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By A. T. Adema

The cohesive zone, where the ore fed into the blast furnace softens and melts, is critical to the blast furnace performance and stability due to its influence on the gas and solid flow. This paper de-scribes a project for the development of a process model to predict the cohesive zone properties and the results of its first step; the solid flow model. The process model is expected to describe a realistic solid burden flow and the formation of the cohesive zone, its shape, location, structure, permeability, and in particular the mineralogical changes within the cohesive zone. This will be achieved using various simulation and computing tools: a combination of the Discrete Element Method (DEM) and Computational Fluid Dynamics (CFD), the DEM?CFD hybrid approach, together with models for the thermodynamics and reaction kinetics. The key benefits of the hybrid approach lie in the coupling of the continuous phase and the discrete particles, and the possibility of introducing thermodynamics and reaction kinetics into the system in a more realistic manner. Two DEM simulations are presented for a small scale blast furnace to investigate the influence of non-spherical particles on the solid flow. This influence can be observed from a more even solid flow pattern and a reduced deadman size. The results indicate the requirement to include non- spherical particles in a blast furnace simulation to achieve a realistic solid flow.

Jan 1, 2014

Calaverite is a gold telluride found in the Kalgoorlie region, Fiji, Cripple Creek Colorado and numerous other locations. It is known that a high pH is necessary for calaverite cyanidation, with the leach rate increasing substantially above pH 12 due to the hydroxide ion concentration. In most circumstances lime is used to achieve high pH, however lime saturates at approximately pH 12, limiting the maximum pH obtainable in a critical region for calaverite leaching. Plant observations, laboratory experiments and thermodynamic modelling show that the maxi-mum hydroxide ion concentration that can be achieved with lime (CaO) is strongly dependent on common ions. The presence of calcium, as commonly found in saline waters, substantially diminishes the maximum pH that can be obtained with lime. Conversely the presence of sulfate ions, as generated through oxidation of sulfides, substantially increases the maximum pH that can be achieved with lime. Sulfide oxidation during cyanide leaching of complex ores may generate acid and sulfate ions, making overdosing with lime at the front of the circuit, or staged addition down the leach train, important to maintaining the maximum hydroxide concentration.

Jan 1, 2014

By Gu Guohua

The alteration of surface properties of chalcopyrite after biological conditioning with Leptospirillum ferriphilum was studied by adsorption, zeta-potential, contact angle and bioleaching tests. The strains of L. ferriphilum cultured using different energy sources (either soluble ferrous ion or chalcopyrite) were used. The adhesion of bacteria to the chalcopyrite surface was a fast process. Additionally, the adsorption of substrate-grown bacteria was greater and faster than that of liquid-grown ones. The isoelectric point (IEP) of chalcopyrite moved toward that of pure L. ferriphilum after conditioning with bacteria. The chalcopyrite contact angle curves motioned diversely in the 9K culture with and without chalcopyrite powders. The results of X-ray diffraction patterns (XRD), scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS) analysis indicated that in the bioleaching process by L. ferriphilum, the surface of chalcopyrite was covered with sulfur and jarosite. Furthermore, iron phase dissolved preferentially from chalcopyrite surface during bioleaching from EDS detection. The copper extraction was low resulting from the formation of a passivation layer. The major component of the passivation layer that blocked continuous copper extraction was sulfur, not jarosite.

Sep 1, 2012

By H. R. Manouchehri

The importance of the grinding environment and its effect on sulphide minerals flotation behavior has been known for many years. The grinding environment may play a role in controlling fine and coarse particle flotation along with dissociation of different chemical species in grinding environment. Dissociation of different chemical species and ions within the process water may result from changing the grinding environment. The mining and mineral processing industry undertakes activities that may impact on water resources. These include use and storage of chemical storm-water management, process water management, mine dewatering and management of tailings. In mineral flotation understanding and controlling water quality is paramount important not only because of its effect on flotation but also with respect to control the quality of the water which is released to the environment. Releasing of different anionic and/or cationic chemical species in the process water results from the interactions among different mineral within the ore, process water, and the milling environment. In fact grinding mill acts as an electrochemical reactor which affects the flotation performances of different value minerals as well as the quality of the tailing products. An increasing in antimony content in process/discharge water at Boliden?s Tara processing plant in Ireland to above limitation level was reported in April 2010 which needed to be controlled. An increase up to 6 times of the permitted level was reported which needed an immediate action to control due to environmental considerations. Therefore attempts were made to detect why this higher amount of Sb is released and how to control and minimize its release to the process/reclaim water. This paper discusses how/why Sb content in process/reclaim water was increased by changing the mill electrochemistry and the strategies were taken into considerations to control it. Different strategies, including electrochemical controlling of the milling section, Fenton process, using Bauxsol in treating the process water, etc., have been considered and tested which are described herein. All strategies taken into consideration for solving the problem were successful which indicated good understanding of the issue and good decision making. Furthermore, for each solution the capital and operational costs were roughly estimated. Accordingly, the Sb content in process/discharge water was controlled to a value lower than allowed limitation, i.e., 1 ppm. Keywords: antimony, water contamination, mill electrochemistry, ag milling, grinding media, eh-ph, sulfide minerals, fenton process, bauxsol, lime addition

