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By Joël Kapusta

La pyrométallurgie du cuivre est essentiellement une chaîne de trois étapes successives d’oxydation préférentielle du fer et du soufre et des impuretés moins nobles que le cuivre qui sont contenues dans le concentré de cuivre issu de l’usine de concentration du minerai, aussi appelée concentrateur. La Figure 1 illustre la chaîne complète d’élaboration du cuivre depuis la mine jusqu’au cuivre pur. La voie hydrométallurgique traite le concentré par lixiviation, c.à.d. par dissolution en phase aqueuse à température typiquement inférieure à 100 ou 150⁰C, alors que la voie pyrométallurgique traite le concentré par fusion à température de l’ordre de 1200 à 1300⁰C.

May 2, 2024

The Industrial Minerals Milling Section of the Mineral Processing Division has been engaged for the past three years in a study of the separation of minerals, by means of electronic sorting equipment, on the basis of their colour. Considerable knowledge of the subject has been built up. Because the object of this study is application as a means of beneficiation, a number of examples of the separations achieved are presented. Introduction T 0 the mineral collector, the colour of a mineral may be pleasing, even fascinating; to the mineralogist, student or professional, it may also be practical. It serves, to some extent, as a distinguishing feature in many minerals, and helps to fix with reasonable accuracy the identity of a few. It may now become a useful tool of the mineral dresser. The idea of using a difference in colour as a means of separation of one mineral from another is not new. Hand sorting dates back to ancient time. However, the means by which this can be done mechanically was developed only during the past decade. As far as the Mineral Processing Division is concerned, interest dates from March, 1960, when the following item was observed in the

Jan 1, 1965

By Paul W. Shelley, Daniel J. Hodges

The mining industry is undergoing a period of rapid transformative change.  This is the result of the social and financial accountabilities that the industry is faced with because of the world’s desire to cap average temperature increase to 1.50C above pre-industrial levels (UNFCC, 2016).  To limit global warming to 1.50C, greenhouse gas emissions must peak before 2025 at the latest and decline 43% by 2030.  In hard rock mining, comminution is identified as the major energy consumer, being responsible for 40-60% of the electricity use.  It follows that comminution is the major greenhouse gas emission process of the mine.  All effort is being made to radically reduce the carbon emissions of comminution. Grinding media plays a large role in the energy consumption and carbon emission story.  In recent years industry practitioners have attempted to quantify the grinding media carbon footprint.  This paper makes a definitive contribution to that discussion.  The grinding media carbon footprint is quantified in Scope 1, 2 and 3 emission terms in the context of a grinding media supplier.  Major emission contributors, steel, natural gas and electricity are discussed in detail.  The steel industry transition is a key factor. The paper will explore the steel industry transition and its effect on grinding media manufacturing.  The carbon footprint of heritage steel process routes are analysed and compared with the process routes of the future.  Emerging steel making technologies are presented and discussed.  The future of the steel manufacturing and procurement route for grinding media is proposed. This narrative allows for a comparison between the heritage carbon footprint and the future carbon footprint of manufactured grinding media.  Of equal importance is the opportunity of reducing the grinding media carbon footprint in the field.  The paper explores possibilities of reducing the grinding media carbon footprint at the customer site.  Media in use options are presented that take account of the mineral characteristics, the mill dynamics, and the product metallurgy to optimise both carbon footprint and media performance. It is intended that this is a landmark paper in the discussion of the carbon footprint of grinding media.

May 4, 2025

By Lebeau M., P. Duguay

"The cost of occupational injuries and diseases in the mining industry in Quebec was estimated for the period of 2010 to 2012. The method used takes into account the financial and human costs assumed by employers, workers, and the community. To better direct research and prevention toward issues with the most significant consequences, the results are presented in various ranking tables, which stakeholders might find useful.RÉSUMÉ Le coût des accidents du travail et des maladies professionnelles dans l’industrie minière au Québec a été estimé pour la période 2010-2012. La méthode utilisée prend en compte les coûts financiers et humains endossés par les employeurs, les travailleurs et la communauté. Afin de mieux orienter les recherches et la prévention vers les problèmes ayant les plus graves conséquences, les résultats sont présentés dans divers tableaux de classement, qui seront d’une grande utilité aux parties prenantes. INTRODUCTIONThe mining industry is much safer today than it was 30 or 40 years ago, mainly due to a more qualified workforce, the use of automated equipment, and a corporate culture more focused on occupational health and safety (OHS); however, the number and the severity of occupational injuries and diseases continue to make this industry one of the most hazardous. In the province of Quebec, the mining industry accounts for approximately 0.4% of paid workers but is the source of 4% of fatal work accidents. It is, therefore, important to continue the prevention efforts already underway in the mining industry.The difficult global economy, which has affected the mining industry in the last few years, is an opportunity to reaffirm that sound management of OHS can have a positive impact on companies’ productivity and profitability. Occupational injuries and diseases are costly for the companies concerned and for society as a whole. Reducing their occurrence makes it possible to reduce not only the size of workers’ compensation board contributions but also several other financial and human costs."

