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By F. W. Wellmer

"I would like to comment on the classification scheme of ore reserves based on geestatistical and economic parameters as proposed by Wober and Morgan in the CIM Bulletin, January 1993.In principle, a classification system that combines quantitative data for levels of confidence and errors with economic expectations must be welcomed. I would like to point out, however, two aspects of the proposed classification system which might create ambiguities, and therefore problems, by working with two levels of confidence and two kinds of block sizes. A normal classification scheme reflects the information density, the highest reserve category such as class A, or proven, or measured reserves having the highest density. This is not necessarily the case in the scheme of Wober and Morgan (1993), unless the definitions are amended.I. Assuming, as the authors do, that the estimation errors show an approximately normal clistribution, at the 95% confidence level, the standard deviation has to be multiplied by about 2 for the error and, at the 84% confidence level by about 104. Reserves (or resources) with the same or even higher information density than class A reserves, which at the 95% confidence level would not fulfill the required economic criteria at the threshold level, i.e. not qualify as ""ore"" at all, could be retained ""on paper"" to class B reserves by just multiplying the standard deviation by the factor 104 instead of 2, thereby narrowing the error.This statistical ambiguity was partly inherent in the old German classification scheme which used varying confidence levels and errors (GDMB 1956; Jahns 1959). In the new German scheme, which was later adopted in Austria in a moclified version, the level of confidence was therefore fixed at 90070 for all reserve categories (Wellmer 1983; ONORM 1989)."

Jan 1, 1993

By A. Kozlowski

We present research on cable fault location methods for mines where coal dust and methane explosions are a frequent potential hazard. The methodology and devices for low- and medium voltage cables fault location are well known and applied in classical power distribution networks. They are based on solutions for underground mines with a high risk of explosion. The lack of a safe solution for the location of a fault has contributed to the initiation of a research project by a group of Polish companies. The consortium consists of research institutes (Institute of Innovative Technologies EMAG, Tele and Radio Research Institute, Central Mining Institute GIG-KD ?Barbara?), Silesian University of Technology and a private entrepreneur MARTECH PLUS. Fast and exact determination of fault location is one of the important factors for minimizing power outage time. The lack of technical solutions to obtain measurements in a secure way leads to the use of the methods connected with a high risk of explosion. For example, the application of high energy can lead to arc discharge where there is a fault in insulation, creating the risk of an explosion. Measurements of methane concentration along the analyzed section of the cable reduce the risk; however the shock wave generated by the electric arc may raise coal dust and make an explosive mixture, which is an object of ignition. Low energy methods, like those based on reflection waves, have low sensitivity for high- and medium-resistance faults. This technique has difficulties in joints, which create false echoes. The fundamental problem is to determine the topology of the network using a reflectogram and find anomalies of a different nature ? not only open and short circuit. Included in the scope of the project is an analysis of Polish legal regulations related to fault location and operational work for low- and medium-voltage networks. Two of the methods used on the surface were selected as feasible to implement under explosion hazard conditions. In the process of development of the fault location methodology, installation features characteristic of underground mines were used, namely access to the whole length of a cable. This is the attribute that provides an opportunity to do measurements that are usually not possible for typical surface power nets. To carry out laboratory tests, a dedicated measuring stand with various types of cables was built. The authors describe the principle of operation of the fault locator and the results of the laboratory tests carried out on the cables with built-in damage (prepared for tests). Results of the work will be the basis for the next stage of the project associated with operational analyses of the prototype.

Aug 1, 2013

By Arnold R. Miller

Overview ? Vehicle Projects LLC (prime contractor) and the Fuelcell Propulsion Institute have developed the world?s first fuelcell locomotive. ? Principal applications are underground mining and tunneling. ? Because fuelcell vehicles solve the problem of underground emissions, mining is expected to be their first commercially viable market. ? The first year of a three-year project to develop a fuelcell mine loader is funded and underway.

May 1, 2002

By D. Monder

Fuel cells are promising sources of electrical energy because of their exceptionally high efficiencies and low environmental emissions. Solid oxide fuel cells (SOFC) are high temperature, ceramic electrolyte cells, which unlike most other fuel cells, can work with a variety of fuels besides pure hydrogen, including hydrocarbons and hydrogen sulfide. In this presentation I present the models we have built for a single H2S fuelled SOFC. The goal is to model the electrochemical reaction coupled with mass transfer, fluid flow and current/voltage distribution in an yttria stabilized zirconia electrolyte fuel cell assembly operated between 750 and 850 °C. Two models of the above SOFC are discussed in this work, 1) an algebraic model derived by integrating a one-dimensional model along the thickness of the cell, and 2) a two-dimensional finite element axi-symmetric model. Important physical and kinetic parameters in the 1-D model are fitted using experimental data sets at three different temperatures and reasonable fits are obtained for the data sets at 800 °C and 850 °C. However, the third data set at 750 °C does not give a good fit using this model. We need to apply the curve-fitting to more data sets to investigate it further. The main conclusion that can be drawn from the present study is that the ohmic resistance of the cell is very high. Contact resistances are believed to be the reason behind this although there could be contributions from resistive interphases. The 2-D model also gives reasonable fits to data sets. One of the publications by the laboratory group doing the experimental work in our department presented very interesting data that shows the cell performance being a strong function of fuel flow-rate. We want to model this behaviour and will have to depend on the 2-D model as the 1-D model does not have flow-rates as parameters.

