Search Documents

By Gerhard Melcher, Hermann Hilbrans, Michael Gamroth

"IntroductionSeveral new smelting processes have been proposed and developed during the last 20 years. This has been true, in particular, for copper smelting technology. The important impulses for the advances in this field have been the recent demands regarding the environmental protection, energy saving and improved utilization of the metals contents of deposits, in particular that of complex raw materials.The methods developed more recently for pursuing these objectives have been outlined in several papers. In some of them the advantages and drawbacks of certain developments have been stressed. These documents are of great importance for assessing the different processes. The following paper tries to explain some details of the cyclone smelting process taking into consideration a few of these well-known presentations. The effectiveness of operation of the cyclone smelting process indicates that this process presents a significant achievement when compared with other conventional methods.The application of the CONTOP smelting cyclone range s beyond the field of copper metallurgy or the smelting of sulphide concentrates with the aid of oxygen. The research work carried out in the pilot plant of KHD Humboldt Wedag AG in Cologne-Porz also includes the recovery of the metal contents of intermediate products and processing of smelter residues which have to be converted in a disposable stat e, free of environmental pollution. This paper explains a few examples in this regard."

Jan 1, 1987

By Deni Lessard, Roger Demers, Noël R. Billette

"The Quebec Mining Association has for many years been supportive of the activities of the Centre de recherches minérales which were initiated to ensure regular production hoist and cable inspections to maintain safety and productivity standards in underground mines in Quebec. CRM and CANMET have agreed to fund a Quebec Mineral Development Agreement contract to capture this accumulated knowledge. Using VP-EXPERT to process the information and subdirectories to store regulations, the prototype access D-BASE III records on hoist information and LOTUS 123for simulating working conditions that meet local regulations and expert rules of thumb criteria. Objectives are to improve safety in emergency operating procedures, maximize hoist productivity and safety, and promote knowledge transfer to operators."

Jan 1, 1992

By Gordon E. Agar

"The effectiveness of two this compounds for copper sulphide depression in molybdenite flotation has been examined with batch bench scale tests.Both thioglycollate and trithiocarbonate proved to be good depressants producing results similar to those f or cyanide and hydrosulphide. Ferrocyanide was ineffective on the samplematerial tested.The depressing effect of thioglycollate was readily reversed by an addition of xanthate.IntroductionThe separation of molybdenite from copper sulphide minerals has been practised for a long time(1,2). The predominant scheme is to depress the copper sulphides while capitalizing on the ready floatability of molybdenite to effect the separation. There are many recipes for depressing the copper minerals(3), among them the addition of sodium cyanide, particularly if the copper is present primarily as chalcopyrite; some form of sulphide whether as sodium sulphide, sodium hydrosulphide or phosphorous pentasulphide when there is a mixture of copper sulphides such as bornite, chalcocite and chalcopyrite; potassium ferro cyanide may be used when chalcocite is the principal copper sulphide; peroxide or hypochlorite; as well as heating in the presence of lime. There are different mechanisms by which these reagent s depress the copper sulphides. Sodium cyanide and the sulphide-producing compounds apparently reduce the potential of the copper sulphides to the point where they ar e rendered unfloatable by xanthates . Another study(4) showed that after cyanide addition, chalcopyrite was rendered un floatabl e until the REDOX potential (measured with a gold electrode with a saturated calomel reference) had become more positive than -250 mY. If the chalcopyrite pulp was conditioned after the cyanide addition the REDOX potential increased slowly, whereas if air was introduced during the conditioning the potential r ose much more rapidly. The difference in time to reach the desired level of - 250 mV was as much as 20 minutes' 25 minutes being required when air was absent but less than 5 minutes when air was admitted . These observation s demonstrate some of the problems encountered when using cyanide to depress sulphides such as chalcopyrite . The system adjusts to counteract the depressing effect of the additive. To overcome this tendency it is necessary to either add an overdose at the beginning or to more or less continuously add the regulating reagent. In this study cyanide solution was added under automatic control to maintain a specified REDOX potential."

