelike sample, due to the formation and growth of fission gas bubbles."14 This highly disrupted lattice has made any determination of the stability of UC at these temperatures impossible. Nevertheless, it has always been tacitly assumed that the UC particles were still present. Recently, postirradiation, high pressure-high temperature tests have been performed on irradiated uranium containing a secondary phase of UC. 14 Examination of these samples after 100-hr, 900°C tests revealed that the carbides are not stable, and the results of these tests are presented here. 1) EXPERIMENTAL PROCEDURE The samples, high-pressure equipment, and subsequent analytical techniques are the same as those described elsewhere.14,15 Briefly, cylindrical samples of commercial-purity uranium that had been irradiated at <350°C to 0.37 at. pct B.U. were subjected to 90O°C, 100-hr anneals in NaK at pressures ranging

Jan 1, 1970

By N. C. Fick, R. L. Rickett

DESPITE the large volume of literature on alloys of iron and silicon,1 there is little published information dealing specifically with the constitution, at various temperatures, of the alloys containing less than 0.10 per cent carbon and from 0.5 to 4.5 per cent silicon that are used extensively in the electrical industry. Because such information was needed by those engaged in the production of these alloys in, sheet and strip form, the constitution was determined of a series of commercial silicon steels containing 0.05 to o.08 per cent carbon and 0.20 to 4.31 per cent silicon, over the temperature range 1300° to 2500°F. These alloys were all from regular production heats and of commercial quality. The results of, the tests are given in Fig. I and for comparison the constitution diagram of iron-silicon alloys with 0.01 to 0.02 per cent carbon, taken from the literature, is also presented. MATERIAL AND PROCEDURE All steels were hot-rolled to a thickness of 0.060 to 0.080 in. and used in this condition. Their chemical compositions, including over-all check analysis, and "center" analysis for carbon and silicon, are given in Table I. The so-called center analysis was determined on samples pickled to remove the outer surface and leave only the center third of the gauge thickness-the portion of the sample on which metallographic ratings were based. In most, but not all, of the alloys, slightly higher carbon was found at the center than when the whole strip was sampled; the two methods of sampling show relatively little difference in silicon. Two of the steels, A and E, contain relatively high phosphorus, while I and K are somewhat higher in manganese than the others. [ ] The procedure consisted essentially of heating specimens (about 1/16 by 3/8 by 3/4 in.), protected from oxidation or change in carbon content, at a temperature in the desired. range and for a selected period, after which they were quenched in iced brine; the degree of transformation that had then occurred was determined by metallographic examination. The soaking periods were selected after preliminary investigation had shown that a con-

Jan 1, 1946

THE 144th* meeting of the American Institute of Mining and Metallurgical Engineers was held in New York, Feb. 18 to 21, 1935. It consisted of the annual business meeting, 45 technical sessions at which 216 papers were presented (approximately the same number of sessions and papers as at the previous annual meeting), two sessions of the Board of Directors, three meetings of Section delegates, two formal lectures and two addresses, luncheon Monday, Tuesday and Wednesday for members and guests, six group dinners and eight group luncheons, ten committee meetings, the annual reception and dinner dance, an informal dance, a smoker-dinner and the annual meeting of the Woman&apos;s Auxiliary. Attendance was generally greater than for the two preceding meetings; the statistics follow (figures are in the order 1935-1934-1933); total registration, 1609-1534-1475; dinner dance, 577-543-426; dinner-smoker, 490-425-394; informal dance, 279-295-250; women&apos;s registration, 179-160-133; general luncheons, 1132-1034-734. The Coal Division held two general sessions on Monday and a symposium on coal-mine ventilation on Tuesday morning. The Committee on Bituminous Planning, Edward Steidle, chairman, presented a report at the Monday morning session. C. B. Huntress, President of Appalachian Coals, Inc., was the principal speaker at the luncheon on Monday, at which Eli T. Conner, Chairman of the Division, presided. Mr. Huntress was preceded by Howard N. Eavenson, President of the Institute, who spoke briefly. The Sectional Committee on Classification of Coal met Wednesday afternoon. A feature of the meeting concerning three Divisions-Iron and Steel, Institute of Metals, Petroleum-was the symposium on Use of Metals in the Petroleum Industry, Thursday morning and afternoon. Five of the papers presented at this symposium have been published in METALS TECHNOLOGY&apos;. Another feature, of general interest, was the Tuesday morning session in the Auditorium, devoted to Federal Government and Mineral Industries. Dr. C. K. Leith delivered the principal address, on "A, Mineral Policy for the United. States." . The Institute of Metals Division held technical sessions Tuesday afternoon and Wednesday. morning and afternoon and on Thursday

