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By Jacob Wood, Robert Matusewicz

The Outotec® Ausmelt Top Submerged Lance (TSL) Process has achieved widespread commercial acceptance over the past 40 years for the processing of copper, nickel, lead, tin, zinc and precious metal bearing feeds. The continual development and evolution of the technology during this period has resulted in a more intense smelting process with higher energy efficiency and lower operating costs. More recently, considerable effort has been invested in decarbonisation of the process through improvements such as increased oxygen usage, dry feed injection and use of low-carbon auxiliary fuels. This paper covers a number of these recent advances to the technology and highlights their impacts on energy consumption and CO2 emissions for a range of non-ferrous smelting flowsheets. INTRODUCTION Relentless demand for improvements in the profitability, safety and environmental performance of non-ferrous smelting plants has driven a continual development and evolution of processing technologies in this industry. In response to these demands, a number of bath smelting technologies have emerged over the past 40 years and have been implemented for the treatment of primary and secondary feedstocks. The Outotec® Ausmelt Top Submerged Lance (TSL) Process (henceforth Ausmelt Process) is one such bath smelting technology which has been widely adopted in a large number of greenfield projects and brownfield plant modernisations (Wood & Hughes, 2016). Emissions of CO2 from the production of non-ferrous metals represent approximately 4-5% of global totals (Rankin, 2012), comparable with the almost 10% attributed to iron and steel production. Despite significant improvements in the energy efficiency of modern smelting technologies (Coursol, Mackey, Kapusta & Cardona Valencia, 2015), primarily through increased oxygen usage, further innovation and development is still required to address their reliance on fossil fuels such as coke and coal. Transformation of the non-ferrous smelting industry to low-carbon technologies and process flowsheets is lagging behind the power and transport sectors, which have witnessed significant growth in clean/renewable energy technologies to reduce CO2 emissions and address the issue of anthropogenic climate change (IRENA, 2018; IEA, 2018).

Jan 1, 2019

By M. Hashemzadeh

The efficiency of water use is a top priority for the global minerals industry, especially in regions with limited freshwater supplies. In these areas, the freshwater shortage has prompted mining companies to search for alternatives to freshwater sources. Seawater has been proven to be a potential water source for mineral beneficiation and metal extraction processes. This study compares chalcocite leaching behavior with ferric chloride to that with cupric chloride. We carried out leaching tests with a highly pure chalcocite sample in jacketed reactors under fully controlled pH and solution potential. The effect of chloride concentration, oxidant concentration, and temperature on copper extraction was quantified in both cupric and ferric chloride systems. In the ferric chloride system, increasing ferric concentration showed a positive effect on the first stage of chalcocite leaching. In the second stage, increasing temperature markedly enhanced copper extraction. In the cupric chloride system, chloride concentration presented a considerable effect on both the first and second stages of leaching, while temperature had a remarkable effect only on the second stage. The findings of this study would be beneficial to mine operations aiming to replace fresh water with seawater for heap leaching of chalcocite. INTRODUCTION Mineral processing operations/plants are normally operated adjacent to mines which are often located in remote and arid area, such as northern Chile, southern Peru and Australia with limited access to fresh water (Liu, Moran, & Vink, 2011, 2013). Water scarcity in these areas has prompted mining companies to invest in sustainable technologies to reduce the water use and/or increase the water use efficiency. One of the current sustainable approaches in mineral processing operations is to replace fresh water with seawater. Seawater is now being increasingly used for mineral beneficiation and metal extraction processes (Hernández et al., 2015). Another application of seawater could be for heap leaching of copper secondary sulfides, mainly chalcocite. However, the high concentration of chloride ion in seawater may significantly affect leaching kinetics of copper sulfide concentrates and ores (Watling et al., 2014). Therefore, it is essential to develop a fundamental understanding of the leaching of chalcocite in chloride media.