Jan 1, 1984

By J. G. Bensley, K. S. Detheridge

"Many plants use computers for process control and most have computerized Management Information Systems but few have been able to have these systems interact with one another. Developing this system interaction is not a one-step process but requires careful planning and implementation. This paper describes two projects that were implemented to provide the bridge between the process control and management information systems of Cominco Limited. Both projects include the replacement of essentially process control systems installed in the late 1960s. These original systems provided an enhanced level of control in the form of Direct Digital Control (via computer/manual analogue control stations) and a management reporting capability of process data. The experience gained from the use of these systems over a period of fifteen years formed a basis for the evaluation and planning for the new systems. The new systems were commissioned in 1985 and 1986 and operating and further developments leading to a totally integrated process information and control system are underway. INTRODUCTIONThe concept of hierarchical control involves a control structure consisting of a number of defined levels. Each level performs a defined function with information consolidated and combined as it moves up through the hierarchical structure. The commonly accepted structure of a hierarchical control system echoes the structure of the plant which is being controlled. Referring to Figure 1:Level 0 - Sensors and ActuatorsSensors and actuators, such as thermocouples and flow control valves, interface directly to the process and are generally connected directly to the controllers or multiplexers at Level I.Level 1 - Regulatory ControlThis level provides basic PID control (proportional/integral/ derivative) typically using microprocessor based controllers and programmable controllers for digital control of motors and machines. Systems at this levelare usually segregated by plant unit, e.g, crushing, flotation, drying. Control is concentrated on achieving optimum conditions for a particular feed rate."

Jan 1, 1989

"Technological innovation is an extremely complex activity. The author presents his interpretation of innovation and the innovative process. He reviews the strategy used by participants in coal mining innovation in the past and discusses changes required to meet the challenges of the future.Introduction if an industry is to be successful and viable in today's world, the companies active within the industry must remain close to the frontiers of knowledge. The coal mining industry is no exception. Technological problems facing the coal mining industry are basically economic and social. Economic problems are those concerned with the long-term growth and profitability and social problems, with the health and safety of the mine worker and the impact of the mining operation on the environment.Technological innovation can be a key factor in meeting these problems successfully. The general belief is that the information base for technological innovation exists within mining companies and governmental agencies but current industrial and governmental strategies and structures impede the transformation of this knowledge into the mining products and processes required for growth.The purpose of this paper is to determine where Canada is in terms of coal mining on the innovative ladder. The paper as presented: defines innovation and innovative process; gives an historical ""broad brush"" review o f innovation in the industry; and suggests the challenges to be faced in the future."

Jan 1, 1985

By Margaret Armstrong, Normand Champigny

"In order to define the ore/waste boundaries as finely as possible, mine planners often insist on kriging very small blocks (relative to the spacing of the available sample grades). These kriged estimates for very small blocks are over-smoothed. For several simple sampling patterns the relation between the block size and the variogram range, and the kriging results were studied. Meaningful estimates of individual blocks are obtained when the variogram range is large compared to the block size and the sample spacing. For a variogram range less than half the sample spacing, the kriged block estimates were found to be uncorrelated with the actual grades. The over-smoothed estimates should not be used for calculating recoverable reserves IntroductionNowadays most mining companies know that the geostatistical estimation method, kriging, gives the best estimates of individual block grades. As most mining engineers and geologists are now familiar with the basics of geostatistics, the definitions of the variogram and of kriging will not be repeated here. An appendix containing definitions and mathematical formulae is given at the end of the article for the sake of completeness.Even though it is well known that the kriged estimates for very small blocks are over-smoothed, mine planners who want to define the ore/waste limits as finely as possible (especially for selective underground mines), are often tempted to krige very small blocks. So we ask how small is ""too small""? Clearly ""smallness"" cannot be expressed in yards or metres. It depends on the nature of the orebody under study and this is reflected in the variogram model chosen to describe it.To answer this question, the changes in four key parameters are studied:• the kriging variance,• the variance of the estimated grade,• the slope of the linear regression of the true but unknown grade on its estimated value, and• the coefficient of correlation between the actual grade and the estimate;as a function of the block size and the variogram range. (Definitions of these four parameters are given in the appendix). Ideally the kriging variance should be low while the variance of the estimated grade should be equal to the dispersion variance of the blocks. The slope should be l.0, and so should the correlation coefficient.These four parameters have been calculated for several simple 2-D examples. The effect of using kriged block estimates that are too heavily smoothed are shown, and the dangers of trying to use these estimates for predicting recoverable reserves for small blocks (i.e. selective mining units) are pointed out."