Jan 1, 2018

By J. J. Denny

IN a preliminary paper (1) it was shown that the addition of small quantities of metallic aluminium powder almost completely inhibited the solubility of siliceous material in the beaker. Six rabbits exposed to quartz dust for six months all showed well developed silicosis. Seven rabbits exposed to quartz dust plus 1 per cent metallic aluminium powder for the same period did not develop silicosis. At that time, we were not in a position to state either the manner in which metallic aluminium reduced the solubility of siliceous material, or, from the animal experiments, whether the aluminium was acting locally or systemically, or for what period after the cessation of dusting it would continue to act. This paper reports the further progress of this investigation. CHEMICAL EXPERIMENTATION The technical details pertaining to the various substances used in the experiments are given in an appendix which is on deposit with the American Documentation Institute, Washington, D.C. For lack of space, it is not printed here. The term 'solubility' is used to indicate the concentration of silica in the solution under the conditions as noted, determined colorimetrically (2), and expressed as parts per million (p.p.m.). The term 'reduction in solubility' indicates the difference between the solubility of the .silica in the presence of the aluminium powder and its solubility in the absence of aluminium powder. It will be noted that the solubility figures for different samples of quartz with no added aluminium vary considerably. The figures do not refer to an equilibrium solubility of silica but to the actual amount of silica dissolved from a given sample in a given time at a given temperature. In view of the fact that quartz dissolves extremely slowly, it is evident that the actual figures in any case will depend upon the surface exposed, i.e., fineness of grinding of the different samples.

Jan 1, 1939

By G. N. A. Senhorinho, J. A. Scott, C. A. Laamanen

"Closed mine sites are widely regarded as a negative asset due to their legacy of environmental impacts. These sites are often characterized by waterbodies with elevated metal concentrations and low pH that are traditionally considered to have little or no value. These sites are potential sources of beneficial biocompounds produced by microalgae in response to environmental stresses. A bio¬prospecting program found that certain microalgae from waterbodies near historical mine sites exhibited higher antibacterial activity than any microalgae previously reported in the literature. There is potential for the mining industry to be involved in examining features such as tailings ponds at mine sites for high-value compounds, including ones that might help mitigate rapidly growing microbial resistance to current antibiotics. ¦ KEYWORDS Antibacterial, Closed mining sites, Metabolites, Microalgae, Stressed environments RÉSUMÉ Les sites miniers clôturés sont généralement considérés comme des actifs négatifs en raison de leurs répercussions sur l’environnement. On trouve souvent sur ces sites des étendues d’eau affichant de fortes concentrations en métaux et un pH faible, généralement considérées comme ayant peu, voire pas de valeur. Ces sites sont des sources potentielles de biocomposants bénéfiques produits par des microalgues en réponse aux perturbations environnementales. Un programme de bioprospection a permis de déterminer que certaines microalgues trouvées dans ces étendues d’eau à proximité de sites miniers historiques présentaient une activité antibactérienne supérieure à celle mentionnée dans toute la docu¬mentation existante. L’industrie minière pourrait bien participer à l’examen de particularités telles que la recherche de composants à haute valeur dans des bassins de décantation des résidus sur des sites miniers, notamment des composants qui pourraient aider à atténuer l’augmentation rapide de la résistance micro¬bienne aux antibiotiques actuels. ¦ MOTS CLÉS antibactérien, environnements perturbés, métabolites, microalgues, sites miniers clôturésINTRODUCTION The mining industry is one of the largest economic drivers in the world. Within Canada, for example, it contributed 2.8% (C$57.6 billion) of the 2016 gross domestic product (Marshall, 2016). Canada also has the highest non-ferrous exploration budget worldwide (Marshall, 2016); therefore, it is likely that mining operations, mine waste disposal, and the number of closed sites will continue to grow in Canada. The environmental impact of mining operations stems from the volume of tailings produced, which can be up to 97–99% of the total volume of ore processed at a mine (Adiansyah, Rosano, Vink, & Keir, 2015). In 2010, mining was the world’s largest industrial producer of waste at a total of 65 billion tonnes: 51 billion tonnes of waste rock (mine overburden) and 14 billion tonnes of tail¬ings (Jones & Boger, 2012)."

