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By R. L. Bruening, R. M. Izatt, N. E. Izatt, S. R. Izatt

"Molecular Recognition Technology (MRT) is a simplified, green chemistry process with applications in selective separations of Ni(II), Co(II), and platinum group metals in primary ore beneficiation processes and secondary recovery operations from spent products, scrap, and environmental waste solutions. Simplification in MRT processes is achieved by non-use of solvents, reduced space requirements, and a simple separation system involving columns packed with metal-selective SuperLig® resins. Minimal waste is generated and metal recovery is achieved at 99% levels from g L-1 to <mg L-1 concentrations. MRT systems are attractive technologically and economically compared with solvent extraction, ion exchange, and precipitation separation processes. Commercial examples of MRT use include removal of impurity metals Cd, Cu, Ni. Fe, and Pb to mg L-1 or lower concentration levels from Co streams to produce battery-grade Co. Highly purified Co is required for optimal function of lithium ion rechargeable batteries and superalloys associated with aerospace and gas turbine operations. Impurity metals are recovered for reuse or proper disposal rather than being discarded to landfill. Green chemistry processes, such as MRT, are needed in metal separations going forward into the 21st century to achieve global metal sustainability in processing of native ore and treatment of secondary sources.INTRODUCTION Maximizing efficiencies of metal separations and optimizing metal recovery rates during separation processes are important goals on the road to achieving metal sustainability. Achievement of these goals is consistent with stated principles of green engineering (O'Connor, Zimmerman, Anastas, & Plata, 2016) and green chemistry (Anastas & Eghbali, 2010). Molecular Recognition Technology (MRT) separation processes using SuperLig® resins have a 25-year record of performing competitive, commercial metal separations with metal recovery rates approaching 100% (Izatt, Izatt, Izatt, Krakowiak, & Bruening, 2017). SuperLig® resins are characterized by high selectivities for specific metals over concentration ranges from g L-1 to mg L-1 or lower. MRT systems use no solvents and are simple in design and operation resulting in reduced capital and operating expenses."

Jan 1, 2017

By W. Hawker, A. M. Ivana

"Pressure oxidation is used to liberate gold from refractory sulphide ore and concentrates with over fifteen autoclaves in operation. Despite the importance of pressure oxidation, the autoclave chemistry and chemical thermodynamics are not well established. For example, there is no consensus on aqueous iron speciation or stability of jarosite phases. Additionally, there remains questions about basic ferric sulphate formation and stability. In addition to a review of the current state of knowledge, a methodology to study the ferric precipitation reaction and relate the results to chemical thermodynamic predictions is presented which will be used to accurately define the phase boundaries of the iron precipitates in the future (hematite, jarosite and basic ferric sulphate).INTRODUCTION With declining availability of orebodies that respond to simple leaching conditions, pressure oxidation has become a prevalent technology to liberate gold locked in sulphide mineral matrices. Gold pressure oxidation was established 32 years ago, with McLaughlin being the first facility in 1985 (Thomas & Pearson, 2016). Pressure oxidation is carried out at elevated temperatures ranging from 180 to 240°C as shown in the summary of operations in Table 1 (Ruonala et al., 2016; Fleming, 2010).A considerable amount of research has been done to study iron solubility and precipitation under autoclave conditions (Tozawa & Sasaki, 1986; Umetsu et al., 1977; Sasaki et al., 1993; Fleuriault, 2016; Cheng & Demopoulos, 2004; Papangelakis et al., 1994; Yue et al., 2003). These reports provide a description of the process chemistry and iron behaviour in the autoclave. However, there remain questions about the type and stability of aqueous species and solid phases. This detailed information is required to build a robust chemical thermodynamic model of the system, allowing for equilibrium and kinetic reaction limitations to be discerned."