Jan 1, 1936

By P. Hadzeriga

There are two places in the world where potash, trade name for potassium chloride, is economically recovered from naturally occurring brines by solar evaporation. One is at the Dead Sea and the other at Wendover, Utah. American Potash and Chemical at Trona, Calif. recovers potash from natural brines, but uses fuel to accomplish evaporation. Solar evaporation is always desirable, because of low costs, however artificial evaporation may be economical if a group of very valuable salts are recovered. This is the case for the American Potash operations at Trona. Solar evaporation is limited by low working temperatures, which in most areas of the world is between 18 and 45°C. In many cases the average working temperature is about 25°C. However, solar evaporation will have to accommodate itself to the highs and lows of each 24 hour period, and to the different average temperatures during the months of the year. Therefore, solar evaporation, although more economical than artificial evaporation, has a tem- perature limit which greatly reduces the chances of its application. The feasibility of solar evaporation as a means of recovery of values from a particular brine, may be evaluated by the use of phase diagrams showing the several components present. This paper is restricted to the five component system: C1-, SO4=, Na+, K+, Mg++, and H2O, which correspond to brines found at Wendover, Utah, the Great Salt Lake, and sea water bitterns. THE BONNEVILLE OPERATION AT WENDOVER, UTAH For more than 25 years Bonneville, Ltd., now a division of Standard Magnesium and Chemical Co. (recently acquired by Kaiser Aluminum and Chemical Corp.), has been recovering potassium chloride from the brines found in the desert area just east of Wendover, Utah. Solar evaporation of the brines is possible as a consequence of relatively low precipitations (year average: 4.8 in.), and of dry and hot summer months. The brine, collected by a series of approximately 67 mi. of ditches crossing the desert, is fed into solar evaporation ponds. Evaporation which takes place from around the middle of May to about the end of September, permits the crystallization of approximately 90% of the originally present NaCl on what is called the "General Pond Area". Further evaporation,

Jan 1, 1964

By John P. Hager, Adolfo R. Zambrano

The thermodynamics properties of the liquid Pb-Ag-Au system have been determined from galvanic cell measurments five pseudobinary systems of fixed XAg/XAu ratio. The galvanic cell employed a molten PbO-SiO2 electrolyte and was operated between 775" and 1030°C. The thermodynamics properties of lead were obtained directly from the experimental data, whereas the excess integral molar properties and the activities of silver and gold were obtained by means of the Gibbs-Duhem equation. The calculated proper -ties of the Ag-Au system agree well with the published properties. The liquidus surface of the Pb-Ag-Au system has been determined at 1200°K. In Parts I&apos; and 11&apos; the galvanic cell Mo,Pb(l)|(PbO-SiO2)(l) SiO2(s) |Pb(alloy)(l), Mo [I] was used to determine the thermodynamics properties of the Pb-Ag and Pb-Au systems, respectively. The use of cell I, in which a molten oxide electrolyte is employed rather than the classical fused-salt electrolyte, was shown to result in more accurate ther-modynamic measurements in that the displacement reaction at the alloy-electrolyte interface (l/Zb)B(alloy) + (I/za)A+Za = (1/Za)A(alloy) + (1/Zb)B+zb [1] was minimized. For the Pb-Ag system, where B = Ag(l), the error in the activity of lead (aPd) re-sulting from Reaction [I] was calculated to be less than 1 pct.l For the Pb-Au system the error in aPb was calculated to be less than 0.5 pct.2 Also, electro-transport measurements on the PbO-SiO2 electro-lyte1,2 established that the conduction was entirely ionic and that lead was present only in the divalent state. In the present study the experimental technique is extended to an investigation of the thermodynamic properties of the liquid Pb-Ag-Au system. Five pseudobinary systems of fixed X Ag/XAu ratio were selected. The experimental results were then combined with the previous measurements on the component binary systems Pb-Ag1 and Pb-AU2 to calculate, by means of the Gibbs-Duhem equation, the molar and partial molar mixing properties for the liquid ternary solutions.

