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By R. J. McLeod

"Grinding at Giant Yellowknife is done in two stages. The first stage consists of two ball mills in closed circuit will: mechanical classifiers, the classifier overflow goes to flotation. The tailings from this flotation circuit are separated into slime and sand portions, the slimes go to an additional flotation circuit while the sand portion goes to the secondary grinding mills.Milltronic automatic sound control units were installed on each of the two primary ball mills and put into operation September 3, 1966. After about two months adjustments to the control units the operators were taken off the grinding circuit on November 1, 1966. The operators duties were taken over by the automatic control units while miscellaneous work was taken over by the helpers in the mill. The labour saving by the installation is approximately $2250.00 per month.After a short period of operation it was apparent there was a slight change in grind. The screen analysis of the primary classifier overflows for the period May to August 1966 averaged 62.23% minus 200 mesh while for the period September to December 1966 averaged 62.0% minus 200 mesh. This is a slight coarsening of the grind. The change in the primary grind has manifested itself also in the screen analysis of the final grind. Before automation the final grind was 80% minus 200 mesh, while after automation it was 7 5% minus 200 mesh. A change of grind was also noted in the flotation concentrates. Before automation the screen analysis of the concentrates was 35% plus 200 mesh and 50% minus 3 25 mesh. A ft er automation it was 35% plus 200 mesh and 47 .5% minus 325 mesh. In other words the grind got coarser or perhaps we should say there was less overgrinding. Another significant change took place in the assays of the slime and sand portion of the primary flotation tailings. It was usual under manual control for the slime portion to assay higher in gold than the sand portion. The reverse is now true."

Jan 1, 1967

By M. A. Keogh

This paper reviews the physical properties that make low-density polyethylene the most practical and economical material for launder• fabrication in the majority of mine and mill applications. The basic design features and use of other launcher• materials are also discussed.

Jan 1, 1976

By D. Bernard

Over the last decades, the wrought aluminum casting industry has made significant progress with regards to process consistency by the introduction of new technologies in the field of liquid metal processing and casting. These technologies, combined with the application of best practices, have led to increases in productivity as well as better process performances and product quality. The competition in the addedvalue aluminum products (by opposition to P1020 production) is, however, very strong and involves players that did not hold a major role five years ago but who are now exerting a strong competitive pressure on our industry even sometimes from far abroad. There are still technical and technological challenges remaining in the different areas of aluminum casting production, amongst which metal pre-treatment, furnace operations, in-line treatment and casting hold a predominant influence. The comprehension of the contribution of each individual process step to the entire process chain is a key element and must be considered in future process optimisations. This paper presents the technological position of the casting industry and tries to highlight areas where further progress can be made.

Jan 1, 2006

By K. Kudo

Magnesium rods of 99.95% purity and approximately 6 mm in diameter were continuously cast at rates of between 15 and 25 mm/min by a heated mould process and their mechanical properties evaluated. It was found that rods cast at 15 and 20 mm/min consisted of a single crystal, while rods cast at a speed of 25 mm/min were multi-crystalline and showed a unidirectional structure. Although room temperature tensile ductility to fracture varied widely, it was found that with an appropriate crystal orientation, cast rods can exhibit elongation by as much as 215%.

Jan 1, 2006

By S. J. Cook

The system of mining statistics for Canada, as it exists today, represents the result of long years of progress, first by the Geological Survey, later and more comprehensively by the Mines Branch of the Department of Mines, and now by the Mining Branch of the Dominion Bureau of Statistics-all supplemented by the very comprehensive reports published by the several provincial departments of mines. It is the purpose of this paper briefly to state the development and present status of Canada's statistical service, more particularly in regard to information on mineral production, and to show that in its evolution continuous progress has been made in the elimination of factors tending to duplication and overlaping, with the result that the construction of an adequate statistical service has been carried out with the least possible expenditure of .public funds. For the purpose of this discussion, the subject of mineral statistics may conveniently be considered from two points of view. The technical difficulties in obtaining satisfactory and complete data from the variety of industries represented in the mining fields of Canada must be apparent to all. Methods of record-keeping are almost as numerous as mines and even the larger concerns which maintain elaborate records for their own information, often find it difficult to compile the statistical reports required of them, because the specific form of inquiry differs from the method in use in their offices.

