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By A. Brown

"The first printed report on Canada's coal resources was published in Paris in 1672(1. Written by Nicholas Denys, then Governor for France of Isle Royale (Cape Breton Island), the report dealt exclusively with the coal of the Atlantic region because little or nothing was known about the interior of North America. Clearly, also, he wrote about a resource of which much was known among the military and early settlers of that day. This early knowledge is not surprising because the presence of coal is clearly displayed in the coastal cliffs of Cape Breton as it was also, at a later date, to the first arrivals on Vancouver Island.An example of early use was that of the French garrison at Fort Louisburg in the first half of the 1700s. Still earlier, in 1643, Governor Winthrop of New England reported the receipt of a small ship load of coal from New Brunswick (2). Despite this early knowledge there was no significant development of coal mines until the 1800s. This had to await the ending of wars between the French and British factions and the growth of population. Basically, also, its development awaited the beginning of the Industrial Age. Organized coal mining began in Canada in 1825 with the formation of the General Mining Association. This British firm was the creation of a group of London jewellers which had been granted royal rights, by the British crown, to all minerals in Acadia (substantially the present Maritime Provinces). The Association took over a number of existing small mines and opened up larger operations in the Sydney coal field. Subsequently, it expanded to the mainland Nova Scotia fields at Stellarton and Springhill. The Association continued in existence as the major coal producer in Canada until 1899 when it sold its properties to the Nova Scotia Steel and Coal Company, Limited (3). This Montreal-based firm managed the coal mines as a major Canadian producer of coal until 1968 when financial problems led to the expropriation of the mines by the Government of Canada. The federal government established the Cape Breton Development Corporation to operate the larger mines on Cape Breton Island. This Crown corporation continues to be a .major producer of coal in Canada."

Jan 1, 1985

By H. Memarian

In the last few decades, many developing countries have tried to expand and improve upon higher education, which is acknowledged to be the leading factor for development. In this respect, develiping countries have significantly increased the number of tertiary institutions and their students. These rapid expansions, along with all the benefits, have drawbacks as well. An example is the status of mining engineering education in Iran. Presently, the number of active mining engineering departments in Iran (27) is more than the sum of similar departments in Canada, Australia, the United Kingdom, and South Africa (23 altogether). Also, the number of annual mining graduates in Iran (645) is more than the cumulative graduates of the United States, Canada, the United Kingdom, and Australia (613). The expansion of mining engineering education in Iran has coincided with the closing or merging of similar mining departments, as well as a decline in the number of interested students in the industrialized world. The present study shows that the need for development and the excessive number of high school graduates, resulting from high population growth in the early 1980s, are the two primary factors influencing the significant expansion of mining engineering education in Iran.

Jan 1, 2007

By T. Orser

In 2010 Newmont made the decision to purchase a 42 foot (ft) Semi-Autogenous Grinding (SAG) mill from Metso and a 28 Mega-Watt (MW) Gearless Mill Drive (GMD) from ABB for the Conga Project in Peru. The test and study work showed that a single line 42 ft SAG mill circuit gave the most favorable project economics in comparison to an equivalently powered single line 40 ft SAG mill circuit. This paper does not address the process design or the project economics, but instead focuses on the key aspects of the SAG mill design, GMD design and the associated component manufacturing. This paper also addresses, where applicable, the potential reliability differences between the initially proposed 40 ft SAG mill and the finally accepted 42 ft SAG mill.

Jan 1, 2012

By Shichang Liu, Hongli Jia, Zhaolian Wang, Maotang Liu, Ltd. Shandong Huate Magnet Technology Co., Fengliang Liu

