Search Documents

By Garston Blackwell

Abstract - During geostatistical estimation of block grades, the kriging process produces a measure of error, the kriging variance or the kriging standard deviation. Estimation of the block error depends on the semi-variogram model for a deposit, which reflects fundamental characteristics of a deposit such as (1) nugget effect, (2) range of influence of grades, (3) different local spreads of data as a function of average grade (proportional effect), (4) nested structures, and (5) underlying anisotropies in the data; this model may be affected by sampling or assaying limitations, however. Because the kriging error incorporates so many features of both the deposit and data to be used for estimation, it may offer a substantial improvement on block classification over traditional procedures such as data density. Practice indicates that the relative kriging standard deviation (RKSD) is particularly useful for block classification in measured, indicated and inferred categories. Plots of RKSD in plan and section also can be used to demonstrate where extra drilling and sampling would be most advantageous for upgrading the class of some blocks. Moreover, the use of grade and RKSD filters can show where material near cut-off grade is poorly defined, indicating sampling target areas to improve block classification in the vicinity of the ore-waste boundary.

Jan 1, 1998

By S. N. Dixon

"Maximizing the value of each tonne of processed ore is the goal for all operations. Cyanidation processing of gold-copper ores has been challenging since its first use in 1889. The current practice treats a bleed or the total flow of mill solution to recover copper as copper sulfide (by sulfidization, acidification, recycling, and thickening), or to recover the cyanide (by acidification-volatilizationneutralization). The process presented uses the adsorption of copper cyanide by carbon and the selective elution of copper from carbon to concentrate copper into a smaller stream. Copper contained in the smaller stream is precipitated as copper cyanide.RÉSUMÉ Toutes les exploitations ont pour objectif commun d’optimiser la valeur de chaque tonne de minerai traité. Depuis sa première utilisation en 1889, la méthode de traitement par cyanuration des minerais aurifère et cuprifère s’est révélée complexe. La pratique actuelle traite la saignée ou le débit total d’une solution de traitement du concentrateur pour récupérer le cuivre sous la forme de sulfure de cuivre (par sulfuration, acidification, recyclage et épaississement), ou pour récupérer le cyanure (par acidification, volatilisation et neutralisation). Le procédé présenté dans cet article utilise l’adsorption sur charbon actif de la solution de cyanure de cuivre et l’élution sélective du cuivre depuis le charbon pour concentrer le cuivre en un plus petit jet. Le cuivre contenu dans ce plus petit jet est précipité sous forme de cyanure de cuivre."

Jan 1, 2017

By S. Banisi, J. A. Finch, A. R. Laplante

"A technique for on-line simultaneous estimation of gas and solids holdup (volume fraction), based on a combination of conductivity and pressure difference measurements, is proposed and tested in a laboratory flotation column (10cm in diameter and 447cm in height). Fundamental concepts underlying this technique and the effect of relevant parameters are discussed. In the studied range, 3-30 %v/v gas holdup and 2-18 % v/v solids holdup, experimental results showed good agreement between the estimated and actual holdup values (as determined by an isolating technique). The relative accuracy of the solids holdup estimation increased when solids density or solids concentration increased. Frequent re-calibration of pressure transducers was found necessary for accurate phase holdup estimation.IntroductionGas holdup is a key parameter in controlling the performance of flotation columns. For example, flotation rate is affected by bubble size and gas rate both of which, in turn, affect gas holdup. Moreover, gas holdup also determines the slurry residence time which indicates a direct influence of gas holdup on recovery.Gas holdup determination has been the focus of many studies (e.g., Castillejos, 1986; Marchese et al., 1992). Some of the techniques which have been used are given in Table 1."