Jan 1, 2019

By Patrick Andrieux

Numerous rock blasting design methodologies have been developed over the years, relating either to the primary objectives of blasting, such as the size distribution of the blasted material, or to its undesirable side effects, such as damage to the remaining rock mass. All existing methodologies, while of use, do have serious shortcomings. The question remains whether further improvements can be achieved in the field of practical rock blasting engineering. One approach that seems to hold promise is the relatively new matrix-based rock engineering systems (RES) methodology. It has been conceptually demonstrated that RES could be efficiently adapted to blasting. A brief overview of rock blasting design techniques and their main shortcomings is followed by the basic concepts governing rock engineering systems and a discussion on their pertinence to blasting. The paper concludes with a review of current efforts to develop a useful practical blast design tool using RES. SOMMAIRE Le potentiel d?application des systèmes d?ingénierie du roc aux tirs à l?explosif. De nombreuses méthodologies de conception d?abattage du roc à l?explosif ont été développées au cours des années, qui ont adressé soit les principaux objectifs des tirs, comme par exemple la granulométrie du matériel dynamité, soit ses effets secondaires indésirables, tels les dommages au massif rocheux. Toutes les méthodes existantes fonctionnent dans une certaine mesure et sont utiles - elles sont cependant pour ainsi dire toutes affectées par des limitations ou défauts plus ou moins sévères. La question demeure quant à savoir si des améliorations supplémentaires peuvent être apportées dans le domaine de la conception pratique des opérations d?abattage du roc à l?explosif. Une approche alternative qui semble prometteuse est celle relativement récente des systèmes matriciels d?ingénierie du roc (?Rock Engineering Systems?, ou RES). Il a été démontré de manière conceptuelle que les RES ont le potentiel d?être adaptés aux opérations de sautage. Une brêve revue des principales techniques de conception des tirs à l?explosif est suivie d?un énoncé des principes de base gouvernant les RES, ainsi que d?une discussion sur leur pertinence aux opérations de tir. Cet article conclut avec la revue d?un projet de recherche axé vers le développement d?une méthodologie de conception des tirs à l?explosif basée sur les RES.

May 1, 2002

By O. Guyot, A. Broussaud, M. Revalor, G. Legrand, D. Kok, E. Roux

"The paper describes the advanced grinding control system implemented at Newmont Ahafo gold mine, Ghana in 2009 and 2010. It shows how the different components of the Advanced Process Control (APC) system cooperate for increasing plant performance.The SABC circuit processes hard rock from different pits mixed with a variable proportion of oxides. The control strategy is designed to address specific disturbances, including start/stops of pebble crushers, unavailability of oxides, changes in rock size distribution resulting from segregation in the stockpile, and changes in ore type and hardness.The system consists of an expert system per se with extensive use of fuzzy logic, supplemented by an online dynamic model of the process used as a soft sensor, a VisioRock™ rock size measurement system over SAG mill feed before addition of recycled pebbles, and an AudioMill™ system to analyze the SAG mill sound and detect impacts on liners. All these components are embedded in the same OCS© software platform, which, among other benefits, makes it easy to support the entire system remotely. The paper details the physical constraints and the variables that are manipulated. It describes the control strategy and the contribution of each component of the system. It also describes the project implementation and the performance of the system. In addition to a strong involvement and support of management, the very good acceptance of the operators has been facilitated by the remote access system that made it possible to immediately modify the system each time it was needed during the baby sitting phase.The system made it possible to increase gold production significantly through increases in tonnage and recovery thanks to a better control of the grind size through a stabilization of the secondary ball milling circuit and an improvement of the operating conditions of the classifying cyclones."

Jan 1, 2012

By H. C. L. Reemeyer

One of the fundamental trade-offs for copper concentrators is between grinding circuit product size and copper recovery. The capital and operating cost savings and throughput increases for a coarser grind should be evaluated against potential recovery reductions. Other benefits of coarser grinds, such as GHG emissions reductions and favourable effects on tailings and water management should also be considered. This paper assesses the formation of laboratory and pilot test programs, design of process flowsheets, equipment selection, and evaluation methods to determine the most appropriate and economical grind size for a given deposit. The paper will include an evaluation of case studies. INTRODUCTION The majority of the world’s mined copper comes from sulphide deposits, which are mostly processed using crushing, grinding, flotation and dewatering flowsheets to produce copper-bearing concentrates for smelting. Ores must be ground to a sufficiently fine size to achieve an acceptable level of liberation to allow both high recovery of copper and valuable by-product minerals while efficiently rejecting gangue to tailings. Therefore, a key design parameter in process plant design is the grind size of the flotation feed. Copper concentrators use a variety of grind size targets that depend on various factors, including ore mineralogy and the grain sizes of valuable and gangue minerals; the sensitivity of valuable mineral recoveries in the rougher flotation stages to grind size, ore hardness; electricity costs; and mining vs. processing throughput constraints. Typically, copper and by-product recovery increase as grind size is reduced, which can improve revenue, but finer grinds increase power and grinding media operating costs and may have implications for tailings management. This paper explores the trade-offs that should be assessed in determining the optimum grind size, and to answer the question if coarser grinds are worthwhile. METALLURGICAL AND FLOWSHEET FACTORS Recovery-by-size behaviour of sulphide-bearing particles In base metals sulphide flotation, it is typical that flotation recoveries vary by particle size. Metal sulphide particles rendered hydrophobic by collector in intermediate size ranges (e.g. 10 to 100 um) usually show very high recoveries, often approaching 100%. Recovery usually falls away in finer size fractions (<10 um) as fine particles have little inertia and can move around bubbles without colliding and attaching to them. Coarser particles (>100 um) are susceptible to particle-bubble detachment and dropback (Jameson, 2019).