Jan 1, 1924

By Yin Guangzhi, Song Zhenlong, Li Minghui, Li Wenpu, Deng Bozhi

"Darcy's law is widely used to describe the oil and gas flow characteristics in the multi-pore media reservoir. However, the low-velocity non-Darcy flow of oil and gas occurs in the multi-pore media reservoir under low permeability conditions. Meanwhile, the high-velocity non-Darcy flow of oil and gas occurs in the multi-pore media near the wellbore. The gas flow velocities in coal in different deformation stage under different gas pressure gradient were tested and the relationships between gas flow velocity and gas pressure gradient were discussed, which can help us to investigate the transformation conditions of gas linear flow and gas nonlinear flow in coal. The results showed that the gas flow in the coal under low effective stress environment can be described by Darcy's law. The low-velocity non-Darcy flow of gas gradually occurred and the start-up pressure gradient increased in the coal as the effective stress increased. The low-velocity non-Darcy flow of gas also occurred in the coal at the yield deformation stage, however, the start-up pressure gradient decreased as the effective stress increased in this stage. In post-peak stage, the highvelocity non-Darcy flow of gas occurred in the coal under low effective stress environment. The gas flow in the coal gradually returned to be Darcy flow as the effective stress increased. The mechanism of the phenomenon is discussed based on the experimental results. The research results can be used to guide well test analysis and prediction of oil-gas production. INTRODUCTIONThe oil and gas flow in original multi-pore media reservoir are usually regarded as steady and linear processes and can be described by Darcy’s law. However, the low-velocity non-Darcy flow of oil and gas occurs in the multi-pore media reservoir under low permeability conditions. Meanwhile, the highvelocity non-Darcy flow of oil and gas occurs in the multi-pore media near the wellbore or workface. The gas flow in the multi-pore media even may be unsteady under some conditions such as gas emission and outburst.The phenomenon of underground water low-velocity flow in clays was deviated from Darcy’s law was found in the end of the nineteenth century (King, 1898). The deviation from Darcy’s law was later reported and investigated more (Swartzendruber, 1962; Miller and Low, 1963). These researches revealed that the start-up pressure gradient exists under low permeability conditions. Klinkenberg (1941) proposed that the permeability constant as determined with gases is dependent upon the property of the gas, and is a linear function of the reciprocal mean pressure. This effect can be explained by taking into account the phenomena of slip, which are related closely to the mean free paths of the gas molecules."

Jan 1, 2015

By M. Potesser

Higher prices for natural gas or oil have motivated the copper industry to reexamine the modes of oxygen and oxy-fuel burner usage at operating plants. With rising energy costs and the growing importance of environmental protection, burner usage and burner operations have become the focus of several investigations and optimization efforts. One possible approach to lower energy usage is through combustion using tonnage oxygen. When such oxygen is used, the flame temperature increases and operational efficiency is improved. As well, with the correct technology, due to the presence of lower levels of harmful substances such as NOx in the off gas, there is improved environmental performance. As regards copper production, furnaces are employed for both concentrate smelting or for melting and casting operations. The use of tonnage oxygen in concentrate burners for smelting provides for a higher thermal efficiency. For furnaces employed for melting, air-operated burners may in fact have an initial advantage because a long radiant flame is typically generated, thus providing for a higher degree of heat transmission. This paper describes the new experimental burner chamber of Messer Austria GmbH which provides for testing of the combustion of natural gas with oxygen or oxygen-enriched air and the use of special water cooling ducts that simulates a metal charge during melting, The operational effectiveness of the burner is determined from temperature and off-gas analysis data. The paper also discusses future trends in burner technologies including a new patented burner. Cu2007 - Volume III (Book 2) The Carlos Diaz Symposium ou Pyrometallurgy Edited by A.E.M. Warner, C.J. Newman, A. Vahed, D.B. George, P.J. Mackey, A. Warczok Toronto, Canada,

