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By T. T. Campbell

Studies were conducted by the Bureau of Mines to develop a process for preparing thorium-magnesium master alloys or pure thorium metal by magnesium reduction of thorium tetrachloride in a semicontinuous reactor. Thorium tetrachloride was prepared in a fluidized-bed reactor by chlorination of thorium oxide or thorium oxalate. Conditions were established for producing a suitable thorium oxide feed for a fluidized-bed reactor. Thorium tetra-chloride was purified by vacuum sublimation and subsequently reduced by magnesium in a semicontinuous reactor to form thorium-magnesium alloys. Relatively pure thorium was produced by removing magnesium from the alloys by vacuum sublimation. Close to 100 percent of the thorium fed into the reactor was recovered either as metal (~93 percent) or as thorium oxide (~7 percent). The oxide can be recycled directly into the process.

Jan 1, 1971

By John W. Buch

At a meeting of the Anthracite Investigations Advisory Committee in July 1944 at Washington, D. C., the initial work and objectives of the Anthracite Mechanical Mining Section of the Federal Bureau of Mines were discussed. It was learned that interest existed in an improved performance of mining thin, steeply pitching beds above the gangway by mechanical methods. One company offered the use of one of its mines for experimental work, and this offer was accepted. Following acceptance, an effort was made by Bureau engineers to devise a mechanical method with a performance better than that of a new hand method proposed by company engineers for an actual mining condition. The method proposed by the Bureau was to drive 30-degree slant chutes across a 10-foot bed pitching 85 degrees. These chutes were to be advanced by using a lightweight, compressed air-powered, shearing machine of German origin that had been tried in a flat Pennsylvania anthracite bed in 1934, and which did not then prove successful because of blasting difficulties. An attempt was made to obtain one of these machines from England, where it was known machines of this type had been used. Shortly thereafter John W. Buch was sent to Europe as a member of the Solid Fuels Mission to the European Theater of Operations organized by the Technical Industrial Intelligence Committee of the Joint Chiefs of Staff. Through his efforts the Bureau of Mines obtained two such machines, known as the Eickhoff model DEK, one from England and one from Germany. This report covers the preliminary testing of these machines in order to obtain mechanical operating data for use in determining the power requirements for cutting anthracite with machines of this design.

Jan 1, 1949

By H. F. Weaver

The 19th National First-Aid and Mine Rescue Contest was held in the Civic Center, Charleston, w. Va., on October 2, 3, and 4, 1961. The meet was sponsored by the Bureau of Mines and the Joseph A. Holmes Safety Association, in cooperation with State mine inspection agencies, management and labor of the mineral extractive industries, and other groups interested in safety. The Arrangements Committee, as authorized by the General Committee, made the necessary arrangements for conducting the 1961 contest. Members of the Arrangements Committee were: George Trevorrow (chairman), Bituminous Coal Operators' Association; James B. Benson, Southern Coal Producers' Association; Charles Ferguson, United Mine Workers of America; Harry Gandy, Jr., National Coal Association; and James Westfield, Bureau of Mines.

