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By James Noll, Sam Janisko

Underground miners are exposed to some of the highest levels of diesel particulate matter (DPM) in the United States. Therefore, it is important to monitor the exposure of miners to DPM, but it can be difficult because of the complex composition of DPM and the number of interferences. Currently, elemental carbon (EC) is used as a surrogate because it makes up a significant fraction of the DPM and is not affected by interferences. Standard measurement methods for EC can be time consuming and only record end of shift results. In this research, a laser absorption technique that enables one to measure EC concentration in near real time was shown to be a beneficial tool. The real time data showed that the fresh air being drawn into a stone mine was not properly reaching the working area and needed to be redirected to decrease DPM concentrations. The real time data also provided a more accurate efficiency ofan environmental cab compared to just using the standard method by detecting the opening of the cab's window and door. The EC optical monitor was also worn by researchers in a mine to show how it can give not only the average concentration for the shift but also reveal when and where a miner is exposed to DPM. Keywords: Laser absorption, diesel, elemental carbon, mining, exposure

By Xintan Chang

MFIRE is a computer simulation program that performs normal ventilation network planning calculations and dynamic transient-state simulation of ventilation networks under a variety of conditions. The program is useful for the analysis of ventilation networks under the influence of natural ventilation, fans, fires, or any combination of these. MFIRE simulates a mine's ventilation system and its response to altered ventilation parameters such as the development of new mine workings or changes in ventilation control structures, external influences (varying outside temperatures), and internal influences (fires). Extensive output enables detailed, quantitative analysis of the effects that the alteration will cause to the ventilation system. The program was developed at Michigan Technological University (MTU), Houghton, MI, with support from the Bureau of Mines. A personal computer (PC) version of the program was completed under contract for the Bureau by MTU. The purpose of this report is to document the installation and use of the PC version of the program MFIRE.

Jan 1, 1990

By Stephen E. Stewart

This document presents the explosion-proof enclosures used severity of certification tests solutions to linear transient thermal and stress analyses of in underground mines. The results were used to assess the for enclosure windows relative to possible loads occurring in the actual mine environment. Cast iron electric light enclosures with polycarbonate and glass windows were analyzed under steady state thermal conditions (light burning) and for thermal shocks corresponding to an internal explosion (ignition of volatile mine gas) or external quenching (mine water spray system). Thermal shocks to the enclosure, caused by ignited gases or water spray, were applied via a series of load steps in the transient analysis. The temperature dependence of material I properties and of the film heat transfer coefficients were included in the model. The work demonstrates that thermally induced stresses are strongly influenced by the way the window is mounted in the enclosure. It also shows that the MSHA Thermal Shock Test, if performed on an unsupported lens (or window), produces lower stresses than the lens (or window) may experience in the mine environment.

Jan 1, 1984

By E. G. King

As low-temperature heat-capacity and entropy data were available for only one sesquisulfide (cerium sesquisulfide), it appeared desirable to augment the information for this class of compounds by measuring the sulfides of antimony and indium. In addition a pressing need existed for data on indium sulfide to supplement vaporization studies in progress in the Department of Mineral Technology, University of California. This Bureau of Mines paper reports low-temperature heat-capacity measurements and entropy evaluations at 298.15° R. of antimony sesquisulfide of stoiehiometric composition (Sb2S3) and of indium sesquisulfide which was somewhat deficient in sulfur (In2S2.93). The data for the latter substance were adjusted to correspond to the stoichiome tric composition (In2S3 ) . Indium sesquisulfide has a lower entropy at 298.15' K, than either antimony sesquisulfide or cerium sesquisulfide, in line with the higher atomic density of the indium compound.

Jan 1, 1962

By Lyda W. Hersloff

An environmental monitoring program was established to assess the baseline of parameters which may be impacted by a research and development hydraulic borehole mining operation. During the baseline program, two aquifers were identified at the borehole site with the overlying sand aquifer being distinct from the ore sand aquifer on the basis of radiological parameters. The direction of flow of groundwater was determined to be north 19° west at a rate of 1.82 feet per year. Tests to determine the effect of backfilling the boreholes indicated that using overburden from the open pit mining operation would not significantly increase the radiological consti¬tuents of the ore sand aquifer. Mining measurements of the- radon flux from the borehole indicated that the actual release rate of 0.035 pCi/sec was several orders of magnitude less than the calculated estimate by the Environmental Protection Agency. Finally, a gamma survey conducted at the site indicated that the terrestrial component of background radiation was consistent with that in areas near uranium deposits. The methodology used as well as the supporting data are given in this report.