"Introduce and promote a latest technology and equipment for magnetite. It’s featured of purifying concentrate, lowering tailing grade, high concentrate recovery rate and stable operation. HUATE® New Style Elutriation Electromagnetic Separator is an equipment to obviously upgrade magnetite. The slurry is fed into separation area through feeder. Generated by excitation coil, the working magnetic field distributes specially in separation area. Under the combined effect of the background field, excitation and demagnetic field and gravity, the mineral particles float downwards in the form of magnetic chains, and interact with the rising water. The gangue, non-magnetic particles, lean intergrowth,etc will be discarded as tailing via overflow tank and pipe. While the magnetic will be discharged from concentrate pipe. Its grade is 2%-10% higher than that of traditional magnetic separation equipment. It adopts the technologies of transformer oil cooling, alternative and uniform pulsation magnetic field controlling the tailing grade, larger drum feed-in device, more uniform umbrella scattering discharge and stabler output current, and realizes lower coil temperature raise, stabler magnetic field, more uniform discharge, effective isolation of weak-magnetic area from non-magnetic area, more obvious upgradation and recovery rate and lowering tailing mFe%. It’s more suitable to purify and thicken the high grade and ultrafine iron powder. Compared with traditional elutriation equipment, it adopts new technologies in removing impurities, operation, large-scale, process simplification, water-saving, remote control, etc. It optimizes the comprehensive beneficiation index, expands its application scope, reduces resource wastes and increases economic benefits.INTRODUCTIONMagnetite accounts for a comparatively great proportion in various iron resources. As it’s a kind of strong magnetic mineral, we must adopt the weak magnetic separation equipment in magnetic separation process to realize removing Si and lowering impurities. While it cannot do very well to use the common weak magnetic separation equipment in the final cleaning to remove Si and lower impurities. At present, the plants, adopting single magnetic separation process to realize cleaning and removing Si and lowering impurities, are in the minority. Most magnetite plants adopt the flotation separation process to remove Si, lower impurities and purify the concentrate. Though with stable indexes and high Fe recovery rate, the flotation process is very complicated, high-cost and with lots of environmental pollution. If adopting the weak magnetic separation equipment can realize removing Si, lowering impurities and the final cleaning, the magnetic separation process should be the primary choice."

Jan 1, 2016

By Atul Bhatnagar, M. P. Sinha, Md Zahid Ahmad, Pallav Garg, Sanjay Kumar Singh, Shashi Ranjan, An Ecolab Company Nalco Water

"Froth Flotation is undoubtedly one of the most critical processes in coking coal washing plants. This work was carried out at Bhelatand Coal Preparation Plant of Tata Steel was with an objective of cost optimization in fine coal processing. The sources of raw coal for the plant include coal from underground mines of Jharia coalfield and procured open-cast raw coal. Coal from different sources vary in quality and possess different floatability characteristics.Synthetic collector is being used in plant as a flotation reagent. An alternate collector with new chemistry was developed for reducing total treatment cost without compromising product yield and quality. A series of laboratory tests were conducted to assess the performance of various sources of raw coal and plant scale trial was started. At first, the new generation coal collector was entirely substituted with the existing collector in the laboratory scale. However the plant scale trial data was not in accordance with laboratory results and indicated inferior flotation performanceThe issue was studied and data based conclusions were drawn that the new generation collector aids faster and uncontrollable kinetics. A decision was taken for co-dosing of the synthetic and new collector for the second phase of the trial. A detailed laboratory analysis was done again and few dosing ratios that predicted optimum results were selected for plant trial. The dosing ratio was optimised as per flotation yield and product ashes during the plant trial. The results showed significant improvement from the first phase and optimum dosing rates were decided based on plant observations and data collection. The influence of various process indicators including water quality, feed and product ashes and process yield was studied during all the trials and promising results were established. The co-dosing of both the collectors conferred cost advantage and enabled to achieve superior performance."