Jan 1, 1970

By Frederic H. Lahee

After abandoning two dry holes, on the Mrs. Daisy Bradford land, C. M. Joiner finally completed his No. 3 on Sept. 8, 1930, at a total depth of 3592 ft. This well is 735 miles somewhat north of west of the town of Henderson, in Rusk County. Between Oct. 2 and Oct. 6, this well made numerous heads which indicated that it would produce about 300 bbl. daily. By Nov. 27, two dry holes,&apos; completed near the Joiner well, taken in conjunction with the small production from this well, served to dampen any enthusiasm among those who hoped for a major pool; but by December 18 three other producers had been completed. On Dec. 28, 1930, E. W. Bateman&apos;s Lois Della Crim No. 1 drilled itself in with an estimated daily yield of between 10,000 and 15,000 bbl. from a depth of 3650 ft. This well, 10 miles north of the Joiner well, also in Rusk County, initiated the leasing campaign that led to the later orgy of drilling. On Jan. 25, 1931, Moncrief, Farrell and others completed their J. K. Lathrop 1 as another big producer, 7 miles east of Gladewater in Gregg County and 14 miles N. 20" E. from the Bateman Crim well. The Lathrop well, 3574 ft. deep, flowed 320 bbl. in 1 hr. through a ½in. choke. The first well completed in Smith County was Cook No. 1, drilled by Guy Lewis et al. in the James Jordan Survey, 4.7 miles west of the Joiner discovery well. On Mar. 30, 1931, it flowed 137 bbl. in 33 min, through a ¾-in. choke. The top of the pay sand was found at 3672 ft. Finally, in Upshur County, on May 5, the Mudge Oil Co. et al. completed the Richardson No. 1, which flowed 274 bbl. through a 4 2/64-in. choke in 2 hr. This well is 4 miles northwest of the Lathrop producer. Development It is unnecessary to give a lengthy description of the rapid development of the area discovered in these five far-separated wells, or to discuss the speculations offered as to whether there were several pools or only one.

Jan 1, 1932

By Edward Keller

Although the subject matter contained in this paper is presented under a new title, its writing was induced by the work of S. Skowronski and K. W. McComas.&apos; A discussion of the latter is here combined with the presentation of new and independent data. The&apos; physical constants quoted by the authors of that paper, such as melting and boiling points, as also the chemical reactions of the substances involved, are so well established that the numerous confirmatory experiments and their application to metallurgical conditions leave little or no room for criticisms. On the contrary, they will greatly aid to dispel any lingering skepticism as to possible considerable losses of copper accruing when the metal is melted in the presence of its own and, probably, other chlorides and when no provision is made for the recovery of volatile products. Exception may be taken, to some degree, to that part of the work under the caption Melting Drillings of Copper Mixed with Sodium Chloride. These experiments should have been extended in order to make the implied reactions clear and the results convincing. The latter are stated to be, "that when sodium chloride is present above certain minimum quantity relative to copper some of it is found to volatilize in the melt while another part reacts with the metallic copper to produce the volatile cuprous chloride, and that when smaller quantities of sodium chloride are present the reaction is complete and all chlorine is found to have volatilized as cuprous chloride." Metallic copper and sodium chloride are mentioned as the sole reagents in this chemical process, acting, according to the authors, in a neutral atmosphere of carbon dioxide. The chemist, quite naturally, wi11 inquire into the formula according to which that reaction takes place and will find that it presents itself as follows: 2Cu + 2NaCl = 2Na + Cu2Cl2 It would appear that the truth of this formula will be challenged and a more rational explanation of the reaction sought. Apparently, carbon dioxide is neutral relative to metallic copper in its molten state; whether it remains neutral in the presence of sodium chloride is quite another

Jan 1, 1921

By William A. Longacre

In a previous paper the author discussed the problem described by the title of this paper, outlining and reviewing the Gish-Rooney method, with comparison and brief analysis of the interpretation techniques of Roman2 and Tagg.3 Some aspects of the simple type of two-layer system were reviewed from various sources.4, 5, 6 The Two-layer Problem For the configuration shown in Fig. I, and for any electrode separation A, the SurfAce of earth p, DepthH i P2 Infinite depth Fig. i.—Two-Layer system. apparent resistivity is a function of the relative depth the overburden resistivity pl, and a factor K defined by the equation P2 + P1 where p, is the resistivity of the lower bed. Thus, by the known theory of electrical images, p = pi [1+ */(*-7)] where The Multilayer Problem As the number of isotropic, homogeneous, horizontal layers increases, the difficulties of interpretation multiply. The theory becomes much more involved, and in view of the state of our knowledge, the general problem is virtually impossible of exact solution. However, certain types of multilayer problems can be worked out in terms of two-layer theory. Humme1,7 Pirson,8 Tagg,3 Watson,9 and others have pointed out the possibility of building up approximations of multilayer resistivity curves with suitable combinations of two-layer curves. Many three-layer curves can be constructed in this way to a good degree of accuracy, and special types of four-layer curves can be approximated. It is very likely that as the number of layers increases, the method of combination will not give good approximations except in very special cases. In the analysis of actual field data, the author has found that many obviously multilayer curves can be solved partially with a good degree of accuracy, using the theory that thin adjacent beds may be considered as one layer or zone, and applying two-layer theory to the extremities of the field curve. Modified Tagg Method of Interpretation Tagg&apos;s second method, though superior to his first, necessitates a large number