Jan 1, 1981

By Paul M. Ambrose

ADVANCES in mining and processing technology made it possible to reopen the De Beers diamond mine in South Africa, originally located in 1871 by Cecil Rhodes and closed in 1908. Radioactive material was used to indicate the efficiency of hydro-cyclones used in diamond concentration. Added interest was shown in recovering diamond from the sea off the coast of South-West Africa. Production of crude artificial abrasives declined because demand was paritally met by withdrawals from stocks. The value of graded grain-coated abrasives and grinding wheels surpassed those of 1962.

Jan 1, 1964

By Robert Vinson

This article examines the spatial variability of dust concentrations within a coal miner?s breathing zone and the impact of sampling location at the cap lamp, nose, and lapel. Tests were conducted in the National Institute for Safety and Health Pittsburgh Research Laboratory full-scale, continuous miner gallery using three prototype personal dust monitors (PDM). The dust masses detected by the PDMs were used to calculate the percentage difference of dust mass between the cap lamp and the nose and between the lapel and the nose. The calculated percentage differences of the masses ranged from plus 12% to minus 25%. Breathing zone tests were also conducted in four underground coal mines using the torso of a mannequin to simulate a miner. Coal mine dust was sampled with multi-cyclone sampling cans mounted directly in front of the mannequin near the cap lamp, nose, and lapel. These four coal mine tests found that the spatial variability of dust levels and imprecision of the current personal sampler is a greater influence than the sampler location within the breathing zone. However, a one-sample t-test of this data did find that the overall mean value of the cap lamp/nose ratio was not significantly different than 1 (p-value = 0.21). However, when applied to the overall mean value of the lapel/nose ratio there was a significant difference from 1 (p-value < .0001). This finding is important because the lapel has always been the sampling location for coal mine dust samples. But these results suggest that the cap location is slightly more indicative of what is breathed through the nose area.

Jan 1, 2007

By W. I. Nissen

This Bureau of Mines report presents the design for a commercial-sized flue gas desulfurization (FGD) demonstration plant that uses the citrate process. The goal of the Bureau&apos;s citrate process is to minimize the undesirable environmental impacts of industrial plants emitting SO2-bearing gas. The FGD plant is located at the George F. Weaton powerplant, Monaca, Pa. Construction was completed in April 1979 and will be followed by preliminary testing and a 1-year testing and evaluation program. Design capacity of the FGD plant is 156,000 scfm of 0.2-volume-percent-SO2 flue gas yielding about 16 tons of sulfur per day. The plant is intended to (1) clean fly ash, SO2, and Cl- from the gas while cooling the gas in a venturi scrubber, (2) absorb SO2 from the gas using 1,200 gpm of a countercurrent-flowing citric acid-sodium citrate-sodium thiosulfate solution, (3) react the absorbed SO2 in two 13,000-gal stirred closed vessels with added H2S, thus precipitating elemental sulfur and regenerating the citrate solution for recycle, and (4) recover the sulfur from the slurry by air flotation, followed by melting in a heat exchanger and separation from the occluded citrate solution in a sulfur decanter at 35 psi and 135° C.

Jan 1, 1979

Provide the mining industry with a simple, accurate and readily available means of measuring the gas flow from pipe outlets such as gob holes Approach The Bureau of Mines conducted laboratory studies to establish correction or method factors for anemometers when used to measure gas flow from pipe outlets. Using the Anemometer Anemometers are used by the mining industry to make air velocity measurements in mine entries. Although the instrument has no appreciable influence on the airstream in mine entries, especially since the cross-sectional area of an entry is much larger than the cross-section of the anemometer, correction or method factors are used to correct the center line anemometer velocity to average velocity. This adjustment is made because the air velocity in a mine entry is highest in the center and lower at the sides. Anemometers can be used to measure gas flow from small diameter pipe outlets; however, since the instrument diameter is much larger than one-sixth of the pipe diameter, it will influence the air-stream from these small outlets. Resulting velocity measurements are erroneously high by as much as 30 percent. Method factors must be applied to such anemometer measurements taken at pipe outlets. Through a research investigation the Bureau of Mines established a set of method factors for center-line anemometer readings taken at the discharge end of 4-to 8-inch diameter pipes. These method factors were combined with method factors which were developed by the National Coal Board of Great Britain for 12-to 30-inch diameter pipes. The anemometer was mounted on the end of a short rod and held against the pipe for support except on the 4-inch pipe where the instrument was started and stopped remotely to prevent hand interference with the air-stream during measurements. Method factors were determined by comparing the anemometer measurements at the pipe outlet to the true average airflow which was simultaneously determined upstream by venturi measurements. Consequently, a method factor is nothing more than the ratio of the true velocity to an anemometer measurement.