Jan 1, 2017

By J. Dennett, M. Faris, M. Antonio, M. Collins, N. Tuffrey, R. Ellenwood, V. Reddy

"In January 2012, AngloGold Ashanti Córrego do Sítio Mineração, with assistance from Sherritt International Corporation, commissioned a new autoclave for pressure oxidation of refractory gold concentrate at the Córrego do Sítio operation in Brazil. Start-up of the plant occurred in a few weeks and enhanced gold recovery was realized almost immediately, with 94% gold extraction achieved in carbon in leach (CIL), compared to less than 70% without pressure oxidation. This paper describes start-up and commissioning of the plant and provides an overview of plant performance over the last five years.INTRODUCTION In 2008, AngloGold Ashanti purchased the former São Bento property from Eldorado Gold, which, along with AngloGold Ashanti’s existing Córrego do Sítio mine, was renamed AngloGold Ashanti Córrego do Sítio Mineração (AGA Mineração). Later that year, the Sherritt Technologies division of Sherritt International Corporation (Sherritt) was contacted to begin batch and continuous pilot plant tests to determine the amenability of the AGA Mineração refractory gold concentrates to the pressure oxidation process. Based on the results of the batch and pilot plant tests, AGA Mineração requested basic and detailed engineering studies to be conducted by Sherritt, eventually leading to commissioning of the plant in January 2012. AGA Mineração’s plant is located in southeastern Brazil in the state of Minas Gerais, near the city of Belo Horizonte. AGA Mineração`s Phase 1 mine plan covers three sites in the Laranjeiras, Carvoaria Velha and Cachorro Bravo ore bodies, and is designed to process 60,000 tonnes of refractory gold concentrate per year to produce 140,000 ounces of gold per year with an 11 year life of mine (AngloGold Annual Financial Statements, 2010). Recovery of gold at AGA Mineração is based on Sherritt`s pressure oxidation technology for refractory gold concentrates (Berezowsky et al., 1991; Collins et al., 2011a; Collins et al., 2011b). This process had previously been applied to the recovery of gold at the São Bento site (Carvalho et al., 1988; de Silva et al., 1989), in a plant that was operational between 1986 and 2007 (Silva et al., 2004)."

Jan 1, 2017

By J R. Barber, B. E. Rogers, R. Fukuzawa

Mercury is sometimes present in non-ferrous ores including gold, zinc, copper and lead. The selection and use of appropriate mercury abatement technology is critical for preventing its release to the environment during ore processing and to protect workers from mercury exposure. This paper presents a general decision-making process for mercury abatement technology selection for major emission sources in the gold industry. Mercury abatement can be accomplished through making process changes and/or by adding a process step to an existing system (i.e. "end-of-pipe control"). Advantages and limitations of the technologies along with waste / by-product management options are discussed through case studies of current operating mercury abatement systems.

Jan 1, 2015

By A. Blackmore, D. Baker, L. Human

"Mechanical mixing equipment is common in a wide variety of mining, metals and process applications, such as hydrometallurgical reactors, solvent extraction, digestors, and tanks for storage of slurry or hydrocarbons. Computational Fluid Dynamics (CFD) has been applied successfully to single-phase mechanical mixing problems for several decades and is established as a reliable design tool. As computational power and CFD codes have improved over the years, there have been significant advances in modelling capabilities including improved models of turbulence, interaction of rotating and stationary components, multiphase flows, and modelling of free surface interfaces, for example. This paper will provide an overview of the application of CFD to mechanical mixing problems. First, it will review the traditional single phase Multiple Reference Frame (MRF) approach and introduce a range of advanced modelling techniques. Three examples of the application of CFD to industrial mixing problems will be given. It will be demonstrated that CFD is an effective tool for reducing technical risk in design, for identifying the root-cause of mixing problems, and testing modifications to existing operations."

Jan 1, 2015

By P. C. M. Knops, K. Rijnsburger, R. M. Santos

To overcome the challenges of mineral CO2 sequestration, this work utilizes a unique proprietary Gravity Pressure Vessel (GPV) reactor technology, and focuses on reaction products of high economic value. The GPV provides intense process conditions through hydrostatic pressurization and heat exchange integration that harvests exothermic reaction energy. Here, laboratory-scale tests of the envisioned process was performed in tubular and continuously stirred tank reactor (CSTR) autoclave reactors. The mineral used was Olivine (~Mg1.6Fe2+0.4(SiO4) + ppm Ni/Cr), although asbestos, steel slags and oil shale residues are also under investigation. The effect of several process parameters on reaction extent and product properties was tested: CO2 pressure, temperature, residence time, additives (buffers, lixiviants, chelators, oxidizers), solids loading, and mixing rate. The products (carbonates, amorphous silica and Chromite) were physically separated (based on size, density and magnetic properties), characterized (for chemistry, mineralogy and morphology) and tested in intended applications (e.g. as pozzolanic carbon-negative building material). Economically, it is found that product value is the main driver for mineral carbonation, rather than, or in addition to, the sequestered CO2. The approach of using a GPV and focusing on valuable reaction products could thus make CO2 mineralization a feasible and sustainable hydrometallurgical process.

