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By S. McCarthy, K. E. Waters, A. Jordens

The beneficiation of rare earth (RE) element bearing minerals has become an active area of research as applications for these elements grow while the supply to non-Chinese consumers is restricted by export quotas. One of the most interesting beneficiation techniques for RE minerals is froth flotation as their unique chemistry suggests that collectors with a specific affinity for RE cations should be able to selectively recover these minerals. Existing literature, focusing mainly on bastnäsite flotation, identifies hydroxamic acids as excellent collectors for RE minerals. The high stability of hydroxamate-RE cation complexes is the explanation most often offered for the observed selectivity of these reagents in bastnäsite flotation however some research has also suggested that mineral solubility plays a crucial role in the success of hydroxamic acid flotation of RE minerals. This work investigates the interaction of allanite, a relatively insoluble RE-silicate mineral, with benzohydroxamic acid using zeta potential measurements and microflotation. The effects of Fe(III) and Fe(II) ions as potential activating ions (cations that form stable hydroxamate complexes) on benzohydroxamic adsorption to the allanite surface are investigated as a potential solution to promote hydroxamic acid adsorption. The results indicate that the optimum conditions for separation of allanite from quartz occur at pH 4 using FeCl2 as an activator for benzohydroxamic acid adsorption.

Jan 1, 2014

By K. Mayhew, A. Lossin, H. Salomon-de-Friedberg

"The proportion of arsenic-bearing copper concentrates that supply the copper industry is on the increase. The current strategy of miners and smelters to blend feeds to reduce average arsenic levels is rapidly becoming unsustainable as more concentrates with even higher arsenic levels enter the marketplace. In addition, the capability of smelters to manage increasing arsenic levels to more stringent and restrictive environmental standards is limited by available process technologies.CESL Cu-As Technology is a viable technical and economic alternative to traditional smelting. It offers the advantage of simultaneous leaching and precipitation of the arsenic in a single processing step while achieving high copper extractions. The process has been piloted in six separate, fully-integrated pilot campaigns for feeds ranging from ~1% to 12% arsenic in concentration. This paper will focus on the behaviour of arsenic in CESL’s leaching/precipitation step and operational factors that influence it, and on the chemical and physical characteristics of the subsequent iron-arsenic residue that represents today’s best available technology from a long-term sustainable (capital/operating costs, metal recovery, safety, environmental) perspective.The examples provided will demonstrate copper extractions approaching 99% and arsenic deportment to residue of 99%. Instantaneous settling rates of the residue were measured at 15+ m/hr. Data from subsequent short and long-term stability testing of the residue confidently support the view that the scorodite-bearing residues from the process will be stable and provide an acceptable arsenic management practice. The technology offers increased revenue and environmental certainty for miners, smelters & refiners to support the development of metallurgically challenged copper-arsenic deposits. Furthermore, results will be presented demonstrating the technology’s ability to successfully incorporate hazardous arsenic containing smelter by-products such as dust into the process feed and simultaneously extract copper value while fixing the arsenic in a stable residue."