Jan 1, 1946

By William A. Longacre

In a previous paper the author discussed the problem described by the title of this paper, outlining and reviewing the Gish-Rooney method, with comparison and brief analysis of the interpretation techniques of Roman2 and Tagg.3 Some aspects of the simple type of two-layer system were reviewed from various sources.4, 5, 6 The Two-layer Problem For the configuration shown in Fig. I, and for any electrode separation A, the SurfAce of earth p, DepthH i P2 Infinite depth Fig. i.—Two-Layer system. apparent resistivity is a function of the relative depth the overburden resistivity pl, and a factor K defined by the equation P2 + P1 where p, is the resistivity of the lower bed. Thus, by the known theory of electrical images, p = pi [1+ */(*-7)] where The Multilayer Problem As the number of isotropic, homogeneous, horizontal layers increases, the difficulties of interpretation multiply. The theory becomes much more involved, and in view of the state of our knowledge, the general problem is virtually impossible of exact solution. However, certain types of multilayer problems can be worked out in terms of two-layer theory. Humme1,7 Pirson,8 Tagg,3 Watson,9 and others have pointed out the possibility of building up approximations of multilayer resistivity curves with suitable combinations of two-layer curves. Many three-layer curves can be constructed in this way to a good degree of accuracy, and special types of four-layer curves can be approximated. It is very likely that as the number of layers increases, the method of combination will not give good approximations except in very special cases. In the analysis of actual field data, the author has found that many obviously multilayer curves can be solved partially with a good degree of accuracy, using the theory that thin adjacent beds may be considered as one layer or zone, and applying two-layer theory to the extremities of the field curve. Modified Tagg Method of Interpretation Tagg&apos;s second method, though superior to his first, necessitates a large number

Jan 1, 1946

By W. C. Hagel, H. J. Beattle

DURING an earlier examination of high-temperature alloy, A-286, the presence of an unknown intermetallic compound was verified by X-ray diffraction. Owing to its prominent appearance at grain boundaries, the arbitrary name of G phase was assigned.&apos; Low-silicon, vacuum-melted heats were found to contain no G phase, and this investigation was initiated to determine the influence of silicon on G-phase formation; additional work was undertaken to extend existing data on other intermetallic compounds and the aging reactions in this group of alloys. Taylor and Floyd2-4 observed that the Ni3Al phase (y&apos;) and the Ni8Ti phase (7)) are the only equilibrium intermetailic compounds in nickel ternary alloys containing up to 25 pct Cr and 10 pct Ti or Al. They found that y&apos; can dissolve considerable nickel, chromium, and titanium, although the stoichio-metric composition of 7 remains fixed. Nordheim and Grant5 confirmed that age hardening of 80 pct Ni-20 pct Cr alloys of the Nimonic-80 type is due to precipitation of y&apos;, where aluminum is partially replaced by titanium. They suggest that optimum hardness and ductility result from increasing the titanium to aluminum ratio toward the end of the y&apos; solubility range and from increasing total titanium and aluminum content to the maximum limit permitted by processing. Such information is necessary for those seeking to improve the service-temperature range and long-time structural stability of high-temperature components. Experimental Methods Compositions of materiais studied. are listed in Table I. Alloys D, E, and F possess representative A-286 analyses; silicon increases from less than 0.02 to 1.75 pct in alloys A to H; in alloys I to K, titanium decreases from 2.24 to 0.39 pct, and aluminum increases from 0.1 6 to 240 pct. Alloys A and D were solution heat treated for 4 hr at 1700°F, oil quenched and aged for 0.5, 2, 6, 12, 30, 70, 200, and 1000 hr at 1200°, 1300°, 1400°, and 1500°F. Therefore, a total of 33 specimens was required for each