Jan 1, 2015

By T. Plikas, T. Porretta, M. Al-Dojayli, B. Pretorius, J. Woloshyn, H. Ghorbani

"Water-cooled ducts represent an integral part of high temperature off-gas systems in metallurgical processes. Typically, off-gas enters these ducts at significantly elevated temperatures; therefore, water cooling may be required to maintain the duct skin temperature within allowable design limits. These off-gases are typically of high mineral content that could lead to dust buildup, and there is a possibility of slag buildup / molten metal splashing. Therefore, dust cleaning provisions may be necessary in order to remove or minimize accretion on the duct wall, which could otherwise impact the water cooling and the system process efficiency. These ducts may have complex geometry and experience a wide range of loading, including gravity loads, water and gas pressures, cyclic thermal loading and dynamic impact forces. Consequently, the thermo-mechanical assessment of such water-cooled ducts is critical and requires consideration phenomena such as high temperature gradients, potential nucleate boiling, thermal ratcheting and fatigue failures. Such assessment is not comprehensively covered by design-by-rule design codes and guidelines due to its complexity. This paper presents a successful implementation example of design-by-analysis methodology to improve the design and extend the life of a water-cooled furnace transition duct using Computational Fluid Dynamics (CFD) and Finite Element Analysis (FEA).INTRODUCTION Water-cooling represents an important part of high temperature off-gas systems in metallurgical processes. Typical temperatures of the off-gas in the furnace uptake are in excess of 1400°C, and thus there is a need to maintain the water-cooled duct and jacket skin temperatures within their material allowable design limits. Water-cooled channels have been used effectively in arc furnace roof design (Sosonkin et al., 1972; Smolyarenko and Khainson, 1988) and other furnaces as well as in furnace fuming jackets (Scholey et al., 1994). The design of these systems was based on one-dimensional analysis to ensure sufficient cooling is available under extreme furnace conditions (Smolyarenko and Khainson, 1988; Scholey et al., 1994). With advancement in furnace and fuming system designs, water-cooled duct designs have become more complicated in geometry. Numerical techniques, such as three-dimensional fluid flow and heat transfer modeling, are therefore needed to more accurately calculate water velocity, temperature and convective heat transfer coefficients in the water-cooled channels (Haywood et al., 2002; Henning et al., 2010). This is of particular importance around geometric corners where stagnant water flow may lead to local nucleate boiling at the critical heat flux, causing hot spots (Bergman et al., 2011). High wall skin temperatures increase the risk of failures due to thermal stresses as well as increasing corrosion rates (Gelfi et al., 2012), leading to costly equipment downtime and potential safety risks."

Jan 1, 2017

By P. R. Brito-Parada, A. Norori-McCormac

Positron emission particle tracking (PEPT) has become an important tool for flotation research, as it is able to resolve directly the behaviour of particles in laboratory scale flotation vessels. The first applications of PEPT to flotation showed only the motion of an individual particle in the pulp and the froth, but nonetheless allowed interpretations of behaviour not previously possible. Since then, PEPT measurement and data analysis techniques have improved significantly and now ensure a high level of confidence in the particle behaviour obtained. In particular, statistical analysis of long-duration experiments allows time-averaged data to be collated, ensuring spatial accuracy and allowing rigorous comparison of different conditions. It will be shown that these PEPT techniques can be used to compare directly the effect of operating conditions and particle properties in a laboratory flotation system. Particle tracks will be illustrated, as well as analyses of particle speeds, average flow streamlines and occupancy that show marked differences in behaviour near the interface and impeller.