Sep 1, 2012

By Rodney J. Hundermark, Sharif Jahanshahi, Shouyi Sun

"The major platinum producers in South Africa make use of electric furnaces for the melting of PGM bearing nickel - copper concentrates. To gain better understanding of the furnace operation, research was conducted at CSIRO Minerals in Melbourne, Australia. One aspect of the research project was the investigation of the factors affecting the electrical conductivity of melter type slags.Electrical conduction in slags can occur through two mechanisms: ionic and electronic. There is good understanding of the ionic mechanism. In slags containing high levels of iron, the dominant mechanism is electronic. There is limited understanding of the electronic mechanism and one of the aims of the research was to investigate this mechanism further.Experimental work was carried out on Al2O3.CaO.FeOx.MgO.SiO2 slags similar in composition to the melter slags. Conductivity increased significantly with iron oxide content. Above 20wt% FeOx, electronic conduction was significant and the conductivity varied with the oxidation state of the slag. As the iron oxide content was increased further, the electronic mechanism became more dominant. The conductivity reached a maximum at around pO2 = 10-7 to 10-4 atm., although this value was dependent on the total iron oxide content and basicity of the slag."

Jan 1, 2003

By B. Y. M. Bueno

Biosorption of heavy metals can be an effective process for the removal of heavy metals ions from aqueous solutions. In this study, the adsorption properties of Rhodococcus opacus biomass for Pb(II) and Cu(II) ions was investigated. The effects of initial pH, initial metal concentration and biomass concentration on biosorption efficiency were studied in a batch system. Results showed that the initial pH would play an important role in the Pb(II) and Cu(II) ions removal by R. opacus and affected the zeta potential of R. opacus. The equilibrium adsorption was reached with 60 min. The Langmuir and Freundlich models were used for describing of adsorption isotherm data. The maxi-mum adsorption capacities of biomass were determined as 94.3mgg-1 and 32.2 mgg-1 for the Pb(II) and Cu(II) ions, respectively. The experimental data fitted to pseudo second order kinetic model. Adsorption capacity of Pb(II) ions was found to be reduced by the presence of the other competing metal ions in the system. The FT-IR results of R. opacus biomass showed that biomass has different functional groups and these groups are able to react with metal ions in aqueous solution.

Jan 1, 2014

By K. Trybalski

Facing the optimization activities, which purpose is to minimize the copper processing costs, the main sources of their occurring were presented. In this purpose, the costs analysis was performed, divided to individual standings, for one of the polish copper beneficiation plants. It was proved, that the main component of the copper beneficiation costs is energy consumption, generated mainly in grinding and classification node, particularly by operating mills. The technological system ? grinding and classification node ? in KGHM Polska Miedz S.A., ZWR region Lubin was then selected to investigation. To evaluate the grinding and classification node, the energetic factors W were proposed, calculated on the basis of the energetic-technological data of process, given by node monitoring system. The correctness of the energetic factors selection to evaluate the work of this node and their practical application in industrial conditions was experimentally proved in other technological object. The selected technological object ? grinding and classification node ? was then mathematically modeled and optimized. The calculated energetic factors were the basis to build mathematical models, identifying industrial copper grinding and classification process. The models described correlation and character of dependency between factors and energetic-technical data of the process. These were regressive and neural networks models. On the basis of factors models, the optimization tasks were determined, which purpose was to select the optimal points of grinding and classification node work. Also, the estimated economical effect, possible to achieve after introduction of given monitoring values to grinding and classification node optimization system, was presented.