Jan 1, 1989

By J. W. Smith, J. Van Dusen, A. Papachristodoulou

"As part of a study to evaluate factors affecting tankroom air quality, the mechanism of aerosol generation from bursting bubbles in electrowinning operations has been investigated. Typically 2 to 3 mg/m2.s are produced in zinc tankrooms. Analysis shows that the rate of production of film drops (geometric mean diameter - 2 urn] increases with decreasing bubble size, and that jet droplets (geometric mean diameter - 20 um) are not produced with gas bubble larger than - 4 mm. Both mechanisms of drop formation and current efficiency are affected by surface active agents, with an over-all reduction in emission of up to 60% to 70% being achievable. A source control system which does not adversely affect electrolyte properties is always preferred, and coalescence of all gas bubbles in to a continuous stream of gas at a single point on the electrolyte surface would eliminate aerosol emissions. This objective was the basis for design of a coalescence device which, in laboratory tests, reduced the emission rate by over 95%.The control device fit s over the electrodes in the electrowinning cell and is partially immersed in the electrolyte. A number of changes in the design which resulted in significant improvement in the performance of the device are reported.Field tests have shown that only about 75% of the aerosol below 10 um can be eliminated by coalescence. The remainder (up to 95% of the total) is controlled by coalescence of droplets, by impaction on the exposed collector surface and gravitational settling.The device does not interfere with operation of the tankroom, handles the effect of surges in power during harvesting, and is simple and inexpensive to maintain. IntroductionDuring the electrowinning of metals (such as zinc and copper) gases are evolved along the electrode surface forming small bubbles. The bubbles travel upwards and burst on the electrolyte free surface generating, in this way, small droplets. Because the electrolyte is often highly acidic or contains toxic materials, the whole process can result in the formation of an aerosol in the atmosphere above the electrowinning cells which poses a serious health hazard to workers in the area, and corrodes equipment."

Jan 1, 1988

By G. Macfarlane

"In 1985, a crushing plant, located in the feed preparation area of Kidd Creek's copper smelter, was modified. The plant, which originally had treated only copper-bearing materials for the smeller, at a rate of 10 tonnes per hour, was expanded to 40 tonnes per hour capacity and modified to treat silica ores to meet the smelter’s flux requirement and also gold ores from the company's Hoyle Pond property. In the storage area adjacent to the crushing plant a 300 tonne per day gold mill was constructed.This paper outlines the construction and first year of operation of the crushing plant and gold mill with emphasis placed on the capital and operating advantages to be gained by utilizing an existing metallurgical infrastructure.IntroductionThe Kidd Creek Mines Ltd. copper-zinc-silver orebody is located 24 km north of Timmins, in Northern Ontario . Mining of this massive sulphide de posit commenced in 1966 and, in the ensuing years, a concentrator and zinc plant were constructed at the metallurgical complex, approximately 17 km by rail from the mine site . At this same site, in 1981, a copper smelter and refinery were commissioned. The smelter which utilizes the Mitsubishi smelting process for the continuous production of blister copper from copper concentrate, has been comprehensively described in previous papers.At the time of the smelter construction, a small (10 tonnes per hour) crushing plant was installed in the smelter's feed preparation area. This plant was used to treat the copper-bearing revert material produced by the smelter, and, apart from periods when slags and matte were produced through furnace drainage at the end of each operating campaign, it was generally under-utilized. This fact, together with the requirement to devise a more cost effective method of providing silica flux for the smelting operation, was the basic rationale for modifying and expanding and crushing plan t. At the same time, development at Kidd's Hoyle Pond orebody had progressed to such a stage that a gold mill of 300 tonnes per day was warranted."