Jan 1, 1987

By Stan Henning

The monthly summary of the climatological record for the demonstration mine is presented in Table 1. Tear normal temperatures occurred throughout the growing season. From May to October precipitation was more than normal except in June when it was 2.55 inches below normal. Corn and soybean plantings were delayed until June 2-7 because of wet field conditions. This is about one month later than normal for corn planting. Insect infestations were much less than those encountered in previous years. Cutworm activity was not noticed and alfalfa weevil infestation were small and patchy. Stalk rot in corn was a significant problem at harvest and resulted in much Milk lodging. The wet and generally overcast conditions of July, August and September were bend 10 beneficial al to certain plant disease organisms. For example, pumpkins planted in a small garden area at the demonstration mine did not ripen because of a powdery mildew resulting from overcast, wet conditions. Field operations and row crop plantings were greatly delayed by wet field conditions. It was difficult to plant by conventional tillage because the soil remained soft and sticky where the moldboard plow had been used. Plots in the no-tillage system could he planted before conventionally tilled plots could be traversed. Plant emergence and plant density at

Jan 1, 1982

By Richard E. Thill

The Bureau of Mines&apos; Oil Shale Data Bank (OSDB) was created in 1976 to serve as a centralized source for the storage, retrieval, and dissemination of technical literature, patents, and information on research projects in oil shale. Thousands of bibliographic references, patents, and research projects relating to the mining of oil shale have been identified, abstracted, and indexed according to selected keyword topics. The resulting data bank listings are contained in three sections, each with a separate keyword breakdown for use in rapidly identifying references pertaining to a specific subject. All references cited in the OSDB were published prior to an established cut-off date of May 1, 1981, when a redirection of Bureau of Mines programs resulted in the loss of project funds and the subsequent phasing-out of data bank operations. ACKNOWLEDGMENTS The oil shale data bank listings are the result of a team effort of the project staff. The contributions of Jimaleen Jansma for keypunching, information acquisition, and data entry, and John Brandenburg and Sandra rake for keywording and information acquisition are gratefully acknowledged. Appreciation is expressed to the staff members of the Smithsonian Science Information Exchange, Washington D.C. for their cooperation in supplying data on recent research projects in oil shale for inclusion in the OSDR listings. Appreciation is extended also to the staff of the Gallegos Research Group for assisting with computer services to obtain the final printouts and transfer of files onto magnetic tape.

Jan 1, 1982

By Lincoln A. Stewart

"INTRODUCTION The First Supplemental National Defense Appropriation Act, approved August, 25,, 1941, authorized the Bureau of Mines to investigate sources of raw, material for western production and appropriated funds for that purpose. Numerous iron deposits and prospects in the Western States were investigated. Among those selected for more detailed investigation were tile Apache and Chodiski deposits in Arizona.The United States Geological Survey had examined these deposits in 1929 3/ and estimated that ""the quantity of minable ore reasonably to be expected in this locality will reach 10,000,000 long tons, but it will require prospecting by core drill to demonstrate this quantity with certainty"". C. H. Johnson, a mining engineer of the Bureau of Mines, made a preliminary examination in October 1941 and proposed exploration of the Apache deposit Canyon Creek.A trench sampling project was set up, and work at the Apache deposit commenced in November 1941. Mapping, trenching, and sampling of outcrops was completed in March 1942. Trenches were laid out at approximately 200-foot intervals for about 9,200 feet along the iron outcrop east of Canyon Creek, and channel samples were taken across the iron formation. The outcrop also was explored by trenching and sampling along a 1,900-foot outcrop on the west side of Canyon Creek.The first diamond-drilling campaign at Apache was initiated in May 1942 and continued to January 1943, when work was suspended owing to depletion of funds. Six holes spaced at approximately 500-foot intervals and, 500 feet back from the outcrop on the east side of Canyon Creek were drilled through the iron formation during this period.While this drilling was in progress, the Chediski deposit was mapped, trenched, and sampled. The trenches were spaced at intervals of approximately 800 feet along 10,000 feet of the iron-ore outcrop."