Jan 1, 2005

By Janne Karonen, Stephen Hughes, Mikael Jåfs, Jan Stål, Hannu Johto

End-of-life electrical and electronic scrap material attracts attention as a good opportunity for new value creation through efficient metal and energy recovery of such materials. On the other hand, the treatment of such wastes becomes important to avoid problems for society and environment. Treatment of such secondary raw materials faces multiple challenges due to their increasing complexity and evolving nature. Processing of these complex scrap materials together with recovery of a wide range of valuable metals with a combination of pyrometallurgy and hydrometallurgy using Outotec technology is discussed in this paper. One key consideration is environmental performance which needs attention when processing such complex secondary E-waste materials. Outotec has successful experience with commercial projects in the countries at the forefront of environmental and operational standards. INTRODUCTION Increasing attention has been drawn to the responsible processing of end of life Waste Electrical and Electronic Equipment (WEEE) as part of metals recycling, especially copper. It has been estimated that the amount of WEEE globally in 2016 was around the level of 46 Mtpa (Balde et al., 2017), representing a major disposal challenge but at the same time huge opportunity for resource recovery. The potential for increasing the recovery is high, because the official recycling rate of WEEE is in 2016 only 20% (Balde et al., 2017) and at the same time the estimated increase of the WEEE amount is between 3 and 5% per annum in the EU (Eurostat, 2019).

Jan 1, 2019

By C. Caners

One of the main uses of fossil fuels is in the transportation sector, leading to environmental consequences such as climate change. In order to move towards a more sustainable energy infrastructure, a transition must begin from fossil fuels to renewable fuels, derived from e.g. biomass. One means of facilitating this transition is to develop reforming technology that can extract hydrogen from a suitable fuel that is either fossil fuel or renewable in origin. The hydrogen would be feed to a 'fuel cell' engine that would power the car, truck or bus. One reforming technology that is attractive for automotive applications is autothermal reforming (ATR). Autothermal reforming is the combination of steam reforming and partial oxidation, whereby a portion of the fuel is combusted using a sub-stoichiometric amount of air, and the resulting thermal energy drives the more desirable steam reforming reaction. ATR is attractive for fast start-up, rapid load following and ease of control. ATR also has the benefit of smaller volume and fewer peripheral requirements as compared to other reforming technologies. Recently, a bench-scale gasoline autothermal reformer (ATR) was constructed and tested. This ATR employs a novel design, consisting of three concentric annuli in order to promote heat transfer from the partial oxidation reaction to the steam reforming reaction. Concurrently, a CFD based model (FLUENT) of the ATR that considers the geometric complexity of the reformer was validated. In spite of the use of simplified kinetics, the model predicted well the observed trends in temperature and overall performance. This paper will discuss the use of the model to improve the design of the ATR. The impact of various system parameters upon performance will be investigated along with alterations in the geometry of the ATR. The various tradeoffs in performance and system volume/size will be highlighted in the context of a fuel cell power system.