Jan 1, 1988

By J. E. Dutrizac

A pyritic Zn-Pb-Cu ore waspercolation leached with acidified ferric sulphate solutions; zinc and copper were leached, lead was oxidized, but not dissolved, and pyrtte was essentially unattacked. High zinc extractions were achieved after a few months leaching, and substantial zinc solution concentrations could be produced by recycle of the oxidized solution. The leaching rate was generally controlled by the transport of the ferric sulphate oxidant. Zinc extractions increased with increasingferric ion concentration or flow rate, but were essentially independent of the concentrations of sulphuric acid, ferrous sulphate, cupric sulphate or chloride ion. The leaching rates were insensitive to the height of the ore column once a minimum height had been exceeded (0.8-1.0 m). Elemental sulphur was the principal sulphidic reaction product, but variations in the ratio of sulphur to sulphate produced anomalous temperature effects.

Jan 1, 1979

By R. J. Twigg, S. D. Chang

"The production of heavy water, the moderator in a CANDU reactor, is examined following a flow sheet of a typical Canadian plant. The process involves the extraction and concentration of deuterium from natural water through a chemical exchange mechanism with hydrogen sulphide. Consequently, corrosion problems associated with sour environments – the use of hydrogen sulphide - are an everyday problem and have led to the development of a highly refined materials selection and testing program to prevent equipment from failing prematurely.IntroductionHeavy water is a naturally occurring compound in ordinary water and is formed from the combination of two deuterium atoms and one atom of oxygen. Deuterium is a heavy hydrogen atom which has a nucleus of on e proton and one neutron. Hence, heavy water is a combination of heavy hydrogen and oxygen and is chemically known as deuterium oxide. It looks and tastes like ordinary water but it freezes at 3.8°C and boils at 101.4°C. The molecular weight of heavy water is 20 as compared to 18 for ordinary water; the density of heavy water is ten per cent greater than that of ordinary water.Although heavy water and ordinary water exhibit only small differences in their chemical and physical properties, there are large differences in their nuclear properties, the most important of which is the neutron moderating ratio, used to measure the ratio o f the slowing down power to the neutron capture characteristics. For heavy water the ratio is 21000 and for ordinary water it is 50. This high moderating ratio is essential for achieving a high neutron economy. Heavy water is, therefore, chosen as the moderating and heat transport fluid in the CANDU reactor."

Jan 1, 1983

By B. E. Jones

"The area of uranium deposition is situated within the Churchill Province on the western edge of the Wollaston Iithostructural domain where it underlies the eastern edge of the Helikian Athabasca Formation. The Collins Bay deposit is 6 miles north-northeast of the Rabbit Lake mine. Two principal zones of uranium mineralization are described.The ""A"" zone is a partly eroded, high-grade pod of metal oxide and arsenides sheathed by clay-like minerals. It trends north-northeast and lies under 25 to 40feet of water. Uranium mineralization is localized at or adjacent to the unconformity between the Athabasca Formation and the basement rocks. The basement comprises a granitoid Archean terrain overlain by paragneisses of the Aphebian Wollaston Group. ""A "" zone ore contains phyllosilicates, quartz, pitchblende, rammelsbergite, pararammelsbergite, carbonaceous material, galena, gersdorffite, niccolite, carbonate and a trace of sphalerite.The ""B "" zone lies 6,000 ft south of the ""A "", and subcrops under till cover. It is a partly eroded zone composed of metal oxide and arsenides which occur within variably altered Athabasca Formation. Minerals recognized are phyllosilicates, pitchblende, niccotite, gersdorffite, millerite, carbonaceous material, pyrrhotite, skutterudite and a trace of galena. The Athabasca Formation varies from 90 to 160ft thick. Granitoid gneisses of probable Archean age and paragneisses of the Wollaston Group underlie the deposit. An easterly dipping thrust fault transects its length.The deposit is typical of the ""unconformity-type"" uraniumnickel deposits of the Athabasca Basin. Observed features fit well with the ""diagenetic-hydrothermal"" model for such deposits, as envisioned by Hoeve and Sibbald (/978)."