Jan 1, 2016

By Chas Kemsley

NO. 6 shaft at Dome Mines, Limited, is an internal shaft going down vertically from the sixteenth, or 2,000-ft., level to the twenty-ninth, or 4,000-ft., level, with loading station and sump below this. It is located approximately 4,600 feet east of No. 3 shaft, the latter being Dome's main shaft through which ail ore, men, and material are handled. The decision to sink this shaft was made in May, 1935, and work was commenced almost immediately. To reach the site of the new shaft, 3,100 feet of cross-cutting, and 1,400 feet of slashing to widen existing cross-cuts, was necessary. On account of the long haul and the large amount of material to be handled, trolley haulage was decided upon and installed as soon as possible to facilitate the removal of waste rock from the crosscut and other necessary excavations. Figure 1 shows a cross-section of the cross cut and the manner in which the trolley wire is supported and guarded. For hanging each individual cross-piece, two holes are drilled into the roof and filled with snug-fitting wooden plugs. Into these, %-in. ragged hanger bolts arc driven by means of a stoper. The bolts are of various lengths to allow for irregularities in the face of the rock, and they have sufficient thread to permit several inches of adjustment for proper alignment of the cross-pieces. These hangers are spaced at 8-ft. intervals except at the curves, where 5-ft. spacing is used. A 2 in. by 6 in. cedar plank is fastened to the cross-pieces directly over the centre of the track. To this the trolley-wire supports are bolted, and 1 in. by 10 in. cedar boards are nailed on each side to act as guards. Two power-supply cables, one telephone cable, and one .Y2-in. conduit lighting circuit are also supported on the trolley-wire hangers, as shown in Figure 1. A 20-in. ventilating pipe and a 10-in. air line are placed as shown, thus acting as a guard to prevent workmen from walking on the track.

Jan 1, 1938

By A. E. Flynn

THERE is at the present time a revived interest in amalgamation, due to the number of mines starting up, usually on high-grade ore, and utilizing this relatively cheap and convenient means of recovering gold, more especially in their initial stages of production. The marked increased use of the amalgamation process has revealed a dearth of amalgamators and there is no doubt the art of amalgamation has stood still for a generation or two and is not readily applicable to the modern practice of milling gold ores. Mill operators of long experience are learning the art for the first time and are giving it intelligent study, and considerable testing and research work is now being undertaken Most millmen consider amalgamation a simple process, and so it is when we have a clean ore with coarse gold, specially when stamps are used for crushing. In treating Nova Scotia ores by stamps and amalgamation, recoveries of 95 to 97 per cent are common and easily obtained. So-called 'under-water feed' is almost universally used in Nova Scotia and is quite beneficial. The water is supplied through jets between the dies and below the die surface and maintains this space as a live trap which catches the gold particles before they are overground and spoilt for amalgamation. With this method, the portion of gold recovered in the battery is higher than usual and often amounts to 80 per cent of the total gold in the ore, the remaining 20 per cent being caught on the plate. As a continuous amalgamator, the simple plate cannot be excelled. Some of the modern devices having moving or covered and not very accessible plates, which cannot be readily inspected and dressed to keep them in condition, do not give the best results in service. An exception might be drawn in the case of amalgamation of very heavy ore or concentrate which would bank up unless the plate is carried at such a steep inclination as to weep mercury. Difficulties in stamp-mill amalgamation are encountered when acid water is used or when grease is present. Also, certain sulphides and graphitic and talcose ores give trouble, resulting in poor gold recovery and high mer-cury loss. The older literature on gold milling deals with the common troubles of this type and the old-time amalgamator was well able to take care of day-by-day difficulties. When the difficulties were unsurmountable, the ore was classed as 'refractory' and other processes were used.

Jan 1, 1939

By B. K. Gorain

"The Air-Metabisulfite (AMBS) process has been developed to treat complex copper, molybdenum and precious metals (gold, silver) bearing ores using brackish and sea water. This process was able to produce significantly better copper concentrate grades and higher recovery than possible using conventional lime and/or cyanide based processes for certain complex ores with high sulphide gangue minerals. The AMBS technology in now used commercially following a rigorous evaluation process emanating from laboratory curiosity to plant applications. In addition, many projects have embraced this technology at a feasibility level involving various complex ore bodies.This paper presents a summary of the findings from testing the AMBS technology on various ores types. Experiences gained from this successful development from bench to piloting and then to plant applications are also presented in this paper.INTRODUCTIONProcessing of sulphide copper, molybdenum and precious metal ores typically involves flotation of copper bearing minerals while depressing non-sulphide and other non-copper sulphide minerals such as pyrite, pyrrhotite and sometimes arsenopyrite. Though in many precious metal ores, the values are in these sulphide minerals as well. The conventional method employed in the industry to produce a saleable copper concentrate requires depression of these non-copper sulphide minerals using an alkaline pH above 9.5, though 10.5 to 11.5 is more common. Alkalinity is controlled by the addition of a pH modifier. Lime is normally employed as a pH modifier due to its relatively low cost; however, the costs associated with adding lime can be significant and the effectiveness of lime as a depressant could be drastically reduced when the process water supplied to the flotation circuit contains high level of dissolved salts. In some cases, a small amount of cyanide is used along with lime to depress non-copper sulphide minerals especially when its proportion to copper sulphide minerals in the ore is higher than three."