Jan 1, 2005

By Aleksandar N. Nikoloski, Tendekayi Tapera, Glen P. O’Malley

Chalcopyrite (CuFeS2) and enargite (Cu3AsS4) are among the most important copper sulfides. At present, many known deposits of these minerals are uneconomic to process because they are of too low grade, insufficient size or too remote to be cost effectively treated with conventional technologies that can deal with their refractory nature. Therefore, developing an effective, low cost extraction process for recovery of copper from them is important. The research presented in this paper will deal with potentially cost effective strategies involving catalysed processing, studied under conditions relevant to recycle heap leach conditions. The present account summarises some of the main findings from the research program carried out at Murdoch University between 2014 and 2018 that has investigated the effects of the common leaching parameters, major and minor species present in the leach system and additives on the rate and extent of copper extraction from low-grade ores, in which primary copper sulfide minerals such as chalcopyrite and enargite were the dominant copper minerals. The study involved batch leaching tests, detailed structural and mineralogical characterisation and thermochemical modelling under conditions relevant to heap leaching. The results have demonstrated that silver in particular has a strong catalysing effect on the extraction of copper from ore under the leach recycle conditions and, at an adequate dosage, can effectively overcome surface passivation, enabling almost complete extraction of copper from chalcopyrite as well as enargite. The aim of this paper is to present the effect of the studied additives and to briefly elaborate on the mechanism of the silver catalysed leaching process. In addition, the presence of certain secondary agents was shown to lower the critical dosage of silver and promote extraction. The data from the study allowed the development of a theory for the silver catalysed reaction mechanism, which enables further optimisation and cost-effective application of this strategy in practice. INTRODUCTION Researching the extraction of copper from chalcopyrite is important as it is the most abundant copper mineral in the earth’s crust. The majority of ores containing this mineral are processed by flotation to produce a concentrate, followed by smelting and electrorefining. However, most reserves available nowadays are of low grade or limited in size, and therefore not suitable for this conventional approach. Hydrometallurgical processing via heap leaching with or without the aid of bacteria has been shown to be potentially economical. Chalcopyrite is refractory though and suffers from slow leaching kinetics and poor overall extraction, so understanding the mechanism of how it leaches has received significant attention by researchers working in this field over the past 50 years. The refractoriness, which is the main issue with the hydrometallurgical approach, is generally described as passivation of the chalcopyrite surface whereby a surface coating is formed that blocks the reaction interface or wetting of the chalcopyrite, limiting the copper extraction. Exactly what this layer is made of or how the issue could be overcome has been the subject of intense study and debate for many years. One of the limitations of the work to date is that much of the research focus has been on typical initial leaching conditions, while there has been relatively little research into how the leaching is affected under recycle solution conditions where certain metal ions (Fe, Mg, Al) have often accumulated in the liquor. This occurs because the leach solution exiting a heap contains many species from the dissolution of gangue minerals and typically this solution is returned to irrigate the heap, once the copper has been removed, leading to an accumulation of these species.

Jan 1, 2019

By Z. Zhong, Y. J. Hu, D. Elsworth

"A standard triaxial apparatus was set up to perform sliding tests. Slide-hold-slide (SHS) tests, with hold times from 10 to 3000s and at invariant effective confining pressures of 1MPa, incremented to 3MPa and then 5MPa, were conducted on both dry and wet split limestone samples to study the evolution of fracture friction under holding and sliding processes. Limestone fracture shows time-dependent behaviors in SHS tests, friction drops (creep) gradually during hold periods, and recovers (healing) after re-slide. Frictional healing and creep increment are proportional with hold times, while are inversely proportional with effective confining pressures. Moreover, the wet sample displays heavier healing than the dry one, whereas creep increment of the wet sample is lighter than the dry one. We conclude that the evolution of limestone fracture friction is significantly controlled by mechanisms of fluid-rock interactions.INTRODUCTIONThe evolution of the mechanical properties of fractures and faults exerts a critical influence on the behavior of fault zones and on the earthquake cycle. In addition to natural processes, this behavior has broad implications in induced seismicity and influences oil and gas production, the sequestration of carbon dioxide and the disposal of nuclear wastes.Fault friction is typically measured by slide-hold-slide experiments, where fault gouge is deformed at low velocities (<0.1 mms-1) and over small shear offsets (<30 mm) (Dieterich, 1979, 1981; Mair et al., 1999; Marone, 1998, 2004) or alternatively with rotary-shear devices, that enable higher slip velocities over very large shear offsets (Hirose & Shimamoto, 2005; Mizoguchi et al., 2006). Typical experiments (Dieterich, 1972; Marone, 1998; Olsen et al., 1998; Bos & Spiers, 2002; Tenthorey et al., 2003) show significant creep during the holding period and frictional healing (strength gain) upon reloading. Fault creep and healing are often time-dependent with longer hold times typically resulting in greater magnitudes of creep and in strength gains (Tenthorey et al., 2003; Yasuhara et al., 2005; Carpenter et al., 2012). Frictional healing may arise from growth of grain contacts (potentially induced by pressure solution) (Rabinowicz, 1951; Dieterich & Kilgore, 1994; Yasuhara et al., 2005), strengthening of the contacts (correlates with cementation) (Hickman & Evans, 1992; Beeler et al., 1994; Karner et al., 1997; Olsen et al., 1998; Muhuri et al., 2003; Tenthorey et al., 2003; Li et al., 2011) or via other changes in state including changes in porosity and rearrangement of force chains. Experimental evidence (Dieterich, 1979, 1981; Johnson, 1981; Marone & Scholz, 1988; Marone, 1998; Saffer & Marone, 2003; Moore & Lockner, 2007; Ikari et al., 2007; Ikari et al., 2011; Carpenter et al., 2012) quantifies both the mode and magnitude of second-order changes in the velocity-dependent (including velocity- strengthening and weakening) evolution of frictional strength."