Jan 1, 2007

By Michel Guillot

Gaz metal arc welding is commonly used for producing large frames and assemblies. Even for light aluminum and thin wall assemblies, the GMAW technique is increasingly preferred over the GTAW technique. This is particularly true where the welding gun motion is achieved accurately with automated or robotic systems and when using pulsed or regulated metal deposition. In this study, butt joints in floor welding position are tested at speed ranging from 1.5 to 16 m/min. Attempts are made of find parameters providing good and repeatable joint quality with minimal distortion and good appearance even at high travelling speeds. Taguchi experimental plans are proposed with different parameters tested with sheet metal samples. The parameters include typical GMAW machine settings, joint preparation geometries, wire gages, gun angles, wire feeds, and more. The robot motion speed and the proximity of the part are also considered. Direct monitoring of machine welding current and voltage is achieved. Once is found the best set of parameter settings, additional tests are carried out to verify the repeatability of weld quality. Secondly, these conditions are applied for joining and testing a floor panel made of several extrusions. Weld quality is established with Vickers micro-hardness measurements, cross section geometries of the weld pool including penetration, tensile tests and metallographic observations to establish the amount of porosity and weld microstructure in the HAZ.

Jan 1, 2011

By Xuanxue Mo, Zengqian Hou

"Yidun Island Arc in Sanjiang Region is one of the important Kuroko-type volcanogenic massive sulfide deposits (VMS) districts in southwestern China. Tectonically, the region is situated in the eastern portion of the Tethys orogenic belt, and is a late Triassic extensional island-arc. The island-arc underwent earlier arc construction, intra-arc rifting, later arc construction and backarc spreading during its evolution and formed a complete trench-are-basin system, i.e., the Ganzilitang suture zone, forearc basin, outer are, intra-arc rifting zone, inner arc and back-arc basin from east to west across the island-arc.Kuroko-type VMS deposits and occurrences discovered so far are limited to within the intra-arc rifting zone of the Yidun Island Arc and tend to occur in groups or clusters distributed in separate faultbound basins; e.g., Zengke, Gacun and Xiangcheng basins, in which submarine volcanic rocks, especially bimodal volcanic suites, were extensively developed. The VMS deposits formed in the waning stages of volcanic eruption in the late Triassic and are hosted in the uppermost section of acidic volcanic rocks (rhyolitic-dacitic) within a bimodal suite. The orebodies are associated with these host rocks: rhyolitic-dacitic pyroclastic rocks and exhalites and chemical sedimentary rocks.All VMS deposits in Sanjiang are of the Zn-Pb-Cu type. The architecture of the deposits is twofold, consisting of concordant lenses and layers of massive sulfides and an underlying discordant stockwork. All deposits show metal zoning. The hydrothermal alteration related to mineralization is strong and asymmetrical, and is found dominantly within the stockwork zone and host rocks surrounding the ores. There are two alteration patterns: (1) chloritization - sericitization - silicification from outer sides to core of the alteration pipe; and (2) silicification + sericitization - silicification + carbonate from the lower to upper part of the alteration pipe.The mineralization temperatures of ore-forming fluids vary in the range 200°C to 335°C. Thermal evolution of the fluids displays temperature profiles that first increase and then decrease with progression of mineralization processes. The majority of black-ore minerals (Groups I and informed during intensifying stages of hydrothermal activity, and the majority of semi-yellow-ore minerals (Group III) formed during a thermal maximum. There followed the formation of fine-grained black-ore minerals (Group IV), which interacted with barite layers during decreasing temperature phases.Oxygen and hydrogen isotope studies show that the sources of ore-forming fluids for the Kurokotype VMS deposits are two-fold: seawater and magmatic hydrothermal solutions, represented by the Kuroko deposits in Japan and Kuroko-type VMS deposits in Sanjiang, respectively. In the latter case the hydrothermal solutions reacted with host rocks and mixed with cold seawater percolating downward, and circulated through volcanic rocks resulting in development of alteration zones and formation of ore minerals in Kuroko-type VMS deposits."