Jan 1, 1994

By Jeffrey S. Loen

"Abstract - The size, morphology, surface texture, per cent mineral inclusions, and bulk chemistry (Ag and trace elements) of placer gold particles vary systematically according to transport distance from source rocks, as indicated by a case study from the Pioneer district in Montana, and data from the literature.Placer gold samples show a rapid decrease in mean and maximum particle length, and a gradual increase in flatness index (F.I. = length + breadth/2 X thickness) from about F.I. = 2 in bedrock deposits, to as much as F.I. = 45 over transport distances of several tens of kilometers. Primary mineral inclusions (mainly quartz, sulfide minerals, and iron oxides) are mostly lost within 10 km to 20 km of fluvial transport; this loss of quartz and trace metals causes a major change in bulk chemistry of placer gold samples. Following the loss of inclusions and the development of flakes, edges of flakes are folded and the mean number of folded edges in a sample increases with distance. When viewed under the electron microscope, surface textures of placer gold particles also become progressively more pitted with distance.Analysis of placer gold particles can be used to help evaluate placer source-area problems (placers with no known hard-rock gold deposits). For example, coarse placer gold containing abundant inclusions indicates a proximal source. On the other hand, an abundance of thin flakes is evidence of a long transport distance and possible reworking from older gravels. Placer gold characteristics can therefore provide information on distance to mineralized source rocks."

Jan 1, 1995

By F. Prescott, D. Hiam-Galvez, J. Hiam

Mines are frequently located in remote areas with little conventional employment and few opportunities for the existing population. The development and operation of the mines results in several years of intense activity followed by a near-complete reduction in employment and opportunities after the mines are closed. Designing Sustainable Prosperity (DSP) is a method for rectifying this situation by designing for long-term growth in areas that host mines. This process involves the participation of local and national governments, local community, mining companies, investors, academics and those with sector expertise. The mines will be the catalyst for regional sustainable development. If successful, long-term economic and environmental prosperity should be the result for the areas affected by mining and, in some instances, promoting the regions as centres of excellence for a particular industry. This paper will describe how the concept works using the copper producing region of Peru and Chile as an example. Designing sustainable prosperity starts by looking at regions based on the natural resources and skills available, the infrastructure and possible energy sources. Integrated natural resource models and innovative market studies, followed by education and skills requirements, are then established to determine the potential for the region and what needs to be done to realise the possibilities. INTRODUCTION Industry 4.0, or i4.0, dubs the fourth and current industrial revolution. Where previously they have been founded on ever-increasing consumption and production, i4.0 distinguishes itself by its partial focus on reducing resource intensity; lightweighting, energy efficiency, sensors and automation to improve resource efficiency. Industry 4.0 is an era of artificial intelligence, genome editing, biometrics, renewable energy, 3D printing, autonomous vehicles and the Internet of Things (Lu, 2017). These drivers represent key opportunities for the economic future of nations and regions.

Jan 1, 2019

By K. M. Deen, E. Asselin

Hydrometallurgical processes, i.e., Cu extraction from a mineral concentrate and Zn electrowinning, are coupled in a battery-like system. A naturally-sourced CuFeS2 concentrate mixed with activated carbon is used as a positive slurry electrode separated by a membrane from the negative compartment. The Zn is deposited on the negative Al current collector from the circulating solution containing 100 g L–1 Zn2+ in 0.2 M H2SO4. In this battery-like system, both CuFeS2 oxidation and Zn deposition are possible during the charging cycle. The additional benefit of this setup is the energy storage if discharged by re-dissolving the Zn in the negative compartment. Cyclic charge/discharge testing revealed oxidation of the mineral concentrate supported by the Zn2+/Zn redox reaction. The coulombic and energy efficiencies increased monotonically to 95.6% and 43%, respectively, with approximately 7% Cu extraction during the first 10 charge/discharge cycles (completed in 2.4 hours). The discharge energy density also increased from 2.7 to 36.2 mWh L–1. In the following 90 cycles, the low energy (~14%) and coulombic (~33%) efficiencies that were obtained confirmed the progress of irreversible reactions e.g. Cu extraction from the mineral concentrate. Overall, approximately 16% Cu was extracted from the mineral concentrate over 100 charge/discharge cycles (or about 12.2 hours). INTRODUCTION Chalcopyrite (CuFeS2) is the main economic copper-bearing mineral, which is generally processed through pyro-metallurgical methods to produce Cu. However, environmental challenges with smelting, depletion of high-grade ores and a large number of impurities (some toxic) have resulted in continued research aimed at the development of hydrometallurgical technologies to process CuFeS2. There are a number of different proposed hydrometallurgical routes in the literature to treat CuFeS2 concentrates, but only a few have attained commercial acceptance (Dreisinger, 2006). Zn is another commercially important metal that is mainly produced via acid leaching of roasted sphalerite (ZnS). The pregnant leach solution is rigorously purified to remove all the soluble metal impurities, particularly those that are electrochemically more noble than Zn and present large kinetic activity towards H2 evolution (Hu & Piron, 1992; Mackinnon, Brannen, & Fenn, 1987; Mureşan, Maurin, Oniciu, & Gaga, 1996). Metal impurities such as Cu, Co, Ni, Cd, Pb, Sb, As, Ge and Fe etc., if they exist in the leach liquor beyond the tolerance limits, can decrease the current efficiency during electrowinning and deteriorate the deposit quality (Alfantazi & Dreisinger, 2001). A complete flow sheet, describing the process steps of Zn metal production from mine site to pure metal is presented elsewhere (Brown, Meisenhelder, & Yao, 1983).