Jan 1, 2015

By B. R. Maas

Processing material at a consistent rate through the continuous countercurrent decantation (CCD) thickeners presented a major bottle neck to unlocking additional value from one of the post-flotation streams at the Kansanshi processing plant. The manual operation of the thickeners making up the CCD train resulted in frequent imbalances and process upsets across units. The automation of CCD trains is notoriously tricky as the available manipulated variables are outnumbered by the parameters requiring regulation. The implementation of an advanced, auction-based, control philosophy to manage the movement of both slurry and solution inventory through the train addressed this parameter imbalance and lead to the stabilisation of the circuit. Since the commissioning of this control strategy: an additional 7 200 dmt/day (+36% throughput) of material can reliably be processed through the train, the number of monthly downtime events has reduced, and a saving of $354 000/month in reagent cost has been achieved. INTRODUCTION CCD operation Agitated leaching is a common method used in hydrometallurgy to extract a metal from its host ore. The host ore is initially finely ground to liberate the surfaces of the valued minerals and improve the kinetics of the leaching process. The ore is then contacted in an agitated tank with a lixiviant to dissolve the desired metal into the aqueous phase. The resultant slurry from the leaching process comprises of a solution pregnant in the metal salt and a barren ore. The first purification step taken after leaching is to wash the pregnant liquor solution (PLS) from the depleted ore. On the industrial scale, a set of between two to ten thickeners arranged in a countercurrent configuration is often used to carry out this separation (Perry & Chilton, 1973). The slurry is introduced at the head of the train and a wash solution at the tail. The two streams are pumped through each thickener countercurrent to one other. At each stage the residual PLS in the slurry is mixed and diluted down with the countercurrent overflow solution from the downstream thickener. The diluted slurry is fed into the thickener where the solids separate out through gravity sedimentation. The settled solids are channelled towards the underflow of the thickener by a rake mechanism and pumped downstream to the next thickener in the train. The outcome is the recovery of a PLS from the overflow of the lead thickener and a slurry of washed solids from the underflow of the tails thickener.

Jan 1, 2019

By Zhang Wei

"Pulang Copper Mine is located in Shangri-La county, Diqing Prefecture, Yunnan Province, with currently defined copper reserve of 4.8 million tonnes of copper metal and an average grade of 0.34% Cu. The mineralized zone in a dome shape is 2,300 m long, 600–800 m wide, and 1,000 m high. At present, the project is at a construction phase, with a first-stage mining and processing capacity of 12.5 million tonnes of ore per year. Ore haulage is planned via a drift and ore pass development system. The cavability of mineralized rock is classified into three types (II, III, IV), with type III accounting for more than 98% of the total reserves. The cavability of the orebody is generally considered to be good and block caving mining method is planned. Semi-autogenous grinding and ball milling are adopted for the mineral processing. The tailing dam construction method is a center-line method.INTRODUCTIONAs the China's largest underground nonferrous mine, Pulang Copper Mine is located in the northeast of Shangri-La County, Diqing Prefecture, Yunnan Province, China. It is 62 km northeast of Shangri-La city. Shangri-La County is a Tibetan-dominated, multiple-ethnic region, with a population of approximately 163,000 in 2009. The county is rich in mineral and water resources, thriving with tourism. Its economy is also dominated by agriculture. To date, the defined copper reserves at the Pulang Copper Mine is 4.8 million tonnes of copper metal at an average grade of 0.34% Cu. In addition, it contains a gold reserve of 145 tonnes, a silver reserve of 2,754 tonnes, a molybdenum reserve of 0.19 million tonnes, and a sulphur reserve of 10.5 million tonnes. The first-stage mining and processing capacity is planned at 12.5 million tonnes of ore per year. When it ramps up to this production rate, the mine will produce copper concentrate containing 50,000 tonnes of copper and molybdenum concentrate containing 968 tonnes of molybdenum. A drift and ore pass system is planned for ore haulage and mining method is a block caving method. Semi-autogenous grinding and ball milling are considered for mineral processing. A center line dam is adopted for the tailing dam construction (Feng, 2010; Feng, Li, & Wang, 2011; China Enfi Engineering Corporation, 2014)."

Jan 1, 2016

By V. Cvetkovic, L. Zou, L. Jing

"Sorption process plays a significant role for solute retardation in rock fractures. In this paper, for the aim to investigate the effect of sorption on solute transport in a single rough fracture, a 2D model of representative single rock fracture was built and its roughness was statistically characterized based on the measured data of rock surface topography by laser scanning. A Finite Volume Method (FVM) code was developed to solve the Navier-Stokes (NS) equations and transport equation for numerical modelling the process of fluid flow and solute transport in the rock fracture model. Two groups of simulations were conducted: with and without the consideration of the sorption process with different average flow velocities. The results show that the surface roughness increased the complexities of flow fields, and the non-linear sorption process plays a significant role in the retardation of solute transport through rock fractures. The sorption process caused an obvious lagging time in both the solute concentration fields (plumes) and corresponding breakthrough curves. This lagging time increases with the distance from the inlet boundary, and relatively decreases with the increase of mean velocities. INTRODUCTIONFluid flow and solute transport in fractured rocks is an important research topic for performance and risk assessments for rock engineering projects concerning geo-environment safety, such as radioactive waste disposal, mining, geothermal extraction, reservoir engineering and other contaminant transport processes in geosphere (Berkowitz 2002).The solute transport in the rock fractures mainly involve the advection, surface sorption, matrix diffusion, dispersion, radioactive decay and chemical reactions, governed by general transport equations (e.g. Bodin et al., 2003). Among these transport phenomena, the sorption on the fracture walls can alter solute migration between the fractures, and play an important role in natural retention of solute transport (Weber et al., 1991; Wels et al., 1998; Kumar 2007; Dai et al., 2012). The aim of this study is to investigate the effect of sorption on the solute transport in a single rock fracture with rough surfaces. More complex transport processes, such as matrix diffusion, dispersions, radioactive decay and chemical reactions, are not included in this study."