Jul 1, 1947

By C. Lurie

This final report describes the work performed by Gulton Battery Corporation under USBM Contract No. HO-112033, entitled "Research and Development on Lithium-Nickel Fluoride Batteries For Mint Life Support Equipment". The lithium-nickel fluoride couple was chosen For this investigation because of its high theoretical energy density (626 Wh/lb), its ability to operate at ambient temperatures and the fact that it showed promise as a secondary system. The theoretical energy density of the lithium-nickel fluoride couple is ten times greater than that of the widely used lead-acid battery and three times greater than the silver-zinc battery which has the highest theoretical energy density of the commercially available secondary systems. The experimental program first evaluated the cell components individually. The results of these studies then formed the basis for investigations of cell performance using experimental three-plate cells. These cells consisted of one nickel-fluoride and two lithium electrodes. All work was performed in a glove box under an argon atmosphere which was sufficiently pure to maintain the shiny appearance on freshly prepared lithium surfaces. The major portion of the work effort was concerned with the nickel fluoride electrode. Binder, conductive diluent, fabrication technique, as well as the nickel fluoride active material itself, were considered. Criteria for binder materials were established and six classes of materials encompassing thirteen binders were evaluated. The candidate materials were initially screened for appropriate chemical and physical properties and finally evaluated in three.-plate cells, Two epoxy powders emerged as the most promising binders. Two types of conductive diluent were evaluated. The first is a carbon black of low bulk density and high surface area. This material is a good conductive diluent; however, electrodes fabricated with it lacked good mechanical strength. It was hypothesized that a uni¬form, small particle size, low specific surface area would improve the mechanical properties of the electrodes. Therefore, two samples of graphicic materials, milled to uniform powders in the one-to-ten micron range were evaluated. Electrodes prepared with the graphitic materials had superior mechanical properties, However, their electrical performance was significantly poorer and voltage losses of 0.2 to 0.3 volts were observed. Several electrolyte solutions were evaluated. N-Methyl-2-Pyrrolidone was tested but found to be incompatible in the presence of lithium. Lithium perchlorate, lithium hexafluoroarsenate, and lithium bromide were tested as two-component electrolytes in propylene carbonate solvent and their performance compared with that of the single electrolyte solutions, Lithium perchlorate gave the best performance. Lithium hexafluoroarsenate was also evaluated in methyl formate and appears to give equivalent performance. The lithium perchlorate-propylene carbonate system is preferred as it is easier to handle and less expensive.

Jan 1, 1973

By L. D. Patts, J. D. Noll, S. E. Mischler, G. H. Schnakenberg

In this study, we evaluated the ambient diesel particulate matter (DPM) concentrations (at the intakes and exhausts of the mine) as the entire vehicle fleet of a stone mine switched from using 35% biodiesel to using a water emulsified fuel (PuriNOx). Elemental carbon (EC) was reduced by 45% when a PuriNOx blend containing 10% water replaced 35% biodiesel and by 57% when a PuriNOx blend containing 20% water was used. Other factors such as engine duty cycle and production changes could potentially cause some day-to-day EC fluctuations, and no direct comparison to commonly used dieselfuels (No. 1 or No. 2) was achieved. Therefore, a second study was performed in a controlled “isolatedzone” environment to fametal mine, comparing PuriNOxto No.1 diesel fuel in a load haul dump vehicle. The EC fraction of the DPM was reduced by about 71% when the PuriNOx blend containing 10% water was used and by about 85% when the PuriNOx blend containing 20% water was employed. This study did not determine how the water emulsified fuel would affect the engine or power.

By F. S. Wartman

This paper gives an account of the production of ductile-grade titanium powder in 100-pound batches by reduction of purified titanic Chloride with magnesium, grinding, leaching, and magnetic-separation of the reaction product. Apparatus, technique, and methods of controlling product quality are described and some data on operating costs are given.

Jan 1, 1949

By J. W. Town

This report summarizes the results of laboratory investigations made by the Bureau c! Mines on the recovery of mercury from caustic sulfide solutions by aluminum precipitation and by electrodeposition. Statistical methods were used to design the experiments and evaluate the resulting data. Precipitation studies demonstrated tint metallic mercury could be recovered from mercury sulfide-sodium sulfide solutions with aluminum. Other metals and their salts and aluminum, salts precipitated only black mercury sulfide. Over 95 percent of the mercury was precipitated from solutions prepared with reagent-grade chemicals and from cinnabar leach solutions. Two equivalents of aluminum were required to obtain 95 percent precipitation of the mercury. Under optimum conditions 1 gram of aluminum precipitated from 4 to 7 grams of mercury; the excess Aluminum was recovered for reuse. The effects of time and temperature on the precipitation of mercury were minor when compared with the effects of mercury concentration and aluminum equivalents. The particle size of aluminum had no significant effect over the ranges studied. When aluminum was used as a precipitant, the mercury concentration in solution was reduced to below 1.0 grams per liter. Adding arsenic and antimony sulfides to the mercury solution resulted in their coprecipitation with the mercury when the aluminum was added From 95 to 99 percent of both the arsenic and antimony were precipitated as metal, which amalgamated with the mercury.