Jan 1, 1958

[Separates of all the Technical Publications published in 1928 are available at Institute headquarters. All the papers are on file in public, university and technical libraries, and when so indicated in the list, may be found either in the TRANSACTIONS or in the special volumes issued by the Institute.; METAL MINING TECH- NICAL TRANS. PUBLI- TITLE AUTHOR MEETING VOLUME CATION AND PAGE* No. 50 The Eötvös Torsion Balance D. C. Barton New York Method of Mapping Geologic Feb., 1928 Structure 52 A Cartographic Correction for the C. A. Heiland New York Eötvös Torsion Balance Feb., 1928 61 Liquid-oxygen Blasting at Chuqui- H. C. Schultz, New York camata, Chile F. K. Middleton Hunter Feb., 1928 76, 108, 123 64 Working Methods of Practical Geo- Hans Haalck New York physics Feb., 1928 65 Experiments with Eötvös Torsion P. W. George New York Balance in the Tri-State Zinc and Feb., 1928 Lead District 74 Gravity Surveying in Great Britain H. Shaw New York Feb., 1928 75 The Computation of Eötvös Gravity E. Lancaster-Jones New York Effects Feb., 1928 82 Earth-resistivity Measurements in W. O. Hotchkiss, New York the Lake Superior Copper Country W. J. Rooney, Feb., 1928 James Fisher 83 Mining Methods and Records at the Roy W. Moore New York 76, 56, 90 United Eastern Mine Feb., 1928 98 Recent Results in Electrical Pros- Hans Lundberg New York specting for Ore Feb., 1928 101 Relation between the Oxygen Bal- G. St. J. Perrott, New York ance and Propulsive Strength of N. A. Tolch, Feb., 1928 Eight Gelatin Dynamites J. E. Crawshaw 102 Effect of Oxygen Balance of Gelatin G. W. Jones, New York Dynamites on the Gaseous Prod- G. St. J. Perrott Feb., 1928 ucts of Detonation 108 The Financial Report of a Min- Henry B. Fernald New York ing Company-Its Content and Feb., 1928 Meaning 116 What Duty to Support the Surface R. G. Bosworth New York Does a Subsurface Owner Owe? Feb., 1927 136 Comparison of Branch Raise and C. A. Mitke Los Angeles 76, 93, 103 Combined Shrinkage and Caving Sept., 1928 Methods 141 A Mining Company Balance Sheet G. F. Wolff New York Feb., 1928

Jan 1, 1927

By A. Lawley, H. W. Schadler

TWINNING has long been recognized as a possible mode of deformation in crystalline solids and has been studied in a wide variety of crystals.&apos; Recently, deformation markings which have the topographical characteristics of twins have been seen in tungsten" and the body-centered cubic alloys of tungsten and molybdenum with rhenium.3-7 These markings have been identified as twins because: 1) they are visible after polishing and etching;2,3 2) their formation is accompanied by an audible click and a drop in load;4 and 3) the habit plane is {112}, the plane which has been identified as the twinning plane for several body-centered cubic metals.&apos; However, there has been no published evidence for the specific determination of the twinning direction in rhenium alloys of tungsten and molybdenum, because usually the deformation twins were not broad enough to be detected with a conventional X-ray beam. Consequently, [111] is inferred as the twinning direction since the latter must lie in a plane of symmetry perpendicular to the twinning plane (112). As Sims and Jaffee3 and Lawley and Maddin4 have shown, the addition of rhenium to molybdenum and tungsten increases the ductility of the alloy over that of the pure metal, but twinning is much more profuse in these alloys than in the pure elements, particularly at Mo-35 pct Re*and W-30 pct Re. Since twinning is often associated with brittle fracture in iron8 and the silicon-irons,9 direct experimental proof that the deformation markings in tungsten and molybdenum alloys of rhenium are twins seemed to be needed. Using the Laue back-reflection technique, the deformation markings in a Mo-35 pct Re alloy are shown to be deformation twins. The twins have a (112) habit plane and the twinning direction is <111>. The Mo-35 pct Re specimen used was taken from a 0.060-in. zone-refined single crystal deformed 6 pct in tension at 78°K. The Laue back-reflection technique, with a film to specimen distance of 2 cm, and white radiation from a copper target were used.

Jan 1, 1962

By B. D. Cullity

This investigation of bismuth-selenium alloys was made in an attempt to find a suitable material for use in thermoelectric generators. These devices are simply thermocouple circuits designed for the efficient production of electrical energy from thermal energy, which may in turn be derived directly from solar radiation or from the combustion of fuels. The requirements of a material for use in a thermoelectric generator are obviously quite different from those of a material used in a temperature-measuring thermocouple. Naturally, for power generating purposes, the thermoelectric power (voltage produced per degree difference in temperature between the junctions) must be as high as possible. Furthermore, in order to obtain reasonably high power outputs, the materials used in the generator must have an electrical conductivity which is as high as possible. Finally, in order to minimize heat lost by conduction to the cold junction, the thermal conductivity must be as low as possible. The relation between these several factors and the efficiency of conversion of thermal into electrical energy—the thermoelectric efficiency—has been discussed by Telkesl in a recent review of the subject. She gives the thermoelectric efficiency as: W o Efficiency = -Wo ______________i____________ TR-TC+ O2TR-Tc) where W, = power output in external load (watts) Wi = rate of heat input to hot junction (watts) TE,T, = temperature of hot and cold junctions (oA) K1,Kz = thermal conductivity of the two thermocouple materials (watts/cm°C) p,,pz = electrical resistivity of the two thermocouple materials (ohm cm) 9 = thermoelectric power (volts0/C) For many materials, some of the desired properties (for example, high electrical and low thermal conductivity) are almost mutually exclusive; the problem thus becomes one of finding a material which has the optimum combination of pfoperties. Bismuth-selenium Alloys work on the equilibrium diagram of the bismuth-selenium alloys has been reviewed by Hanson who gives the diagram reproduced in There are two intermediate phases in this system, BiSe and Bi²Se3. The existence of an alpha and beta modification of BiSe has not been demonstrated satisfactorily and the writer found no evidence of it in the present work. BiSe and Bi2Se3 have, like bismuth, a rhombohedra1 crystal