Jan 1, 2015

By Matthew Russell, Bobby Randhawa, Leopoldo Mariscal Samaniego, Jose A. Puente, D. Brosig, Paykan Safe

The La Caridad copper smelter, located in Nacozari, Mexico, have started a multi-year plan to reduce sulfur dioxide and particulate matter emissions into the environment. In 2014 the smelter completed a voluntary plant-wide SO2 process emissions inventory as part of the smelter’s proactive environmental stewardship policy. In turn, this triggered the development of several environmental projects to alleviate these emissions. A strategy consisting of improved capture efficiency of the sources with greatest impact has been followed to maximize cost-effectiveness. The reduction of secondary emissions from the Teniente Converter, as well as of primary and secondary emissions from the Peirce-Smith Converters have been key areas of priority. Additionally, a new system to capture and recover particulate matter from the Anode Refining Furnaces off-gas is also in the process of being implemented. This paper presents an overview of the work developed behind this effort and the smelter’s vision towards a greener future. INTRODUCTION The La Caridad copper smelter is owned and operated by Metalurgica de Cobre S.A. de C.V. (a subsidiary of Grupo Mexico). Currently, the smelter has a production capacity of 300,000 tonnes of anodic copper per year. The smelter is coupled with a 300,000 t/y electrolytic refinery. Other by-products (such as precious metals and sulfuric acid) are also generated as part of an integrated process. The original smelter started operating in 1986 with one Furukawa concentrate dryer, one Outokumpu Flash Smelting Furnace (FSF), two slag cleaning electric furnaces (SCFs), three Peirce-Smith Converters (PSCs), two Anode Refining Furnaces (ARFs) and one casting wheel. In 1997, a plant expansion project was concluded with the installation of one steam dryer, one Modified Teniente Converter (MTC), one additional ARF, one additional casting wheel, and the electrolytic refinery [1]. Over the years, the smelter management has implemented numerous environmental projects to alleviate SO2 and particulate matter (PM) emissions. The smelter process gas handling system captures the process gases from the FSF, MTC, and the three PSCs. The process gases are cleaned and conditioned and sent to the two acid plants. The first acid plant (with a capacity of 226,000 Nm3/h, wet basis) was commissioned in 1988 to process the FSF and PSC off-gases. A second acid plant (with a capacity of 195,000 Nm3/h, wet basis) was commissioned as part of the smelter expansion project [1]. The PSCs also have a secondary gas handling system with a dedicated baghouse and stack. The Furukawa dryer off-gas reports to a dedicated electrostatic precipitator (ESP) for dedusting before venting via a local stack. Process gas from the two SCFs, along with hygiene ventilation from various sources inside the smelter (including matte and slag tapping hoods from the FSF) report to a baghouse-based gas handling system and vent to atmosphere via a local stack. The original ARFs do not have an off-gas handling system, however, each ARF has a post- combustion chamber which naturally vents the process gases to the atmosphere via a dedicated stack.