Jan 1, 2015

By Alan Galley, Tom Hynes, Michel Plouffe

"Mining in Canada’s economy• Employs 320,000+ workers; Wages 30-60% above other sectors• Operates 220 producing mines, 33 smelters and refineries• Paid $8.4B in taxes and royalties to governments in 2010• Invests about $30B in capital projects annually • Largest private employer of Aboriginal Canadians 2• Core supplier to clean-technology sectors• Attracted 18% of world exploration spending in 2010• Efficient TSX processes - 1400 mining companies listed, ~50% of mineral projects are outside Canada• Estimated 1000 Canadian companies in 100 countries• Minerals account for 21% by value of Canada’s goods exports• Top 5 World Producer in uranium, potash, nickel, platinum, aluminum, diamonds, zinc, met coal"

Jan 1, 2012

By L. C. So, S. Faucher, S. Mostaghel, A. Triwahyuono, D. Sauter, S. -Y. Oh, S. K. Lee, K. Aswin

"Molten hauling and water granulation are the commonly used slag treatment methods in the production of nickel. Water is present in these processes either to accelerate cooling of the dumped slag or in the granulation itself which creates an inherent safety risk of explosions. Even good design and operation are not sufficient to prevent explosions or injuries from occurring. Several dry methods to treat slags have been intensely studied. However, most of these technologies have never been commercialized due to numerous challenges including scalability, cost, low heat recovery efficiencies, and difficulties in heat utilization. Ecomaister-Hatch has recently developed and commercialized a reliable and simple Dry Atomization process, which eliminates water and allows for heat recovery. As part of the development towards other sectors, laboratory-scale and pilot-scale trials have been completed in a number of base metals and PGM facilities. Recently, Dry Atomization of a nickel laterite slag was successfully demonstrated at the laboratory-scale. The current paper introduces the technology and reports the test results obtained from atomization of the nickel slag.INTRODUCTION The processing of nickel laterites produces vast amounts of slag with over 90% of the feed to the furnace reporting as slag. Slag handing is therefore of critical importance to a laterite smelter. Traditionally there are two ways in which the slag is handled (1) Molten hauling, dumping, cooling and quarrying (2) Water granulation, dewatering, stockpiling. There are inherent disadvantages of both methods that will be outlined in this paper. An alternate route of Dry Atomization provides distinct advantages over the two conventional routes that are of particular interest to the nickel producer such as elimination of molten hauling, dumping and quarrying, elimination of water and improved safety. There is also the potential to convert the slag, which is typically regarded as a waste product, into a value added product and the continuous nature of slag tapping makes it amenable to heat recovery. Hatch has recently conducted laboratory-scale test work on laterite slag to demonstrate its viability for Dry Atomization. Results of this work are presented."

Jan 1, 2017

By Takashi Nakamura, Atsushi Iizuka, Yong Fan, Etsuro Shibata

The level of iron in typical copper slag reaches nearly 40% by mass, in the form of iron silicate. We designed a method to oxidize the nonmagnetic iron silicate to magnetite, permitting the selective recovery of the slag’s iron content by magnetic separation. This would effectively decrease the volume of dumped slag; the reclaimed iron could be used for iron and steel making. The crystallization behaviors of magnetite and hematite were studied as reaction products of the molten oxidation of copper slag. A gas atmosphere of 1% by volume of oxygen was found to effectively precipitate the slag’s iron content as magnetite.

Jan 1, 2015

By M. Kosugi, Y. Kon, M. Kawata, J. V. Satur, K. Mitsuhashi, C. Tokoro, K. Horiuchi, R. Kawarabuki, B. Calabia

"Liberation of copper minerals is important in ensuring high flotation efficiency in copper sulfide flotation. The high pressure grinding roll (HPGR), microwave (MW), and electric disintegration (ED) are known to feature enhanced liberation over conventional comminution machines such as jaw crushers and ball mills by producing internal stresses on minerals or mineral grain boundaries through high compressive forces, thermal expansion of minerals, and pulsed high voltage discharges, respectively. In this study, each of these methods was applied before ball mill grinding to investigate its effect on enhancing the liberation of copper minerals in a low grade and fine-grained copper ore. The copper minerals observed in the tested ore sample are bornite, chalcocite, and chalcopyrite, and their grain sizes range from 10 to over 100 µm. Calcite, quartz, and feldsparare confirmed as gangue minerals. The liberation of the copper minerals by the different methods was analyzed using the mineral liberation analyzer (MLA) and compared. The result showed that the HPGR crushing was the most effective for enhancing copper mineral liberation. HPGR bench-scale test was then conducted on the copper ore and flotation was applied on a HPGR-treated sample to confirm the improvement in the flotation performance by applying HPGR.INTRODUCTIONIn order to recover copper minerals by flotation, copper ore is usually ground by ball milling to liberate the copper minerals from gangue minerals. In the case that the fine size copper minerals are targeted, grinding of the copper ore to a finer size is necessary to increase the copper recovery. However, finer size grinding by ball mill increases energy consumption significantly, which might deteriorate the economies of the mineral processing operation. HPGR, MW, and ED have been recently the focus of researchers as new techniques for enhancing the mineral liberation in mineral processing (Tavares, 2004; Kingman, 1998; Wang, 2010).HPGR crushing is considered to generate micro cracks along mineral boundary when rocks pass between two rolls by applying high compressive force. In the MW treatment, micro cracks are reported to be generated at crystal boundaries by differential thermal expansion of crystals attached to each other. In the ED treatment, micro cracks are known to be produced by plasma current flowing along mineral grain boundaries. These treatments are expected to increase mineral liberation (Fujita, 2001),improve flotation performance(Michaelis, 2005), and reduce ball mill work index(Kaya, 2010)."