Jan 1, 2019

By J. E. Nesset, E. R. Bobicki, K. L. Bilaniuk

The introduction of froth flotation technology in Canada, and in particular, in British Columbia, began not long after it was successfully applied in the Broken Hill mining area of Australia which began around 1905. It proved to be a revolutionary and transformative technology that resulted in marginal operations in copper, lead and zinc becoming profitable in spectacular fashion. The paper presents the technology of both oil flotation and froth flotation in the context of the challenges of the time and its early application in British Columbia at the Le Roi No.2 mine (1903), the Britannia Copper mine (1912), and at the Allenby concentrator of the Copper Mountain mine (1918-19). New-found archival documents indicate the Britannia application to be the first production application of froth flotation for copper ore outside Australia, a claim that is currently made by the Braden mine (now El Teniente) in Chile. Flotation was initially an add-on process following gravity methods but was rapidly shown to be far superior method for the bulk and selective recovery of metal sulphides. Flotation proved particularly successful for the recovery of zinc sulphide (the so-called ‘zinc problem’) which was considered a contaminant at the time. The ‘copper problem’ related to the poor recovery of fine copper sulphide particles that were not amenable to gravity methods. The success of flotation led to changes in both the scale and methods of mining, concentration and smelting in a manner that allowed integrated mining companies to flourish. Many are still with us today. INTRODUCTION The advent of froth flotation in the early 20th century was truly a revolutionary technological development, not only for the mining and metallurgical industries, but arguably more so for business and society overall. The Canadian technology historian Jeremy Mouat stated (1996) “The development of flotation was the greatest single metallurgical improvement of the modern era...it is not overstating the case to claim that flotation was of central importance to the smooth functioning of the global economy”. It should, therefore, be a story of interest to us all. The aim of this paper is not to retell the full story, that has been well covered by others (Hoover, 1912; Rickard, 1916a; Hines & Vincent, 1961; Lynch et al., 2010) but rather to add some Canadian perspective and the key role played by companies and individuals in those early days, focusing on events in British Columbia’s copper industry. EARLY DEVELOPMENTS During the later half of the 19th century, a number of flotation-related patents were issued. These include the 1860 patent (Britain) granted to William Haynes for a process to separate sulphides from ground ore by mixing it with oil (1-10% wt) followed by a separation process in a water-filled vessel; the 1877 patent granted to Georg and Adolph Bessel (Germany) for a process involving the mixing of oil and graphite ore followed by boiling in water to produce a high grade graphite froth (>90% carbon); and the 1885 patent granted to Rebecca ‘Carrie’ Everson for the separation of sulphides by mixing sulphide ore with small quantities of oil, and adding water followed by sulphuric acid. These processes are more properly referred to as bulk oil flotation due to the relatively large quantity of hydrocarbon used.

Jan 1, 2019

By R. Liu

As Building Information Modeling (BIM) becomes widely adopted by the construction industry, it holds undeveloped possibilities for supporting Facility Management (FM). Some FM information systems on the market claim to address the needs for FM requirement. However, the question of whether the functionalities provided by the current BIM-based FM software companies are those actually required by the FM Professionals still need to be answered. The data is required by FM professionals in the operation and maintenance phases of facilities and type of maintainability problems that frequently occur, which can be solved early in design phase, have not yet been addressed. The aim of this paper is to clarify the frequently occurring maintainability problems and to investigate the potential areas that can use BIM technology to solve the maintenance problems in early the design phase. A survey was conducted to collect perspectives from the industry practitioners for the maintenance problems and their frequency. The survey results indicated that maintainability considerations should be taken into consideration during the facility design phase. The results also address the perceived areas by practitioners that need maintainability consideration in design phase