Jan 1, 2014

By B. Csoke

To improve the efficiency of the crushing/screening plant of Bazalt-Középko Kobányák Ltd. (Hungary), the implementation of computer aided quality control is planned. In the current phase, the R & D work aims at the solution of high-priority tasks: 1) Developing the process models, validation of the models by means of industrial measurements. 2) Developing the algorithm for the process control of the crushing/sizing plant. 3) Developing the suitable computer program. To develop the mathematical models of crushing (breakage and probability functions) and to determine the model parameters, the experimental industrial trials were carried out on hydrocone crushers of types Svedala H 4800 EF and H 4800 F, changing the gap size and crushing relatively narrow grain size fractions. Additionally, the parameters of the separation function for the screens operating in the system were determined. It was established that the crushing probability depends on the grain size of the feed (Y) and the gap size (s), so the breakage probability S, for each cone crusher, can be well characterised by the function formed using the ratio of these two parameters: SfYsf==. The distribution of the broken grains can be described reliably using the relative grain size distribution function B(? = x/Y) (usually Schuhmann-Gaudin- or Rosin-Rammler-shaped function). For the screens, the probability function ()2()111/NTx = xd ???---???? is suitable for cha-racterising the separation (where x? grain size, ?-open-area ratio, d ? rectangular screen aperture size, N ? number of appearance of the particle on a screen surface). Using these functions, the comminution circuits were described by means of vector/matrix equations. The calculations and measurements verified the reliability of the developed models and algorithms.

Jan 1, 2014

By H. C. E. Regidor, M. G. Mena, H. D. Mendoza

Cyanidation leaching has always been the most widely used method of extraction of gold in the world. Its low cost and high selectivity has made it the prevalent choice for mining companies, and even for the small scale miners. The use of cyanidation in small scale mining has been an issue for the longest time, mainly due to the operation’s lack of safety measures, health care or environmental protection regulations. In pursuit of more environmentally friendly methods of extraction of gold, several alternative extraction processes have been explored, one of which is chlorination. The chlorination process is advantageous when recovering refractory gold locked in sulfides, as it simultaneously oxidizes the surrounding sulfides as well as dissolve any gold exposed to the lixiviant. This research was conducted to study and develop a safer alternative way of extraction of gold from small scale mining operations, without compromising the recovery of gold. In this study, a variation of the chlorination process has been employed for a refractory flotation concentrate wherein the majority of the gold is locked in sulfides. Hypochlorite-bearing reagents were used as the leaching reagents, and the method developed was a 2-stage leaching process in differing pH conditions. The solution pH and Eh was monitored all throughout the runs, and aliquot samples were taken at time intervals for analysis. SEM-EDS imaging was used to determine the mode of oxidation of the chlorination process, and the image obtained showed that the oxidized layer followed the shape of the particle, suggesting a diffusion controlled process. XRD analysis of the sample before and halfway through leaching further confirmed the oxidation of the sulfides. The amount of gold dissolved in the aqueous solution and in the solid residue were used as the basis for the determination of the recovery of gold. An average gold recovery of up to 84.38% was obtained using the developed method in just 7 hours of leaching. This method was then employed for a pilot-plant scale test and a gold recovery of 79.2% was obtained.

Jan 1, 2018

By T. Moloane, C. Bergman, Heloise Thiele

"A pilot test campaign was undertaken to evaluate dense medium cyclone separation efficiencies on samples of iron ore fines (-1mm +300µm). Evaluations were done using both gas and water atomised FeSi types across a range of operating conditions in the presence of slimes build-up. A Mineral Liberation Analyser (MLA) was used to measure size, density, shape and liberation data of DMS feed and products. The results of the test work were used to obtain parameters for modelling of the partition size/density response. The findings indicated that accurate density characterisation of the feed ore is essential in understanding product quality and recovery, particularly due to the effect of porosity and micro-inclusions. A significant off-set between cyclone underflow density and separation cut-point (D50) was found indicating that relatively low feed media densities (about 3.4g/cm3) are required to achieve high density cutpoints of over 4.0g/cm3. In agreement with CFD modelling, the separation quality is dominated by viscous effects, hence FeSi type and slimes content will need to be carefully controlled to ensure efficient separation.INTRODUCTION In the South African context, future resources of hematite are expected to be both of lower head grade and will contain a higher content of banded iron formation (BIF) (1). These ores may require finer crushing in order to liberate the high-grade fractions and will thus increase the amount of -1mm material to be processed. In order to efficiently upgrade these materials, it becomes necessary to re-examine both traditional and novel processes to treat material finer than 1mm in size. These include spiral and up-current classifiers, wet high intensity magnetic separation processes, Reflux classification and potentially includes dense medium separation (DMS). This study presents a technical evaluation of fines DMS using a mineralogically-based particle tracking analysis method (PTA) to calculate efficiencies of separation."