Jan 1, 1962

By Raja V. Ramani, Wilson Miola

"The potential health effects of quartz-bearing airborne dust in mine and mill atmospheres point to the need for the quantification of quartz content in the source material for determining the source-sink relationships and for choosing applicable control measures. While a standard method exists from a regulatory point of view for the sampling of coal mine atmospheres for determining (i) respirable dust concentrations and (ii) the amount of quartz in the samples, there is no generally accepted standard method for quartz analysis in bulk samples of coal and host rocks. Generally, the bulk sample is reduced to a powder for producing quartz analysis samples. Extensive controls arc necessary to ensure representativeness of the analysis samples when these are very minute fractions of the bulk samples. Since the amount of analysis sample is not limited, alternative methods for quartz analysis may also be tried. It is, however, necessary to adopt a procedure which will satisfy several statistical requirements to guarantee representativeness of the quartz analysis samples.In this paper, the important factors in the preparation of quartz analysis samples from the host rocks and bulk samples are discussed. The method developed to prepare the analysis samples is outlined. The results of application of the procedures are presented. The procedure developed for quartz analysis sample preparation is based on sound statistical foundations. The procedure has been validated for reproducibility and homogeneity.The current methods used for quartz analysis in powders are the P-7 infrared spectrometry and quantitative X-Ray Diffraction (XRD). Both have similar restrictions concerning the sample characteristics and operational problems, which arc intrinsic to radiation beams, device geometry, mechanics and controls of the radiation behavior. Although improvements can be made in the spectrometers and diffractometers, some of the most important steps are the procedures for analysis sample preparation from bulk samples and for calibration of the instruments. The sample preparation process is often referred to as one of grinding and sizing the bulk sample to generate the powder for the scanning devices. The particle sizes are referred to and their influence emphasized but the representativeness of the sample is assumed. Assuring sample representativeness during the sample preparation procedures is critical.For the sampling of airborne respirable dust in coal mines, the collection devices, the collection procedures and the analysis procedures are defined. This is not true for bulk samples where weights must be reduced thousands of times to generate the analysis samples for the scanning devices. The specifications to be developed may include bulk sample amount, sample reduction procedures, sample particle size distribution and sample amounts. However, the common problem of insufficient sample amount which is often encountered with mine airborne dust samples need not exist for bulk samples. Further, the same bulk sample can yield analysis samples for several experiments. The latter, of course, requires sample homogeneity.Three concepts are important in the selection of any procedure for sample preparation and analysis. These arc accuracy, reproducibility and representativeness. The adopted procedure has to guarantee a homogeneous sample representative of the population, a defined level of accuracy and reproducibility. Important statistical concepts are embedded in these requirements, particularly with respect to estimation and dispersion errors. Accuracy and reproducibility are totally different though not independent concepts. Estimation is related to accuracy and the true value. Dispersion is related to reproducibility and is measured by the classical statistical standard deviation of the distribution of a series of measurements or analysis performed over the same lot or analysis sample. The dispersion variance (or dispersion error) does not tell a"

Mar 1, 1992

By J. C. Holtz

Since 1937 the Bureau of Mines has conducted investigations to provide the technical information necessary to guide the safe use of diesel engines underground in the United States. Coincident with the beginning of the technical study, a survey was made of State regulations pertaining to the use of internal-combustion engines underground.3/ At that time it was found that owing to the known hazards of gasoline locomotives, many States had enacted legislation or regulations limiting or prohibiting their use underground. Some of this legislation prohibited, or could be interpreted as prohibiting, the use of any type of internal-combustion engines in underground workings. After World War II diesel-powered equipment was introduced underground in many States, and pertinent questions are received frequently by the Bureau of Mines about the regulations that permit such applications. Because it was known that new and revised regulations had been made effective in some States in the nearly 20 years that have elapsed since the previous survey,3/ the Bureau decided that a review of the latest regulations in the leading mineral-producing States would be a valuable source of information for those engaged in the production of minerals as well as others. Accordingly, where feasible, this report includes abstracts of State laws and regulations as they affect the use of internal-combustion engines underground, particularly diesel engines. The substance of comments from State officials also are included when these appear to be helpful to interpretation of the regulations.

Jan 1, 1957

By Jack E. Tress

The Bureau of Mines has been involved for several years in the development of processes for the recycling of solid wastes. As part of this program, a project was initiated to determine the feasibility of producing secondary pig iron from auto scrap. During the test period, 86,000 pounds of shredded auto scrap, along with petroleum coke and fluxing agents, was charged to a submerged-arc furnace of 1-ton nominal capacity. Eighty-eight thousand pounds of pig iron, with an average carbon content of 3.90 percent and an average copper content of 0.2 percent, was produced at an electrical consumption of 512 kW-hr per net ton. A cost estimate of the process showed that the pig, iron might be produced at a cost of $57 per ton.