Jan 1, 1993

By P. K. Gummer

Gold was fir t di covered on the Seabee property in 1947 by the Con olidated Mining and Smelting Company Limited. Acquired by Claude Resource Inc. in 1984, the property is now being explored by Placer Development Ltd . in joint venture with Claude Re ources. Between Augu t, 1985 and March, 1986, Placer completed 54 drill holes, extending the main o. 2 and o. 5 vein y tern to a depth of 1000 feet below surface and di covering two new satellitic gold zone 800 feet west of the o. 5 gold zone. Drill proven and probable geological re erve in four zone ( os. 2, 5, II, 14) to a vertical depth of 1000 feet, are approximately 1,120.000 tons averaging 0.32 oz. Au/ton.

Jan 1, 1986

By D. Bouchard, M. Forté, A. Charette

A transparent replica of a casting die was built to achieve a better understanding of the filling mechanisms of aluminum in high pressure die casting. Water and tomato paste were respectively used as analogues for the Newtonian liquid aluminum and the non-Newtonian semi-solid aluminum. The transparent die was installed on an industrial casting press and filling was filmed with a high-speed camera. Differences between the Newtonian and non-Newtonian fluids are presented and discussed.

Jan 1, 2006

By T. H. Adair

"IntroductionCONTINUOUS casting of ferrous and non-ferrous metals is not a new innovation. Patents describing machines for continuous casting are on file as far back as the year 1842. In the middle of the last century, Sir Henry Bessemer conceived and built a continuous casting• machine for the production of mild steel sheet.The production of billets and slabs of both non-ferrous and ferrous metals is being carried out by the continuous method on a fairly large scale on this continent and abroad. At present, the volume of production of •copper and aluminum and their alloys in billet and slab form is much greater than the continuous casting of steel products. The new installation of a continuous casting unit at Atlas Steels, Limited, is designed primarily for the casting of alloy steel billets and slabs.As an introduction to the art of continuous .casting of metals, it is interesting to examine a few of the many devices which have been developed. As previously mentioned, Sir Henry Bessemer constructed a machine for the direct casting of mild steel sheet. His discoveries and ideas of continuously casting steel formed the foundation for the work of other pioneers in this field, all of whom have contributed to the improvement of this art through the ensuing years. The machines which will be selected for examination are those of Bessemer, Poland-Lindner, Williams, Ennor, and Junghans. The last unit to be discussed will be a modification of the Junghans machine recently installed at Atlas Steels."

Jan 1, 1954

By R. C. Gilmore, J. McMack, G. E. Bogin, J. F. Brune, C. DeRosa

"Researchers at the Colorado School of Mines are designing and building a 1:40 scaled physical model of a fully operational longwall coal mine. The purpose of the model is to minimize the occurrence of methane explosion hazards by testing various ventilation strategies and determining optimal methane sensor placement throughout the longwall face. Fluid scaling factors were analyzed using Computational Fluid Dynamics software Ansys FLUENT™ at both full and 1/40th scales. Researchers were able to identify key scaling factors and subsequently developed suitable flow parameters that would maintain full scale accuracy of flow patterns in the 1/40th model. KEYWORDS Coal, Longwall, Methane, Explosion, Scale Model, Ventilation, Fluid Dynamics, Richardson, Gob, Porous INTRODUCTION Mine ventilation systems are a key component for ensuring a safe working environment by introducing fresh air from the surface and diluting explosive gases and hazardous contaminants. This holds true for longwall coal mines where the emission of flammable methane gas from the longwall face as well as the gob can create explosive mixtures of methane and air. Therefore, an effective ventilation strategy can help mitigate the potential for accidents within a mine. Developing an effective mine ventilation system (MVS) requires a detailed understanding of the physics of gas transport and how this relates to specific geometries and obstructions in the face. Researching this phenomenon requires the development of computational fluid dynamics models capable of simulating fluid flow and methane species transport that can be validated through physical experimentation. Unique site conditions determine ventilation layouts for every coal mine. Researchers have designed a 1/40th scaled physical model of a longwall coal face and adjacent gob that includes movable shield supports and a movable shearer with rotating cutter drums that can be adjusted to a variety of ventilation conditions. The proposed work will address the need for an improved Mine-wide Atmospheric Monitoring System (AMS), and provide the ability to link existing MVS models with AMS in real time. By accurately representing the coal face, the gob area and the mining equipment, gate roads and bleeder entries, the scaled model accurately represents all relevant structures, geometry, and dynamic conditions. A Plexiglas cover allows full optical access for sensor equipment as well as visual inspection of the fluid flow and species transport."

