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By L. M. Pidgeon

MAGNESIUM metal, with a specific gravity of 1.73, is two-thirds the weight of aluminium and one-quarter that of steel. It is the lightest metal which is stable in the atmosphere. Before the war it had begun, though somewhat slowly, to take a place among the established metals. In 1939, magnesium production on this continent amounted to some 3,000 tons per annum and was confined to one company. At that time, Germany produced perhaps 20,000 tons. The advent of war, however, increased the demand to fantastic heights and introduced production problems of unprecedented magnitude. By the end of 1943, North American production is expected to reach 300,000 tons per annum (1), an increase of one hundredfold. Such a rate of expansion has not been witnessed previously in the history of metallurgy. It has given the metallurgist an opportunity to try new production methods and to learn in a short time what might otherwise have taken many years. The metallurgy of magnesium is still in its formative years and at this time widely different production methods are in operation side by side. This paper will discuss these methods in so far as information is available for publication at this time. A general description of the new Canadian industry will be included.

Jan 1, 1944

By W C. Shakespeare

The Ontario Committee on Taxation is making a comprehensive study of taxation in the Province of Ontario, and in this connection has received representations concerning mining taxation from a number of interested parties. Some of the more important recommendations on mining taxation are reviewed in this article. Introduction FOLLOWING the appointment of the Federal Royal Commission on Taxation, the Ontario Government, effective in November, 1962, appointed the Ontario Committee on Taxation to review taxes and revenues available to the Province of Ontario and its local governments, to co-operate with the Royal Commission on Taxation and with any other bodies of enquiry appointed by other provincial governments, and to make such recommendations as it sees fit to the Prime Minister of Ontario and the Executive Council. The members of the Committee are: MR. L. J. SMITH, F.C.A., Toronto, (Chairman) MR. ERIC HARDY, Toronto DR. R. CRAIG MCIVOR, F.R.S.C., Hamilton MR. CARL A. POLLOCK, Kitchener MR. R. BREDIN STAPELLS, Q.C., and Toronto. Like its Federal counterpart, the Royal Commission on Taxation, the Ontario Committee has held public hearings, has received written

Jan 1, 1965

By N. C. Carter, Wm. H. White, J. E. Harakal

"Of twenty-one ore deposits in British Columbia which are either in production or advanced stages of exploration, five have potassium-argon ages in a range of 165-205 m.y., eight are in a range of 44-55 m.y. and the remainder are either ca. 140 m.y. or ca. 100 m.y. old. Deposits of the oldest group have generally similar geological environments and radiometrically indistinguishable ages of magmatic and hydrothermal minerals. Deposits of the youngest group also have similar geological environments, with successive magmatic and hydrothermal events closely intermingled in time and place. Such deposits find no comfortable home in existing classifications of ore deposits. 1t is suggested, therefore, that those epigenetic deposits which can be shown by radiometrie and/or geologie means to be coeval with genetically related magmatism be designated as ""paramagmatic deposits."""

Jan 1, 1968

By E. E. Mason

THE Myrtle group of mining claims is situated on Barkerville mountain in the Cariboo mining district of British Columbia, west of the old mining town of Barkerville. An 1,800-foot adit, known as the Shamrock tunnel, was driven in 1935-36 from the Barkerville road and in the general direction of the Myrtle group. It was proposed to enlarge this adit to more convenient section, extend it 2,500 feet int0 Myrtle ground, and from there drive a main entry 3,000 feet along the length of the group. Several laterals were also to be driven off this main entry as part of the tunnel schedule. It was thus originally proposed to drive 5,500 feet of new adit and 1,800 feet of laterals, a total of 7,300 feet of new work. Work was commenced with a bulldozer on April 21st, 1941, cutting a bench on the hillside for a plant site. The power plant was ready for operation on August 8th. Slashing and re-timbering of the old adit rook longer than was expected. It was found that 57 per cent of the length required timbering, chiefly by fore-poling, and there was also trouble in several sections with swelling ground. First round in the new face was taken on September 17th, when a 2-shift daily schedule was commenced. Due to delays in delivery of electrical equipment, it was not possible to add the third shift until November 14th. From then on, a 3-shift daily schedule was maintained with the exception of holidays and fortnightly change Sundays until August 1st, 1942, when shortage of labour caused the dropping of a shift. All work was suspended on August 14th. The ground through which the tunnel passed was such that the driving was often interrupted by the need of protective timber at the face. Further, crews were continuously employed timbering behind the face, and in maintenance of timbered sections in swelling ground. Roughly 980 feet of the new workings are now timbered, about 21 per cent of the total.

