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By Diego L. Romero, Joy P. Romero

"IntroductionMinerals may be classed broadly as ferromagnetic (magnetite for example), as paramagnetic (attracts to regions of magnetic field convergence) and as diamagnetic (attracts to regions of magnetic field divergence). High-intensity separators are not necessary to separate ferromagnetic minerals from other classes. Rather, low-intensity units that generate fields below 5000 gauss are adequate for this purpose. However, paramagnetic minerals, such as ilmenite, with high magnetic ""attractability"" require fields of up to 10 000 gauss; those with low attractability may require even higher fields. Table 1 shows approximate ranges of field intensities necessary to separate ferromagnetic and paramagnetic minerals from minerals of lower attractability, along with the force with which they are attracted relative to iron in a standardized magnetic field.Uniform magnetic fields, not useful for separators, are generated between flat parallel surfaces; non-uniform fields, useful for separators, arise when at least one of the surfaces is of irregular shape. The diagrams below show how magnetic lines of force align relative to north and south poles.If a particle is placed in a uniform field, it feels no displacing force unless the particle distorts the applied field assymmetrically. This is not the case in non-uniform fields which are required for magnetic separators.Magnetic fields can be generated by permanent magnets (low intensity), by electromagnets (medium and high intensity) and even by superconducting coils (100 000 gauss fields and higher), although the latter are not as yet useful in production environments .The magnetic force of attraction per unit of mass, that acts on a paramagnetic mineral such as hematite, increases in proportion to the strength of the field . Unfortunately, the highest fields attainable with electromagnets is of the order of 20 000 gauss. Fortunately, the gradient of the fie ld (that is, the degree of convergence of magnetic lines of force) is important, because the attractive force per unit mass is proportional to it also . This can be stated:"

Jan 1, 1989

By M. Tanaka, H. Narita, T. Fuchikami, K. Morisaku, K. Nagao, T. Yoshida, K. Kuroda

The effect of various N-substituents on the performance of amide-containing tertiary amine compounds in the extraction of Rh(III) from HCl solutions was investigated to optimize the structure of these compounds for industrial use. It was found that N-2-ethylhexyl-bis(N-di-2-ethylhexyl-ethylamide)amine and tris(N-di-2-ethylhexyl-ethylamide)amine, which have long, branched alkyl chains, were suitable for Rh extraction, because they were soluble in a practical diluent (80 vol% n-dodecane?20 vol% 2-ethylhexanol) and stable against highly concentrated HCl/Rh solutions, and showed high selectivity for Rh(III) over Pd(II) and Pt(IV).

Jan 1, 2014

By O. Lashkari

Swirled Enthalpy Equilibration Device (SEED) is a new patented Slurry-on-Demand, SoD, processing route. The semi-solid slug preparation is carried out by off-center swirling of aluminum melt in a metallic mould. As part of the current research program on the semi¬solid processing of aluminum alloys, the morphological evolution of 356 aluminum foundry alloy microstructure is reported here. Semi-solid slugs were prepared using two different pouring temperatures of 645°C and 695°C respectively. Morphological evolution of the semi-solid microstructure was characterized using image analysis through measuring of primary a-Al particle size, number density, aspect ratio and sphericity. The possible relationships between microstructural features and process parameters were also investigated. The current report covers the effect of pouring temperature on the morphology of primary a-Al dendrites and attempts are made to explain the differences between the predicted percentage primary a-Al phase and those of the actual values in the as-cast slugs.

Jan 1, 2004

By Si Qin

Unknown goafs and roadways of abandoned coalmines can be a great water inrush hazard for coalmine workers. Consequently, advance detection of such hazards is of great importance. By detonating seismic charges in underground coal seams, we can collect seismic data using a surface survey line, which is located across the ground projection of the underground shot point. This experiment was conducted in a coalmine in Shaanxi Province, China. After surface elevation compensation and travel time adjustments, we accurately determined the position of the goaf boundary along the survey line based on the wave velocity anomaly on the seismic record. Then we used a scattered wave imaging technique to enhance the energy of the scattered waves that are generated when the coal seam roof slide wave (refracted wave when the incident angle bigger than the critical angle) hits the roadway, thus confirming location of a geological discontinuity (roadway). This experiment shows that the coalmine ground seismic method, employing an underground explosive charge and a surface seismic array, has the ability to detect an abandoned roadway and goaf in advance of coal mining, thus can improve worker safety.