Jan 1, 2019

By Waghmarem Umesh V., Vinay Jain, Pradip, Beena Rai

"The hematite surface plays a vital role in several processes of industrial and technological importance, such as, in beneficiation of iron ores, catalysis, and geochemical processes. Therefore, it is imperative to have a clear description of the structure and composition of this surface, which forms the underlying basis for such a wide variety of complex phenomena. Particularly, from the perspective of beneficiation of Indian alumina-rich iron ore slimes and fines, a clear understanding of the surface structure and composition of hematite surface and its difference from the alumina surface will facilitate identification and/or design of selective reagents which can be used to separate the two minerals. In this work, the hydroxylated hematite (0001) surface was modeled using density functional theory (DFT). The computed planar relaxations are consistent with X-Ray crystal truncation rod diffraction results reported in the literature. It is demonstrated that only one type of surface, that is, the (OH)3-Fe-H3O3-R is stable under aqueous conditions, as the relaxations for the second type of termination: (OH)3-Fe-Fe-R do not match quantitatively with experiments suggesting that its coexistence with the (OH)3-Fe-H3O3-R surface is unlikely. A detailed analysis of this surface shows that two of the three (OH) groups are not connected to the Fe surface atom. Instead, they form H2O molecules by combining with the H-atoms on the O-layer beneath the Fe-terminated surface leaving the Fe surface-atom bonded to only one OH-group. This undercoordination of Fe-atoms on the surface explains its higher reactivity as compared to hydroxylated alumina.INTRODUCTIONThe hematite surface plays a vital role in several processes of industrial and technological importance. A few examples are: flocculation/froth flotation of iron ores (Ravishankar, Pradip & Khosla, 1995), catalysis (Muhler, Schlögl & Ertl, 1992; Samsonov, 1973), and geochemical processes (Brown, Henrich, Casey, Clark, Eggleston & Felmy et al., 1999; Sposito, 1989). Therefore, it is imperative to have a clear description of the structure and composition of the hematite surface, which form the underlying basis for such a wide variety of complex phenomena. Particularly, from the perspective of beneficiation of Indian alumina-rich iron ore slimes and fines, this is an important problem, as a clear understanding of the surface structure and composition of hematite surface and its difference from the alumina surface will facilitate identification and/or design of selective reagents which can be used to separate the two minerals. Our current research focus is at employing molecular modeling techniques to come up with such selective reagents and then test their efficacy in the practical scenario through selective dispersion – flocculation labscale experiments and subsequently plant trials. Obviously, the correct structure and composition of the hydroxylated hematite surface is a fundamental prerequisite for such investigations."

Jan 1, 2016

By D. Bronkhorst, J. Rheault

"Backfill practices at the Williams mine have evolved significantly since underground mining began in 1986. The use of conveyors as a means of transporting fill material to stopes has been discontinued in favour of load-haul-dump equipment. The method of adding binder to the fill product has been refined along with the placement technique. Slurry preparation has been fully automated and flyash is now included as a binding agent. Surface preparation of the fill product has evolved substantially with the quarry operation coming into full operation and the construction of pennanent crushing, screening, and storage facilities. Company personnel have replaced all contracted labour involved in backfill operations. Some changes have been made to achieve a higher standard of quality control while others were implemented as a matter of cost reduction. BackgroundThe Williams mine is one of three mines operating at the Hernlo gold deposit, located 40 km east of Marathon, Ontario, along the north shore of Lake Superior. Daily production at the mine is 6000 Ud yielding an annual gold production of approximately 500 000 oz. The orebody extends from surface to a depth of 1300 m dipping north at 70 degrees. The average orebody width is 25 m, but varies from 45 m on the eastern boundary to about 10 m at the western probable limit and at depth. Proven and probable reserves currently stand at 32 million tonnes grading 6 g/t.The Williams orebody has been divided into four separate mining zones: the A-zone, the West-of-Dyke zone, the B-zone, and the C-zone (Fig 1). Ore production originally was from the A-zone open pit operation while the A-zone and B-zone underground workings were being developed. The mining method employed underground is blasthole open stoping with delayed rockfill. Mining block dimensions are nominally 20 m along strike by 25 m high. Stope extraction is sequenced to achieve a relatively short pillar life and 100010 ore recovery. Pillars are extracted as soon as the adjacent primary stopes are two cycles ahead. Primary stopes are filled with consolidated rock fill after mining. This allows pillars to be blasted right against the consolidated fill, but also requires that the fill be self supporting to a height of 30 m.The Williams mine places approximately 1.4 million tonnes of rockfill and 50 000 tonnes of binding agents each year, with about three quarters of the fill placed being consolidated. The consolidated fill placed at the Williams mine contains Portland cement and flyash as binding agents."