Jan 1, 1949

By P. K. Foster, C. M. Payne, A. McNabb

Some measurements of the rate of loss of hydrogen from cylinders of iron and steel are analyzed in terrns of a trapping theory. The apeement is encozcraging and gives rise to estimates for the density of traps in the metal. Furthermore, the results appear to be consistent with the assumption that the diffusion constant D for the steady flux of hydrogen through iron lies on the extrapolation of the linear curve (log D us 1/T) obtained at higher temperatures. IT has been shown in a previous paper1 that the literature relating to hydrogen diffusion in steels contains sufficient evidence to invalidate the application of Fick&apos;s laws to hydrogen diffusion in steel at low temperatures. To account for the deviations from simple diffusion behavior a trapping theory was developed, and the fundamental laws modified accordingly. In the present paper, new data on the evolution of hydrogen from long cylinders are presented, and together with some published data are examined in terms of the requirements of the theory.&apos; Properties of solutions of the basic equations derived previously1 and appropriate to the present experimental conditions are outlined in the first section as they determine the form in which the experimental data must be presented for a comparison of theory and experiment. Two new solutions not previously reported have been derived as described in the Appendix. The experiments and treatment of data are then given in Sections 2 and 3 and the results are discussed in Section 4. 1) THEORETICAL CONSIDERATIONS The hydrogen-diffusion theory1 applied in this paper postulated that lattice-dissolved hydrogen at a concentration C diffuses randomly in accordance with Fick&apos;s first law, but that the lattice contains a uniform density N of traps which can capture and delay hydrogen atoms. kC atoms are trapped per second in a region containing unit concentration of vacant traps while p are released per second in a region containing unit concentration of occupied traps. On this basis it was shown (Eq. [30] of Ref. 1) that, when local changes in the lattice-dissolved concentration C are slow enough for equilibrium to be established with the traps, the system is represented in dimensionless form by the equation:

Jan 1, 1965

Iron Ores and Blast Furnace Practice Concentration of Iron Ores in the United States. By T. R. Counselman. (Metals Technolog), December 1943) Selection of Blast-furnace Refractories. By Hobart M. KrANer and E. B. Snyder. (Metals Technology, April 1944) The Washing of Pittsburgh Coking Coals and Results Obtained on Blast Furnaces. By C. 1). King. (Metals Technology, September 1943) Steelmaking The Role of Basic Slags in the Elimination of Phosphorus from Steel. By Richard L. BArrett and William J. McCaughey. (Metals Technology, April 1944) The Relative Deoxidizing Power of Boron In Liquid Steel and the Elimination of Boron in the Open-hearth Process. By B. W. Gurry. (Metals &apos;Technology, December 1943) Manufacture and Properties of Killed Bessemer Steel. By C. C. Wright. (Metals Technology, June 1944) Hardenability Effect of Sixteen Alloying Elements on Hardenability of Steel. By Irvin R. Kramer, Robert Hafner and Stewart L. Toleman. (Metals Technology, September 1943) Effect of Quenching Temperature on the Results of the End-quench Hardenability Test. By Clarence E. Jackson and Arthur L. Chrjstenson. (Metals Technology, December 1943) Effect of Some Elements on Hardenability. By Walter Crafts and John L. Lamont. (Metals Technology, January 1944) Effect of Several Variables on the Hardenability of High-carbon Steels. By I?. S. Rowland, J. Welchner and R. IS. Marshall. (Metals Technology, January 1944) Mechanical Properties Influence of Hydrogen on Mechanical Properties of Some Low-carbon Manganese-iron Alloys and on Hadfield Manganese Steel. By Herbert H. Uhlig. (Metals Technology, June 1944) Aging and the Yield Point in Steel. By J. R. LOW, Jr., and 14. Gensamer. (Metals Technology, December 1943) Tensile Properties of Medium-carbon Low-alloy Cast Steels. By H. A. Schwartz and W. Kenneth Bock. (Metals Technology, August 1944) Variables Affecting the Results of Notched-bar 1mpct Tests on Steels. By CLarence 15. Jackson, MYRon A. Pugancz and Frank S. McKenna. (Metals Technology, August 1944) The Notched-bar Lmpact Test. By John H. Hollomon. (Meta1s Technology, April 1944) Hardness Measurement as a Rapid Means for Determining Carbon Content of Carhon and Low- alloy Steels. By K. L. Clark and NIcHols Kowall. (Metals Technology, January 1944)