Jan 1, 2019

By X. J. Guo, Q. K. Wang, S. P. Zhong

With depletion of traditional clean copper reserves and fast expansion of the global copper demand and smelting capacity in the past decade, more and more copper smelters have to treat copper concentrate with increasing content of complex arsenic-bearing minerals. Developing economically viable and environmentally reliable methods and approaches for arsenic control in copper smelting has become more critical for sustainable growth of the copper industry. This paper will report the recent effort of Zijin Mining Group Ltd. in developing processes for improving arsenic control and management in the Zijin Copper Smelter. The arsenic distribution and balance data for matte smelting, converting and refining operations in Zijin Copper Smelter is reviewed for understanding of the current challenges in arsenic control. The processes developed for treating the arsenic bearing waste acid bleed stream from the smelting-converting off-gases wet cleaning circuit and the arsenic sludge produced in the refining electrolyte purification circuit for arsenic disposal are discussed. INTRODUCTION With fast expansion of the global copper smelting capacity to meet the world copper demand and depletion of traditional clean copper reserves, more and more copper smelters have to treat copper concentrate with an increasing content of complex arsenic-bearing minerals. China is the world largest copper consumer and also has the largest copper smelting and refining capacity, but majority of its smelting capacity relies on supply of imported copper concentrate. In order to meet the increasing copper demand and ease the tight supply of clean copper concentrate, the Chinese copper industry has to look at the domestic opportunity of developing non-traditional copper resources, specifically those of lower grades, more complex mineralogy, and increasing level of deleterious elements especially arsenic and also process imported copper concentrate with increased arsenic content. Due to a significant and growing environmental issue associated with arsenic contamination, developing economically viable and environmentally reliable methods and approaches for arsenic management and control in unlocking the maximum value of such arsenic bearing copper resources has become more critical for sustainable growth of the industry.

Jan 1, 2019

By J. L. Jambor, M. J. Baker, M. J. Logsdon

"Abstract - Prior to the development of the Diavik Diamonds Project, baseline studies were conducted to determine the geochemical characteristics of four kimberlite orebodies as an aid in the design of both the water-management system and the facilities for containment of processed kimberlite and ore stockpiles. Materials tested included field samples of volcaniclastic and pyroclastic kimberlite, processed kimberlite (i.e., kimberlite ore which had been screened and washed as part of the processing procedure), and sedimentary mudstone (a minor xenolithic unit which was assimilated during kimberlite emplacement). Approximately 200 samples of kimberlite materials were collected as part of the geochemistry program. Test-work included whole-rock chemical analyses, acidbase accounting, kinetic leach tests using columns, and mineralogical analyses. Diavik kimberlite has major oxide and trace-element concentrations consistent with global averages for kimberlite. The mean total-sulfur content of the kimberlite material is 0.22 wt% S, but with a significant range. The kimberlite has an excess of carbonate minerals over sulfide minerals (average CO2 = 4 wt%, present mainly as calcite), and has a mean neutralization potential of 311 kg CaCO3 equivalent/tonne. A reactive form of framboidal pyrite associated specifically with the mudstone xenoliths is the primary source of sulfide-sulfur. Long-term kinetic tests confirmed the preliminary interpretations that were made from the static-test results. Kimberlite and processed kimberlite are net acid-consuming materials that produce alkaline drainages and have low but detectable leaching rates for SO4 and specific trace metals such as Al, Co, Cu, Ni, and Zn. If segregated from the kimberlite, mudstone xenoliths are acid-generating (pH = 3) and produce an effluent with elevated concentrations of SO4, Fe, Al, Cu, Ni, and Zn. The study demonstrates that xenolithic units in Diavik kimberlites have an important effect on the environmental geochemistry of the ore rock. The mineralogy and aqueous geochemistry of the kimberlite materials are such that they may not be suitable for general earthworks or as an alkaline agent and should report to an engineered facility to protect site water quality."