Jan 1, 2019

By Roger Potvin

Abstract The demand for pure zirconium and titanium metals in Germany increased considerably during the war. Pure zirconium was used in flash bulbs, in vacuum tubes, and in time fuses for bombs, where it has a decided advantage because it gives no gas in burning. Under the form of alloy, it was used with other rare elements for making substitutes for platinum; it was also used as a scavenging agent in high-grade steels. Metallic titanium was mainly used in connection with the manufacturing of special alloys. The authors were sent to Germany by the Department of Reconstruction and have investigated the German process developed for producing these rare metals. They describe the procedure and special equipment used for their commercial production in Germany during the war. General Metallic zirconium and titanium were .produced on a commercial scale in Germany by the thermal reduction, with metallic sodium, of potassium fluozirconate and titanium chloride, respectively, using a mixed potassium and sodium chloride flux. According to the information gathered, the sole German producer of these rare metals in pure form was the Deutsche Gold und Silber Scheideanstalt (commonly called Degussa), at their Werk II, 215 Gutleutstrasse, Frankfurt/Main, which was visited by the authors on September 18th, 1945. As far back as 1934, Degussa was carrying on active research on the manufacture of zirconium, and nearly one ton of the pure metal had been produced before September, 1939. Concurrently, a quite similar process was worked out for the recovery of titanium and it was in commercial operation in the year 1938, during which the production totalled about half a ton (metric). The demand, especially for pure zirconium, increased considerably during the war, attaining a total of about 48 tons during the period October, 1939, to the end of 1944, and reaching a peak of more than 15 tons in 1943. In 1944, the plant was slowed down due to the frequent and disastrous bombing by the Allies, especially in March and September.

Jan 1, 1946

By Subrata Dutta

Sindesar Khurd Mine is situated in Rajasthan, India, and operated by Hindustan Zinc Ltd, under Vedanta Group. The base metal mine is high in reserves of Lead, Zinc and silver and has been producing since 2007 with initial production of 0.3 mtpa. Recently the mine has gained prominence as a base metal underground mine in introduction of latest mining techniques and achieving high production at lowest costs. The promising Lead-Zinc reserves of Sindesar Khurd Mine (SKM) and high-tech exploration adopted by Hindustan Zinc Ltd (HZL), (Vedanta Group), raising the reserves and resources from a meager 9 Mt (1997) to 81 Mt (2012), has prompted HZL management to ramp up the mine production from 0.3 mtpa (2006-07) to 2 mtpa by 2013-14 with ambitious plans to reach 3.5mtpa subsequently (presently largest underground metal mine in India). The complete trackless system underground mine, recently equipped with latest leaky feeder communication system (unique in India), utilize modern drilling, mucking and hauling equipment aided with various utility/service vehicles. Excavation optimization and quality recovery maximization from the open and post filled stoping methods, continual expert analysis and feedback from International consultants like AMC (Australia) and SRK (UK), and involvement of renowned bodies in management excellence, have lead the mine towards highest productivity and lowest mine operating cost, earning the mine a prominent place in the global base metal industry. The paper deals with how the various challenges in mine planning and designing, mine development, operator skill, equipment introduction and maintenance, expertise availability, provide training and exposure to officials, prompt and effective communication/service, control of ground vibrations, maintain ventilation standards etc are faced in attaining high operational excellence and thus attain a record mine output/man shift (OMS) of 14 ton/man shift with targets to reach 20 ton/man /shift. Scientific designing using 2D/3D numerical mine-modeling techniques, faster stope sequencing with introduction of paste filling ( first time in India),latest leaky feeder communication system, control ground vibration to stringent standards using electronic delay system, faster raising techniques using raise borers to enhance development and ventilation, cavity scanners to monitor large stope voids, fast shaft sinking at 100 m/month(Chinese expertise) and maintaining adequate ventilation with close software monitoring are some of the highlights discussed in the paper towards achieving the targets.