Aug 1, 2013

By K. Mayhew, R. Bruce, A. Heidel, G. P. Demopoulos

"Teck and Aurubis are working together to commercialize a technology for the processing of copper arsenic sulphide concentrates that is economic and sustainable with regards to the environment and community. The pressure hydrometallurgical approach is a desirable option as mineral extraction and arsenic fixation can take place in a single autoclave vessel. A test work program was carried out where a range of copper concentrates with varying arsenic grades was processed under CESL leach conditions. This paper discusses the stability character (in terms of arsenic) of the resulting residues and their mineralogy. The basic ferric arsenate sulphate phase (BFAS; otherwise known as type 2) was identified as the main arsenic carrier. All CESL residues demonstrated high stability (<1 mg/L As) through a range of aggressive (pH and ORP) environmental leach conditions.INTRODUCTIONArsenic deportment and control in the copper industry needs an integrated approach involving each stage of the value chain, i.e. exploration, mine operation, refining process and mine closure. Teck Resources Limited (Teck), Canada’s largest diversified mining company and Aurubis, Europe’s largest copper producer, have formed a partnership to advance the application of CESL copper-gold technology for the development of high arsenic bearing copper resources (Bruce et al., 2011).Among the options for arsenic control in the metallurgical treatment of copper concentrates is the precipitation of ferric arsenate, which is widely accepted as the most suitable method for stabilizing arsenic (Ferron and Wang, 2003). The pressure hydrometallurgical approach to processing arsenic bearing copper concentrates is a favorable option as mineral extraction and arsenic fixation can take place in a single autoclave vessel. Under CESL pressure leaching conditions (150 °C, 1380 kPa) high copper extraction and arsenic (V) fixation is possible.Within the pressure leach autoclave, arsenate and ferric iron react to form scorodite type phases. The precipitate formed under CESL conditions is dependent on the Fe (III) /As (V) ratio and the tenor of cations and anions, particularly excess sulphate (Gomez et al., 2011a). Previous studies on CESL residues have found arsenic to be present as crystalline scorodite (FeAsO4.2H2O) (Bruce et al., 2011), basic ferric arsenate sulphate (BFAS: Fe(AsO4)1-x(SO4)x(OH)x·(1-x)H2O, where 0.3<x<0.7), and/or arsenate adsorbed on to hematite (Gomez et al. 2011b). Although not a focus of previous work, scorodite was the predominant precipitate formed when the concentrate Fe/As was <1.5 (Mayhew et al., 2010), and BFAS was the predominant precipitate when the concentrate Fe/As was >10 (Gomez et al. 2011b)."

Jan 1, 2012

By K. Eklund, T. Ahokainen

The Flash Smelting process is the most used production method for primary copper in the world. The basic idea of the Flash Smelting is to utilize the thermal value of sulfidic concentrates and melt the reaction product, in controlled conditions, without a need for external energy. This basic principle is utilized both in matte smelting and in Direct-to-Blister Flash Smelting Processes. In this paper, the behavior of normal (CuFeS2) concentrate of FSF-process is compared to the behavior of high grade feed material produced by Outokumpu Concentrate Upgrade Process with the aid of computational fluid dynamics (CPD) simulation using add-in subroutines developed by Outokumpu Technology. Results consist of the information concerning the behavior of the suspension, reaction efficiency and other parameters concerning the reactions of the feed material. It will be shown that, using the Upgrade Process, the throughput of copper from the Flash Furnace can be almost tripled.

Jan 1, 2007

By Songgen He, Jianchun Guo

With the development of complex, unconventional and deep reservoirs, it shows that many rocks behave plastically with the influence of clay and confining pressure. Traditional linear elastic hydraulic fracturing initiation models are not good predictors for elastic-plastic reservoirs. With the deformation theory of plasticity, a power hardening constitutive equation was developed in piecewise approximation method. Based on the nonlinear constitutive equation, a model of the stress field around the wellbore was developed considering fracturing fluid penetrating effect and in-situ stress anisotropy. At last, coupled with the maximum tensile strength criterion and Mohr-Coulomb criterion, a new elastic-plastic hydraulic fracturing initiation model was built. The following conclusions were summarized in the paper: (1)The piecewise power hardening constitutive equation based on the deformation theory of plasticity can accurately describe the nonlinearity of elastic-plastic deformation. (2)Whether the rock is yielded or not is determined by in-situ stress, yield stress, Biot coefficient and pore pressure. (3)Plastic yield has little influence on radial stress but significant impact on circumferential stress. The radius of the plastic zone is positively correlated with in-situ stress but negatively correlated with yield stress, power hardening index, pore pressure and Biot coefficient. (4)Initiation modes include tensile failure and shear failure when rock is yielded. (5) For elastic-plastic reservoir, the initiation pressure predicted by linear elastic model is much lower if the rock is yielded.