Jan 1, 1973

By Nicholas Kyriazi

A joint effort by the U.S. Bureau of Mines and the U.S. Mine Safety and Health Administration (MSHA) was undertaken to determine how well self-contained self-rescuers (SCSR's), deployed in accordance with Federal regulations (30 CFR 75.1714), survived the underground environment with regard to both impact damage and aging. This report presents findings regarding laboratory-tested SCSR's from 1982 through 1990. The SCSR's were tested on human subjects and on a breathing and metabolic simulator (BMS). These results indicate that most of the apparatus, if they pass their inspection criteria, perform as expected except for units with manufacturing defects or design deficiencies. However, when the apparatus are carried in and out of the mine daily and stored at the working section, they may suffer abuse. Physical signs of abuse, unless extremely obvious, are frequently not detected by the miners or mine operators. This poses a potential danger to a user in an emergency. Recommendations include improved training in inspection procedures.

Jan 1, 2010

By Michael D. Balen

During the years 1987 through 1989, the Bureau of Mines Alaska Field Operations Center (Bureau) in cooperation with the Western Field Operations Center and the Alaska Division of Geological and Geophysical Surveys (ADGGS), conducted mining, geological, and geochemical investigations in the 5.7 million-acre Valdez Creek Mining District (VCMD). This investigation was conducted as part of the Bureau's continuing Mineral Land Assessment (MLA) mining district studies program. The Bureau's MLA program is designed to provide reliable and comprehensive mineral resource information that supports mineral resource policy and land use decisions made by Congress and Federal land management agencies. The information also provides the basis for decisions that would expand the domestic supply of important mineral resources, primarily strategic and critical minerals. Much of the MLA work is done jointly with cooperating State or U.S. geological surveys.

Jan 1, 1992

By Barry L. Warner

This program involves testing to determine whether a fire hazard exists when the exposed wood surface area of timber in a mine passageway equals 40 percent of the surrounding strata surface, excluding the sill. Twelve full scale fire tests were conducted in a simulated mine passageways, using kerosene pan fires as the ignition source. The tests included three timber sizes, plus one test with roof lagging, two wood types, plus one test with treated timbers, and two ventilation air velocities. The results show air velocity to be an important factor in the occurrence of flame propagation, and that the 40 percent surface area ratio of wood to surrounding strata appears to b0. a valid criteria for fire safety at 150 fpm, but not at 350 fpm.

Jan 1, 1975

By Jerome J. Hoeppner, Walter W. Fowkes

The Federal Bureau of Mines has determined the distribution of forms of sulfur for several lignites and gasification chars and noted the changes induced by the gasification process . A method was adopted for quantitatively determining sulfide sulfur that was found to be present in the chars , although absent in the lignites . Changes in the behavior and distribution of sulfur forms were further investigated concerning the ashing of lignites and chars under standard conditions , as well as at various temperatures , and the determination of volatile matter applied to both chars and lignites . The authors concluded that the first and greatest change in the form of sulfur present in natural lignite , upon heat treatment , resulted from the reduction of pyritic and sulfate sulfur to sulfide . Organically - bound sulfur originally present is less reactive , but largely disappears on strong ignition . An appreciable part of the sulfur content of natural lignite is fixed in the char as sulfide and in the ash as water - soluble sulfate and will affect the summation of constituents , to a greater or lesser degree , in reporting the ultimate analysis of a lignite or char .

Jul 1, 1960

By M. Paczkowski

The use of inert gas systems to extinguish mine fires has been the subject of research for some time in the United States. In some European countries, it is an established practice. Tests were conducted with the CMI Inert Gas System (CMI), which is being used by the Polish mining industry. This system utilizes a modified jet aircraft engine and afterburner as a compact source of combustion products with a very low (less than one percent) oxygen content. Water injected into the combustion products stream provides evaporative cooling and forms a mist with a high cooling capacity. The CMI system was used under controlled conditions to extinguish coal pile fires at the U. S. Bureau of Mines Experimental Mine in Bruceton, Pennsylvania. The test results show that the CMI system can be used conveniently to extinguish fires quickly and to maintain an inert atmosphere in the fire zone to prevent re-ignition.