Jan 1, 2001

By M. Fainerman-Melnikova

The use of strong base ion exchange resins for the extraction of uranium was pioneered in the 1950?s. Ion exchange technology is applicable to dilute leach solutions such as those obtained from in-situ, heap leaching or in-plant processing of low grade ores. A further advantage of ion exchange processes is that fluidised bed technology allows for treatment of solutions with a relatively high concentration of suspended solids and resin-in-pulp technology can treat leach slurries. However, the extraction of uranium with strong base resins is severely affected by the presence of chloride ions in solution. In areas where high quality water is not readily available, the use of saline water as process water would extend the potential application for ion exchange in uranium processing. Our research program has studied the effectiveness of a wide range of commercially available ion exchangers in uranium extraction from saline solutions. In the present work, we examine the impact of salinity (ranging from chloride concentrations found in groundwater to those present in sea water), on the uranium extraction with weak base anionic resins (WBA). The effect of pH and the presence of the competing impurities are also discussed.

Aug 1, 2010

By Carlos Nieble

Ferteco Mineracao, belonging to the CVRD group, is one of the several iron ore mines in the south east of Brazil. Some of these mines have pit walls of over 350-m height and operations under difficult geo-technical conditions are steadily increasing. In order to mine the 15 million tonnes of high grade hematitic ore remaining in the Fabrica pit, Ferteco had to deal with the following restrictions: Warrant power to its concentrator and pellet plant, relocate the load-out rail road loop, stabilise a poor phillyte slope, relocate a creek on a bench, lower the water table and mine at maximum angles at a slope with phillyte and loose itabirites directly under the rail road loop. Considering these aspects, 3 stages of operations were designed, considering a safe operation, but with the lowest possible security factors at the last mining stage, before the pit would be filled in again with tailings. Stage one above the rail road loop and below the high tension power mast, where the poor phillyte slope was secured by a flexible retaining wall, using old rails and anchors up to 27 meters (80ft) with a working pressure of up till 30 tonnes and stage two with different slope angles, and deep wells, high wall blasting perpendicular to the highwall with relief holes and rerouting the creek in steel half culvert and stage three, the filling in with tailings and recuperation of the deep well pumps. Following studies and analysis were made: Geotechnical and geological studies of all rock formations including rock strength test, a hydrological study to define the lowering of the ground water level, slope stability analysis for every bench and all possible combination of benches, definition of blasting parameters close to the pit slope, a monitoring plan, including topographical movements, vibrations due to blasting, piezometers and pressure cells as well as a plan how to fill up the pit again with tailings in combination with the rising of the ground water level. A close co-operation between the geo-technical consultant, pit operations, the blasting contractor and the geological department resulted in an operation without any incidents, lowering the pit with an additional 3 benches and mining an additional 5 million tonnes of high grade ore.

May 1, 2003

By Emmanuel Henry

The Kiruna Mine, operated by Luossavaara-Kiirunavaara AB (LKAB), is a large-scale sublevel caving operation located in Arctic Sweden. Iron ore is extracted at a rate of 60 000 tpd from a four-kilometre long, 80-100 m thick and 60-degree dipping orebody. Actual production depth is 800 m under the top of the footwall and about 550 m under the average regional ground level. Because no support is left between the footwall and the hanging wall and despite the relatively low mining depth, extraction results in the formation of a huge stress shield modifying the original stress field and concentrating it just beneath the mining level. Effects of stress concentration on the rock mass are monitored through field observations and a seismic system. Severe stress-induced deterioration of openings is visible to a certain radial distance from the mining level: pillar crushing and fault slips are more and more common and extended. The seismic system, installed in collaboration with CANMET, confirms the field observations and completes them in the rock mass: fault slips and major seismic events are recorded. The system proves its effectiveness to outline the extension of the dynamic response of the rock mass, which actually seems much larger than field observations let think.