Jan 1, 2017

By Z. Ren, M. Tomlinson, E. Asselin

"Organic carbon blinding is a common, yet often partial, solution to the reduction of preg-robbing. A quantitative method to assess the extent of adsorption of a given blinding agent is presented herein. The adsorption of several blinding reagents on various carbon samples is quantified using electrochemical impedance spectroscopy (EIS). EIS results showed that kerosene is more strongly adsorbed on carbon than sodium lauryl sulphate (SLS), while SLS can hinder the charge transfer process of the oxygen reduction reaction on the carbon surface more effectively. The effectiveness of SLS is pronounced when its concentration is higher than 100 ppm. Raman spectra are presented for selected carbon samples: as the area ratio of the disordered peak to the graphitic peak increases, blinding agent adsorption increases.INTRODUCTION The presence of naturally occurring constituents in gold ores may adversely affect the extraction of gold in cyanide leaching since the gold cyanide complex, Au(CN)2–, can be adsorbed by these constituents (M. Adams & Fleming, 1989; Afenya, 1991; Miller, Wan, & Díaz, 2005). Such ores are known as “preg-robbing”. Preg-robbing behavior may arise from natural carbonaceous materials in the ore (M. Adams & Burger, 1998). In the past decades, a number of pre-treating methods have been developed for refractory carbonaceous ores (Arriagada & Osseo-Asare, 1984; Beer, 1994; Dunne et al., 2007; Jiang, Liu, Xiao, & Yang, 2012; Kohr, 1997; Kulpa & Brierley, 1993; Menne, 1992; Menne & Revy, 1994; Moyes & Houllis, 2010; Petrie, Craw, & Ryan, 2005; Simmons, 1996). The method known as blinding is one of the most effective and economical pre-treatment methods (M. D. Adams & Burger, 1998; Albert, 1923; Darrow, 1924; McQuiston & Shoemaker, 1975; Van den Berg, 2000). Blinding, also referred to as blanking or passivation, uses a chemical reagent to passivate the preg-robbing carbon by selective absorption or wetting (Bas, Altinkaya, Yazici, & Deveci, 2012; Brierley & Kulpa Jr, 1993; Dunne et al., 2012; Van den Berg, 2000; Yang, Qian, Song, & Dong, 2013; Yen, Amankwah, & Choi, 2008; Zhou, Jiang, & Choi, 2014). Organic reagents, which selectively adsorb on the surfaces of activated carbon and “smother” the surface, have been used for blinding carbonaceous matter in gold ores prior to cyanidation. Two comprehensive studies by Abotsi and Osseo-Asare and Adams and Burger have been published on this topic (Abotsi & Osseo-Asare, 1986; M. D. Adams & Burger, 1998)."

Jan 1, 2017

By Saikat Chatterjee, Xintong (Brett) Liu, Kinnor Chattopadhyay

Magnesia carbon bricks are commonly used in BOFs and are generally pre-heated before the BOF goes into service. Owing to very stringent emission regulations, the BOF pre-heating process need to be controlled and optimized so that, the emission standards are met. One of the major concerns in organic emissions are its stringent limits on emission rates and total volatile emissions. In the present work, an attempt has been made to integrate CFD and Thermodynamic models to predict the emission rate of volatile organics during the pre-heating process. A one dimensional heat transfer model was developed using visual basic and then integrated with thermodynamics calculations using FactSage 6.4. The parameters that affected organic emissions were the pre heating procedure, gas composition of the burner, heating rate and type of the burner. Typical composition of MgO-C bricks and binder materials were obtained from literature and vendor data sheets. Chemical reactions between organic materials, refractory and burner gasses were considered. The model predictions indicated that certain burner conditions could destroy all organics before it exits the vessel while other conditions needed the use of an after burner at the mouth of the vessel. The model was also able to predict the organic emission rates based on the chosen pre-heating profile. This kind of predictive model will be very useful for the steel industry and enable them to justify permit limit applications and stick to the limits by fine tuning their pre-heating process.