Jan 1, 1942

By R. E. Martin

"The Westerose Leduc (D-3) pool, a Devonian reef reservoir situated in Central Alberta, Canada, has now been producing for over seven years. As a unit operation, the pool pro-vides an interesting example of the full exploitation of gravity segregation tendencies. The reef has a 238-foot oil column, underlain •by bottom water and over-lain by a substantial gas cap. The original hydrocarbons in place were 147.96 million STB oil and 94.4 MMMCF of Taw gas cap gas. Nine-teen producing wells on 80-acre spacing have been completed, most of which are highly productive. Gas injection operations return solution gas to the gas cap. A study of the rock and fluid properties of the pool show it to be conducive to production by gravity segregation at high rates. Monthly average producing rates have varied between 800 B/D and 8,000 B/D and have recently totalled 3,000 BID to 5,000 B /D. Recovery and performance predictions under partial pres-sure maintenance at 10,000 BID indicate an ultimate recovery of 66 per cent of the original oil in place. In the absence of pressure maintenance, recovery would be only slightly less."

Jan 1, 1960

By D. J. Wesolowski, D. A. Palmer, P. Bénézeth, S. Hilic

The equilibrium solubilities of gibbsite, Al(OH)3, and boehmite, A1OOH, have been extensively studied in our laboratory from 30 to 90°C, and 100 to 300°C, respectively, to ionic strengths of 5 mol.kg-1 (NaC1) over a wide range of pH. The resulting solubility constants have been treated with consistent empirical models that incorporate appropriate experimental data taken from the literature. These studies were initiated in part to understand and quantify scale formation in geothermal fields as a result of fluid re-injection from electric power generating plants. Most of the experimental results were obtained through application of a unique potentiometric method that allows for rapid, precise measurement of the in situ pH and allows the approach to equilibrium to be monitored from under- and super-saturation. The experimental program was extended to deal with more basic solutions (e.g., five molal NaOH), in which the dissolution of boehmite was measured for application to the refining of bauxite by the Bayer process. More recent results in strong caustic solutions at temperatures below 90°C were obtained to investigate the dissolution of aluminum-containing sludge from holding tanks at the Savannah River waste reprocessing site. In this case the solubility enhancing effects (kinetic and equilibrium) of triethanolamine were also established and quantified. Finally, potentiometric solubility experiments were conducted (50°C in 0.l mol-kg-1, NaCl) on aluminum alloy sheets to identify mainly the nature of the aluminum oxide/hydroxide surface layer formed under these conditions.

Jan 1, 2004

By L. G. Bergh

The experience developing a supervisory control and information systems in a SX pilot plant is presented. The plant is located at the Process Control Laboratory, Santa Maria University, in Chile. In this work, the problem of controlling this process is discussed and related literature is briefly reviewed. Then, an innovative control scheme organized in three levels, local, hydrodynamic, and metallurgical supervisory controls is presented in an architecture including field controllers, PLC, and PC networks. Operating decisions in the metallurgical supervisory control are taken with incomplete information from on-stream analyzers. The control proposed is based on metal and acid concentration predictions of intermediate and exiting streams through the use of dynamic and static models and flow rates and input concentration measurements. Preliminary results are presented. The main objectives are to develop and test intelligent techniques in a hybrid system, and to study measurement and supervisory control problems. It is expected to produce reliable results that will contribute to improve the efficiency of this emerging and important process.