May 1, 2001

By A. J. Sinclair

"Abstract-Geology contributes essential information toward obtaining high-quality resource/reserve estimates. In this context, geology can be considered under the following overlapping topics: regional geology, detailed (deposit) geology, mineralogy, ore deposit models and continuity, with geological mapping being fundamental to all. Each of these topics is considered here in terms of potential contributions to "improved" mineral inventory estimation. Some of the principal conclusions are:1. Regional geological relations must be consistent with deposit geology. It is common that important geological relations are more clearly evident in various regional locales than in highly altered and/or highly deformed mineralized areas containing mineral deposit.2. Detailed geology provides information for a geometric model of a deposit, a model that serves as a basis for mine planning. It is important to distinguish fact from interpretation in such models. Substantial effort is required to characterize the geometric margins of a deposit and the relation of these margins to the simplistic geometric form that normally emerges as an interpretation.3. Mineralogical studies relate to many aspects of deposit evaluation including abundance of ore and deleterious minerals, spatial distribution of ore and deleterious minerals, grain size characteristics of important minerals, mill design, etc.4. Ore deposit models contribute substantially to confidence in developing a three-dimensional geometric model of a deposit for mine planning. Specifically, they are a basis on which to develop rules for interpolation and extrapolation of ore, and they contribute to recognition of domains, each with its own characteristic continuity and margin character.5. Continuity is dependent on mineralization style and may be controlled structurally and/or chemically. It is important to distinguish geological continuity and value continuity. A wide range of classical geological methods are useful in examining geological continuity; value continuity is best viewed as a statistical characteristic that is quantified by any of several measures of autocorrelation."

Jan 1, 1998

By R. T. Erskine

"IntroductionIn this paper it will not be possible to cover all details of the reagent systems at Brunswick Mining and Smelting but it is hoped that a description of the evolution of these systems will be of some benefit. The concentrator of Brunswick Mining and Smelting located near Bathurst, New Brunswick was originally designed as a 3,000 ton per day operation but before construction commenced was uprated, with 4,500 tons per day being treated by the summer of 1964. Development of the open pit at another ore body five miles away was initiated in 1965 and additional concentrator and crusher facilities went into operation in September, 1966. Present total daily throughput is over 8,000 tons per day. The ore at Brunswick is very high grade but mineralization is very fine grained and requires grinds generally over 75% minus 400 mesh for liberation. The amount of surface exposed using grinds of this order understandably requires great quantities of reagents, Reagent mixing systems for the original concentrator allowed only for batch mixing and were very expensive in labour cost especially.During the first three years of operation total number of men employed in reagent handling reached a peak of four men per shift and six men on dayshift unloading cars for a total of 22 men. At present only one man is employed on shift, and four men on dayshift take care of unloading and mixing reagents, a total of 8 men. The man on shift is almost entirely occupied with checking feeder operation, flow rates, and head tank levels. Most commonly used reagents are tabulated in Fig. 1 showing average monthly and daily requirements in the Brunswick operation as well as pounds per ton of mill feed as found in 1969. It is very obvious that with over seventeen tons each of lime and soda ash and six tons of copper sulphate used each day, opening of bags and mixing batches of solution is an inefficient undertaking."

Jan 1, 1970

By X. J. Luo, F. Zhang

"Metallurgical slag (MS) such as steel slag, copper slag is a renewable resource and its compressive strength exceeds 200MPa in general. Because pure metal slug can easily be mixed into MS, complex recycle system is necessary in order to realize MS’s recycling. Meanwhile, there is high equipment failure rate in conventional crushing system. New crushing systems with inertial cone crusher could solve this problem very well. Recovery rate of MS tailings requires that crushing product can’t contain too much oversize product, so the essential equipment include two crushers and one sieve in the traditional crushing system. The new crushing system which only includes two crushers can meet the requirement and simplify the crush process. Investment of crushing equipment and infrastructure can be cut down. Operating and maintenance costs can be obviously reduced due to the simple process, which also could achieve high energy saving and excellent economic efficiency.INTRODUCTIONMetallurgical Slag (MS) such as steel slag, copper slag is a typical industrial solid waste and it threatens our environment’s safe. Metallurgical enterprises must take action to settle these wastes in order to protect our environment. Because pure metal slug can easily be mixed into MS, its uniaxial compressive strength (UCS) will exceed 200Mpa. If crushing station employs traditional crushing equipment, equipment failure will be easily caused because of these pure metal slugs. Coarse crushing equipment usually adapts jaw crusher in traditional Crushing technology and rod mill will be utilized to finish the secondary and fine crushing works. And the same time screening machinery should be used to ensure the suitable particle size (Figure 1)."