Jan 1, 2016

By A. H. Lang

Introduction Tin continues to be as much a strategic metal as it was during the war. This situation is due to the fact that the tin mines in the major producing areas of Malaya and the Netherlands East Indies have not yet reached their pre-war production. Moreover, the world requirements for tin in certain fields, particularly in the food pack industries, are steadily increasing. At present, tin is still under International allocation by the Combined Tin Committee, of which Canada is a member nation. This Committee reviews periodically the availability of refined tin for export from the producing countries and makes allocations of tin to ensure equitable distribution to the consumer countries. In 1947, availability permitted an allocation of only 70 per cent of stated requirements. From 1935 to 1938 the price of tin in New York averaged 49 cents a pound and during the war the price in Canada was controlled under a subsidy programme at levels from 60 to 70 cents per pound. Just recently, this price has been raised to 96 cents. The value of the Canadian production amounts to about half a million dollars annually and the whole of this is obtained as a by-product of the lead-zinc-silver ores of the Sullivan mine in British Columbia. In 1947 Canada's imports of tin were 3,961 long tons valued at over $6,000,000. In addition, tin plate to a value of $8,000,000 was imported from the United States; the tin content of this is estimated to be from 650 to 700 long tons. An increase in domestic production would, therefore, be of great national importance, and the present high price may make the search for and development of tin deposits more attractive than it has been in the past. Although no one can foretell what future prices will be, there is reason to believe that, unless there is a drastic downward revision of production costs, the price will be maintained at present levels for some years. A number of tin occurrences are known in Canada, but none of these have been developed for their tin content alone.

Jan 1, 1948

By N. R. Andrade-Gonzalez

In this paper, the effect of magnesium and strontium additions on the heat treatment behaviour of cast A319,2 alloy was investigated, Permanent mold samples were heat treated at 495 °C for 4 and 24 h, then quenched in hot water and aged at 180 °C and 220 °C for different temperatures, It is found that multiple aging peaks are present in the age-hardening curves of Al-Si-Cu alloys, mainly when Mg and Mg-Sr are added, The results of electron probe microanalysis (EPMA) observations reveal that the age-hardening behaviour is related to the precipitation sequence of alloys, For the Al-Si-Cu alloy, the first aging peak is the result of the high-density GP zones, while the subsequent peaks arise from metastable phases, Obvious intervals during the transition from GP zones to metastable phases may be the main reason of the formation of multiple aging peaks, It is seen that addition of Mg (-0,40 wt %) leads to the precipitation of coarse Al5Mg8SioCu2 particles. When modifying the high Mg alloys, Cu-intermetallics segregate in areas away from the growing Al-Si eutectic regions, Modification with strontium retards the precipitation of the silicon out of the matrix.

Jan 1, 2005

By P. R. Warner

This paper reviews the development of certain aspects of the electrical specifications of Anglo American?s suite of specifications for gearless mill drives (?GMDs?). These specifications are based on experiences in both Anglo American?s and others? operations, benchmarking against large hydro generators, the advice of industry and university experts, and continuous close co-operation with OEMs. To achieve a step change in availability additional final testing and electrical protection have been implemented, insulation requirements have been specified for machines to be operated at high altitude and clean area and access control systems have been developed.