Jan 1, 2007

By A. M. A. Mohamed, F. H. Samuel, S. Valtierra, H. W. Doty, A. M. Samuel

"The influence of Fe, Mn, Cu and Mg alloying additions, Sr modification and grain refinement on the microstructure of as-cast and solution heat-treated Al-10.8% Si alloys was investigated using optical microscopy and EPMA techniques. The results showed that the modification effect of Sr diminished with increasing Cu and Mg additions, due to Sr-Cu-Mg interactions. Strontium caused segregation of AlzCu in areas away from eutectic Si regions, and altered the precipitation sequence of the a-Ah5(Fe,Mn)3Siz iron intermetallic from post-dendritic to pre-dendritic, with the phase observed within the a-Al dendrites. Depending upon the alloy Fe and Mn content, a coarser variation (""sludge"") of the a-Fe phase occurred, in the form of polyhedral shaped particles. The AhCu phase dissolved almost completely during solution heat treatment, while Al5Cu2Mg8Si6, sludge, and a-Aln(Fe,Mn)3Siz phases persisted in all alloys, particularly at high Mg and Fe levels. The f3-Al5(Fe,Mn)Si phase dissolved partially in Sr-modified alloys, the dissolution becoming more pronounced after solution heat treatment."

Jan 1, 2006

By J. Budac, J. Dennett, D. Mayne, P. Nawrocki

"The Nickel/Cobalt operation in Fort Saskatchewan, Alberta has successfully used an oxidative ammonia leach process to refine a variety of feeds into high quality nickel and cobalt products for over 60 years. Fundamental changes to the refining process were made when the major feed was converted from nickel concentrate to cobalt rich mixed sulphides in the early 1990s. Since the early 1990s, the production capacity of the refinery has expanded to match increases in both mixed sulphides and other feeds. In addition to increasing the production capacity of the refinery, other changes have been required in order to improve the operability and reliability of the refinery as well as to deal with increasingly stringent safety and environmental requirements. This paper describes recent changes at the refinery including changes to the flow sheet, improvements in unit operations, incorporation of new feeds, management of byproducts, and control of impurities.INTRODUCTION The Cobalt Refinery Company (Corefco) plant in Fort Saskatchewan processes nickel-cobalt mixed sulphide intermediate produced at the lateritic nickel mine and high-pressure acid leach (HPAL) facility in Moa Bay, Cuba. Both operations are jointly owned and operated by Sherritt International and General Niquel of Cuba. The mixed sulphide, along with other feed materials, is processed at the Fort Saskatchewan refinery using a pressure ammonia leach-hydrogen reduction process to produce nickel and cobalt metal. This refinery was originally constructed in 1954 to treat nickel concentrate from Sherritt’s Lynn Lake mine in Manitoba. (Benson and Colvin, 1964; Boldt and Queneau, 1967; Forward, 1953; Forward and Mackiw, 1955; Kerfoot, 1989) From the mid-1970s until the early-1990s, the facility operated as an independent refinery, treating nickel-bearing feeds from around the world. The flowsheet was changed in 1992 to address the increased cobalt content of the feed. (Cordingley and Krentz, 2005; Kerfoot and Cordingley, 1997) The flowsheet was adapted further in 2009 to improve cobalt speciation in the leach process, which allows better cobalt-nickel separation. The 2009 iteration is shown in Figure 1. Three ammonia leach stages were used to ensure high recoveries of nickel and cobalt. Underflow solids from the final leach stage contained mainly iron oxides. One of the features of the leach process is the innovative recycling of ammonia. Ammonia vented from the leach process in tail gas and from atmospheric tanks is recovered and recycled into the refinery using water based scrubbers and a high pressure distillation process. Indeed, roughly 250 t NH3/d is recovered as distillate and recycled back into the process. Also, air enriched with ammonia which is vented from the later first stage autoclaves is recycled to the lead first stage autoclaves to maximize oxygen and ammonia utilization."