Jan 1, 2019

By K. Reipas

"Westmin Resources Ltd. operates the 3300 TPD H-W underground copper/zinc mine on Vancouver Island. Ore storage underground is handled in a 6000 tonne coarse ore bin and a 3000 tonne fine ore bin. Both of these bins have experienced significant wear since excavation and construction in 1985. Wear problems have included both deteriorating rock walls as well as worn out steel liners and concrete at the discharge points from the bins. Extensive rehabilitation work was completed in 1993.The basis o/this paper is the rehabilitation work done on the coarse ore bin. The design and installation of ground control measures are discussed. The bin access methods used to allow the work to proceed quickly and safely are also presented. This involved the use of a Tekfoam safety bulkhead to protect workers.IntroductionMine DescriptionThe H-W mine was commissioned in 1985. Mine access is by vertical shaft with most production areas at a depth of about 500 m. Host rocks are composed of andesite and rhyolite. Mine capacity of 3300 tonnes per day is achieved mainly by longhole open stoping methods, complemented by room and pillar mining. Metals recovered from the massive sulphide ore are copper, zinc, gold, and silver. Mineable reserves at January I, 1994 were 9.7 million tonnes."

Jan 1, 1995

By Anthony J. Deevy

"The Magino gold mine is located 45 km northeast of Wawa, Ontario. There was limited gold production in the late thirties. The present operation was officially opened in October 1988 and produced gold until September 1992. It was a 635 tonnes per day, decline-accessed mine, with ore coming from several small blast hole and shrinkage stopes.The host for the gold is the Webb Lake granodiorite stock which was intruded into the Goudreau Lake Deformation Zone. This east-northeast-striking deformation zone overprints the generally east-west- striking isoclinally folded metavolcanic and metasedimentary rocks, which make up the east end of the Michipicoten greenstone belt. The ore-shoots are controlled by dextral delatancy associated with the Goudreau Lake Deformation Zone. Shearing, bleaching and silicification accompanied the gold emplacement. IntroductionThe following is a general information paper on the Magino gold mine which is located 45 km- northeast of Wawa toward the east end of the Michipicoten greenstone belt. This paper summarizes the discovery, exploration and development history of the deposit. The geological characteristics are described, including regional geological setting, local mine geology, mineralization, alteration and structural history. The mining methods and the contribution of the geological staff to the successful development and mining of the gold deposit are also mentioned."