Jan 1, 2016

By Weimin Fu

Chondrite-normalized rare earth elements (REEs) profiles and high field strength elements (HFSEs) in rocks and minerals represent important tracers of geological processes. Of these the birdwing-shaped profile with negatively-sloped light REE ((La/Sm)N >1), positively-sloped heavy REE ((Tb/Yb)N <1), and strong negative Eu anomalies is commonly associated with large-scale hydrothermal systems or granitic intrusions. In a different way, severe deviation of Nb/Ta, Hf/Sm ratios from those of chondrite may also indicate hydrothermal signatures in the rocks involved as these ratios are generally stable and chondritic in normal magmatism as a result of their nearly identical ionic radii and charge. In this study, we present a typical setting where birdwing-shaped REE profiles together with Nb/Ta, Hf/Sm ratios unusually higher than those of chondrite, are systematically developed in a series of garnetite, quartzofeldspathic gneiss, Fe- or Mg-rich aluminous gneiss, and sulfides and magnetite. These units and associated Cu-Au mineralization form a VHMS-style hydrothermal system in the granulite-facies 1.4 Ga -1.35 Ga volcano-plutonic, arc-related Bondy gneiss complex (BGC), western Grenville Province, Canada. Outside the recognized hydrothermal system of the BGC, such REE profiles are not observed. Instead the surrounding felsic and mafic gneisses display primary trace element characteristics of island-arc magmas, suggesting that granulitefacies metamorphism did not modify significantly the trace element signatures of the protoliths. Although magmatic fractionation of accessory minerals can produce birdwing-shaped profiles, it cannot explain the extreme fractionation of isovalent trace elements (Nb-Ta) and the high Zr content of the hydrothermal rocks. Neither is it compatible with the lack of significant Nd depletion that would normally incur during this process. Following our study, we demonstrate that F-rich fluid and mineral phases enriched in LREEs and HREEs respectively must have been involved in the main hydrothermal alteration and REE fractionation process in the BGC. Preferential removal of REEs from the interstitial glass of the volcanic protoliths together with dissolution of plagioclase and subsequent external influx of HREEs and HFSEs can produce birdwing-shaped REE profiles. In turn, such profiles and/or unusual Nb/Ta, Hf/Sm ratios can be used as a sensitive marker of hydrothermally altered rocks in targeting mineral exploration.

May 1, 2003

By Candido Bariáin

A new vapochromic material of formula [Au2Ag2(C6F5)4(bipy)2]n (bipy = 2,2´ bipyridine) has been developed and used for the detection of some volatile organic compounds as acetone either in vapour or in water solution. The material is presented in the form of powders which colour changes with acetone vapours turning from bright yellow in the absence of vapour to white in the presence of vapour. By using the sol-gel technique, the powder ? dispersed in tetraethyl orthosilicate- was easily deposited on optical fibres. In order to study experimentally the behaviour of this material for construction practical optical fibre sensors, a sol-gel material doped with the vapochromic material is deposited onto an extreme of a monomode fibre connected to a coupler. The behaviour of the material was studied for different wavelengths and concentrations of acetone vapours and acetone/water solutions. Changes up to 4dB in the reflected optical power were detected. Optical fibre sensors have many advantages over conventional ones, such as electromagnetic interference immunity, passivity behaviour, possibility of using multiplexation techniques, low weigh and little size, etc. Actually, there is an increasing interest in developing optical fibre sensor for vapour detection in the chemical industry and in fact many sensor had been developed [1]. Some are based on the deposition of a sol-gel-based material either over the core of an optical fibre [1] or onto the thinner zone of a biconically tapered optical fibre [2]. Others are based on Fabry-Perot interferometers [3]. Also there are sensors based on the reflection of the light on films, on the fluorescence of dye-doped polymer cladding in fibre, on colorimetric reagents in the core of a silica fibre or on surface plasmon [4]. The possible materials for the construction of such sensor should be colorimetric reagents able to change the colour or refractive index in the presence of same organic vapours. There are not many metallic complexes with these properties, although same interesting examples have been reported in the chemistry of palladium and platinum as [Pt(p-R-C6H4NC)4][Pd(CN)4] described by Nagel [5] and Mann [6], which reported the construction of some LEDs. We recently reported the preparation of a novel vapochromic material (Fig 1) [7] which can be used for the construction of optical fibre tapered environmental sensors [8,9] of vapour organic compounds (VOC´s). Also we reported other nickel and palladium derivatives which present this type of behaviour [10]