Jan 1, 2015

By David E. Pearson

"There are many tests that can be used to characterize and classify coals, and describe their quality. One of the easier tests, and most versatile in its application, is petrography. Rank and coal type are precisely defined by petrographic evaluation, and in this paper they are compared with other definitions of rank and coal type. Brief descriptions are given of the various rank tests, and of rheological and coking tests used to describe coking-coal quality in Canada. Similarly, tests used to evaluate thermal coal quality are discussed. Finally, the use of these tests as parameters to classify Canadian coals is examined with reference to four coal classifications.Introduction Among all coals there are two independent variables that are required to evaluate coal quality. These are, coal rank and coal type (or composition), and although coal petrography can be used to precisely define them, other methods are often used to provide values that are, in fact, functions of rank and coal type. For example, volatile matter yield is used as a proxy for rank, and free swelling index is used as a proxy for coal type in the International Classification of Hard Coals by type. Currently, there are a number of methods in use in Canada to define rank. The approach taken here, (obviously the author's bias), is that Romax, the mean maximum reflectance of vitrinite, is both a quick and an accurate measure of rank. It is logical to compare the other techniques employed in the measurement of rank to this favoured method. Coal type is, in theory at least, simply a quantitative measure of the various varieties of coal. In practice, the microscopic entities are assigned to a Reactive or Inert category, and at that point objectivity fades from petrography. Despite this somewhat subjective approach, petrographic composition of coals remains an independent variable of such.importance that its place in the evaluation of coal is essential. In this paper, a variety of me.thods that are used to assess rank and coal type are reviewed and compared; the influence of these variables over other parameters that are used to determine the quality of metallurgical and thermal coals is examined, and their usefulness in coal classifications is discussed."

Jan 1, 1985

By R. S. Douglas

Introduction The operations of The Granby Consolidated Mining, Smelting and Power Company, L1mited, have always been concerned with the mining of low-grade copper ores. In the fifty years of this Company&apos;s existence, nearly 60,000,000 tons of such material has been successfully mined and treated. During these years, many changes in mining practice took place. However, at Copper Mountain, due to the large tonnages of very low grade material, it was realized that something more than changing mining methods would have to take place if these low-grade orebodies were to be mined at a profit and the Company and. its employees enjoy many years of successful operation and employment. Production costs were mounting commensurately with rising taxes and the increasing cost of supplies, labour, freight, and smelting, while the value of the product on the market was not increasing in price to compensate for the higher costs of production. A survey of the mineable ore in 1944 indicated that, of the 12,000,000 tons in the reserves, only 3,500,000 tons was now profitable ore. This reduction in the commercial ore reserves was a serious matter, as it meant that the mine had only two years of life at the profitable shipp1ng rate of 4,800 tons per day. Further, the location in the mine of the orebodies making up the 3,500,000 tons was not suitable for such high production.

Jan 1, 1950

By Trang T. Tran-Valade

With continually increasing energy prices, the mining industry has been on the search for new energy optimization technologies. One area that is garnering great interest is Ventilation-On-Demand (VOD). Prior to selection and implementation of a VOD solution, it is important to fully understand the mine requirements as well as its existing infrastructure and the interaction with other automation in place at the site. With this information, a business case can be generated including a cost versus benefit comparison for various control strategies. To assist in the development of the business case, this paper will identify key areas for consideration and recommendations for an implementation plan.

May 1, 2013

By G. Grassmück

The question of whether the air curtain principle could be used under conditions prevailing in Canadian metal mines was investigated. A vertical, portable BERRY air curtain was tested, at first in a wind tunnel built at Ecole Polytechnique at full scale (8-by 8-ft cross section) to simulate a drift and its lateral connections, and then in the haulage ways of a metal mine under actual conditions. The results permit us to predict under what conditions this type of air curtain is capable of acting as an air stopping or flow regulator and how it could be further developed.