Jan 1, 1994

By Xianglin Yang, Hong Zhong, Jingjing Xiao, Guangyi Liu

"The selective adsorption of a flotation collector to a mineral plays a crucial role in enhancing the hydrophobicity of targeted mineral particles for attaching air bubbles in pulp. The recent progress of the structure-reactivity relationship of flotation collectors, the characterization methods for mineral surfaces with adsorbed collectors and their commercial application are reviewed in this paper. Particular emphasis is placed on the density functional theory (DFT) for understanding the reactivity of new collectors, the surface analysis techniques including time-of-flight secondary ion mass spectrometry (ToF-SIMS), in situ scanning electrochemical microscopy (SECM) and atomic force microscope (AFM) to characterize mineral/collector interface, and the flotation technologies for optimizing recovery of valuable minerals. Especially, the recently developing collectors such as Gemini, alkoxyalkylthiourea, dithiourea, amide-hydroxamate and oximido-thiol surfactants, and their specificity to given minerals are evaluated. Based on this crucial review, it is evident that the structural modification approaches for minerophilic or hydrophobic groups, and combined surface analysis approach for further understanding the adsorption mechanism of collectors on mineral surfaces will lay a solid foundation for the future development of flotation collectors. INTRODUCTIONIn mineral processing, flotation is the main process for separation and recovery of valuable minerals from the ores contained them (Fuerstenau et al., 2007). One of the key requirements in flotation process is to increase selectively the surface hydrophobicity of the targeted minerals by collector adsorption so that these mineral particles can preferably attach to air bubbles in a slurry or pulp (Fuerstenau et al., 2007). Flotation collector is a kind of functional surfactant, which is composed of polar and non-polar groups (Somasundaran, & Wang, 2006). Non-polar portion, commonly being linear, branch or ring hydrocarbon group, is termed hydrophobic group. The polar portion, exhibiting strong affinity to mineral surfaces, is known as minerophilic group (Nagaraj, 1988). According to mineral types including saline, oxide and sulfide minerals, flotation collector divides into sulfide and oxide mineral collectors. For efficient recovery of valuable minerals from the refractory complex ores, insights into the adsorption mechanism, hydrophobic model and subsequent flotation approach of flotation collectors have been regarded as an indispensable issue in mineral processing."

Jan 1, 2016

By Louise Corriveau

A Targeted Geoscience Initiative transect in the eastern Grenville Province reveals an extensive VHMS-style cupriferous hydrothermal system among rhyolitic pyroclastic rocks of the Wakeham Group at La Romaine, Québec. The volcanic rocks outcrop sporadically along a < 10 km-wide by about 100 km-long belt correlated with the south-eastern extension of the Wakeham Group. This belt occurs among voluminous, magnetite-bearing, granitic gneiss. At Lake Musquaro, 1.51 Ga metarhyolitic to dacitic lapillistones and flows, locally with aluminous nodules and veins, are intruded by 1.49 Ga feldspar porphyries. This volcanic package was deposited on typical Wakeham Group arenite (< 1.52 Ga) interbedded with nodular, muscovite- and fibrolite-bearing gneiss, and minor marble hosting finely layered garnetiferous hornblendite, garnetite and magnetite-bearing coticule. The latter are interpreted as meta-exhalite and with the associated albitite (sodic alteration), aluminous veins (hydrothermal leaching) and magnetite-rich granitoids, they are key elements in the search for concealed mineral deposits in this area. At La Romaine, to the south, 1.5 Ga lapillistones outcrop structurally above metasediments and below a composite amphibolite unit of uncertain origin (lava or sills) with magnetite-rich (BIF?) units. An extensive zone of aluminous gneiss, with lapilli textures, provide evidences for severe hydrothermal leaching of the volcanic rocks prior to metamorphism. An adjacent siliceous vein-textured unit likely represent a zone of intense silicification (74 wt.% SiO2), while aluminous, hematite to magnetite-bearing veins in adjacent felsic gneiss (tuff?) preserve evidences for the sequence of alteration events. Despite granulite-facies metamorphism, the main characteristics of the amphibolite unit persist along the entire belt. This competent unit likely served as a cap rock; the garnetite, diopsidite and hornblendite it hosts provide effective guides to the sites of fluid discharge and mineralization. A number of Cu showings, modest in size, were discovered in this unit. Their systematic occurrence, in a structural-stratigraphic sense, indicates that this setting is attractive for mineral exploration despite high-grade metamorphism and deformation. Late-stage veins laden with fluorite crosscut these alteration zones, and are themselves metamorphosed, indicating that hydrothermal activity was polyphased. SHRIMP U-Pb ages obtained on detrital zircons (1 arenite) and on igneous zircons (5 volcanic rocks, 1 porphyry and 6 granitoids), pervasive arc-type geochemical signatures and presence of in situ rafts of barium-rich garnetite in the granitoids indicate that sedimentation and volcanism occurred between 1.52 and 1.49 Ga coevally with hydrothermal activity and emplacement of a sub-volcanic 1.5 Ga granitic batholith with early, 1.53 Ga tonalite intrusion. Such a geological context can sustain large-scale hydrothermal cells and development of VHMS, Cu-Fe oxides or SEDEX deposits.