Jan 1, 1962

By J. Girard-Dwyer, T. Camm

Direct costs such as medical, legal, administrative, and worker’s compensation costs, property damage, lost earnings, and lost benefits are typically used to compute the economic impacts of occupational injuries. However, there are also a number of less obvious, indirect costs that substantially contribute to the overall loss costs. In fact, for every $1 of direct costs an estimated $3 to $5 of indirect costs are also incurred. This paper presents a systems approach that incorporates engineering, economics, psychology, and sociology in order to evaluate the total value of investments in safety. By studying the interrelated system comprised of the injured worker, their family and coworkers, as well as the organizational structure that was the setting for the incident, a methodology can be developed that will more accurately capture the true costs of mine injuries.

By J. Ronald Lawter

The purpose of the work described in this report was to measure the effects of diesel engine emissions on the air quality of work areas in a coal mine. Concentration measurements of a number of diesel related air contaminants were made at the Martin County Coal Corporation Mine in Inez, Kentucky. Compounds measured included carbon dioxide, carbon monoxide, formaldehyde, nitric oxide, and nitrogen dioxide. In addition, concentrations of the two classes of odorous compound;, aromatic hydrocarbons, and oxygenates were obtained along, with aldehyde concentrations. Surveys were made of the mine by odor analysts to determine the perceived intensity of diesel-produced odors. It was found that the concentrations of the measured species were well below their Threshold Limit Values. Odor intensity levels in the moderate to strong range were observed in the mine.

Jan 1, 1977

By Russell Levens

A strategy for prioritizing mining health and safety research by evaluating the potential for risk reduction through interventions is proposed. Mining has one of the highest incidence rates of injury and disease found in major industries. The main premise of this paper is that often the best opportunities to reduce these rates are not revealed by retrospective analysis of injury and illness data. Instead, a proactive approach is needed that accounts for risks to specific hazards that can be abated by engineering or behavioral interventions. The process proposed here begins with development of prospective interventions. The degree of reduction in risk to be expected from an intervention then is determined from statistics on the mining worker population, the expected degree of success of the intervention, and the expected change in the severity of injuries resulting from the intervention. Three disparate mining health and safety concerns are presented to demonstrate common problems in assessing risks of injury and illness and describe additional data needs. Information on events preceding injuries and illnesses and more detailed demographic data on the mining work force are needed to analyze injury and illness data more precisely. Detailed information on exposure to specific hazards is necessary to evaluate the potential for an intervention to reduce risk of injury or illness.

By Thys B. Johnson

The mine system analysis and evaluation study presented in this report was part of the U. S. Bureau of Nines&apos; Tertiary channel project conducted under the Heavy Metals program. The Badger Hill pit, located on the west end of the San Juan Ridge area, near Nevada City, California, was the site of the Bureau&apos;s field work. The objectives of this study were: (1) Determine potential alternative mining systems for some of the large tertiary channel gold-bearing gravel deposits, and (2) Identify areas of technology where further investigation would be merited because of their potential inclusion in a mining system for such deposits, The study involved the development of a mineralized block inventory, an economic block inventory, determination of optimum ultimate mining limits and a preliminary economic mining system evaluation. Computer programs were developed and utilized for each of the study phases stated above. The sampling program conducted at Badger Hill by the Bureau Delineation Group together with confidential drill hole data provided by the San Juan Gold Co. formed the basic gold values and distribution information from which a deposit model was developed. The deposit was divided into minable block units and net economic values were assigned to each block for various configurations of both open-pit and underground mining methods based on cost and performance data provided by the various Bureau of Mines Research Centers. A number of controllable variables such as: (1) Mining method (open-pit and underground), (2) depth of mining cut, (3) production rate and (4) equipment type and capacity were evaluated. The prime measures of effectiveness on which the mining systems where judged were discounted cash flow rate of return and maximum utilization of natural resources. The analysis showed that underground mining of the Six-Mile Tertiary channel gold-bearing gravel deposit under consideration was uneconomical and did not permit maximum recovery of the resources within the channel. It was also apparent that mining the Six-Mile Deposit for gold alone is uneconomical or at best marginal at a gold price less than $80 per ounce. The analysis showed that the potential for an economic mining operation within the Six-Mile Deposit exists when the gravel resources of the channel are considered together with the gold. It was determined that the highest rate of return would be realized with a 20-year open-pit mining operation yielding 745,000 ounces of -gold and 55 million cubic yards of usable gravel.

Jan 1, 2012