Aug 1, 2013

By S. Vaidya, R. C. McKellar, N. K. Sinha

Nominally [001]-oriented nickel-base single crystal (SX) superalloy CMSX-10 was investigated at 900°C under constant load, equivalent to an initial stress of 700 MPa, for creep strains from 7% to fracture strain (18.2%). The cross-sectional dimensions of initially uniform cylindrical specimens were measured along their entire length after the tests. The cross-section changed from circular to near elliptical shape. The anisotropic deformation, measured in terms of eccentricity, increased with the increasing strain level, but for a given strain level, it remained constant along the entire length of the initially uniform gauge section. The results are discussed in terms of diameter, eccentricity, area, local stress and microstructural observations. The most striking observation was the fact that all the specimens displayed a yoke-like shape, or the reduction of cross sectional area, at two locations within the originally uniform gauge section. Such observations have not been reported in the literature for single crystal superalloys.

Jan 1, 2006

By K. N. Subramanian, H. Kanduth

"It is well known that chalcopyrite can be dissociated into simple sulphides by heating with elemental sulphur at about 475°C:CuFeS2 + S -> CuS + FeS2Experimental work was undertaken to determine whether this ""activation"" could be used to advantage in the selective leaching of copper from chalcopyrite concentrate.A method of treating copper concentrate with molten sulphur was developed and the activated product was leached in dilute sulphuric acid using oxygen, ferric iron or manganese dioxide as the oxidant. The object was to obtain a solution suitable for electrowinning with minimal purification, but it was impossible to obtain rapid extraction of copper without simultaneously dissolving a large proportion of iron. This was attributed to the fact that some of the copper was present as a low iron-copper sulphide (idaite) and that the pyrite formed during the ""activation"" step was more easily oxidized than natural pyrite."

Jan 1, 1973

By Agbo Chima

Low-lying sections of open-pit mines accumulate water, especially during the rainy seasons, preventing access to resource-bearing areas. To sustain mining operations, the water must be lifted out of the flooded pits at a high flow rate using pumps. These pumps need to be mobile so that they can be removed during drill-and-blast operations. Most mobile pumps rely on diesel engines with high maintenance requirements. A special pump design was developed to address the unique needs of open-pit mining while making the dewatering process more sustainable. Using the target flow rate and head data, an efficient pump was designed, encased, and deployed in the open pit. A variable speed drive (VSD) was installed in a protective skid so that the pump could be tuned to match the preferred flow rate at any point during its operation. This system was tied to the national electrical grid instead of being powered by diesel pumps, which reduced the carbon intensity per kilowatt-hour. The high availability, low maintenance requirement, and greater reliability reduced the use of spare parts, the fuel consumption, and the logistics associated with operating the pump. This further reduced the carbon footprint of the dewatering process. This paper provides some of the two-year performance metrics for a deployment in West Africa. With a focus on availability, maintenance costs, average cost per volume lifted, and carbon footprint, this encased pump system is compared to the diesel-driven pumps that it aims to replace.

Jan 1, 2023

By Philippe V. Scheers

Polycrystalline gold, glassy carbon and gold-activated glassy carbon electrodes were compared for the production of hydrogen peroxide by the cathodic reduction of dissolved oxygen. Gold was deposited on glassy carbon by sputtering with a sputter coater and by electrodeposition from a diluted KAuCl4 solution using short potential steps. The sputtered gold particles were not adherent enough, but there were no adhesion problems with the electrodeposited gold particles. The gold coverage of the glassy carbon surface could be varied by applying a different number of potential steps. The overpotential for the electroreduction of oxygen to hydrogen peroxide decreases with increasing gold coverage of the glassy carbon surface, and for gold coverages exceeding about 16 %, the overpotential is close to that observed on polycrystalline gold.