May 1, 2003

By Kari Niiranen, Andreas Boehm

LKAB (Luossavaara-Kiirunavaara AB) is operating underground iron ore mine, with three beneficiation and pelletizing plants in Kiruna, Northern Sweden. The wet low intensity magnetic separation (WLIMS) is regarded as the crucial part of silicate mineral separation from the ore. The Kiirunavaara iron ore deposit shows a rather low content of silica (ca. 2.3 to 3.3 % SiO2) but the silica grade is expected to increase in the deeper parts of the deposit. This can be problematic in the case of DR pellet quality with an average silica grade under 0.75 % SiO2. A laboratory scale methodology was developed for the systematic characterization of the ore for mineral processing with the focus on silicates at the Institute of Mineral Processing, University of Leoben. This methodology is combining mineralogical, geochemical and process mineralogical characteristics. Automated mineralogy (QEMSCAN) was used to study the modal mineralogy, the distribution of silicate minerals in different particle size classes after comminution, the deportment of silicon (Si) between various silicates and degree of liberation and intergrowth of magnetite and silicates. Based on the mineralogical investigations, actinolite, phlogopite and even quartz and albite are the predominating SiO2 bearing minerals in the ore. The important result of the investigations was the discovery of two separate subtypes within the high silica ore type B2 based on their mineralogy and mineral processing characteristics. The crucial part of the investigations of intergrowths and liberation of magnetite results was the magnetic separation tests carried out with the Davis magnetic tube. The binary intergrowths of magnetite and the silicate minerals (mostly actinolite) are the most common type of mineral association discovered. The significant characteristics in the intergrowths of magnetite and actinolite are the fine-grained magnetite inclusions in actinolite which may end up increasing the SiO2 grade in the magnetite concentrate despite magnetic separation.

Jan 1, 2016

By Jean-François Lagueux

Goldex Mine is an underground mine located near the town of Val-d?Or. Multiple innovations were required to work the mine. Due to its low grade, it was important to develop a bulk mining method to economically extract the ore. The method used is a combination between shrinkage stope and long hole stope methods. This modified method is more than adequate; however, all of the ore body must be liberated in a very short period of time. Therefore, to bring down 23 Mt of ore, large blasts up to 1.8 Mt are required. The situation is also complicated by the fact that the mine is located in a residential area. No less that 40 homes are built within a 1 km radius of the mine site. In addition to managing mass blasts, means must also be found to mitigate the vibrations produced by the blast to diminish the disturbance to the neighbourhood. Therefore, the mine used numerous tools to properly plan the blasts and reduce the impacts. A program to control vibrations was one of the first tools put in place. The program?s aim was to draw up an action plan to ensure a follow-up of the homes by inspecting them. The second tool was to develop a methodology to plot a reliable attenuation curve and to adequately determine the maximum charge weight for each blast. Finally, effective communication tools were developed to inform the neighbourhood. There was a huge amount of work to be done in relation to the bench. Reliable and fast loading techniques had to be found to load large blasts in a very short period of time. Adequate logistics had to be developed to send underground more than 20,000 kg of emulsion per day while performing the daily underground operations. Technology had to be developed to adapt the i-kon electronic blasting system to large blasts. Since the control of the charges was the major factor to reduce surface vibrations, it was important to employ loading techniques that would permit decking of the long holes to reduce the charge weight per delays without adversely affecting the loading. All of this work requires an enormous amount of energy but also close collaboration between the different stakeholders (various departments, suppliers and consultants).

May 1, 2011

By S. Fox, Y. Fujita

Increasing demand for rare earth elements (REE) is expected to lead to new development and expansion in industries processing and or recycling REE. For some industrial operators, sending aqueous waste streams to a municipal wastewater treatment plant, or publicly owned treatment works (POTW), may be a cost effective disposal option. However, wastewaters that adversely affect the performance of biological wastewater treatment at the POTW will not be accepted. The objective of our research is to assess the effects of wastewaters that might be generated by new rare earth element (REE) beneficiation or recycling processes on biological wastewater treatment systems. We have been investigating the impact of yttrium and europium on the biological activity of activated sludge collected from an operating municipal wastewater treatment plant. We have also examined the effect of an organic complexant that is commonly used in REE extraction and separations; similar compounds may be a component of newly developed REE recycling processes. Our preliminary results indicate that in the presence of Eu, respiration rates for the activated sludge decrease relative to the no-Eu controls, at Eu concentrations ranging from <10 to 660 µM. Yttrium appears to inhibit respiration as well, although negative impacts have been observed only at the highest Y amendment level tested (660 µM). The organic complexant appears to have a negative impact on activated sludge activity as well, although results are variable. Ultimately the intent of this research is to help REE industries to develop environmentally friendly and economically sustainable beneficiation and recycling processes.

Jan 1, 2016

By Robert Boutilier

For more information on what the social licence means, see the following: Joyce, S. and Thomson, I. 2000. Earning a social licence to operate: Social acceptability and resource development in Latin America. The Canadian Mining and Metallurgical Bulletin, 93(1037) Nelson, J. and Scoble, M. 2006. Social License to Operate: Issues of Situational Analysis and Process. Vancouver, BC: Department of Mining Engineering, University of British Colombia. Thomson, I. and Boutilier, R.G. 2010. The Social License to Operate In P.Darling, (Ed.), SME Mining Engineering Handbook: Littleton, CO: Society for Mining, Metallurgy and Exploration. Much of what has been written and said about the social license to operate focuses on what the company has to do or not do. But the social license is a two-sided relationship. We also need to look at what the community has to do, or not do, in order to be capable of issuing a social license that is meaningful.

May 1, 2010