Jan 1, 2017

By B. Tonn, F. Kröger

"The continued development in engine technology is leading to an augmentation in power density which steadily elevates the requirements for thermally and thermo-mechanically highly loaded components such as cylinder heads and pistons. Due to these high performance requirements conventionally applied Al-Si alloys have reached their application limits, since their mechanical properties deteriorate quickly under the influence of heat. Improved applicability is given by Al-Cu-based casting alloys which have a superior high-temperature strength than Al-Si alloys. Since Al-Cu alloys exhibit insufficient casting characteristics, especially regarding hot tearing susceptibility and increased tendency for porosity, it is currently not possible to cast geometrically complex components in robust permanent mold casting processes. The further development of Al-Cu alloys is aimed at finding an optimum between improved castability while high-temperature strength and thermal conductivity are not deteriorated. It is known that a high amount of eutectic reduces the hot tearing susceptibility of an alloy, but it reduces thermal conductivity at the same time. In this paper it will be presented how the conflicting objectives – improved high-temperature strength, good thermal conductivity and reduced hot tearing susceptibility – can be brought together to develop an optimized Al-Cu alloy for application in permanent mold casting.INTRODUCTION At the beginning of the 21st century car, engine blocks were primarily made of gray cast iron (GJL). Less than half a decade later, the choice of material had shifted towards lightweight materials. Ever since, the car engine manufacturing is dominated by aluminum-based alloys. The weight of car engine blocks could thus be reduced by around 50% due to the lower specific weight of aluminum alloys compared to gray cast iron. Furthermore, the high thermal conductivity of aluminum alloys allowed a reduction of complex cooling channel systems and thereby promoted the advancement of this material group. The further development in engine technology leads to an augmentation in power density which elevates the requirements for thermally and thermo-mechanically highly loaded components. For example, in diesel-powered car engines the upper required limits can reach an ignition pressure as high as 230 bar and gas temperatures of up to 1000°C. Thereby, thermal loads can cause high alternating thermal stresses (Grzincic, 2003) which can effectively be reduced by providing high thermal conductivity."

Jan 1, 2017

By Mauro Torres, Gabriel Zarate

"AngloAmerican used the extractant M5640 at Mantos Blancos and Mantoverde and uses PT5050MD at Los Bronces Division, which are aldoxime and modifier blends. In the first case, the modifier is the esther TXIB, while in the second case is the tridecanol TDA. It is a well-known fact that the extractant degrades while the modifier does not and with time the oxime/modifier ratio can change significantly, depending on the operating conditions of each plant.In order to evaluate the effect of this varying modifier content in the plant organic, especially in the organic losses, a complete metallurgical test work program was conducted at laboratory and pilot plant scale by Flomin SNF, a new extractant supplier. Results showed that the addition of an aldoxime without the modifier did not affect the chemical performance of the extractant, but there was a significant decrease in the viscosity and density of the organic.Based on the results obtained in the metallurgical program, it was decided to run plant scale tests at the SX plants of Mantos Blancos and Mantoverde. In these tests, instead of adding extractant to maintain the organic inventory, CuPROMEX 3406 which is an unmodified aldoxime was added until the original oxime/modifier ratio was reached. This was obtained after 6 months of operation and since then both plants are running with the extractant CuPROMEX 3302 both supplied by Flomin SNF.In the case of Los Bronces, the pilot plant work was completed and it is programmed to run similar plant scale tests. In this case, the oxime/modifier ratio increased and TDA will be added until reaching the original ratio.The plant results obtained at Mantoverde and Mantos Blancos, together with the pilot plant test results obtained at Los Bronces, are discussed in this paper."