Jan 1, 2016

By K. E. Waters, C. Marion, T. Grammatikopoulos, A. Jordens

"The Nechalacho deposit, located in the Northwest Territories, Canada, is a heavy rare earth element (REE) deposit. The main REE-bearing minerals in the deposit are zircon, allanite, bastnäsite, synchysite, columbite (Fe) and fergusonite. Previous work investigated the use of gravity and magnetic separation in the processing of this ore and showed that coarse particles following grinding were enriched in zircon, suggesting the potential for selective comminution. The current work investigates the possibility to selectively comminute gangue minerals and concentrate REE-bearing zircon into coarser size fractions. The ore was ground wet in a laboratory rod mill for various lengths of time (0, 10, 20, 30, and 40 min). The resultant products were analyzed using ICP-MS, to determine the distribution of zirconium and REEs in the different size fractions produced after grinding, and QEMSCAN, to identify mineral phases, mineral liberation and the distribution of minerals. Optimum grind sizes for the upgrading of zircon due to selective comminution were then proposed, and dense medium separation was investigated as a means to further concentrate zircon.It is important to note that this process is not representative of the currently selected process design or recovery for the Nechalacho deposit. Any application of this process to this deposit would require optimization in order to ensure appropriate grade and recovery targets are met.INTRODUCTIONThe rare earth elements (REEs) are the fifteen elements in the lanthanide series of the Periodic Table, as well as yttrium (scandium is excluded in this work). Traditionally, REEs are categorized into two groups: the cerium sub-group of “light” rare earth elements (LREEs); and the yttrium sub-group of “heavy” rare earth elements (HREEs) (Golev et al., 2014). The LREEs comprise the first six lanthanides (lanthanum through samarium) and the HREEs comprise the remaining nine lanthanide elements (europium through lutetium) coupled with yttrium (Golev et al., 2014). HREEs are much less abundant in the earth’s crust and on average are more expensive than LREEs (Seredin, 2010). Of the fifteen REEs, the production of neodymium, europium, terbium, dysprosium and yttrium has been determined to be most critical due to their scarcity, high demand and criticality in many high-technology and clean energy applications, such as in illuminated screens for electronic devices and permanent magnets in wind turbines (Seredin, 2010; U.S. Department of Energy, 2011). These five elements are classified as critical rare earth elements (CREEs) (U.S. Department of Energy, 2011)."

Jan 1, 2016

By Lorant B. Geller

Sixteen miners died tragically at the Paymaster gold mine at Timmins, Ontario in February, 1945, when a badly corroded hoist rope broke. The investigation of the Royal Commission that followed arrived at a number of recommendations (Investigations, 1947) aimed at avoiding future disasters of this kind. One consequence was the development, and legislated use in Canada, several decades ago, of powerful electromagnetic (EM) instruments for the nondestructive testing of mine shaft wire ropes. The authors have been involved for many years in the design, production, and testing of EM instruments (Geller and Udd, 1990 and 1992, Geller and Kitzinger, 1991, Geller et al., 1993). Since the mid-1990s particular attention was paid to the design and operational results obtained from the computer- controlled portable MagnographJ II wire rope tester (Geller et al., 1995 and 1998). In the present article the authors summarize further hardware- and software-related developments of this instrument. Further, an account is given of the results obtained from the most recent design known as the PermaScanJ testing system. This is also a computerized dual-function system. In it, however, the sensor head is designed primarily, if not solely, for permanent installation and for remotely controlled operation. This represents a basic departure from traditional designs, which were intended for ad hoc temporary installations. The remotecontrolled instrument described in this paper has now been in operational use for more than 4 years.

May 1, 2003

By Samuel Frimpong

Green house gases have become a major concern within the international community over the last two decades due to their potential link to global warming. Carbon dioxide (CO2) is the principal greenhouse gas. In the Kyoto Agreement, Canada has committed to reduce emissions by 6 % below 1990 levels by 2012. This presents a serious economic challenge to Canada and Alberta. Over the next decade, oil sands production expansion, population and industry growth and energy demand will increase CO2 emissions. Current and future CO2 emissions and their economic implications in Alberta will be critical in formulating a comprehensive and balanced policy for dealing with concerns in this area. Disposal of carbon dioxide (CO2) in land aquifers is a potentially viable option for Alberta in dealing with long-term CO2 emissions. Studies have confirmed the existence of appropriate aquifers in the Alberta Basin for CO2 storage over a long geological period. Carbon dioxide is an ideal candidate for aquifer disposal because of its high density and solubility in water at relatively high pressures. In this study, the authors develop a computer simulation model of a scaled aquifer disposal system. The scaled model consists of an injector well, aquifer environment with dominant Ca++ and Mg++ cations. Liquefied CO2 is injected at an appropriate pressure and concentration through an injector well model. The injected CO2 migrates from the point of contact between the injector well and the aquifer domain to the main regime of the latter. The rate of migration is a function of porosity, permeability, cations, aquifer fluid flow regime and CO2 injected pressure. These models are validated using flue gas data from the 546 MW Wabamum Power Plant in Alberta. The total energy requirements for aquifer CO2 disposal system are distributed between a minimum of 105 MW and a maximum of 172 MW, with a mean of 132 MW and a coefficient of variation of 10%. The results show that there is significant variability in all the energy requirements for the CO2 disposal system. The total energy requirements for the disposal system as a fraction of the total power generated by the Wabamum plant of 546 MW could be between 0.19 and 0.32. This is a very significant energy requirement and thorough analysis must be carried out to reduce this variability and energy requirements.