Jan 1, 1980

By M. H. Moys, J. A. Engelbrecht

"Large-diameter flotation columns are subject to severe axial mixing which has reduced column recovery and has generally limited it to cleaner applications. It has been assumed that columns with diameter greater than 1 m should be baffled to reduce axial mixing, but little work has been reported quantifying the effectiveness of baffling. Tests were done on a 0.2 m by 2 m column fitted with baffles of different geometry. It was generally found that the inclusion of baffles in the column worsened rather than improved mixing conditions in the column. This is explained in terms of a model for the effect of poor gas distribution on the behaviour of the column; this showed that under typical conditions a 16% excess of gas flux in the one compartment of a two-compartment column could result in one of the compartments being ""dead"" (i.e. with no net flow of slurry through it), resulting in a substantial loss of performance. The quality of mixing in the laboratory column was only reliably improved when the baffle was raised so that its top was positioned above the froth-slurry interface level. It should be possible to increase column recovery substantially with this configuration. The improved residence time distribution also means that columns can be used more effectively in roughing and scavenging applications. IntroductionFlotation columns have generally been used in cleaner applications, starting with their dramatic success at Mines Gaspe(1). Their lack of applications as roughers and scavengers is probably due to their poor residence time distribution (RID) when compared to the conventional cells they would replace. Espinosa-Gomez et al,(2) recently used them in rougher applications but installed three columns in series, presumably to cope with this disadvantage.Dobby and Finch in their seminal papersl(3,4) on the scale-up of flotation columns were the first to quantify the impact of axial mixing on the performance of industrial flotation columns. Laplante et al.(5) collected further data from the literature for column diameter D, ranging between 5 cm and 183 cm, gas superficial velocity Jg ranging between 0.7 cm/s and 2.8 cm/s and per cent solids in the feed S ranging between 3% and 52%. These data were analyzed with reference to the axial mixing model using the boundary conditions for closed vessels (the latter are more appropriate for flotation columns but the model is more difficult to use because analytical solutions for the RID are not available). The data were correlated by:"

Jan 1, 1993

By K. Thuro, B. Sellmeier, M. Krautblatter

"Recent rockfall events, like the Tramin rockfall at January 21st, 2014, underline the significance of a comprehensive hazard assessment. A common way of estimating the hazard along infrastructure is the performance of run-out modelling using 3D rockfall codes like Rockyfor3D or RAMMS::Rockfall (Dorren, 2010, Bartelt et al., 2013). The potential block volumes are often roughly estimated from talus material and an overview of the source area, where the magnitude assessment is usually physically and intellectually demanding. Nevertheless especially for increased magnitudes, the volume estimation is crucial in terms of hazard analysis. Mid-Magnitude-Events exceed the load capacity of the most mitigation measures and their date of failure is hard to predict. Here we define the term Mid-Magnitude-Events as block volumes between boulder falls (10-100 m³) and block falls (100-10,000 m³) (Whalley, 1984).The current contribution provides an approach of integral process analysis for a 200 m3 carbonate block above the federal road B 305 near the city of Salzburg in the Bavarian Alps, Germany. We performed detailed analysis of the critical carbonate block exposed to planar failure. The block volume and the dimensions of the failure surface were mapped in detail, due to the unique occasion of an accessible failure surface. The discontinuity persistence was recorded to assess a minimal degree of fragmentation for a potential failure scenario. A maximum degree of fragmentation was estimated due to recording of block dimensions at the talus slope resulting from frequent rockfalls.We performed parameter studies in terms of run-out modelling using the code RAMMS::Rockfall (Bartelt et al., 2013), taking the recorded data for block fragmentation into account. In our contribution, we aim to demonstrate a comprehensive approach for hazard assessment of mid magnitude rockfalls, taking detachment processes, fragmentation and run-out analysis into account."

Jan 1, 2015

By K. Kawagishi, J. Ang, A. Sato, H. Harada

"We have recently proposed a new ""EQ Coating"" bond coat system to solve the problem of secondary reaction zone (SRZ) formation caused by bond coats applied on the hot section components of modem jet engines. A viable EQ coating alloy was previously found for a representative znd generation superalloy, TMS-82+. It would be ideal if the same could be done for a representative 5th generation superalloy, TMS-173. In this paper, we will show that the coating with the best oxidation resistance in the EQ system of TMS-173, although possessing considerably better resistance than TMS-173, did not have sufficient oxidation resistance. In order to improve the oxidation resistance of the EQ coating for TMS-173, we have ventured into ""Pseudo-EQ coatings"". A diffusion couple between the Pseudo-EQ coating and TMS-173, after 300hrs at 1100°C, had a 0-15µm IDZ, but no SRZ. A diffusion couple between a conventional coating and TMS-173 formed a 80-150 µm SRZ. After a 1 hr oxidation test at 1100°C, the PseudoEQ coating formed a thinner oxide layer than the EQ coating, but still contained NiO and spinel. Aerospace"