Jan 1, 2015

By R. B. Nourse, S. F. Gwynn-Jones, S. Nikolic, M. L. Bakker, I. McDougall, H. Joubert

"Tenova Pyromet’s core furnace knowhow and expertise has been built within the ferroalloy and nickel/platinum group metal (PGM) industries with the supply of electric furnaces for a number of nickel/PGM operators, including Eastplats, Lonmin, and Anglo-Platinum in South Africa, Mineraçào Serra Da Fortaleza in Brazil, and Norilsk Nickel in Russia. Tenova Pyromet has also supplied the electrode columns and associated electrode equipment – the heart of the electric furnace technology – for cobalt recovery in furnaces in Zambia and the Democratic Republic of the Congo. The quantity and size of projects undertaken by Tenova Pyromet has provided the opportunity to continuously improve furnace designs and the scope of supply, culminating in the most recent nickel/PGM project currently under construction at Northam Platinum. Through this innovative culture, the Tenova Pyromet Base Metals Initiative was formed in 2015 to develop the Novasmelt™ Furnace; a next generation optimised Top Submerged Lance (TSL) furnace design. The combination of Tenova Pyromet’s advanced Novasmelt™ product with our industry leading electric furnace technology are discussed with reference to applications for nickel and cobalt production. Flowsheet arrangements are compared summarising potential capital savings, operating requirements and achievement of downstream product quality.INTRODUCTION Tenova Pyromet is a leading player in the field of smelting technology development and equipment supply. Tenova Pyromet is the result of the union of three furnace suppliers under the Tenova banner: Techint Technologies (Tagliaferri), Core Furnace Systems Corp (Lectromelt) and Pyromet Technologies. The furnace experience of the combined groups dates back over a century with the earliest Lectromelt going into production in the early 1900s. Throughout the modern era, Tenova Pyromet has developed a reputation for providing dependable innovative smelting technology, high quality equipment and sound project execution to a worldwide client base with customer plants operating in Europe, Southern Africa, North America, South America, Russia, Kazakhstan, the Middle East, South Korea, and India. Tenova Pyromet’s core knowledge and expertise was developed in the South African ferroalloy, base metals, and platinum group metals (PGM) smelting industries. Tenova Pyromet has spent considerable effort on development and has contributed significantly to improve the state of the smelting industry. Tenova Pyromet’s electrode columns have become widely renowned and are now providing significant benefits, especially in increased furnace availability, to many smelting furnace operators. The electrode column is the heart of the furnace as it delivers a controlled amount of electrical energy, at an optimum depth in the burden/bath, to the smelting process. Every furnace is custom designed to the specific operating range and optimal operating point of that furnace and process"