May 1, 2001

By R. St. C., G. E. Morris, M. Zbik, Smart

Effective flocculation and dewatering of slurry streams containing clays (particularly kaolin and smectites which are often <200nm in lateral dimension) is becoming increasingly urgent. Release of water (often >75 wt%), for recycle and reduced make-up water consumption, from slurries in tailings streams and dam beds is usually slow and incomplete. Changes in settling rates and solids density of tailings containing clays can be achieved in practice by changes in pH, dissolved cations and flocculant additions. To achieve fast separation of clays from water and minimization of retained water, individual particles need to be bound in the initial stages of thickening into large, high-density aggregates, which may sediment more rapidly with lower intra-aggregate water content. Quantitative STIMAN (STructural IMage ANalysis) cryo-SEM imaging, shows that the structure of aggregates formed before flocculant addition has a determinative effect on these outcomes. Without flocculant addition, 4 stages occur in the mechanism of primary dewatering of kaolinite: initially separate particles and aggregates are dispersed (<0.3GP, where GP is the gel point); a partially-gelled chain network then forms linking particles edge-edge (EE) still well below the OP but remains largely suspended; after an induction time, this network structure rearranges from EE to face-face (FF) contacts densifying, compacting and dewatering the aggregates with settling rates well above Stoke&apos;s Law estimates for >20µm particles or aggregates; the GP is rapidly reached during settling producing a network spanning the vessel with compressive strength. This sponge-like structure with EE oriented particles limits slurry dewatering because the steric effect in the resulting partially-gelled structure is much more dominant than the electrostatic effects predicted by DLVO theory. Van der Waal&apos;s forces at very close distances, as particles slide across each other, may be responsible for the EE to FF change in structure. In this way, the previously extended network contracts, and when the solid volume fraction is low, the continuous network breaks apart forming aggregates and aggregate associations as flocs which arc able to freely settle. These densified aggregates settle at increased rate, give lower bed density and retain less water after drainage. With flocculant addition, the internal structure and networking of the pre-aggregates is largely preserved but they are rapidly and effectively bound together by the bridging action of the flocculant(s). The STIMAN analysis shows that there is a inverse correlation of intra-aggregate porosity (and void permeability) with Darcian permeability (and extent of dewatering) whereas there is a strong positive correlation of Darcian inter-aggregate permeability with settling and primary dewatering rate.

Jan 1, 2004

By S. A. Jacob

Magnesium sheet is notoriously difficult to form at low temperatures without initiating failure, In the present work cold rolling and annealing conditions are varied to produce samples of AZ3lB sheet with a range of grain sizes. The formability of these samples is investigated using tensile testing and forming limit diagrams (FLD&apos;s), The results are discussed in terms of twin types and frequencies.