Jan 1, 2006

By K. Sun, S. A. Argyropoulos

The assimilation and the exothermic behavior of Zn-Zr metallic powder compacts into molten aluminum was studied by measuring simultaneously the temperatures inside at the centerline of the compact, at its surface, and inside the molten aluminum bath, as well as the net downward force acting on the compact. In addition, the exothermic behavior of these compacts was also investigated in an argon protected atmosphere. The temperature rise inside the compact increases significantly with the mass ratio of zirconium in the compact and to a lesser degree with the aluminum bath temperature. Experimental results on the recovery of these compacts in molten aluminum will also be presented.

Jan 1, 2008

By Roger Lacroix

Presentation outline Project definition Characterization of mine ventilation systems Strategies in place and results Detailed study (2 mines) Other potential energy savings Conclusions Next steps

Feb 1, 2008

By E. L. Martheleur

A general expression for the electric power generated or consumed in a direct-current circuit is obtained by multiplying the reading of a suitable voltmeter connected across the terminals by the reading of an ammeter connected in the circuit. by the reading of an ammeter connected in the circuit. When alternating currents are considered, the product of the volts and amperes as obtained for direct currents does not generally represent the true energy involved; it is greater than this true energy and should be multiplied by a certain factor which may have any value between zero and unity, according to the conditions of the circuit. This factor is called the power-factor of the system, and expresses the ratio of the true energy over the apparent energy. For a three-phase system the expression of the apparent energy is [\/ 3 x E x I; ] while the expression of the true energy, that is, energy suitable for mechanical work, is [v? 3 x E x I x cos A.] The total current of a circuit corresponds to the reading of an ammeter connected in the circuit; it is the resultant of two currents. The first of these is in phase with the voltage, and is that portion which really produces mechanical work; the second is always in quadrature with the voltage, that is it may lead or lag the voltage by 90° according to the condition of the circuit. This second current does not produce any sensible work, and for this reason is sometimes called wattless current or reactive current.

Jan 1, 1924

By G. A. Maki, P. J. Fullman, R. G. Roden

"In October 1984, Rocanville Division began using a stacking system to handle potash mill tailings. Previous to this date, mill tailings were slurried to the top of the tailings pile and allowed to debrine while flowing down the pile. With the new stacking system, slurried tailings are fed to mobile stackers. The stackers consist of cyclone packs to debrine the tailings and drag conveyors with screw discharges to deposit the tailings onto the existing pile. This paper deals with the various aspects of the project from conception to its present state.IntroductionPrevious to 1984, when the stacking project was first implemented, potash mill tailings were handled as follows. Mill tailings were first debrined to approximately 65010 solids using a cyclone cluster. The cyclone underflows were then introduced onto a vacuum scroll filter table. Here the tailings were further debrined and discharged into the disposal tank where the tailings were reslurried with reclaim brine and pumped to the tailings disposal site. At the disposal site the slurry was discharged onto the tailings pile and by a natural settling process the tailings were debrined with the brine ultimately collected in the reclaim brine ponds. The shape and profile of the tailings pile was controlled by building salt dykes to control the flow of the discharged tailings slurry. As the tailings pile grew in height, booster pumps were added to the disposal system."

Jan 1, 1990

By W. Blum

Progress made in improving the creep resistance of Mg alloys is reviewed with the emphasis on microstructural interpretation. Experimental results on the increase of creep strain with time at constant stress a measured for limited times and strains are displayed in a transparent form as creep rate-strain diagrams from which the minimum creep rate stress is safely derived. In addition, data on the thermal stress component a derived from high-precision a-reduction tests are reported. Within a simple statistical dislocation model these data allow one to quantify the relation between dislocation velocity v and a . In combination with structure evolution laws this relation serves as a basis for modeling the creep rate. New alloys have distinctly higher creep resistance than AZ91 where precipitation hardening plays a minor role. This is due to hardening by intermetallic phases which may form a continuous skeleton along the grain boundaries (e.g. Ca-alloyed AZ91) and/or submicron-sized precipitates within the grains (MRI230D, Mg-Zn-Ca alloys).