Jan 1, 1994

By Jeffrey S. Loen

"The size, morphology, surface texture, per cent mineral inclusions, and bulk chemistry (Ag and trace elements) of placer gold particles vary systematically according to transport distance from source rocks, as indicated by a case study from the Pioneer district in Montana, and data from the literature.Placer gold samples show a rapid decrease in mean and maximum particle length, and a gradual increase in flatness index (F.I. = length + breadth/2 x thickness) from about F.I. = 2 in bedrock deposits, to as much as F.I. = 45 over transport distances of several tens of kilometers. Primary mineral inclusions (mainly quartz, sulfide minerals, and iron oxides) are mostly lost within 10 km to 20 km of fluvial transport; this loss of quartz and trace metals causes a major change in bulk chemistry of placer gold samples. Following the loss of inclusions and the development of flakes, edges of flakes are folded and the mean number of folded edges in a sample increases with distance. When viewed under the electron microscope, surface textures of placer gold particles also become progressively more pitted with distance.Analysis of placer gold particles can be used to help evaluate placer source-area problems (placers with no known hard-rock gold deposits). For example, coarse placer gold containing abundant inclusions indicates a proximal source. On the other hand, an abundance of thin flakes is evidence of a long transport distance and possible reworking from older gravels. Placer gold characteristics can therefore provide information on distance to mineralized source rocks."

Jan 1, 1995

By Elaine Ellingham, Francis T. Manns

"The Orostar and Scadding were two small gold mines owned and operated by Orofino Resources Limited. Conventional statistical treatment indicates an identical arithmetic mean grade of 0.22 oz/T Au for both mineable reserves. Further, the deposits are both shown to have cut weighted average reserve grade of 0.21 oz/T. Orostar mined out at 0.206 oz/T and Scadding at 0.156 oz/T Au. The combined exploration and development database contained 1394 fire assays, more than enough for statistical confidence in a normal distribution. Therefore this study was initiated to determine, if possible, why the mill head grades were lower than the averages and to experiment with several methods to determine whether a reliable statistical mill head grade estimation method would emerge. Despite the identical reserve grades, distinct differences in the grade distribution histograms are present. By studying the arithmetic and log-normal grade distributions, with some attention to South African practices, this paper reports on those differences which may account for the considerable divergence in the mill head grades. Furthermore, this study casts considerable doubt on the industry standard method of cut weighted averages.The global mill head grades of the two deposits have been derived from the arithmetic average grades by graphic means. This precise method of mill head grade prediction, if applied to complex orebodies, could permit selective grade control and result in direct cost savings by allowing the operator to detect false value stopes, benches or levels and emphasize reliable regions of not only gold mines, but also uranium or base metal deposits."

Jan 1, 1992

By R. Shamsodini, A. Poor Zaeif Doost, H. Haji Amin Shirazi, M. R. Garmsiri

"With columns being installed in rougher section at Miduk Copper Complex, the rougher feed mainly reports to rougher-scavenger cells. To evaluate the efficiency of regrinding circuit, we conducted flotation experiments on samples of the feed and the products of the regrinding circuit. The grade difference of these products at 85% recovery was considered as the efficiency index. Results show that, with weight recovery of the rougher-scavengers the efficiency of the circuit increases. Exclusion of the rougher-scavenger concentrate from the feed to the regrinding circuit, resulted in an increase in the efficiency index from 10.12 to 17.6%.INTRODUCTIONThe flotation circuit at Miduk Copper Complex consists of five flotation columns as roughers and ten mechanical cells as rougher-scavengers. According to design criteria, 75% of the final product was expected to be produced by the rougher columns, while most of the feed consisting of liberated valuable particles is introduced into rougher-scavengers. To liberate locked particles, the rougher-scavengers concentrate is introduced into the regrinding circuit (see Figure 1 below). The regrind mill is in reversed closed circuit with a secondary hydrocyclones cluster, and the cyclone overflow is introduced into three parallel cleaner columns. Cleaners concentrate reports to concentrate thickener and the column tailings is introduced into six mechanical cleaner-scavenger cells. The cleaner-scavengers concentrate reports to the regrind circuit(Figure 1)."