Jan 1, 2017

By K. Horikawa, S. Kitahata, H. Kobayashi

"It has been clarified that the Al-5%Mg alloys containing 200 mass ppm of sodium showed grain boundary (GB) fracture, even when tested at room temperature, as well as at high temperatures (~500°C). SEM/EDX study revealed that the GB fracture was associated with the segregation of sodium on grain boundaries of the Al-Mg base alloys. Differential scanning calorimetry (DSC) revealed that the GB fracture at room temperature of Al-Mg alloys was caused by sodium segregation in the solid state. It was also shown that the tendency of the GB fracture strongly depended on the heat treatment; the alloys after the solution heat treatment showed severe GB fracture compared with the alloys after the homogenizing treatment. Moreover, it was shown that the GB fracture at room temperature by sodium segregation was suppressed by the addition of bismuth or indium. The suppression of the GB fracture by the additional elements was believed to be the scavenging effects by forming the sodium bearing compounds in grains.INTRODUCTIONIt is widely known that Al-Mg base alloys containing high amount of magnesium(~5 mass%)show better workability at room temperature, while that the alloys show grain boundary (GB) embrittlement at higher temperatures ranging from 200 to 500°C, depending on grain size(Otsuka, 1984), sodium impurity level(Ransley, 1959, Okada, 1997, Horikawa, 2001)and testing strain rate(Yamada, 2012). In the case of coarse-grained Al-5%Mg alloys (~300 ?m), 2 mass ppm of sodium causes severe GB fracture around 300°C, however, the Al-5%Mg-2ppm alloy does not show GB fracture at room temperature. It has also been shown that the GB embrittlement caused by 2ppm of sodium was suppressed by the additional elements, such as bismuth (Talbot, 1995), antimony (Ueda, 1997) and indium (Horikawa, 2012). Basedon these facts, we have concluded that the GB embrittlement at higher temperatures of Al-Mg alloys is attributed to the synergy effects of GB segregation of atomic sodium and GB sliding. For the GB embrittlement mechanism of Al-Mg alloys, involvement of low melting point metallic phases has been pointed out (Lynch, 2002),since the GB embrittlement appeared only at high temperatures. Up to date, the effects of high amount of sodium addition more than 2 ppm on GB fracture were not fully investigated in Al-Mg alloys. In the present study, the effect of 100 ppm ordered sodium impurity on GB fracture of Al-5%Mg alloys was examined, together with the effect of another additional elements."

Jan 1, 2017

By J. Zhou1

"The extractive metallurgy of gold ores is largely driven by their grade and mineralogy. The concentration of gold in the crust is extremely low and highly variable, resulting ore variability in many gold and copper-gold deposits. More importantly, gold in an ore may occur in two or three forms (i.e. microscopic gold, submicroscopic gold and surface gold), making gold ore processing extremely challenging. Geometallurgy is a technique to document variability within an orebody and quantify and evaluate the impact of many factors including geology and mineralogy on grinding, flotation, leaching and metal recovery processes. The objective of gold geometallurgy is to reduce and minimize the technical risk in project evaluation, plant design, mine planning and production forecasting through geometallurgical modelling, representative sampling and subsequent systematic mineralogical and metallurgical testwork. Gold deportment study is a powerful tool in characterization of various gold ores. Effective and quantitative gold deportment results are critical and useful for predicting gold recovery and building geometallurgical models of gold ores. This paper provides an overview of geometallurgy fundamentals and applications in gold processing, with a focus being on the ore characterization and gold deportment study.INTRODUCTION Geometallurgy is an inter-disciplinary approach which links the geological, geochemical and mineralogical characteristics to the metallurgical performance of an orebody. Combined with mine planning, it has been used in scoping, prefeasibility and feasibility studies, process design and optimization of gold, copper-gold, copper-moly, nickel and iron projects among others (Williams & Richardson, 2004; Dobby, Bennett, Bulled, & Kosick, 2004; Bulled, 2007; Bulled, Leriche, Blake, Thompson, & Wilkie, 2009; Kormos, Sliwinski, Oliveira, & Hill, 2013; Muinonen, Sciortino, Korczak, & St-Jean, 2013; Leichliter & Larson, 2013; Leichliter, Jahoda, & Montoya, 2013; Hatton & Hatfield, 2013; Baumgartner et al., 2011, 2013; Hoal, Woodhead, & Smith, 2013; Zhou, 2013). The goal of a gold or copper-gold geometallurgical program is to characterize and understand the metallurgical variability of an orebody, such as comminution, gravity, flotation and cyanidation parameters and metal recoveries, and to build a geomet model which can be used to assist in mine planning and to predict the plant performance. In any geometallurgical program, representative sampling is the key to ensure the results of a geometallurgical study will reflect future performance once the plant is commissioned. Geometallurgy compliments, but does not replace, the traditional mineralogical and metallurgical approach during the development and operation of a gold or copper-gold project. Geometallurgy is a methodology for testwork design and a framework for mine planning. The first part of this paper provides an overview of geometallurgy fundamentals and application in gold ore processing."