Aug 1, 2013

By Neville Jordison

Indirect, gravity flow, heat exchangers have become a well established technology in mineral and metallurgical process plants. The technology is a conventional heat exchanger using high efficiency plates, with a free flowing bulk solid on one side of the exchanger and a fluid on the other side. This simple concept leads to many opportunities for achieving greater energy efficiencies in process plants. Indirect heat exchange is much more efficient than direct heat exchange using air such as in a fluid bed or rotary device. When air is used directly, large fans are required, it may also be necessary to chill the air, both high consumers of energy. By contrast, using water as the cooling medium requires only low horsepower pumps, typically only 10% of fan HP. Furthermore there are no stack emissions with the requirement for removal of dust or emissions. Indirect heat exchange also creates the opportunity to recover energy. This can work in two ways: energy can be recovered from a hot bulk solid, to heat pressurized hot water for steam generation or preheat air. Alternatively recovered energy from elsewhere in the plant in the form of hot water, steam, air or thermal oil can be used to preheat a bulk solid.

Jan 1, 2011

By J. Koponen, M. van de Vijfeijken, L. Bos

"The availability and reliability of large grinding mills and their Gearless Mill Drives (GMDs) are of paramount importance for the grinding process. Although GMDs have been in service for decades, and are known for their operational efficiency (reliability and robustness with reduced operating cost per ton), compared to conventional drives, in the last decade due to certain reasons some failures led to serious unscheduled shutdowns and significant insurance events.The majority of these notable ""insured"" failures have happened on GMDs installed on relatively large mills, as the financial impact of a failure is proportional to the through-put of the mill. Despite the occurrences of these events, as mining operations are driven by lower ore grades and the ability to continue reducing operating costs per ton, the trend for having larger mills is still very present and there is no reason why this trend should not continue.It is obvious that if not handled correctly, the possibility of large value GMD loss events, coupled with the continuing increase in mill size or required availability and reliability targets, could potentially lead to major conflicts as it becomes difficult for the insurance companies to judge the risk and hence may result in hesitation to insure these grinding circuits. This paper will not only describe the conflicting situation from both an insurer's perspective and from an equipment supplier's perspective, but also how these conflicting challenges can be successfully mastered. It has to be noted that not only the mining companies themselves, but also their insurance companies and the involved equipment suppliers have a common interest: to reach the highest availability and reliability in order to avoid or at least minimize unscheduled shut down times, and most importantly prevent unplanned events that result in extended production stoppages or reductions in through-put of GMD driven mills.From the very beginning onwards, the complete service concept together with emergency plans must be integrated on every level in the design of the grinding circuit. This approach must be implemented continuously and without compromises by all involved parties during all following stages, such as basic design, detail design, manufacturing, quality inspection and testing, packing, transportation, storage, installation, commissioning, operation and maintenance. The concept of formal risk analysis related to mill operations, maintenance and spare parts strategies must be an integral part of mining companies’ decisions related to the selection for installation and continued use of large mills powered by GMDs. The service concept in place for operating mills shall also have a clear focus on very early detection of any abnormalities, so that the risk can be mitigated and unscheduled shutdown times avoided. However, if a major failure occurs, then procedures and tools shall already be available in order to ensure that production impact is minimized."