Jan 1, 2016

By F. Chachula, A. Molinaro

"Sulphide mineral flotation operations continuously strive for a balance between mineralogy, mineral liberation, circuit conditions and reagent solutions to maximize the production rate and recovery of payable metals. The Taseko Gibraltar copper – molybdenum mill operations underwent an extensive project focusing on the fundamentals to identify the effects of process conditions and mineral liberation to improve the bulk circuit copper – molybdenum recovery efficiencies in the bulk flotation circuits. This discussion will provide process data that demonstrates; 1) fundamental relationship between mineral liberation to recovery and grade, 2) flotation circuit condition testing and optimization, 3) reagent combinations resulting in efficient/economical mineral recovery, and 4) the development of a xanthate free reagent solution. The data presented and discussed will also touch on flotation parameters including pH, retention time, kinetics and the effect on bulk circuit recovery performance.INTRODUCTION Taseko's is the owner (75%) and operator of the Gibraltar copper-molybdenum mine, located in south-central British Columbia, the second largest open pit copper mine in Canada and the largest employer in the Cariboo region. Taseko restarted Gibraltar in 2004. From 2006 until 2012, the company invested ~$700 million to expand and modernize the operation which was originally scheduled for demolition when the company acquired it in 1999. In the spring of 2011, construction commenced for Gibraltar Development Plan 3 (GDP3). GDP3 included the construction of a standalone 30,000 ton per day concentrator, built adjacent to the existing 55,000 ton per day facility. The new design capacity of Gibraltar was designed to be 85,000 tons per day. An integral part of the project was a new molybdenum recovery facility. In addition to the new concentrator, the mining fleet was upgraded with a new mining shovel, production drill and ten haul trucks (Taseko, May 2015). In May of 2015, the Company completed an updated mine plan for Gibraltar featuring a 50% decrease in strip ratio. This new mine plan was a result of a detailed, six-month engineering study and forms the basis of an updated NI 43-101 compliant reserve (Taseko Announces Improved Economics At Its Gibraltar Copper Mine, 2015). The new mine plan took into account lower milling costs as a result of the modernized processing facilities (Taseko, May 2015)."

Jan 1, 2018

By M. B. Kime

"Discrete-element method (DEM) modelling is a powerful tool for studying particulate systems within the mineral processing industry. DEM simulations were conducted to investigate the power draw, load behaviour, and impact energy profile of an experimental ball mill under different milling conditions. The variables considered were mill rotational speed (percent critical speed), ball size, and lifter face angle. The simulation results indicated that the grinding efficiency would be enhanced by using 80% critical speed, 30 mm ball diameter, and 45° lifter face angle. These findings can be useful in guiding actual ball milling tests involving an ore sample.RÉSUMÉ La modélisation par méthode des éléments distincts (MED) est un outil puissant qui permet d’étudier les systèmes particulaires au sein de l’industrie de traitement des minerais. Des simulations par MED ont été menées de façon à étudier le profil de la consommation énergétique, du comportement de la charge et de l’énergie de rupture d’un broyeur à boulets expérimental dans diverses conditions de broyage. Parmi les variables prises en compte figuraient la vitesse de rotation du broyeur (vitesse critique en pourcentage), la taille des boulets et l’angle de coupe de la cornière élévatrice. D’après les résultats de la simulation, on pourrait améliorer l’efficacité de broyage en utilisant une vitesse critique de 80 %, un diamètre de boulet de 30 mm et un angle de coupe de 45 ° de la cornière élévatrice. Ces résultats peuvent se révéler utiles pour les essais concrets de broyage à boulets impliquant un échantillon de minerai.INTRODUCTIONComminution is a very energy intensive process. It consumes approximately 5% of the electricity produced worldwide and more than 50% of the total energy used in mineral processing plants (Pokrajcic, 2010). Among all the comminution stages, ball milling is one of the most energy intensive processes. In ball mills, rotational movement provides the rise of the load and the media that are projected and impact on the mill shell at lower angular displacement, resulting in particle breakage. Ball mills are able to reduce particle size over a relatively wide range of particle sizes. This explains their wide applicability in research laboratories and the mineral processing industry."