Jan 1, 2012

By K. Esmaieli

ABSTRACT We conducted a series of numerical experiments to investigate the influence of rock mass foliation on impact-induced damage on ore pass walls. The 2D Particle Flow Code was used to simulate three distinct rock masses surrounding an ore pass, characterized by foliation angles of 60°, 90°, and 120° (clockwise from horizontal). Subsequently, we projected a rock fragment against the ore pass walls at a constant impact angle and velocity. The resulting damage increase

Jan 1, 2014

By V. W. Shtenko, B. J. Ennis, P. H. Bridge

"The northeastern region of British Columbia contains large quantities of high-quality metallurgical coal. To market the coal, it was necessary to provide the required infrastructure which included rail access. This paper presents the role of the British Columbia Railway in the northeast coal development.In 1976, B.C. Railway undertook to study two main routes, one originating at Chetwynd and the other at Anzac, both located on the main line, north of Prince George. The routes studied are briefly described, detailing the methodology and engineering analysis carried out to permit the selection of a single route that would be the most cost effective, taking into consideration the construction, maintenance and operating costs. The operating parameters, track and grade standards, anticipated tonnage, construction costs and the final route selected are also presented.Pre-engineering analysis and studies of the route selected originating at Anzac, known as Tumbler Ridge Branch Line, and which commenced in 1977, were concluded in 1978. New mapping was developed to a scale of 1:2000 with good vertical and horizontal control. Based on the mapping data, terrain analysis, and designs developed, an estimate of construction costs and schedule of work was developed.Authority to proceed with the final design and construction was provided in December 1980, with the first shipment scheduled for December I, 1983. Final designs of all structures are discussed, including schedules, cost to completion, and control systems utilized. The decision to electrify the Tumbler Ridge Branch Line and related topics are discussed, with a brief description of train operations. The present status of the project is also presented."

Jan 1, 1983

By H. Scott Swinden

"ForewordA symposium on base metal deposits was held in Bathurst, New Brunswick, from June 10-13, 1990, sponsored jointly by the Geological Surveys Branch of the New Brunswick Department of Natural Resources and Energy, the New Brunswick Prospectors and Developers Association, and the Geology Division of the Canadian Institute of Mining, Metallurgy and Petroleum . Papers prepared for the symposuim are being published as a series of articles in the CIM Bulletin. This second paper (the first was by Fyffe, et al., in Vol. 83, No. 938) in the series presents an overview of the paleotectonic settings of massive sulphide deposits in the Dunnage Zone of Newfoundland with emphasis on volcanic geochemistry.ABSTRACTCambrian and Ordovician volcanic sequences of central Newfoundland, which record the history of the Iapetus Ocean, are prolific hosts to volcanogenic massive sulphide (VMS) deposits. Geochemical, isotopic and geochronological studies show that the vestiges of Iapetus in Newfoundland probably record a complex series of island arcs and back-arc basins that were marginal to, rather than part of, the main ocean basin of Iapetus. The geochemical and isotopic data provide a means of characterizing the tectonic environment of individual volcanic sequences, and allow us to identify a number of distinct tectonic environments in which VMS depositiontook place.Four tectonic environments have been identified as being associated with VMS deposition: (I) back-arc environments hosting VMS deposits include both N-MORB-type ophiolites (e.g. Skidder?) and volcanic sequences with oceanic island (or within plate) tholeiite characteristics (e.g. Great Burnt Lake); (2) primitive arc environments include both supra-subduction zone (SSZ) ophiolites (e.g. Betts Cove, Rambler) and volcanic/epiclastic sequences (e.g. Point Leamington, Duck Pond) and are characterized by abundant arc tholeiites, with lesser refractory lavas and rhyolites; (3) mature arc environments comprise dominantly thick felsic and mafic volcanic piles in the Buchans - Robert's Arm Belt (including the Buchans camp) and are characterized by dominantly calc alkalic basalt and andesite; and (4) continental rift environments occur in the Hermitage Flexure area (e.g. Strickland deposit) and are characterized by dominantly felsic volcanic sequences.Island arc environments are by far the most prolific hosts to VMS deposits. Patterns of VMS distribution in central Newfoundland show that similar tectonic settings may be recorded by very different stratigraphic sequences (e.g. both ophiolites and thick volcanic/ epiclastic sequences may record primitive arc rifting) and emphasize the importance of the rifting in VMS generation, irrespective of the details of the tectonic or stratigraphic setting. The ability to judge the prospectiveness of a volcanic sequence by using whole rock geochemistry to evaluate its tectonic environment may prove useful in area selection at the grassroots exploration level."