Jan 1, 2005

By M. Rafieazad, P. Fathi, X. Duan, M. Mohammadi, A. M. Nasiri

"Direct metal laser sintering (DMLS) is a metal additive manufacturing technology that creates highly complex components by fusing metal powder into a solid part. In this study, the impact of surface roughness on corrosion resistivity of AlSi10Mg_200C alloy manufactured through DMLS was investigated. The as-printed DMLS-AlSi10Mg _200C alloy was subjected to various surface finishing processes including grinding and sandblasting. The corrosion performance of the surfaces was then evaluated using potentiodynamic polarization testing and electrochemical impedance spectroscopy (EIS) in a 3.5 wt.% NaCl solution to mimic seawater environment. Surface characterization and corrosion morphology of the samples were assessed by Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray (EDX) spectroscopy. The results of this study show that the surface finishing process and the resultant surface roughness has a significant impact on the corrosion resistivity of the DMLS-AlSi10Mg_200C alloy in the seawater environment.INTRODUCTION Direct Metal Laser Sintering (DMLS), also known as Selective Laser Melting (SLM) (Sames, List, Pannala, Dehoff, & Babu, 2016), Laser Beam Melting (LBM), or Laser Metal Fusion (LMF) (Herzog, Seyda, Wycisk, & Emmelmann, 2016), is an additive manufacturing process that utilizes a precise, high-power laser to micro-join powdered metals and alloys layer by layer to form almost fully dense and functional components in three dimensions from the 3D computer-aided design (CAD) data. Complex geometries not possible with conventional manufacturing processes can be readily manufactured with high accuracy using the DMLS process with no need to time-consuming tooling."

Jan 1, 2018

By S. J. van Rensburg

Competition for resources, including water and arable land, refocused attention on water and gold tailings management with respect to quantity and quality. MINTEK established and validated an "Advanced Leach Facility" to record kinetic leach information aimed at gold refractory sulphide ores. This facility was developed because of the need for additional leach process information to enable proactive decision making. Instead of focussing on optimised gold recovery only, the impacts of pre-oxidation methodologies were evaluated by considering key parameters, including cyanide speciation, reagent consumption, thiocyanate, arsenic, heavy metals, salt loads, water quality and residue stability. Results from oxidative leaching of a refractory gold ore employing oxygen, ozone, ultra-fine grinding, high shear and pressure oxidation are discussed. The relative cyanide and lime costs and environmental and sustainability effects associated with these technologies are briefly outlined.

Jan 1, 2011

By M. Leijd, K. S. Forrester, M. Saxon, M. Oczlon

This paper provides an introduction to wet high intensity magnetic separation (WHIMS) and its successful application to the beneficiation of rare earth element (REE) enriched eudialyte. The analysis includes an in-depth reporting of the deportment of key elements as well as a statistical interpretation of the relative importance of operational parameters including magnetic field intensity, flow velocity, and matrix loading density. Conclusions are drawn on the relative success of the technology, potential areas for process improvement, and the research direction that continues to be investigated. Three original equipment manufacturer (OEM) technologies were subjected to a series of screening and characterization tests to identify the optimal operating parameter set to magnetically beneficiate eudialyte from Norra Kärr, Sweden. Upon the completion of the characterization test it was apparent that the Metso HGMS technology was superior with respect to REE recovery and gangue rejection for the Norra Kärr composite. The Metso HGMS was then subjected to a series of verification tests to confirm the repeatability and reproducibility of the system.

Jan 1, 2014

By J. Oliveira, A. R. Barnes, R. Pandher

Sub-stoichiometric roasting of arsenic-bearing copper ores is a well established practice. However, ores containing calcium commonly prove challenging where very low arsenic levels are desired, but the reasons for this phenomenon have largely been speculative. In the course of treating arsenicbearing copper ores by partial roasting in fluid bed reactors, XPS encountered one of these Ca-bearing ores which proved a challenge to roast to acceptably low levels of arsenic. Mineralogical examination of the calcines using a combination of XRD (X-ray diffraction), QEMSCAN (Quantitative Evaluation of Materials by Scanning Electron Microscope) and EPMA (Electron Probe Micro-Analysis) helped to identify the arsenic bearing species and assisted in developing a workable theory on the sequence of reactions occurring during the roast. With the assistance of thermo-chemical modelling, this allowed adjustment of the roasting conditions to minimise the amount of arsenic retention in the calcine in spite of the presence of calcium in the ore and advance the roasting program to a commercially acceptable solution.