Jan 1, 2017

By V. Gangrade

Recirculation is the major concern associated with the utilization of booster fans. In controlled recirculation, a portion of the return air is purposely mixed with the intake air and the mixture is directed towards a working district, while the air quantity and gas concentrations in the air are closely monitored and managed. The objectives of this study were to determine the gas concentration in intake and return airways during controlled recirculation, and to determine the recirculation fraction for multiple headings. Experiments were conducted in a laboratory model to determine the effect of controlled recirculation on the quality of air circulated through the working faces. Preliminary results showed that recirculation is beneficial to ventilation planning because it reduces the build-up of air contaminants at the working faces and reduces the overall power consumptions. The experimental results were used to quantify the recirculation fraction and to calibrate ventilation models of the laboratory model. These models are used to simulate the controlled recirculation and to predict the gas concentrations in multiple headings.

Aug 1, 2013

By N. Campbell, W. T. Orvine

The metalliferous deposits of British Columbia are largely confined to that portion of the Cordilleran province lying west of the Rocky Mountain trench. Massive sulphides in the coastal area carry important copper •values together with lead and zinc and are composed mainly of pyrite which replaces schists or shear zones. The massive sulphide ore of the interior, on the other hand, contains lead and zinc with little copper. Pyrrhotite rather than pyrite is... the dominant metallic and deposition took place through selective replacement of sedimentary beds.

Jan 1, 1960

By W. G. Hubler

It has been within only the last two or three years that enough progress has been made in preferential flotation to warrant metallurgists in recommending the installation of commercial-sized plants for the treatment of copper-zinc-iron ores. Until the new processes had been worked out successfully, the treatment of this type of ore had proved a stumbling block in the path of metallurgical progress. Separation of lead-zinc ore is comparatively simple. A lead-zinc ore low in iron may be separated and concentrated by gravity con-centration, provided it is not necessary to grind too fine. Owing to the specific gravity of chalcopyrite and sphalerite being so nearly the same, however, their separation by gravity concentration is out of the question. Complex lead-zinc-iron ores in which the several minerals are intimately associated, requiring fine grinding to free them, have been successfully treated by flotation for the past fifteen years. Galena is easily floated, and its flotation, unlike that of chal¬copyrite, is not affected by the reagents used to inhibit the flotation of sphalerite and iron sulphides. When an attempt was made to use the methods of lead-zinc se-paration on copper-zinc ores, it was found that the depressant re-agents added to inhibit the flotation of the iron and zinc minerals would, under certain conditions, depress a large part of the copper. It was also recognized that, in the grinding of copper-zinc ore, soluble salts were generated which were detrimental to flotation unless properly controlled. The main part of this paper will be a discussion of solutions in the grinding circuit in relation to the pro¬duction of soluble salts and their effect on flotation.