Jan 1, 1991

By R. Le Houillier, M. Nagamori, A. J. Plumpton

"Asbestos tailings are a typical serpentine, hydrated magnesium silicate, consisting primarily of antigorite and a few per cent of unrecovered fibrous chrysotile. Serpentine has unique thermal properties in that dehydroxylating calcination at 600 to 700°C can yield an amorphous structure in which most of the magnesia is liberated from the original bond with silica and thereby rendered chemically active. The amount of activated magnesia can be quantified by selective leaching with a weak acid such as acetic acid. Many wet processes have been proposed to extract magnesium values from calcined or natural serpentine by means of various acids and their ammonium salts. However, the only commercial utilization of serpentine today is found in dry processes such as the production of fused magnesium phosphate fertilizer .The present paper reviews the physical chemistry of the dehydroxylation of serpentine and also various wet and dry processes in order to provide a general view regarding the chemical transformation of asbestos tailings.IntroductionAsbestos fibers occur as chrysotile, a serpentine polymorph. More than nine tenths of mined asbestos ores consist of massive non-fibrous serpentine, primarily the polymorph antigorite, which is discarded as tailings after fiber extraction. For many decades, Quebec has been a world leader in the production of asbestos fibers. As a result, colossal tonnages of serpentine have accumulated in the Eastern Townships'!'. Serpentine minerals are found in large deposit s throughout the world, and significant research efforts have been made, particularly in Japan and the USSR, mostly in attempts to extract magnesia or silica values therefrom.The chemical composition of serpentine (chrysotile and antigorite) may be ideally expressed as Mg3Si2Os(OH). which corresponds to 43.7% MgO and 43.3% SiO2. Natural serpentines often contain a few per cent of Ni-bearing magnetite and other impurities, and therefore the contents of MgO and Si02are both about 40% or lower.Serpentine (hydrated magnesium silicate) is virtually insoluble in weak acids. However, when dehydroxylated under controlled conditions, ' it decomposes to an amorphous state in which magnesia and silica are isolated and chemically active. The magnesia so activated is readily soluble in weak acids. This unique characteristic of calcined serpentine, first discovered in 1942,, has since attracted the attention of innumerable researchers, whence many processes have been proposed."

Jan 1, 1980

By John E. Callahan

"A stream sediment geochemical survey covering an area of 13.000 sq. km near Churchill Falls. Labrador. was conducted for Brinex (British Newfoundland Explorations Ltd.) prior to partial flooding by the Churchill Falls power project. Stream sediments (minus 80-mesh) were analyzed for Cu, Pb, Zn, Ni, Ag, Mo. U and Mn, and the heavy mineral, nonmagnetic fraction (minus 60-mesh) for Cu, Pb, Zn, Ni, Ag, Mo, Ba and Mn. A binocular examination of the concentrates for sulphides and pyrope garnet was done on the heavy mineral concentrates. The concentrates were also examined for fluorescent minerals.Two distinct areas with high trace-element values indicate the need for follow-up studies. The first is in an area of gabbro erratics containing massive and disseminated sulphides (pyrrhotite, pyrite and minor chalcopyrite) on the western edge of the survey area along the Esker Road. The second, largest area (several hundred square kilometres) is anomalous in U and Mo and associated with felsic intrusives (Red Wine Complex?), syenites. granite gneiss and sedimentary rocks (Seal Lake Group?).The binocular study showed that almost 15% of the heavy mineral concentrates contained pyrite and no other sulphides. This indicates that this technique may be worthwhile in determining the presence of sulphide minerals in stream sediments from glaciated environments. The only fluorescent mineral observed in the study was zircon."