Jan 1, 2014

By Vic Casaletto

"IntroductionThe Canadian mining industry is under immense pressure to compete with foreign mine operations. The very survival of the Canadian mining industry is threatened by lower ore grades, environmental pressures, high cost of labour, unfriendly tax laws toward exploration and the increasing cost of new technology. In order to compete in the world market, Canadian producers and their suppliers are rethinking age old customer-supplier relationships in favour of preferred supplier relationships which can improve the profitability and enhance the competitive position of both partners.This paper attempts to redefine partnerships with suppliers in the context of a ""win-win"" objective. It will outline the measurable benefits to both partners through a representative product which highlights the keynote structure of any successful supplier partnership The Status Quo...Mines all over North America are plagued with the same recurring questions, ""Who has the best product for my operation at the lowest price... How do we know a product will perform to a supplier&apos;s projections after the sale...What do we do if the product fails to perform as expected?"" These questions have been asked by underground mining operators for decades but rarely have long-term solutions with measurable results been achieved.The LHD industry is one example of the status quo where partnerships will provide large gains toward technological advancement, reducing mobile equipment costs. The underground mining industry is out of sync with their surface counterparts in the open pit business.Partnerships with suppliers in the open pit world are not only a standard practice but a culture which has existed for decades. Open pit operators enjoy concepts which fix their mobile equipment costs for the life of the mine and hold the equipment supplier accountable for performance and fleet economics for 60 000 service hours and longer.Manufacturers are attempting to transfer this culture into the underground mining industry. Figure I illustrates the significance of a capital driven decision."

Jan 1, 1994

By R. A. McIvor, R. S. Rafuse

"INCO Limited purchased a custom designed mobile hoist rope winder/tensioner in 1988 from TimberLand Equipment Limited to handle Large hoist ropes and serve as an emergency hoist. This paper describes the operation of the winder/tensioner and some of the different applications that the machine has been used to handle large loads.IntroductionINCO Limited operates 24 mine hoists in the Ontario Division and has approximately 50 miles of mine hoist rope hanging in the shaft plus an equal amount on spare reels. The mine hoist ropes range in size from )( inch to 2.305 inches in diameter with the majority being 1 3/4 inches and above. Prior to the procurement of a new high powered winder/tensioner in 1988, the mine hoist ropes were handled with a variety of methods and equipment using hydraulic or pneumatic powered reel winders. The largest such reel winder has a pull rating of 8000 Ibs and travels approximately 40 ft/min. Head ropes for the tower mounted friction hoists were installed and removed using a magazine on the hoist drum to wind and unwind the rope because the loads were greater than the capacity of the existing machinery. It was recognized that a large high capacity machine would improve the productivity for handling the larger hoist ropes and a feasibility study was undertaken to determine the parameters for such a machine."

Jan 1, 1995

By M. Leroux, S. R. Rao, J. Kim, J. A. Finch

"Continuous in-plant testing of collectorless Cu/Pb bulk flotation on Lyon Lake ore at Matlabi Mines Ltd. Was conducted using a portable circuit based on 5 L mini flotation cells. It is concluded that collectorless Cu/Pb flotation is a reliable phenomenon for this ore over the usual range of plant operating conditions.IntroductionFlotation of some sulphide minerals without the use of conventional collectors (e.g. xanthates) is now widely recognized. The requirement appears to be some degree of oxidation, although the nature of the surface product formed is still uncertain (Luttrell and Yoon, 1984; Buckley and Walker, 1988). The phenomenon has been termed ""collectorless"" or ""self-induced"" flotation. One of the minerals most responsive to coUectorless flotation is chalcopyrite; in contrast pyrite and sphalerite show little response and galena usually shows intermediate response (Hayes et al., 1987; Shannon and Trahar, 1986).Most of the work on collector1ess l1otation has involved single mineral or batch flotation on ore samples. There are only occasional references to collector1ess l1otation under plant conditions (Sandstrom and Jonsson, 1988; Vargas, 1990; Boyce et al., 1970). Creating and maintaining the appropriate oxidation conditions and differences in water quality are among the reasons why the phenomenon may not transfer readily to the plant (Grano et al., 1990). Periodically from the spring of 1989, Mattabi Mines Ltd. ran full-scale tests of collector1ess bulk CulPb flotation while treating Lyon Lake ore*: the observations confirmed the laboratory finding that chalcopyrite and galena floated without collector (Leroux et al., 1989).To explore this finding continuous in-plant testing using mini flotation cells was conducted which is the subject of this paper. The main objective was to determine if collectorless flotation was a reliable phenomenon over the expected range of redox conditions in the feed pulp to bulk CulPb roughing. As background, the previous work (Leroux et al., 1989; Martin, 1988) is briefly reviewed."