Jan 1, 2012

By Roberto Pena, Cristhian Morales, Darwin Morales, Veronica Cambiaso

"This article makes evident the shortcomings of the current operation of oxygen pipes as well as the damages they cause and why they cause them. When focusing on the causes and effects of these drawbacks, it was possible to develop a new family of thermal lances that could pierce a taphole with the precision of a drill but with the capacity to complete the whole operation. Although efforts have been made to replace oxygen pipes since they are annoying, dangerous and inefficient, nobody had worked to improve the way the traditional oxygen pipe taps/perforates the furnaces and reactors tapholes. In fact, developments made in drills and robotic arms, have failed to replace the oxygen pipe, which despite their negative side effects have been used for more than a century. Observation and theory were key to radically transform this humble tool into a dependable and efficient support in the operation. A good news that it is worthwhile to share for the benefit of all of us, passionate about the world of pyro metallurgy.INTRODUCTION Normally, reports and papers prepared for conventions, symposia or other technical events related to metallurgy aim to relevant topics in the operational field, probably because in them lay the scale economies every company pursues. We intend to give relevance to a matter normally disregarded in operations, but that unmistakably vital: if the furnace or reactor cannot be bled, the pyrometallurgical process will not be completed. Besides, if the tapping task is difficult or is long delayed, the availability of the furnace will be reduced. Consequently, there will be a waste of energy and workers will be exposed to dangerous levels of radiation as well as to work overload and physical injuries Apart from these basic effects, in tapping operations where oxygen pipes are used, we can see serious damages in the smelting furnace, especially in the taphole components such as refractory bricks, taphole jackets and water cooled plates. This paper intends to show that taking care of the tapping task can significantly upgrade not only to the tapping operation itself, but also the whole plant productivity."

Jan 1, 2017

By Alexander Burns, David Dreisinger

The kinetics of the oxidation of uranium(IV) by oxygen gas in aqueous systems is dependent on acid concentration, oxygen partial pressure, and temperature. In order to better understand the relationship between these variables and the speed of oxidation, a series of experiments have been conducted where each parameter has been varied in turn. Data were collected continuously using UVVis spectroscopy, allowing for a detailed examination of the reaction rate over the course of each experiment. The data fit an overall apparent rate law that is 1.5order in uranium(IV), -2order in H+, first order in oxygen, and unaffected by uranium(VI). This relationship does not appear to hold for solutions with <0.2 mol/L initial acid, where a different kinetic mechanism appears to be dominant.

Jan 1, 2014

By A. Hayatdavoudi, K. G. Sawant, F. Boukadi

"In this work, we found that contact between shale and water results in development of micro fractures. Based on results of experiments on Pierre shale, we conclude that appearance of micro fractures begin with saturation of capillaries, ionic and diffusive transport of water into the shale clays and once capillaries are saturated, the cause of micro fracture propagation is the conversion of ionic activity/exchange to excess pressure that did not exist before fracking. Based on these findings, the spread of micro fractures appear to be a time-dependent phenomenon which has not been addressed in the existing macro/micro fracture models.INTRODUCTIONShale has often been involved as a hazard in drilling operations. This hazard can be defined as “destabilization” of shale. When contacted with water-based drilling fluids, some shales readily swell and sometimes, cause the wellbore to cave-in, slough, wash-out, close, and pack-off, impeding the drilling by sticking the drill-pipe. However, once drilling reaches the desired depth or length, the casing is set, cemented, and perforated, and then actually we wish to initiate fractures and destabilize the shale formation, using hydraulic fracturing.Clays constitute a major portion of minerals in shale. These clays contain a large amount of free energy which is the main factor for “slick” water adsorption/absorption. In fact, the reason for using “surfactants” in hydraulic fracturing fluids is to make the penetration of the fluid into the capillaries much easier, thus water meets with less resistance to enter the small capillaries. Also, the result of high capillary suction pressure is due to small Angstrom size capillaries, smaller pores and presence of ions and hydrateable metal atoms. The free energy is thus, related to all the above mentioned and other affects. Capillary pressure, osmotic pressure and other pressures are responsible for creating the micro-fractures in shale, thus, increasing the network of micro-fractures which leads to more gas production. The objective of this study is to evaluate the pressures of the individual ions which are released by the diffusing “slick” water into shale. These pressures would be added to the above mentioned capillary pressure, osmotic pressure, bacterially-induced pressures, chemically-induced reaction pressure, pressure due to exchangeable ion-transport, pressure due to release of free energy of solvation and eventually to the pore pressure as suggested by Terzaghi’s equation."

Jan 1, 2015