Oct 1, 2003

By K. A. Lewandowski

Agglomeration of ore used in heap leaching allows for the immobilization of fine particles that would otherwise migrate and cause permeability problems in the heaps. For copper ore, binders are needed in order to make stable agglomerates. However, the majority of binders break down when introduced to an acidic environment, allowing fine particles to be released from the agglomerate surfaces. These particles migrate through the heap impeding solution flow, leading to a decrease in metal recovery rates. The authors have developed a series of testing procedures to determine the acid resistance of several binders. Only five binders were shown to be acid resistant in soak tests, decreasing fines migration by up to 93%, compared to tests which were agglomerated with leach solution, raffinate, as a binder. Flooded percolation column testing also showed that these binders were able to reduce the "slump" of the ore by up to 82% and increased the hydraulic conductivity by up to 90%, when compared to agglomerating with leach solution alone. The use of binders in the agglomeration of copper ore also showed no negative effects on the bacterial populations throughout a leach cycle.

Jan 1, 2007

By CIM CIM

Why Workplace Important! ?We need Diversity is to do more in the industry as a whole to encourage and support diversity. It has long been an industry of white dudes and we?re not going to survive if that?s how we continue to think.? ? Mark Scott, HR Superintendent, Vale Inco PURPOSE OF MINING FOR DIVERSITY ? Share best practices in the areas of HR Development ? Support industry in attracting, recruiting and retaining a diverse workforce ? Raise awareness of industry HR challenges and collaborate with stakeholders to develop sustainable HR practices

May 1, 2009

By T. Donkin, B. Patterson, M. I. Guthrie, J. T. Ross

"Interest in the use of particle-based ore sorting has increased significantly with recent advances in sorting technologies and higher capacities per unit. Particle-based ore sorting has the potential to provide great value in processing lower grade ores from mines while delivering higher grades to the mill, as well as in upgrading waste rock into ore. Typically the focus is on the amenability of the ore to ore sorting and associated reductions in energy, water, and consumables utilization. However, layout significantly affects the installed cost of a processing plant, and the impacts on layout from fitting an ore sorting circuit into the plant plan need to be carefully considered. This paper examines processing plant layout considerations that play an important role in ore sorting projects, including additional crushing and screening requirements, transport of rejected material back to the waste stockpile (mine fleet requirements), and effects on the processing plant footprint. ¦ KEYWORDS Cold climates, Ore sorting, Plant layout RÉSUMÉ L’intérêt porté à l’utilisation du tri granulométrique du minerai a considérablement augmenté au vu des récents progrès réalisés en matière de technologies de triage et des capacités supérieures par unité. Le tri granulométrique du minerai offre une plus-value intéressante en termes de traitement du minerai à plus faible teneur extrait des mines ; il permet par ailleurs l’acheminement vers le concentrateur de minerai à plus haute teneur et la revalorisation des stériles dans le minerai. On met généralement l’accent sur la susceptibilité du minerai au triage et sur les réductions connexes en termes d’utilisation de l’énergie, de l’eau et de biens consommables. Cependant, l’aménagement physique de l’équipement a une incidence non négligeable sur le coût installé d’une usine de concentration, et les répercussions sur l’aménagement de l’installation d’un circuit de triage du minerai dans l’usine doivent être soigneusement examinées. Cet article étudie les considérations relatives à l’aménagement de l’usine de traitement qui jouent un rôle important dans les projets de triage du minerai, et notamment les exigences supplémentaires en matière de concassage et de criblage, le transport de matériau résiduel jusqu’à la pile de stockage des déchets miniers (nombre de camions requis dans le parc minier) et les effets sur l’empreinte de l’usine de traitement. ¦ MOTS CLÉS aménagement de l’usine, climats froids, triage du mineraiINTRODUCTION Ore sorting has been practised throughout history. An early report by Agricola in 1556 documents how metallic and non-metallic minerals were extracted from rocks by laboriously breaking them with hammers and picks and hand-picking selected material with higher grade (Hoover & Hoover, 1950). The concept has not changed, but sorting technology has evolved significantly over the last 20 years"