Jan 1, 1994

By G. Landry

"IntroductionThe Cape Breton Development Corporation (CBDC) is constantly searching for new technologies that will enhance the marketability of its coal. One technology which shows promise in utilizing Cape Breton coal while at the same time addressing the traditional problem of high sulphur inherent in the Sydney coalfield, is coal-water fuel (CWF).The CWF process incorporates a physical change of coal by grinding it to a flour-like consistency and then mixing additives with it to make a fine coal slurry. The result is a liquid dispersion of fine coal particles that looks like oil, stores and flows like oil but burns like coal. The equipment used in the CWF process is standard mineral processing equipment but application of the equipment to manufacture a specific coal particle size and the specified additives used in the mixing make it a unique technology.The product, which CBDC calls Carbofuel, consists of 70% coal, 29.5% water and 0.5% chemical additives. The key properties of the product are: (I) high solids loading, (2) medium viscosity levels, (3) stability against sedimentation, and (4) good atomization behaviour. Carbofuel specifications are presented in Table I. Carbofuel ProductionThe production of Carbofuel is based on the controlled processing of coal. This involves wet grinding of the coal to a specified fine size (-250 um), cleaning this fine product to remove mineral impurities and formulating (with chemical additives) a finalproduct from the cleaned coal. The flow diagram in Figure 1 indicates the processing circuit for Carbofuel production.CBDC operates a 7-tonne-per-hour continuous production plant complete with state-of-the-art control, full laboratory services, product storage and loadout facilities. The plant has operated since 1983 and has produced over 12000 tonnes for several major demonstrations. The plant is shown in Figure 2."

Jan 1, 1987

By T. Sugawara, H. Sekimoto

Electrorefining of low-grade copper alloys containing various amounts of nickel, lead, antimony, bismuth, arsenic, selenium, silver, and gold in sulfamic acid media was demonstrated. The copper concentration of the alloys used as an anode was 70–90 wt%. The electrolyte contained 100 g L-1 of free sulfamic acid and 40 g L-1 of cupric ion. Galvanostatic electrolysis was conducted at 200–300 A m-2 in the electrolyte using a low-grade copper alloy anode and a stainless steel cathode at 25C. The terminal voltage was approximately 0.8 V at the start of the electrolysis, although it increased periodically to approximately 2.0 V and then shortly returned to its initial value. Nickel, lead, and arsenic from the anode dissolved in the electrolyte and were removed. Antimony, bismuth, selenium, and silver were removed as solids. Consequently, a dense copper cathode was obtained, and the concentration of copper was evaluated by inductively coupled plasma – optical emission spectrometry to be 99.82–99.99 wt%. INTRODUCTION Electrorefining of copper is conventionally carried out in a sulfuric acid electrolyte using crude copper assaying at 99.5 wt% Cu as the anode (Biswas & Davenport, 1994). Elements more noble than copper do not react anodically, and consequently, they are distributed in anode slimes. Elements less noble than copper dissolve from the anode. Nickel and arsenic are stabilized as aqueous species. Lead, antimony, and bismuth react with water, sulfuric acid, or arsenic acid to form barely soluble compounds; thus, they are distributed in anode slimes. An emerging issue in the electrolytic refining of copper is an increase of impurities in crude copper used as the anode (Moats et al., 2013). This is due to an increase in the content of impurities in copper concentrates as well as an increase in the types of secondary copper feedstocks (e.g., E-Scraps, automotive shredder residues, and smelting residues) treated in the copper pyrometallurgical process. An extreme case is a copper smelter that does not use copper concentrates as feedstocks. In such a process, copper-bearing feedstocks are smelted in a top submerged lance furnace to prepare low-grade copper alloys assaying at 80– 90 wt% Cu (Sekimoto et al., 2013). Such low-grade copper is not acceptable as an anode in the conventional copper electrolytic refining process because it is easily passivated during electrolysis. Consequently, electrolytic copper is produced by leaching the atomized low-grade copper in a sulfuric acid solution with oxygen, followed by electrowinning. However, electrowinning should be avoided whenever possible because the electrical energy consumed in electrowinning is 5–10 times higher than that consumed in electrorefining. Therefore, the development of technologies for electrorefining of low-grade copper alloys is desirabl.