Jan 1, 2012

By C. R. Powell, W. H. Maher

"This paper presents a short history of the development of milling at Buchans, Newfoundland, and a description of the operation.History and DevelopmentTHE original ore discovery was made at Buchans in 1905 by Matty Mitchell, a Micmac Indian who was prospecting for The Anglo Newfoundland Development Company, which company was then preparing to build a paper mill at Grand Falls, some 50 miles east of Buchans. A development program, initiated in 1906, was terminated in 1911 because of metallurgical difficulties. Intermittent testing was carried out by The American Smelting and Refining Company, and in 1925 a satisfactory method of concentration by flotation was found. Following this, intensive geophysical reconnaisasnce, succeeded by diamond drilling, uncovered two additional orebodies similar to the original discovery at Buchans River."

Jan 1, 1966

By T. T. Ni

FOR MORE THAN 200 years, the Kochiu district of Yunnan province has been, and it still is, the hub of China's tin industry. The district produces annually from 80 to 90 per cent of that country's out-put of tin, which averages about 9,300 tons a year and places China fifth among the tin producing nations of the world. The tin ore reserves of the country are estimated (1) at 1,873,370 metric tons, of which 1,500,000 tons are in the Kochiu district. The mill of the Yunnan Consolidated Tin Corporation, described in this paper, is the only one of its kind in China. MINING AND SMELTING There are only two tin mines in the Kochiu district operating with modern equipment -the Hsin-Chang and the Lao-Chang, both owned by the Yunnan Consolidated Tin Corporation, a government company. The Hsin-Chang mine has four working levels with cross-cuts 6 ft. by 6 ft. and is equipped with steel mine cars and trucks to haul the ore. The ore is hoisted to surface in a three-compartment shaft and transferred to the mill by a 4-kilometer aerial tram. The Lao-Chang mine has two circular shafts 656 feet apart, each equipped with two cages. Haulage-ways 1,600 meters and 1,000 meters long, respectively, have been driven to the southwest from these shafts and are connected by three cross-cuts.

Jan 1, 1951

By Frédéric Flament

The aim of this paper is to present the development of a data validation software as component of a commercial mass balance package. Data reconciliation through mass balance is basically an optimization problem constrained by the law of mass conservation. As any optimization problem solved with a modern and robust software application, erroneous information or starting point will always lead to a solution, whether it is realistic or not. Moreover, good information wrongly weighted by an incorrect error model will lead to the same bad ending. In an industrial context where competition requires accurate information, data reconciliation without validation can be disastrous and calls for data validation before and after reconciliation. The challenge in automated data validation resides in the development of general theoretical solutions. Until now, none has been presented and only partial solutions are available. The development presented in this paper incorporates some of these partial solutions. The integration of human knowledge into the application paved the way to a more general solution. The combination ?theoretical validation ? human expertise? proved to be flexible and reliable enough to be integrated in a commercial data validation package. Numerous examples though industrial applications are presented. These applications demonstrate the validation of raw measurements, user support in the development of error models and validation of reconciled measurements.