Jan 1, 1931

By A. Quilodran, B. Jakovljevic, T. McCallum, P. Wong

"Rare earth separation by solvent extraction (SX) requires multiple separation plants each consisting of many extract, scrub, and strip stages to separate the individual metals. SX modeling advances have brought benefits to circuit design and process optimization by quickly narrowing test conditions without the need for exhaustive laboratory studies. Modeling can be used to optimize circuit configuration, O/A ratios, and acidities, which allows for CAPEX and OPEX savings. A comparison between pilot plant data and the results expected from modeling is presented for rare earth separations with CYANEX® 572.INTRODUCTIONRare earth separations can be difficult due to limited separation between the elements (Xie, Zhang, Dreisinger, & Doyle, 2014). This requires relatively complex solvent extraction circuits utilizing multiple extract, scrub, and strip stages as well as multiple SX configurations to achieve the desired metal purities. Designing rare earth circuits can be complex, and significant time and testing may be necessary to determine the required staging and optimal conditions.Circuit modeling for rare earth separations has been introduced to the industry using CYANEX® 572 extractant (Soderstrom, McCallum, Jakovljevic, & Quilodran, 2014). CYANEX® 572 is an acidic organophosphorus extractant formulation which has a weaker ligand-metal complex strength than that of the traditionally used phosphonic acid extractants. This allows efficient extraction while requiring a significantly lower acid concentration for stripping (Wang, Li, Zhao, Dong, & Sun, 2015). The reduced acid requirement in strip is expected to provide OPEX savings.The modeling can be utilized to quickly determine the required acidity and organic/aqueous (O/A) ratio for a given separation. It is also expected to reduce CAPEX requirements as optimal staging can be determined, and implemented.CYANEX® 572, combined with modeling, was utilized to produce a purified dysprosium (Dy) stream. To achieve this separation, multiple SX circuits were designed and operational conditions specified to separate Dy from the mixed rare earth chloride feed."

Jan 1, 2016

By P. G. Thornhill

EARLY in 1951, Falconbridge undertook a research program aimed at the development of a sulphate roasting process for the recovery of the non-ferrous rnetals from the nickeliferous pyrrhotite fraction of Falconbridge ore, in order to reduce the tonnage of iron entering the srnelter. Such a method, it was hoped, would permit a high recovery of the nickel from pyrrhotite otherwise entering the smelter feed, thus not only raising the grade of the latter and reducing its iron content, but also providing an iron oxide residue useful as a source of by-product iron ore. At an early stage in the exploratory laboratory test work it was found that the degree to which the nickel could be solubilized by the sulphating roasting treatment was limited by particle size and the ex-tent to which the pyrrhotite concentrates were freed of the nickel occurring as physically separable pentlandite, a mineral relatively difficult to roast. ( 1) Thus the program

Jan 1, 1961

By R. Bashir, J. F. Hatley

ABSTRACT Northern Saskatchewan boasts some of the world’s largest known high-grade uranium deposits. The successful mining of these deposits cannot be accomplished without overcoming technical challenges, however, which include high grade of the uranium ore, specialized mining methods to deal with groundwater at high pressures, and poor ground conditions. This paper discusses the various mechanisms of inflows at three of Cameco Corporation’s sites in northern Saskatchewan. The risk of inflows is quantified in terms of unique challenges due to hydrogeological conditions, rock mass integrity, and uncertainty in geological conditions. Strategies in the case of an inflow are also briefly described.

Jan 1, 2013

By Ron Zevenhoven

In Finland one opportunity for large-scale CO2 capture, utilisation and storage (CCUS) is CO2 mineralisation, i.e. mineral carbonation. A process route under development towards industrial application involves production of magnesium hydroxide or sulphate from serpentinite rock (serpentine = 3MgO·2SiO2·2H2O), followed by conversion either in a pressurised fluidised bed (PFB) reactor, giving magnesium carbonate, or in an aqueous solution process giving magnesium hydro-magnesites. Iron present in the rock is typically obtained FeO(OH). Results obtained with these process routes and progress towards industrial demonstration is addressed, process heat integration and operation on flue gases (without CO2 pre-separation!) being key features for economic viability. A process route utilizing calcium-containing slag by-product from iron- and steelmaking under development towards large-scale application is the so-called slag2pcc concept. It converts an industrial by-product into valuable material, reduces use of natural material and streams to landfills while binding CO2 produced by the process generating the slag. Using ammonium salts, calcium is extracted from steel converter (BOF) slags and subsequently carbonated in a two-stage aqueous process (at ambient temperatures and pressures). Precipitated calcium carbonate (PCC) is produced while regenerating the ammonium salt. Process performance and scale-up while guaranteeing a certain PCC quality are presented.

Jan 1, 2015