Jan 1, 2019

By Dwayne D. Tannant

The Fox Pit at EKATI Diamond Mine reached a depth of approximately 150 m as of September 2005. The pit is designed with 11 m wide benches excavated using a double benching technique leaving 30 m high bench faces. A series of blasting tests were conducted to improve catch bench reliability and increase the percentage of benches that meet an 11 m catch width. The design changes focussed on reducing damage to the bench crest because maintaining the bench crests is the most important factor in achieving good bench reliability. The most significant improvement was obtained by raising the bottoms of the lower trim blastholes by 0.5 m. This change decreases the depth of broken rock below the final bench elevation, and consequently reduces damage to rock that forms the bench crest below. Another improvement was the use of smaller diameter (165 mm vs. 270 mm) blastholes in the A and B rows for the upper trim blast. This change reduces the charge per delay during detonation, reduces the powder factor slightly, and reduces the energy affecting the final pit wall and crest. As mining and the blast testing progressed, the portion of the bench with crest achievements (>11 m) increased from 57% to 75%.

May 1, 2006

By I. Stanoev, V. S. Stoilov, I. Gradinarov, E. D. Visariev, I. A. Bonchev, Aurubis Bulgaria

"Aurubis is the leading integrated copper group and the world’s largest copper recycler. In Copper smelter Aurubis Bulgaria (Pirdop), the residual copper in the slags from Flash furnace and Converters is recovered by flotation. The slag processing comprises: pit cooling, crushing, two stages grinding (autogenous and ball) and flotation. The copper concentrate is thickened and then is filtrated by vacuum disk filter. The thickener overflow is sent to settler for additional clarification. A resent throughput increase resulted in higher solid content in the thickener overflow due to insufficient thickener area. Different scenarios to overcome the issue were evaluated (new thickener, reagents and reconstruction). An increase of the thickening area by installation of lamella modules was chosen as the most promising option. Three lamella modules (1 m3 each) were installed in conventional thickener for the test. Number of sampling campaigns was done to evaluate the effect on solid content in overflow. Parameters of the dewatering cycle were collected during sampling campaign. The products grain size distribution was defined - thickener feed, thickener overflow with and without lamella. The thickener overflow with lamella modules has 2.12 g/L less solid content. The decrease was 71.8%. According to the tests results, the whole conventional thickener was reconstructed with lamella modules. The thickener area was increased by more than 400 m2.INTRODUCTIONIn Copper smelter Aurubis Bulgaria, the copper in slag from the Flash furnace and the Converters is recovered by flotation. The scheme of slag processing is crushing, two stage grinding (autogenous and ball) and flotation. Till 2010 the grinding cycle in the plant was in two stages: the first stage was AG Mill 70×23 working with a classifier and the second stage was ball mill 3.6/5.5 working with a hydrocyclone. In 2010 a new AG Mill 65×78 with hydrocyclone was put in operation in order to increase throughput of the plant. The second stage of the grinding cycle was not changed."