Oct 1, 2003

By R. Cottam

The deformation and recrystallisation of magnesium yttrium alloys containing 0.23, 0.84 and 2.71wt% yttrium and commercially pure magnesium extrusion has been investigated at temperatures between 200 and 350°C. The alloys were produced as billets 7.5 cm diameter, solution treated at 525 °C for 8 h and extruded into 3 cm diameter bar at 390°C. Channel die compression was employed to deform the samples at a strain rate of 1x10-3s-1. For the 0.23 wt% yttrium alloy and the pure magnesium, dynamic recrystallization (DRX) occurred at all temperatures and the amount of DRX increased as the temperature was raised. In the alloys containing 0.84 and 2.71 wt% yttrium DRX was almost completely suppressed at all temperatures. The absence of DRX in the 0.84 and 2.71 wt% yttrium alloys was accompanied by a decrease in the ductility, except at 350°C the highest deformation temperature. It was observed that this increase in ductility was accompanied by a reduction in deformation twinning and the initiation of pyramidal slip. This work highlights the important role that DRX plays in enhancing the ductility of magnesium alloys.

Jan 1, 2006

By Masatsugu Morimitsu

This paper introduces new technology of oxygen evolution anodes which can be applied to produce copper, zinc, cobalt, and other metals by electrowinning. The anode consists of nano iridium oxide particles dispersed in amorphous tantalum oxide matrix as a catalytic layer formed on a titanium substrate. The anode can reduce oxygen evolution potential by 0.25 to 0.55 V compared to commercially available lead alloy anodes and can suppress unwanted side reactions such as manganese oxyhydroxide, lead oxide, cobalt oxyhydroxide which occur during oxygen evolution in the electrowinning solutions. This technology is effective for environmentally friendly electrowinning processes with low energy consumption and less anodic deposition.

Jan 1, 2011

By G. T. Lapidus, R. M. Luna-Sánchez

In the present study, a series of cyanidation experiments were performed on a bulk sulfide concentrate which contained silver in four distinct phases, to determine its extraction rate, varying the oxygen concentration. The results showed that three of the four phases were refractory, aguilarite (Ag,iSeS) being the only leachable phase, and that the effect of the oxidant concentration is minimal. Mathematical simulations were performed, adjusting only the Damkohler number to adequately fit the experimental data. This model, and the mechanism implied, was compared with that found for acanthite (Ag2S) in a previous study, and the differences between the two discussed.

Jan 1, 2005

By Y. X. Li, L. R. Xiao, S. Gong, S. S. He

Porous copper and porous copper based alloys with controllable pore structure have been manufactured successfully by sintering evaporation process. This process consisted of mixing copper or copper based alloys with NaCl powders, hot pressing and final high-temperature sintering to evaporate the filler material of NaCl powders. NaCl was eliminated completely during vacuum sintering, and strong metallurgical bonding in the walls was achieved. The pores’ structural parameter (pore size, shape, and direction) and porosity can be controlled effectively. These porous copper and porous copper based alloys with controllable pore structure have great potential in many fields. Including heat dissipating materials, heat absorbing materials, chemical catalyst carriers, electromagnetic shielding materials, filtering materials, damping materials, silencing materials, battery electrode materials. INTRODUCTION The development of porous materials began in the 1960s. The research of activated carbon with high specific surface area made porous materials enter the stage of material research (Belyakov et al., 2008; Ferey et al., 2008). With the rapid development of science and technology, porous materials play an important role in material research, and gradually become an indispensable part of the material research field (Wu et al., 2012). The research of porous materials has gradually extended to metal, ceramics, plastics and glass and other fields. It has been successfully applied in many fields, such as functional materials, industrial production, aviation, medical materials, biochemistry and electronics, which fully shows that porous materials have considerable development prospects. Porous silicon, plastic porous materials and glass porous materials are the most widely used in the field of non-metallic porous materials (Capelle et al., 2012). Compared with non-metallic porous materials, metal porous materials have developed rapidly in the late 1980s and become new materials with good mechanical properties and excellent physical properties. Porous metal materials have many advantages, such as large specific surface, small specific gravity, good silencing effect, high stiffness, high electromagnetic shielding performance, good shock absorption performance, etc (Li et al., 1999; Ferey et al., 2008). Among its many applications, metal porous materials can be used as both functional materials and structural materials. In some cases, metal porous materials have dual functions and structures. It is a multi-purpose engineering material with excellent performance. At present, porous copper, porous aluminium and porous nickel are the most concerned materials (Chen et al., 2002; Yang et al., 2017; Liu et al., 2018). The preparation methods of porous copper and copper-based alloys mainly include self-propagating high temperature synthesis (SHS), capsule-free hot isostatic pressing (CF-HIP), spark plasma sintering (SPS) (Kvanin et al., 2008; Takahashi et al., 2008; Zhang et al., 2014). However, these methods can not accurately control pore structure parameters (including pore size, shape, orientation, distribution, etc.). In porous materials, pore structure plays an important role in the overall performance of materials. In order to control pore structure parameters accurately and optimize material performance, it is necessary to explore and develop new preparation technology. In this paper, the sintering evaporation process (SEP) was introduced for the preparation of porous copper and copper-based alloys. The core process of the preparation method is hot pressing and evaporative desalination. Hot pressing can make the pore orientation consistent. Evaporative desalination can ensure the complete removal of NaCl in the form of vapor in a short time, thus eliminating the corrosion of residual NaCl on the matrix metal (Gong et al., 2011).