Jan 1, 2017

By A. S. H. Kabir, I-H. Jung, J. Su, Yue. S., M. Sanjari

One of the major problems associated with conventional wrought magnesium alloys is the unwanted basal texture that forms during plastic deformation which generally does not change markedly after post-deformation annealing. Formation of precipitates on the recrystallized grain boundaries during annealing may affect the usual rotation of grains towards preferred basal direction resulting in texture weakening. In this study, Mg-Al-Sn alloy was hot compressed at 250°C and annealed at 350°C for various times. The initial as-deformed microstructure was partially dynamic recrystallized with dynamic precipitates on the grain boundaries. After annealing at 350°C, static recrystallization of the bimodal microstructure took place where at this temperature no static precipitates formed. The goal of this work was to study the effect of dynamic precipitation on the texture evolution during the annealing process. Texture evolution was studied during annealing by electron backscattered diffraction (EBSD) technique through a microstructure tracking process. It was found that precipitates on the recrystallized grain boundaries have significant effect on the usual rotation of the grains towards the basal direction, meaning significant texture weakening, which is beneficial for final mechanical properties.

Jan 1, 2015

By G. Granata, C. Tokoro, M. Matsuoka, K. Horiuchi

"Given the high demand of copper and the lack of new high-grade deposits, low grade copper ores containing copper oxides and refractory sulfides need to be processed as well. However, in order to recover copper from refractory copper ores, the leaching performances should be improved. In this study, we investigated the effect of the mechanical activation in the leaching of copper from covellite. The influence of a mechanical treatment by planetary ball milling on leaching rate in sulfuric leaching media was evaluated by using X-ray diffraction (XRD), mineral liberation analysis (MLA) and X-ray absorption fine structure (XAFS). Results showed a significant increase in copper leaching from around 50%up to 100% along with an improvement of the leaching kinetics when using planetary ball milling. XRD spectra showed the disappearance of the covellite peak from (101) face, thus suggesting the amorphization of covellite associated with the use of planetary ball milling. XAFS results showed that the coordination number of Cu changed from 6 to 3, thereby confirming the effectiveness of the mechanochemical effect.INTRODUCTIONDuring the last decades, while the copper grade in copper ores has been decreasing, the concentration of impurities such as arsenic tends to increase, thus requiring for the processing of low grade copper ores. For a suitable processing of copper minerals, hydrometallurgical processes are preferable due to the lower costs, the lower environmental impact and the easier implementation (Watling, 2006). However, for an economical recovery of copper, the leaching performances must be improved.Among the recent advancements in leaching technologies, the mechanochemical activation allows for an improvement of the leaching performances by means of high-intensity grinding(Mohammadabad et al., 2016). In the first place, the improvement is the result of the dramatic decrease of particle size, which results in an increase of the mineral surface area and the consequent enhancement of leaching kinetics. Furthermore, the intense mechanical stress due to the high-intensity grinding could induce the rupture of the crystal structure producing a decrease of crystallinity. Such changes of the mineralogical structure, also known as mechanochemical effect, can lead to more leachable mineral, thereby resulting in a greater dissolution of copper. Last but not least, whereas the mineral surface might undergo passivation during leaching, the high-intensity grinding can continuously refresh the surface of the mineral, thus exposing portions of unleached bulk mineral."

Jan 1, 2017

By G. Minhas, M. Pule, Y. Laffitte, M. c. McGurn, T. Tzanetakis, Peacey. J., R. Susilo

Titanium (Ti) metal production from titanium tetrachloride (TiCl4) using magnesium (Mg) as a reducing agent is the well-known Kroll process. A chloride route is used to avoid oxidation of the titanium sponge. The sponge is consolidated into ingots and can then be made into powder by melting and atomizing or by hydriding/dehydriding. Attempts at direct powder production have met with difficulties, including low Ti yield and the formation of very fine particles (particles between 25-100 µm are desired). This paper discusses two methods to produce Ti powder in a molten salt medium using magnesium powder as a starting material instead of a pool of molten magnesium. The first method is a direct reduction of gaseous TiCl4 injected in the melt with the magnesium powder in suspension in the molten salt. The second method is a two stage TiCl4 reduction reaction where recycled Ti was used to form titanium dichloride (TiCl2) in the first stage followed by addition of magnesium powder into molten salt in the second stage. A correlation between Ti yield and processing variables such as TiCl4 to Mg ratio, Mg particle size, TiCl2 concentration in the melt, and reaction temperature was studied. The Ti powder formed was also analyzed for particle size distribution. Despite challenges and difficulties encountered, this paper shows some promising results which could provide guidance to others working on direct Ti powder production.

Jan 1, 2015