Jan 1, 2018

By Tamal K. Ghosh

In this study, the QEMSCAN technology is used to acquire quantitative modal, textural, mineral association and liberation data on different products generated from with or without washing, fractionation by size and density using screens and heavy liquids/panning, which has provided significant information on the quality and beneficiability of four categories of low Grade iron ores from Jharkhand-Orissa region. The deposit of low Grade iron ore has been categorized into four categories viz. Grade-I with <45% Fe(t) a) containing shale rich type and b) BHJ rich type; Grade-II with 45-55% Fe(t) and Grade-III with >55% Fe(t) containing conventional flaky, hard, kanga, lateritic, shale and BHJ litho/ore types in varied proportions. Mineralogy is similar across all samples being hematite, martite, goethite, kaolinite and gibbsite. Banded Hematite Jasper has difficult liberation characteristics due to highly compact banded mode of silica mineral occurrence with hematite. In all categories, the grade dilution is by the presence of 1) ?Discrete gangue rich litho types? at lump size and 2) ?Within ore types?. The second type of grade dilution contains coating of gangue phases around the iron ore minerals and different degree of locking of gangue phases within iron ore minerals. Further characterization and beneficiation assessment details are discussed in this paper.

Sep 1, 2012

By H. R. Manouchehri

Sustainable development requires the optimal use of natural resources and recycling of the wastes. In fact recycling is the final productive use of obsoletes. ELVs, obsolete appliances and industrial wastes have become important resources for production of iron and steels, non-ferrous metals, and composites. Within shredding plants, these obsoletes are firstly shredded to the pieces and then processed to recycle different materials, especially ferrous and non-ferrous metals for metallurgy. Traditional and new developed mineral processing technologies are nowadays used for recycling different materials from waste effluents. Shredding and separating plants are currently recycle the wastes by make use of different technologies to mainly produce raw material for metallurgical application. However, other non-ferrous components are also treated for energy conservation and protecting environment. Currently, recovery in shredding and recycling plants maximises to 75% and about 25% of the feed is land-filled. However, recycling rate must be increased in due to the economical, environ-mental and social concerns. A comprehensive study for recycling, with especial focus on ferrous metal recovery, was sup-ported by Swedish Environmental Agency (MISTRA) to look at possibilities to increase the recycling rate and to reduce the amount of disposal. Part of this study was dedicated to study the shred-ding plant facilities and to look for possibilities to improve the quality and quantity of the shredding product streams. The aims were to improve the quality of ferrous scrap (apparent density > 0.9 and Cu<0.25%) for iron and steel production as well as having better quality for non-ferrous metals through the recycling schema, and finally to treat the shredder residue (SR) to recover metals and plastics to reduce the disposals. This paper summarises the results of sampling and conducting separation tests for improving the recovery of the ferrous and non-ferrous metals. The results indicated to be possible to obtain high quality ferrous scrap at recovery of 88%. However, the total recovery for metal scrap has reached 93%. Furthermore, test results on fine, P< 8mm, shredding residue (SR) showed promising prospect in recovery of metals and protecting environment by physical separation, i.e. electrical separation technique.

Jan 1, 2014

By Fangming Liu

The key problems of current flowsheets and equipments are analyzed. A new steel slag&apos;s crushing flowsheet whose key equipments are the improved inertia cone crusher and inertia vibrating jaw crusher is proposed. An advanced two stage open-circuit crushing method is adopted in the flowsheet, with 90% of particle size crushing under 6mm. Using inertia vibrating technology and selective crushing principle the crushers can realize steel slag separating fully into steel and slag and with flexible transmission mechanism the crusher can be protected when iron lump is passing. The flowsheets can enhance the recovery of metal greatly, and expand the application range of tail slag and added value.