Jan 1, 1969

By Claude A. Jr. Seger

Introduction This paper presents in detailed form the results of settling tests that were published in a few preliminary notes in the April 1949 issue of the Bulletin (p. 166). Carborel is the trade name for sodium carboxymethyl-cellulose and aluminium carboxymethyl-cellulose produced by the reaction of monochloroacetic acid on the alkali cellulose to form an ether. The water-soluble sodium carboxymethyl-cellulose has been known in Europe for several years as sodium cellulose glycolate and has been marketed under several trade names. These cellulose ethers, however, are relatively new in North America, where the name carboxymethyl-cellulose is often abbreviated to C.M.C., or they are referred to as cellulose gum. The particular grade of Carboxel used in the settling tests in the mill of Chesterville Mines, Limited, is the high-viscosity sodium carboxymethyl- cellulose known as Carboxel H.V. It is a white, fluffy powder and is hygroscopic, although not deliquescent. Carboxel solutions in water are colourless, odourless, and resistant to beat and light. They are stable to alkalies, but are precipitated by acids when the pH is reduced below 4.0, and also by solutions of soluble lead, iron, copper, aluminium, and chromium salts. Solutions of Carboxel exhibit the properties of hydrophilic colloids.

Jan 1, 1949

By Nick Hazen

Many successful actions are required to bring a profitable extractive metallurgical operation into production. Competent process development performed within the project development schedule increases the chances of obtaining project financing and decreases the risk of engineering design errors being built into the commercial plant. The general sequence of steps in process development is well known: technology review, desktop studies, scoping studies, prefeasibility, and so on, with an increasing requirement for experimental evidence as the studies advance. This paper suggests principles for guiding process development work so that the efforts stay on track toward a smooth startup and a profitable commercial operation. It emphasizes closely aligning the research with the corporate goals of the mining company management, understanding the mineralogy and variability in the deposit, and guiding by flowsheet and material balance. Examples of hydrometallurgical process development leading to the early use of solvent extraction in the mining industry are given.

Jan 1, 2014

By J. Lu, J. B. Wiskel, D. G. Ivey, E. Niemi, H. Henein

Simulated TMCP using a Gleeble was undertaken to evaluate the effect of the austenite to ferrite cooling rate, coiling temperatures of either 400°C or 500°C and the magnitude of plastic deformation at the coiling temperature on the hardness of a Grade 483 (X70) steel. For comparable apparent cooling rates and deformation conditions, the hardness of the samples were independent of coiling temperature The application of a minimum compressive deformation > 8% was required to increase hardness at both simulated coiling temperatures of 400°C and 500°C. An increase in hardness was also observed with increased cooling times between 800°C and 500°C (i.e., slower cooling rates).

Jan 1, 2005

By J. Budac, R. Kofluk, D. Belton, M. Sjogren

A series of tests were performed to determine the flammability limits of mixtures of oxygen, ammonia, steam and nitrogen, over a solution, in a sealed autoclave. The partial pressures of ammonia and oxygen in the vapour space were varied by adjusting the character of the solution and by adjusting the oxygen concentration in the oxidant gas respectively. The data shows that flammable conditions can be minimized by controlling the operating temperature, reducing the ammonia content in the solution, increasing the concentrations of Ni, Cu and Zn in solution and keeping the % oxygen in the gas phase less than 15.5. Observations were also made that suggest that the presence of an aerosol in the vapour space may hinder ignition.

Jan 1, 2004

By P. T. O'Kane

The PLATSOL® process, initially developed for the treatment of the NorthMet Cu/Ni/PGM concentrate, has seen over the recent years its applicability extended to include numerous other Cu/Ni concentrates of the same type, as well as other precious metals-containing feedstocks. However, several concentrates were found refractory to the typical PLATSOL® conditions, more particularly so the platinum. Attempts to extend those conditions, such as higher temperatures (250°C), longer retention time, increased oxidation conditions, higher chloride additions, were not successful. Detailed mineralogical investigation of those PLATSOL® leach residues indicated the main refractory mineral to be cooperite (PtS). Further metallurgical investigations showed that a thermal pre-treatment of the concentrate effectively unlocked the refractory platinum minerals for the subsequent leach. Temperatures between 400 and 750°C were tested, with the optimum being found around 650°C. The kinetics of the pre-treatment process were fast, and one hour at temperature proved sufficient. Under those conditions, PLATSOL® extractions were re-established around 95% for both platinum and palladium. From a mineralogical examination of the calcine, it was shown that the effect of the pre-treatment was to transform the cooperite and other refractory sulphides into metallic platinum and alloys, amenable to the PLATSOL®. The implications of the pre¬treatment step for the processing of PGM concentrates arc briefly discussed.

Jan 1, 2004