May 1, 2001

Orebodies of the Renison Bell - Mt. Bischoff tinfield in Tasmania are stratabound, conformable lenses of massive cassiterite-bearing pyrrhotite, with underlying discordant, fault-fracture-controlled and more siliceous ore. The deposits occur in eugeosynclinal, trough-deposited sedimentary and mafic volcanic rocks which are stratigraphically equivalent to diff erentiated volcanic rocks that contain volcanogenic massive base metal sulphide deposits in a parallel arc to the east. Textures of the massive pyrrhotite ore suggest that it has undergone metamorphic recrystallization. Although the massive ore contains both monoclinic and hexagonal pyrrhotite, a study of a few samples from one orebody suggests that their distribution is stratigraphically controlled, with the monoclinic variety abundant only at the base. The distribution pattern of rare-earth elements in massive ore is similar to that of volcanogenic massive base metal sulphides in New Brunswick, and suggests that mixing of sea water with exhalative hydrothermal brines occurred during ore deposition. Tin is a common accessory element in many volcanogenic massive base metal sulphide deposits providing strong evidence that it, too, is transported and deposited by volcanic affiliated hydrothermal brines. Sedimentary rocks containing the massive orebodies are fine grained, thinly laminated, compositionally banded and of mixed chemical sedimentary-tuffaceous origin. They include finely recrystallized chert, carbonate-rich and pyritic varieties; and soft sediment deformation structures in these rocks suggest that dense sulphides deformed underlying, less dense chert prior to lithification. Close to ore the chert becomes massive and coarsely recrystallized, as does the carbonate, which is here strongly enriched in Fe and Mn. Apatite is present in pyritic, cherty and carbonate-rich beds and in the ore itself, in all of which it shows a similar pattern of rare-earth element distribution, suggesting that it is of marine sedimentary origin. These deposits have traditionally been considered as epigenetic replacements of favourable carbonate horizons by hydro thermal flu ids derived from later Devonian porphyritic intrusions. Some of these intrusions have associated tinbearing greisens. The above relationships suggest, alternatively, that, like massive base metal sulphides, the tin deposits were of original syn-sedimentary origin. Circulating hydrothermal brines generated during early Cambrian eugeosynclinal subsidence and tectonism rose through steep fault-fractures, there giving rise to the discordant orebodies, and were discharged on the sea floor, where the massive pyrrhotite lenses were precipitated with the associated cherts and carbonates. In some places, Devonian intrusions remobilized the earlier deposits, forming greisens and newepigenetic veins. Finally , the geologic selling of these deposits, in trough deposited sedimentary and mafic volcanic rocks, suggests another favourable environment for massive sulphide exploration which is quite different from the domal felsic volcanic environment so heavily favoured currently in North America

Jan 1, 1979

By Neil Campbell

Abstract Following discovery on the Giant property of very promising gold deposits, some of which terminate against the steeply-dipping West Bay fault, a geological study was initiated co locate possible faulted extensions of the ore. Geological mapping revealed that the ore and the shear zones to which the ore is confined are older than the fault and therefore subject co displacement by it. It also disclosed several diabase dykes which seem co provide the best basis for determining the fault movement. After applying various techniques co determine their strikes and dips, the dykes were used as structural markers and it was estimated that, subject co certain possible errors, the movement on the fault was 16,140 feet (3.06 miles) south and 1,570 feet (0.297 miles) down on the west side relative co the ease. Evidence supporting this conclusion was obtained when subsequent deep diamond-drill holes intended to test the hypothesis cut an ore-bearing major shear zone which, so far as can be determined, is nearly identical with its present correlative on the Giant property. Introduction The fault under consideration follows a northerly trend past the west side of the original settlement of Yellowknife, which is situated 600 miles north of Edmonton and 400 miles from the Northern Alberta Railway terminus at Waterways, Alberta. The mining properties chiefly concerned include the southern part of the Giant claims, on the east side of the fault, and the Con-Rycon-Demelt claims, on the west side, 3Y2 miles to the south. Geological data were also obtained from the eastern part of the A. Y.E. property, which lies south of the Giant claims, and from the Negus, Meg, Yellorex, and Kam properties, which are south and southeast of the Con-Rycon-Demelt claims. Recognition of the major faults in the Yellowknife Bay area, including the West Bay fault which appears to be the greatest, resulted from the work of Dr. A. W. Jolliffe (McGill University, formerly of the Geological Survey of Canada) in 1935 and subsequent years. It has been stated with little exaggeration that these faults rank with the largest known steeply-dipping dislocations of the earth's crust. In the winter of 1939, a mineralized shear zone named the Creek Vein was found on the Giant property. It was noticed that the space relationship between the new shear zone and a body of quartz-feldspar porphyry is roughly the same as that between the Con C-4 shear zone and a body of acidic flows lying north of the Con property. Coupling this relation with the assumption that the movement along the fault is dominantly horizontal, it was postulated that the Giant shear zone represented the faulted extension of the Con C-4 shear.