Jan 1, 1981

By A. Blackmore, A. Lamoureux, J. Woloshyn

This paper provides an overview of recent applications of Computational Fluid Dynamics (CFD) to combustion related fugitive emissions problems. The aim is to illustrate the capabilities and discuss the present limitations in this field. Examples include design of retrofitted NOx reduction technology in a kiln and in a boiler, and the prediction of pollutants such as SO2 and metallurgical dust emanating from a copper flash smelting furnace. It is demonstrated that CFD is an effective tool for reducing technical risk in design, for identifying the root-cause problems and testing solutions, and for concurrently assessing emissions reduction and process impact. In addition, the value of CFD for demonstrating due diligence for regulatory compliance is discussed.

Jan 1, 2015

By Heather Budney

Objectives 1. Evaluate the effectiveness of ON?s EA processes using criteria from the EA and policy sciences literature. 2. Recommend improvements to the EA processes and draw lessons from the ON case for the consideration of other jurisdictions. Evaluation Process 1. Chose criteria ? 14 primary criteria (Wood 2003) ? Subcriteria from Wood (2003) and Lasswell (1971) 2. Gathered information ? 6 key informant interviews ? Published literature, policies, legislation 3. Assessed criteria and formed Recommendations

May 1, 2008

By C. Pichler, S. Luidold, C. Wagner, C. Sagadin, D. Kreuzer

Engineers and scientists have been combating the attack upon refractory materials of molten metals/matte and slags for hundreds of years. The details in many cases are still questionable or at least debatable. The corrosion is a major concern for furnace operators as refractory wear or failures inevitably results in reduced production efficiency and furnace reliability. Also the cost to industry is considerable and only a thorough understanding of all the complexities of the process will help to minimize that cost. One of the critical questions to overcome is the correct selection of refractories for the individual process steps to provide long and predictable refractory life together with high furnace availability. To understand the nature of the reactions involved in refractory corrosion, it is crucial to determine the complex thermo- chemical equilibria of the reactions occurring between the refractory materials and the process phases. A simulation model coupled with commercial software like FactSageTM is demonstrated aiming to understand the corrosion mechanisms between refractories and the molten process phases and draw implications for improving the performance of refractories and refractory lifetime. INTRODUCTION The extraction or recycling of valuable materials, e.g. metals, can be done by two main routes, pyro- and/or hydrometallurgical processing, depending on the chemical behavior of the used ore, scrap or pre-treated concentrate. Sometimes it is also necessary to use both process routes for the extraction or the recycling of valuable materials. In the case of a pyrometallurgical treatment, the usage of refractory materials is inevitable. This is mainly caused by high temperatures, prevailing during processing. The interaction between refractory material and slag, metal or matte leads to different reactions and interactions. As a main result corrosion of the furnace lining (refractory material) takes place. Hence, recurring furnace shutdowns occur for renewing the refractories. This leads to reduced production efficiency. Such refractory lifetimes are between some hours and decades, depending on the processes.

Jan 1, 2019

By John J. Barakso

A summary of geochemical dispersion processes is presented. Secondary and tertiary dispersion of uranium was examined at several uranium prospects in British Columbia. The vertical migration of uranium from bedrock (primary dispersion) through overburden into the various soil horizons, and into snow and plants, was studied, and relationships were sought to explain the dispersion patterns in the secondary and tertiary environments. Soil developments were examined to obtain information on factors affecting the dispersion of uranium in soil profiles and tertiary substances; samples were analyzed for a number of elements. Biogeochemical data indicate that plant geochemistry is a possible exploration aid in areas of heavy overburden owing to the high selectivity of certain plants for specific elements. Some new data on the geochemistry of snow are discussed as a matter of research interest in the tertiary dispersion of uranium. Analytical techniques and problems are discussed, particularly extraction techniques, which must be carefully chosen to give reliable information on uranium dispersion.

Jan 1, 1979