Jan 1, 2019

By Chunlin Chen

Published data on thermodynamics of tin in liquid copper, matte and slag have been reviewed, assessed and used in development of thermodynamic solution models of melts. The developed model/database was applied in modelling the Sn deportment in primary copper smelting and e-waste melting processes. The results show that Sn can be removed from the matte through evaporation of various volatile Sn species (with SnS the most volatile) and slagging during copper smelting. The Sn removal increased with increasing matte grade due to the increased gas and slag volume. In the e-waste smelting process, fluxing strategy was developed for smelting e waste to produce a slag with reasonable liquidus and viscosity. Modelling results show that very low amounts of Sn reported to the gas phase due to low S, hence low SnS partial pressure in the system. The black copper produced could contain a few percent of Sn depending on the oxygen potential. The Sn in the black copper could be removed to the slag phase during anode refining. INTRODUCTION Tin is an impurity element commonly found in copper ores, which will be dispersed into various solid, liquid, and gaseous streams during the pyrometallurgical processing of copper. Tin alloy is widely used in electronic soldering due to its low melting point. The growth in treatment of recycled e-waste through primary and secondary copper smelting has led to an increased tin input to the smelting system. Therefore, the deportment of tin between phases is of great interest to the operators of modern smelters. Multi-Phase Equilibrium (MPE) is a thermodynamic package developed by CSIRO for simulating reactions between phases in multi-component and multi-phase systems (Zhang et al., 2002). Over the years the capability of the MPE model has been extended to cover the behavior of a large number of elements in high temperature system (Chen, Zhang, Wright, & Jahanshahi, 2006). In the present paper, the thermodynamic data on tin in liquid copper, matte and slag have been reviewed, assessed and used in the development of a database for Sn slag, alloy and matte phases. The model/database was applied in modelling the tin deportment in primary copper smelting and e-waste smelting processes. The aim of this study is to provide a better understanding of the chemical behaviours of tin in high-temperature copper processing and e-waste smelting.

Jan 1, 2019

By Yongteng Dong, John P. Quinn, Bradford Wesstrom, Guikuan Yue

With increasingly low-grade copper ores being mined, it is difficult to handle growing concentrations of As, Sb, Bi and/or Fe in the whole flowsheet, especially during copper electrorefining. To better elucidate the effects of those impurities on the quality of cathode deposit and/or current efficiency, a detailed speciation study of the electrolyte under industrial conditions is required to quantitatively describe their distribution in the solution, thereby facilitating their effective control and removal. In the present study, a thermodynamic model of complicated iron-arsenic-copper-sulfuric acid electrolyte under industrial conditions was developed. The main species of those elements involved in the electrolyte were first identified, and their thermodynamic data were collected and critically assessed. Those data were then used to estimate the activity coefficients of species, and to calculate the equilibrium constants from 25°C to 70°C. The developed model provides a mathematical tool that is capable of quantifying the concentrations of free ions and complexes in terms of temperature and solution composition. Finally, oxidation-reduction potential measurements were employed to validate the model. INTRODUCTION In copper electrorefining, impurities like arsenic, antimony, bismuth and/or iron can partially dissolve in the electrolyte and accumulate gradually, and eventually cause problems such as bad cathode deposit (co-deposition with copper or mechanical inclusion from the floating slime), lower current efficiency, etc., which eventually increases the operating costs. The presence of impurities may substantially reduce properties of copper products such as conductivity, corrosion resistance, mechanical properties, and leads to more energy consumption (Schlesinger et al., 2011; Jafari et al., 2017). To remove these impurities, various methods have already been proposed and applied in industrial copper production, such as solvent extraction, ion exchange, chemical precipitation, absorption by activated carbon, etc. (Cunningham et al., 1997; Navarro et al., 1999; Toyabe et al., 1987). In addition, adding reducing agents such as sulfur dioxide and trivalent arsenic could also precipitate arsenic, antimony and bismuth from copper electrolyte, by changing the distribution of impurities with various valence (Braun et al., 1976; Xiao et al., 2007). The disadvantages of those methods include high energy consumption, serious contamination, lower selectivity and efficiency, and so on.

Jan 1, 2019