Jan 1, 1944

By Colman Goldberg

IT is customary to plot crystallographic planes or axes on a Wulff stereographic net which is ruled with parallels of latitude and meridians of longitude. If a single crystal is placed at the center of a sphere, the coordinates of a crystallographic plane or axis are the coordinates of the point where the axis intersects the sphere. The standard (HKL) projection is the projection for which the sphere is rotated so that the (HKL) pole is at the center of the projection. Schiebold and Sachs&apos; and many others have published standard projections for the more important planes of a cubic crystal. With Tables I and 11, it is possible to plot any plane (HKL) of a cubic crystal on a standard (001) projection if the absolute values of the individual H, K, and L are nine or less, which is almost always the case. Using the methods outlined by Barrett,&apos; the standard (001) projection can be rotated so that any arbitrary plane is at the center of the projection. The tables are believed to be important for two reasons: 1—The heretofore published standard projections usually are not of the proper size to fit the stereographic nets available. With these tables a standard projection can be made which will be of exactly the proper size for the available stereographic net. 2—With the tables, planes that do not appear on the previously published standard projections can be easily plotted. For these reasons, the tables are especially useful in the study of optical reflections from etched surfaces and can also be used to make a standard projection for the axis which is normal to the macroscopic surface. (This axis can be found by X-ray or optical methods.) Then if the crystal is etched, the effect of the etchant can readily be determined by comparing the latitude and longitude of the reflecting planes (as determined with an optical goniometer) with the standard projection that has been prepared. Use of the Tables Fig. 1 shows the meridians and parallel which have been designated as zero longitude and latitude. The tables themselves are self-explanatory. The

Jan 1, 1953

Iron Ores and Blast Furnace Practice Concentration of Iron Ores in the United States. By T. R. Counselman. (Metals Technolog), December 1943) Selection of Blast-furnace Refractories. By Hobart M. KrANer and E. B. Snyder. (Metals Technology, April 1944) The Washing of Pittsburgh Coking Coals and Results Obtained on Blast Furnaces. By C. 1). King. (Metals Technology, September 1943) Steelmaking The Role of Basic Slags in the Elimination of Phosphorus from Steel. By Richard L. BArrett and William J. McCaughey. (Metals Technology, April 1944) The Relative Deoxidizing Power of Boron In Liquid Steel and the Elimination of Boron in the Open-hearth Process. By B. W. Gurry. (Metals &apos;Technology, December 1943) Manufacture and Properties of Killed Bessemer Steel. By C. C. Wright. (Metals Technology, June 1944) Hardenability Effect of Sixteen Alloying Elements on Hardenability of Steel. By Irvin R. Kramer, Robert Hafner and Stewart L. Toleman. (Metals Technology, September 1943) Effect of Quenching Temperature on the Results of the End-quench Hardenability Test. By Clarence E. Jackson and Arthur L. Chrjstenson. (Metals Technology, December 1943) Effect of Some Elements on Hardenability. By Walter Crafts and John L. Lamont. (Metals Technology, January 1944) Effect of Several Variables on the Hardenability of High-carbon Steels. By I?. S. Rowland, J. Welchner and R. IS. Marshall. (Metals Technology, January 1944) Mechanical Properties Influence of Hydrogen on Mechanical Properties of Some Low-carbon Manganese-iron Alloys and on Hadfield Manganese Steel. By Herbert H. Uhlig. (Metals Technology, June 1944) Aging and the Yield Point in Steel. By J. R. LOW, Jr., and 14. Gensamer. (Metals Technology, December 1943) Tensile Properties of Medium-carbon Low-alloy Cast Steels. By H. A. Schwartz and W. Kenneth Bock. (Metals Technology, August 1944) Variables Affecting the Results of Notched-bar 1mpct Tests on Steels. By CLarence 15. Jackson, MYRon A. Pugancz and Frank S. McKenna. (Metals Technology, August 1944) The Notched-bar Lmpact Test. By John H. Hollomon. (Meta1s Technology, April 1944) Hardness Measurement as a Rapid Means for Determining Carbon Content of Carhon and Low- alloy Steels. By K. L. Clark and NIcHols Kowall. (Metals Technology, January 1944)