Jan 1, 2006

By D. K. Sarkar, Jiawei Xiong

"Self-assembled monolayers (SAM) on the aluminum substrates are used as the adhesion promoter between two aluminum substrates when bonded with the adhesive in adhesive bonding technology. Traditional surface analysis tools are not capable of identifying the presence of SAM on a surface; therefore, EIS has been used to determine their presence on the aluminum substrates. In this study SAMs have been deposited on aluminum using the monomer of (3-Glycidyloxypropyl)trimethoxysilane (GPTS) organosilane. AA6061 aluminum alloys substrates were chemically cleaned with NaOH and HNO3 to remove the native oxides, followed by immersion in silane solutions. In a second method, SAMs were prepared by applying a spin coating of silane solution to the samples. The prepared SAM coated aluminum samples were analysed by EIS in the three electrode corrosion cell using a diluted alkaline solution. The impedance of the SAM coated aluminum is found be higher than the as-received aluminum. It has been also observed that the open circuit potential (OCP) of the SAM coated aluminum is higher than the as-received aluminum. Both elevated values of the impedance and OCP confirm the presence of SAM on aluminum.INTRODUCTIONSelf-assembly (Schreiber, 2000) is defined as the spontaneous formation of complex hierarchical structures from pre-designed building blocks, typically involving multiple energy scales and multiple degrees of freedom. Generally speaking, SAMs are created by the chemisorption of ""head groups"" onto a substrate from either the vapor or liquid phase followed by a slow organization of ""tail groups"" of a molecule. Typically, head groups are connected to a molecular chain in which the terminal end can be functionalized with groups such as –OH, –NH2, –COOH, or –SH to vary the wetting and interfacial properties (Chauhan et al., 2007; Ulman, 1996; Vashist, Lam, Hrapovic, Male, & Luong, 2014). Though there exist several methods to prepare SAM (Chauhan et al., 2007; Chen, Yang, & Zhang, 2014; Cho, Park, Jon, & Choi, 2007; Igor Luzinov, 2000; Reis, de Melo, & Costa, 2006; Song, Zhai, Wang, & Jiang, 2006; Sugimura, Hozumi, Kameyama, & Takai, 2002; Vashist et al., 2014), the two methods vapor phase (Song et al., 2006; Sugimura et al., 2002) and solution(Chen et al., 2014; Igor Luzinov, 2000) are commonly used. Recently, many articles have been published on the fabrication of superhydrophobic surfaces with SAM technology (Cho et al., 2007; Pan, Shen, Shang, & Xing, 2012; Siddaramanna, Saleema, & Sarkar, 2014; Song et al., 2006). Brassard, Sarkar, and Perron (2011) successfully obtained a superhydrophobic film by applying fluoroalkylsilane via self-assembly on monodispersive silica. SAMs are also reported as good candidates for anti-corrosion and adhesion promotion (Chen et al., 2014; Saleema, Sarkar, Paynter, Gallant, & Eskandarian, 2012). However, papers on the characterization of SAM properties are rarely seen. The most commonly used substrate for SAM is silicon and the method implemented is scanning probe microscopy (SPM) such as atomic force microscope (AFM) (Igor Luzinov, 2000; Moores, 2011; Zhang, 2003, 2005). Igor Luzinov (2000) analyzed the epoxysilane SAMs’ surface morphology and microstructure properties using scanning probe microscopy (SPM) and ellipsometry on single-crystal silicon wafers. SAMs have been used to improve the adhesion bonding of aluminum or plastics but no characteristic data have been presented yet (Saleema et al., 2012; Telegdi, 2007; Wang, Xu, Luo, Wang, & Wang, 2009). Recently, Reis et al.(Reis et al., 2006) have studied SAM of alkane diphosphonate (Gardobond X4661) on Al 5052 alloy samples by EIS in a naturally aerated sodium sulfate solution."

Jan 1, 2016