Jan 1, 2019

For the last few years, a new and innovative technique has been successfully used to determine refractory and castable thickness in various metallurgical vessels. The acousto ultrasonic-echo (AU-E) technique uses stress waves to detect metal penetration and delaminations within refractory linings. In addition, it is capable of measuring the thickness of refractory layers and build-up material. The inspection and measurements can be carried out while the furnace is in full operation. The present paper discusses the principles of the AU-E technique, and its advantages and limitations. A number of case studies are presented to demonstrate various capabilities of this new Non-Destructive Testing (NDT) technique.

Jan 1, 2005

By K. G. Markkola

The Minera Candelaria concentrator was commissioned in August 1994, and in October 1997 it doubled its grinding capacity. The concentrator was designed to treat 56,000 metric tonnes of copper ore with a primary crusher, two grinding circuits, pebble crushing, and flotation. The grinding circuit includes two 11.2 m (36 ft) diameter by 4.6 m (15 ft) long semi-autogenous (SAG) mills, each fitted with a 12 MW motor. Throughout the history of Candelaria, different strategies have been developed to maximize the plant's operational time, strategies that include increasing the life of the SAG mill liners and reducing the time involved in changing these elements. This work describes the improvements made in the design of the liners, the change planning, and a new strategy to change the liners with the purpose of increasing their use and throughput.

Jan 1, 2007

By Man-Chao He

One of the critical problems involved in deep coalmines is unusual gas emissions. Many researchers agree that there is a relationship between coal gas emissions and geological features such as tectonics or geological disturbances, gas content, properties of the coal and rock and the mininginduced stress state in the coal seam and rock. Thus, the present paper intends to investigate complex mechanical phenomena during the process of gas emission in underground coal-mines. A program of laboratory testing was undertaken to study the effects of temperature and pressure on mechanisms of gas emission. It must be noted that this paper describes new techniques developed to simultaneously measure deformation and gas pressure, as well as flux during the test, taking the characteristics of gas transport into consideration under certain temperature and pressure conditions. The results indicate that under certain temperature and pressure conditions, gases adsorbed to coal start to desorb, and increase the pore pressure. High pressure gases entering coal fractures can generate high tensile stresses near the crack tips, leading to crack propagation and coalescence, which in turn can cause the specimen to dilate. From the experimental viewpoint, these test results may help us discern why mining seismic events can trigger gas emissions.

Aug 1, 2013

By A. G. Beer

The evolution of microstructure is examined during the annealing of hot worked magnesium alloy AZ31. The influences of deformation and annealing conditions on the developed microstructures are assessed. It is found that annealing at a low temperature (300 °C), after deformation at a low temperature and strain rate (300 °C and 0.001 5-1 respectively), results in the development of abnormally large grains. With increasing values of Z (lower temperatures, higher strain rates), static recrystallization of the dynamically recrystallised structure takes place; smaller annealed grain sizes are attained and the time at which coarsening begins is reduced. Whilst both the deformation and annealing conditions influence the time it takes to reach a stable annealed microstructure, the grain size attained is governed solely by the prior deformation conditions employed.