Jan 1, 1944

By J. W. Fuller

DURING the last 20 years, experimenters have sought to utilize pulverized coal in boiler plants, but refractory and slag troubles have usually overbalanced any, gains in efficiency that were obtained. These troubles were caused largely by lack of knowledge of the proper methods of coal preparation and lack of a furnace design that would be adaptable to pulverized-coal firing. When this information was obtained the results were so much more satisfactory that within the last 5 years approximately, 80,000 boiler hp. have been installed in plants ranging from 1000 to 20,000 boiler hp. rated capacity, which are operating at an average of 174 per cent. of rating. The first commercial installation for burning pulverized coal under boilers was made at the Parsons shops of the M. K. & T. railroad in 1916. Of eight 250-hp. water-tube boilers thus fitted, six were operated continuously for 3 yr., when oil was obtained at such a low price as to warrant its use. Since then, this plant has been operating alternately on pulverized coal and oil, depending on prevailing prices. Recently gas has been discovered within 20 mi. of this plant, so that this fuel may also be used. No change in furnace design was made when changing from pulverized coal to oil or gas firing. One of the principal advantages of this method of firing is its ability to utilize, with maximum efficiency, all kinds of coal, irrespective of quality or physical characteristics. In fact, quite a number of the present pulverized-coal installations were made for the purpose of utilizing coal that could not be marketed or used in any other way. The Pacific, Coast Coal Co., at Black Diamond, Wash., formerly hand fired the boilers, using approximately 125 tons of prepared steam-size coal daily. The Black Diamond steam coal is the best quality of coal for steaming purposes mined in that section of the country, and there is a market for all that can be produced. By installing a pulverizing plant, it was possible to substitute coal of a size and quality that had no commercial value, so that 125 tons daily of the best steam coal formerly used at the mines is now marketed.

Jan 12, 1921

By Frank Firmstone

The furnace from which the brick here referred to were taken, was lined under my supervision and blown-in in May, 1902. It was 75 ft. high and 18 ft. in greatest diameter, and used coke to smelt a lean magnetic iron-ore. The lining was put in as follows:—First, blocks 14 in. long by 6 in. thick; second, 2 in. of loam; third, 13.5 in. of 9-in. fire-brick (one-and-ahalf brick wall) laid in English bond; fourth, red brick to within 2 in. of the iron shell; and fifth, 2 in. of slag-wool between the red brick and the shell. The brand of brick used has been known to me for over 20 years, and in my observation had always proved very durable, notably when used in a small furnace 50 k. high which treated the same magnetic. ore. On revisiting and examining the furnace in March, 1903, it was found that the whole of the lining of 14in. blocks at the top, and for an unknown distance (more than 20 ft.) below, had completely disappeared; and a few weeks later the 13.5-in. lining and the red brick at the top likewise vanished, and the furnace was blown out. N~twithstanding the complete failure of the lining higher up, measurements taken after blowing-out showed no unusual wear in the lower part of the furnace. The exact position in the furnace of the piece of brick-work used in the analysis, given below, is not known; but it came from between 30 and 40 ft. above the bottom. It had formed part of the 13.5-in. wall (no 14-in. brick remaining at that level) and consisted of parts of several bricks so firmly sintered together that fracture occurred indifferently through the joints and through the body of the brick. The joints could, however, be traced by a close examination. The surface which had been in contact with the material in the furnace was covered with a yellowish, translucent glaze, somewhat vesicular, and from

Jan 1, 1904

By E. I. Salkovitz, F. W. von Batchelder

AS Slawson1 and others have already shown, from a geometrical view twinning in the diamond structure may be considered as a reflection across a (111) plane or as a reflection across a (112) plane. An analysis by Ellis and Treuting2 showed that the twinning plane must be the (111) plane, but that a twin might have lateral boundaries along (112) planes. Earlier Slawson1 and Ellis3 had shown that only (111) twinning was present in diamond and germanium respectively. Since an ingot of silicon, 1 in. in diam and 1 1/2 in. long, prepared from Dupont silicon to which 0.2 pct Be had been added was available, it was examined for twinning. The ingot had been cooled slowly from the bottom. A section 1/16 in. thick was ground off from the bottom and then the ingot was sliced vertically through the center. Spectrographic analysis indicated only faint traces of iron and silver, in addition to the beryllium. The sample was first etched with a hot solution of 10 pct NaOH in water.and photographed. Back-reflection Laue patterns were made of the vertical and horizontal sections in the regions designated in Fig. 1. Orientations were obtained for each twin using the Greninger technique. Several regions of the same orientation were found; thus regions A and K were identical, similarly N and P, and C, G, J, and L. Knowing the angles between the traces of the twinning plane on the surface and the specimen axis, the indices of the twinning plane were deduced. In all cases the twinning plane was found to be (111); lateral boundaries, however, were found which were (112) such as the one indicated in Fig. 1. Therefore, as in the case of diamond1 and germanium&apos; only (111) twinning occurs in silicon. We wish to thank Mr. Hino for the use of the ingot as well as for its metallographic preparation. References 1C. B. Slawson: American Mineralogist (1950) 35, p. 193. 2 W. C. Ellis and R. C. Treuting: Trans. AIME (1951) 191, p. 53; Journal of Metals (January 1951). 3W. C. Ellis: Trans. AIME (1950) 188, p. 886; Journal of Metals (June 1950).

Jan 1, 1953