Jan 1, 1947

By Mark W. Booth

THIS paper deals with the subject of inbye power as the mechanical . engineer sees it, and invites discussion, particularly from the electrical engineer. At the outset, it will be necessary to clear the ground a little by some definite statements. In this question of compressed air versus electricity for the transmission of power and driving of machinery in underground workings, we must see that there are definite fields that compressed air on the one hand, and electricity on the other, can fill to much greater advantage than the other, and in which there can be little or no direct competition, at least for the present. It is under conditions where these fields overlap, and as to where the line must be drawn between the two, that the respective merits of each must be considered. Steam was the first means used to transmit power from the surface of a mine to drive underground machinery, and so long as distances were short and means possible to ensure fairly efficient use of the steam, and where the fire hazard was not in evidence, it gave fairly efficient service. I have in mind an instance during my own connection with the mines-a duplex pump at the shaft bottom at Princess colliery, driven by steam, and which used the steam compound and condensing; and, but for the mechanical difficulties, it was a not inefficient proposition. The steam was taken direct from the surface boiler-plant through a line down the shaft, and used directly at the pump, being in effect a straight conversion from coal to steam to work done. It was the mechanical arrangement, and failure of the pump in that direction, that led to its removal and replacement by something better in the way of an electrically driven turbine pump. Given modern mechanical arrangements, such as a steam-turbine drive on a high-speed turbine pump, and all other parts made in accordance with best practice in the art of steam generation and use, a steam-driven unit fully as economical would have been obtained. But the central electric supply station, and all that that means or promises (not always the same), turned the scale against steam.

Jan 1, 1936

By J. P. Piguet, A. Hosni, J. P. Josien, H. Baroudi, R. Hadadou

"The iron ore mines in the Lorraine region of north-eastern France cover a surface area of approximately 3,900 km2 and involve more than 150 cities. A total extraction method was usually used during exploitation, but this technique was sometimes replaced by the room and abandoned pillar technique when it was necessary to protect surface buildings and infrastructure. Rooms and abandoned pillars were initially designed to ensure long-term mine stability. However, this aim was not always reached and numerous collapses occurred in the Lorraine iron basin, either during production or several years after closure. Several subsidence events were identified during a period of one century; the most recent event occurred in 2012. Two groups of events were identified. The first group represents events characterized by sudden surface movement, and the second group includes event characterized by progressive subsidence.Numerous studies conducted during the last decade helped improve our understanding the origin mechanism of spontaneous or progressive (slow) events. These studies led to identifying long-term potentially unstable underground zones (hazard zones), particularly deep zones located under buildings and infrastructure. The latest are currently monitored by microseismic networks. A similar high requirement level is needed for unstable zones without taking into account the kinetics of the subsidence, which is very important for safety. Thus, GEODERIS initiated this study, primarily to acquire a better understanding of the kinetics of the progressive events group and identify the main parameters that could explain why some pillars zones developed a maximum amplitude subsidence on surface within a few hours or days, while it took several weeks to months for others. In practice, the results of this study will facilitate adapting the requirement level of microseismic monitoring system to the kinetics of pillar collapse.To retrieve the real kinetics for each event, historical and sparse documentation was used. Firstly, archives research was conducted, especially testimonies and newspaper articles published during the events. This work helped to gather useful information that sometimes contained a precise description of subsidence duration. The archives research helped to classify some progressive events according to the subsidence kinetics. Secondly, a diagnostic of geotechnical and geomechanical parameters of historic events was realized, combined with a cross analysis of the data. The analysis took into account dimensions of underground workings (e.g., pillar lengths, widths, heights, introduction of a “pillar shape factor”, and stress amount). An original expression was highlighted to connect the pillar geometry to the stress state. The kinetics expression was calibrated to classify the historic events taken into account according to the kinetics of movements. The kinetic criterion was applied to predict subsidence kinetics for the potential unstable zones currently monitored by a microseismic system."