Jan 1, 2016

By Xiaoxing Hu, Guibing Zheng, Yangge Zhu, Xingrong Zhang

"In China, more than 90 percent of titanium resources are reserved in vanadic titano-magnetite deposits. In this type of ore, the same elements such as Ti, Fe, Ca, Mg exist on surface of both ilmenite and titanaugite (the gangue mineral) because of isomorphism, which makes selective flotation difficult. Therefore, how to enlarge the floatability difference between these two minerals has always been a research emphasis and still needs to be studied further. In this paper, the pre-treatment methods using ultrasonic wave were proposed. The results indicate that ultrasonic treatment shows beneficial effect to enlarge the floatability difference, and the effect will be strengthened by extending the ultrasonic treatment time or increasing the ultrasonic power. The mechanism was investigated through infrared spectroscopic (FT-IR) analysis. Collector interacts with Ca and Mg which results in titanaugite flotation, after ultrasonic treatment, the dissolution of Ca and Mg is intensified, which leads to the lack of active points on mineral surface, so the floatability of titanaugite is depressed. Meanwhile, collector mainly interacts with Fe which results in ilmenite flotation, and the present of ultrasonic might promote its oxidation (Fe2+ to Fe3+), so the floatability of ilmenite after sonication is increased.INTRODUCTIONUltrasonic is the sound wave with frequency of 2 × 10-4 Hz~2 × 10-9Hz. Since the first International Symposium of Sonochemistry in 1986, the application of ultrasonic wave is more and more extensive. In researches about mining and metallurgy, various investigators have shown that intensive acoustic fields can modify the state of a mineral, leading to chemical or dispersive effects. Generally, the effect of ultrasonic vibration depends upon the nature of the mineral and also the way ultrasonic wave is applied (Celik, 1989; Ozkan, 2002). In addition, ultrasonic treatment usually plays roles of removal of reagents adsorbed layer from minerals and emulsification of flotation reagents when it is used in flotation (Nicol, Engel, & Teh, 1986; Slaczka, 1987; Djendova & Mehandj, 1992; Farmer, Collings, & Jameson, 2000; Gurpinar, Sonmez, & Bozkurt, 2004)."

Jan 1, 2016

By O. Laitinen, M. Rudolph, J. A. Sirviö, H. Liimatainen, R. Hartmann, University of Oulu

The increasing complexity of the ores composition worldwide calls for suitable collectors with specific properties, such as selectivity, wettability, and in regard to current regulations, environmental sustainability. Therefore, collectors have to satisfy many features to improve the efficiency of flotation processes. Cellulose nanocrystals gain more and more interest due to the versatile synthesis routes which enable the integration of specific functional groups and components with different degrees of hydrophobicity within the molecular structure. Consequently, cellulose nanocrystals can be employed in flotation processes as depressant or collector molecules, respectively. Nonetheless, the usage of cellulose nanocrystals is still limited due to a lack of the characterization of nanocrystal-mineral interactions and the change of the surface wetting properties of minerals after adsorption phenomena between nanocrystals and minerals. In these studies, butyl-amine cellulose nanocrystal (BAC) and quartz are used as model system to investigate physicochemical properties of both, BAC and quartz, and examine the applicability of BAC in flotation processes. Therefore, the surface charge distribution and electrophoretic mobility of BAC and quartz are investigated and compared to understand the effect of electrostatic interactions between BACs, and BAC and quartz. Based on this, the adsorption of BAC on quartz is examined. Finally, microflotation experiments test the efficiency of BAC to be used in flotation processes. The flotation response is correlated to the specific surface charge of BAC revealing the dominant effect of surface charges on effective particle-bubble adhesions.

Jan 1, 2016