Sep 1, 2012

Rotor speed is one of the key hydrodynamic parameters in froth-flotation and it plays an important role in bubble-particle attachment. Laboratory scale studies for optimizing the rotor speed to achieve maximum flotation rate constant (K) of quartz, ground by ball mill, are. Purity of quartz was 99.4 percent and d80 of ball mill product was 230 µm. Each size fraction was separately subjected to flotation at three different rotor speeds, namely, 1200, 1000 and 800 rpm, and the flotation rate constant was calculated. The results showed that the flotation rate constant was high at the rotor speed of 1200 rpm. The flotation rate constants achieved at 1200 rpm were 8.676, 8.232, 7.818, 7.248, 7.068 and 6.984 min-1forthesize fractions of +300, -300+250, -250+212, -180+150, -150+125 and -125+106 µm, respectively. Keywords: froth flotation, rotor speed, flotation rate constant, ball mill, quartz

Sep 1, 2012

By Y. Y. Li, T. T. Yang, R. X. Zhou, Z. H. Shen

"Wetting theory is one of the basic theories of flotation. The effects of concentrations, carbon chain length and pH values of saturated fatty acid collectors (lauric acid, myristic acid, palmitic acid and stearic acid) on the surface wettability of collophanite and dolomite were investigated by measuring the contact angle with dynamic captive-bubble technique and calculating adhesion work of bubble-mineral. The results show that the contact angles both of collophanite and dolomite are higher with enhancement of hydrophobicity when pH value of 5~9. The contact angles both of collophanite and dolomite are reduced with improvement of surface hydrophilicity. When strong acid pH value of 2~4 or strong alkaline pH value of 10~13. The reasons for this are that the fatty acids mainly exist with insoluble RCOOH molecules in strong acid condition, and competitive adsorption of OH- and RCOO- in the mineral surface is formed in strong alkaline condition. With the increase of the collector concentration, the contact angles of the collophanite and the dolomite all first increase then decrease. The formation of hydrophilic micelles results in the decreasing of contact angles and enhancement of surface hydrophilicity opposite when the collector concentration exceeds CMC. The contact angles of the collophanite and dolomite and the WSG of the bubble adhesion increase, the hydrophobicity enhance with the increasing of carbon chains of saturated fatty acid from 12 to 18. The variation tendency for the adsorption quantity of collectors and floatability of collophanite and dolomite are in line with the change trend of contact angle basically. It shows that the wettability of solid-liquid-gas interface can be well characterized by the dynamic captive-bubble technique.INTRODUCTIONPhosphorite resources are the main raw material for producing phosphate fertilizer and producing phosphoric acid (Cao et al.,2005), which is an important strategic mineral resource. The useful minerals in calcareous-magnesium phosphate ore are collophanite, and the main gangue minerals are dolomite (SISH et al.,2003). The lattice ions of the phosphorite and dolomite are both Ca2+, their similar surface properties and similar floatability are the main reason for the flotation of calcareous-magnesium phosphate ore difficultly (Fang et al.,2011). Usually, fatty acid collectors are used for the flotation of calcareous-magnesium phosphate ore under acidic conditions by reversing flotation method to remove dolomite (ABOUZEID et al.,2009), or direct flotation is used to gather collophanite in the alkaline conditions (Gong et al.,2017). The flotation behavior of collophanite and dolomite affects the indexes of concentrate and flotation efficiency directly. Therefore, it is necessary to study the action mechanism and the flotation method of the collector with the phosphate rock and dolomite respectively (Moudgil et al.,1988; Hanna, et al.,1990)."

Jan 1, 2018

By E. Isokangas

The production of minerals for economic use is a two-stage process, involving mining to extract the mineral from the ground, and processing to convert the mineral into a marketable product. Generally, mining and processing have been viewed as self-contained entities. Both have separate objectives, separate cost centres and key performance indicators (KPIs) that do not reflect the customer/supplier relationships that inherently exist. However, mining and processing operations are inter-connected and therefore intimately inter-related with the performance of one operation affecting the performance of another. Optimizing each stage separately without considering the whole system often misses potential economic benefits and energy savings. During the past fifteen years, the authors have been involved in implementing a holistic methodology ?Mine to Mill Process Integration and Optimisation (Mine to Mill PIO)? to maximize the overall profitability of the operation rather than just optimizing any individual process in a mining operation. Metso Process Technology and Innovation (PTI), along with their project partners, have conducted several projects to significantly increase their production- generating typically 5% to 20% higher throughput and improve the overall mine and concentrator performance through PIO methodology. This proven methodology has applications ranging from greenfield projects to long-standing operations with AG/SAG, HPGR or conventional grinding circuits. This paper explains the Mine to Mill PIO methodology and discusses the benefits of such an approach on the energy consumption, the overall costs and benefits of mining operations. The paper also summarizes several case studies illustrating the use of PTI methodology in a variety of applications. Keywords: integration, optimization, simulation, modeling, mine-to-mill, comminution, blast, drill, crushing, grinding