Jan 1, 2015

By D. Tetsuka, H. Okamoto

The amount of impurities to be processed in a copper smelting process has increased for recent years because of an increase in the electronic scrap amount. It has been found that Sb and Ni effect on the operation of our copper electrorefining process. It is found that the current efficiency of the copper electrorefining tended to be decreased as the Ni concentration in the electrolyte increased. The passivation of the process seemed to be more related to SO4 concentration in the electrolyte rather than the Ni concentration in it. The current efficiency decreased when the Sb content in the anode was high. A high Sb content in the anode caused easy passivation by forming a gel-like film in the slime layer. We have developed a method to for see the anode passivation in a short time while generating a slime layer. We confirmed the tendency of passivation through the experiment of changing Pb content in anode. Passivation was easily occur with an increase in Pb content in the anode. The amount of slime increased as the Pb content in the anode increased. This suggests that passivation was facilitated because liquid diffusion near the anode was inhibited. INTRODUCTION The amount of impurities to be processed in copper smelting has been growing in recent years because the amount of electronic scrap has increased. Figure 1 shows that the contents of Sb and Ni in copper anodes have increased since 2007.High Sb and Ni contents in the copper anode decreased the current efficiency of the process and made the quality of copper cathode poor because of the anode passivation and the formation of floating slime in the electrolyte during electrorefining. If these influences of impurities are suppressed, it would be possible to make copper electro-refining current density higher and to process much amount of electronic scrap. We examined the components of our copper electro-refining process like anode composition, slime properties and electrolyte composition, and investigated the mechanism by which Sb and Ni affect passivation and current efficiency. When examining the influence of Ni, we noticed that the SO4 important. The effect of SO42 – was also discussed

Jan 1, 2019

By Adriana Ramirez, Bradford C. Wesstrom, Blanca Olave

The Freeport McMoRan El Paso Copper Refinery optimizes electrolyte quality using a number of systems. The facility controls copper, arsenic, antimony and bismuth using electro-winning cells within the Tank House and Nickel Carbonate Plant Liberator Circuit (NCP). The NCP manages sulfuric acid content utilizing recycled electrolyte in the slimes autoclave as well as operation of the Acid Purification Unit, APU. The El Paso Refinery removes common sulfates using metal hydrolysis with sodium carbonate. Finally, a Mechanical Vapor Recompression, (MVR), at the water recovery plant removes sodium sulfate generated by the NCP. This paper will provide a summary of these operations. INTRODUCTION In the mid 1920’s Nichols Copper Company, in Laurel Hill, New York, recognized the need for a modern copper refining facility in the southwest. Because of the many railroad heads, affordable power and abundant labor supply, and the close proximity to regional copper smelters in Mexico, Arizona, and New Mexico, El Paso became the ideal location. In December 1928, ground was broken for the joint venture refinery between the Nichols Copper Company, Phelps Dodge, and the Calumet and Arizona Mining Company. In September 1930, Nichols Copper Company became a part of Phelps Dodge Corporation after a stock exchange. In July 1938, Nichols Division officially became Phelps Dodge Refining Corporation. In March 2007, Freeport McMoRan Copper & Gold acquired Phelps Dodge. Water is a precious commodity in the desert southwest, making conservation of this natural resource an important goal for the El Paso Operations. In the 1980’s, work on the treatment of slimes was improved through the use of pressure leaching of the refinery slimes using an autoclave. Due to the high tellurium content in the leached slimes solution, it was crucial to implement a method for its removal before the solution returns to the tank house electrolyte. A copper telluride cementation operation was installed for tellurium recovery and the ability for the recycle of the leachate and wash water to the refinery electrolyte. In October of 1997, ground was broken for the construction of the water recovery plant using an MVR to reuse process water, reducing water consumption by 25%. In 2002, electrolyte purification was further improved with the installation of an Acid Purification Unit, (APU) (Sheedy, Pajunen, & Wesstrom, 2007). The APU recycles 90% of the acids (both sulfuric and arsenic acids) back to the tank house electrolyte. The solution that passes through the APU is treated with soda ash to precipitate metals out of solution as carbonates and generates a sodium sulfate solution. This sodium sulfate solution is easily processed in the new water recovery plant, where the majority of the water recycles back into the plant as pure condensate. In 2012, the power plant at the refinery upgraded its Reverse Osmosis System to provide RO water to the tankhouse. This insured that the refinery would not have to bleed electrolyte for metals contained in well water such as: calcium, magnesium, iron and sodium chloride.

Jan 1, 2019