Jan 1, 2006

By J. Satur

In copper mineral processing, pyrite coexisting with copper sulfide minerals like chalcopyrite is separated by flotation as tailings and its oxidation in tailing dams causes the formation of acid mine drainage. This paper proposes carriermicroencapsulation (CME) as a new method for suppressing pyrite flotability, as well as its oxidation. In this method, an organic carrier combined with Ti is used to form a thin Ti02 layer on pyrite, which gives a hydrophilic property and acts as a protective coating against oxidation. To form the coating, a ground pyrite sample was treated with Ti-catechol complex solution under various conditions. Bubble pick-up experiments and flotation experiments showed that the treatment of pyrite with Ticatechol complex changed the hydrophobic nature of pyrite into hydrophilic even in the presence of xanthate as a flotation collector. Oxidation testing of the CME-treated pyrite by 0.02 kmol m-3 HN03 showed that Fe release was suppressed by the CME treatment with respect to the control. This is assumed to be due to the formation of Ti02 coating on the pyrite surface. The effect of CME treatment on chalcopyrite wettability is also discussed.

Jan 1, 2007

By R. O. Grieve

"IntroductionCALEY (1945) and Evans (1950) pointed out that certain instances of convergence between Devonian and Silurian horizons, frequently evident in wells drilled for oil and gas in Ontario, appear to be related to local thinning of salt beds in the Salina formation and they suggested that leaching of the salt beds may have occurred. Exploratory drilling by Imperial Oil Limited since 1945 has brought to light several examples of structures similar to those discussed by Caley and Evans. The writer has had the opportunity to examine cuttings and data from wells which penetrated these structures and the attempt to interpret them in the light of the theory of leaching and subsidence proposed by Landes ( 1945a) to explain the marked brecciation and deformation of Upper Silurian and Middle Devonian sediments which crop out in the Mackinac Straits region of northern Michigan has led to the observations presented in this paper."

Jan 1, 1955

By F. Pinto, C. A. Prato, R. J. Rocca, P. F. J. Huerta Soaje

"The seismic hazard for civil engineering structures is generally defined in terms of deterministic or probabilistic acceleration response spectra at an equivalent rock outcropping. The design of tunnels, however, requires the definition of demands in terms of accelerations at ground surface (near the portals) and in terms of both accelerations and velocities at different depths within the alignment. The design near the portals is controlled by inertial effects and is often times impacted by the possibility of slope instability and rockfall, whereas the design at deep sections is controlled by kinematic effects. These effects are accounted for in practice by introducing deformation patterns in the structure that are related to an assumed wavefield, often times ignoring the effect of the structural stiffness in the response. This paper presents a study regarding the definition of seismic demands for different sections of 14-km long tunnel in the Andes (Argentina-Chile), with a maximum overburden of 1750 m in a seismically active region. The tunnel will pass through volcanic massifs mainly composed by andesites and rhyolites.The study includes the definition of spectrum-compatible seismograms, deconvolution, and definition of accelerations and peak particle velocities for different overburden conditions. A kinematic interaction study for a 500-m tall ventilation chimney shaft is also described, where a simple formulation for the interaction analysis is considered in order to more accurately evaluate shear and bending demands. INTRODUCTIONThe seismic design of linear underground structures, such as shafts and tunnels, generally considers the inertial forces near the shallow sectors (e.g., portals) and the kinematically imposed deformations for the deep sections (e.g., Hashash et al. 2001). The inertial forces are often times evaluated on the basis of design spectra recommended by seismic hazard studies. The kinematic demands for the deeper sections, however, needs to be defined in terms of additional information which is not always indicated by the seismic hazard studies, e.g.; peak particle velocities and accelerations, and their variation with depth. These parameters can be determined by means of a site response analysis, whereby outcrop motions can be deconvoluted in order to evaluate motions inside the ground mass (e.g., Schnabel et al., 1972). Hashash et al. (2001) defines factors that may be used in order to account for attenuation of motions inside the ground mass. However, these factors are provided for depths up to 30 m only, whereas depths of tunnels structures can range up to thousands of meters."

Jan 1, 2015

By Asbjørn Solheim

The service life for aluminium reduction cells is often limited by the cathode carbon, due to preferential wear along the periphery of the cell leading to the so-called "W" wear pattern. The reason for this preferential wear is not well understood. Two mechanisms are suggested in the present paper; 1) non-stationary dissolution of aluminium carbide into a layer of sludge that periodically forms and disappears, and 2) electrochemical formation and dissolution of aluminium carbide within an aluminium carbide layer containing bath-filled pores. The latter mechanism may be related to the high local current density at the periphery of the cathode.

Jan 1, 2011