Sep 1, 2012

By V. K. Gupta

Several approaches to the estimation of the size discrete breakage rate and distribution parameters (kj and bi,j ) of the batch grinding kinetic model are available in the literature. Analysis of a large amount of data available in the literature and our own data on several pure minerals and complex ores has shown that it is not always possible to obtain correct estimates of the two sets of parameters using known approaches as several widely different combinations of k and b parameters can sometimes simulate the batch grinding data reasonably accurately. It has been found that there are two main reasons: (i) all size classes are not well represented in the data and (ii) functional forms used for estimation of the two sets of parameters are sometimes chosen somewhat arbitrarily (especially in the case of complex ores), though they are actually uniquely related through size continuous breakage rate and distribution functions. A suitable experimental methodology has been described and demonstrated using some synthetic data and actual experimental data. A mill function approach, which does not require making any assumptions about the functional forms for k and b parameters, is also described and demonstrated. This approach is promising, but requires further development.

Sep 1, 2012

By Ingvar Ymén, Anders Sandc, Jan Rosenkranzc, Lisa Malma, Ann-Sofi Kindstedt Danielssonb

The understanding of particle surface properties is essential for the study and evaluation of froth flotation phenomena, particularly in the investigation of various chemical or reagent effects. Dynamic Vapor Sorption (DVS) is a method used for the analysis of surface properties of powders for instance in the pharmaceutical industry. To the knowledge of the authors, it has however not been used before in applications related to mineral processing. The DVS technique involves measurement of the water uptake of a relatively small amount of sample as a function of the relative humidity (% RH) in a temperature-controlled environment. The purpose of this work was to evaluate the method and investigate how it can complement existing techniques for surface characterization in mineral processing. Four samples (feed, CuPb concentrate, Cu concentrate and Pb concentrate) from the Cu – Pb flotation process in the Garpenberg concentrator, Sweden, were analyzed by DVS and the traditional capillary absorption technique (Washburn capillary rise). This enabled comparison between the two methods and evaluation of their respective advantages and disadvantages. Both methods give the expected ranking of the hydrophobicity for CuPb concentrate, Cu concentrate and Pb concentrate, but a discrepancy was observed for the feed. Washburn gave a value for the contact angle which was in the same range as for the CuPb concentrate, whereas DVS gave a value for the moisture uptake which was much higher than for the CuPb concentrate. Thus, DVS ranks all samples correctly, but with an unexpectedly high value for the feed whereas Washburn gives good ranking for three samples out of four. Potential reasons for the discrepancies are discussed.

Jan 1, 2018

By Z. L. Huang

A new porous apatite product was prepared using phosphorite from Yichang China by a tem-plate-directed method in self-made reaction equipment under constant temperature and pressure. The product was characterized by XRD, FT-IR and SEM. The results showed that the product was a kind of micrometer porous sphere three-dimensionally structured by apatite nanoflakes, that the average thickness of nanoflakes was about 50 nm, that the average pore size was about 1.2 µm and that the particle average size was about 20 µm. Great amounts of Ca2+channel, high special surface area and regular spherical shape show the potential promising applications of this special porous apatite product in the fields of catalyst, medication, chemical engineering and environment engineering

Jan 1, 2014

By Cheng Wei

Fly-ash was used as adsorbent to remove butyl xanthate from aqueous solution in this study. Adsorption kinetics investigation reveals that the adsorption process abides by the Lagergren-second-order Kinetic Model, and fine fly-ash prepared by grinding has a higher second-order adsorption rate as 1.25 g/mg?min and a higher saturated adsorption amount as 10.92mg/g. Four influencing factors as adsorption temperature, solution pH, consumption of fly-ash and adsorption time were investigated. Testing results indicate that butyl xanthate removal rates declines slightly with the temperature increase within the range of 15-50?, increases slightly when pH rises from 7.27 to 8.01 and then declines from 99.65% to 98.25% when pH rises from 8.01 to 11.10. An enhancement of removal rates can be observed by increasing the consumption of the adsorbing agent or prolonging the adsorption time. Thermal desorption was adopted to regenerate the used fly-ash, and test results show that fly-ash possess good regeneration performance and could be used as adsorbent repeatedly with little influence on the adsorption capacity.

Sep 1, 2012