Jan 1, 1982

By Paul H. Mutschler

The Bureau of Mines sponsored a study of the impact of changing technology on the demand for metallurgical coal and coke to 1985. Individual technologies were analyzed to determine what effect each had on the demand for and the consequent consumption of metallurgical coal and coke in the steel industry. The domestic steel industry demand for metallurgical coal and coke for the production of hot metal will probably increase through 1985. Formcoke if implemented on a worldwide basis could begin to supplant the U.S. export market for metallurgical coal. The major technologies that have contributed to the decline in demand for metallurgical coke per ton of hot metal are (1) the increased usage coupled with higher iron content of agglomerates, (2) modification of blast furnace practices such as high top pressures and blast temperatures, and (3) increases in the injection of supplemental fuels. The projected demand for metallurgical coal and coke under current technology for 1985 are 109.4 and 76.0 million tons, respectively. With future technology implemented, the demand for metallurgical coal and coke will be 82.0 and 56.9 million tons, respectively. The projected domestic demand for metallurgical coke could further decrease by as much as 15 to 20 million tons by 1985 if formcoking proves technologically and economically feasible.

Jan 1, 1975

By Stephen D. Hill

The Bureau of Mines devised and constructed a modified Knudsen effusion apparatus, permitting a constant measure of the weight of effusing vapor, to determine the equilibrium vapor pressure of metal halides at temperatures up to 1,200° K and over the pressure range 10-5 to 10-2 torr. The reliability of the apparatus was established by determining the vapor pressure of potassium chloride. After correcting for partial dimerization of the vapor, data obtained on solid KCl between 750° and 950° K can be expressed by the following equation:

Jan 1, 1966

By V. E. Homme

Low- and high-temperature reduction techniques were employed by the Bureau of Mines in study of conditions favorable to the formation of massive titanium crystals. '1,1,2 low-temperature method, feeding molten sodium to solidified titanium lower chloride-sodium chloride, produced higher quality and high quantity crystalline metal. The percentage of crystalline titanium was increased with increasing reactor diameter, melt depth, and titanium dichloride concentration. The high-temperature technique, feed molten sodium to melts above 8000 C, producing needle-type crystals of lower quality and with less consistent results than the low-temperature method. Layers of titanium foil, sponge, fine needles, wool, and crusts of sin-tered granules were formed during the earl, -art of the low-temperature reduction, and massive crystals were produced beneath this barrier in the latter part of the reduction. Crystalline titanium having an average hardness of Bhn 76 and representing 58 percent of the total titanium was obtained. Lamellar crystals up to 1 1/2 inches long with a hardness as low as Bhn 54 were also produced. A second-stage reduction for reclaiming titanium from offgrade sponge is described. Titanium produced by this method was comparable in quality to that from sodium reduction of titanium tetrachloride.

Jan 1, 1966

Under the Bureau of Mines Research Contract Number H0252071, Foundation Sciences, Inc. has compared the relative effectiveness of roof bolts installed at an angle over the rib with that of bolts installed vertically at the rib side, The information gathered during this investigation was sufficient to supply supplementary information on the mechanics of roof support systems and the general acceptability of field instrumentation methods. During the 140 days of field investigation, 235 bolts were installed, 45 inclined and 190 vertical, in two adjacent intersections. Of these 235 bolts, 30 were in-stalled with load cells and 38 were tested for anchor capabilities. In addition to this instrumentation, the deformation of the opening was measured by convergence meter on 9 lines throughout the two testing areas, and a borescope and photo-elastic gauges were utilized to obtain information on the roof action beyond the surface.

Jan 1, 1977

By M. R. Geer

Traditionally, fine coal is more troublesome than the coarser sizes at every step of the coal-preparation process--screening, cleaning, dewatering, and drying. Therefore the present trend toward a higher proportion of fines in the run-of-mine product, brought about by changes in mining practice necessitated to increase productivity, has added greatly to the task of preparing coal for the market. One of the more difficult and costly problems involved is that of recovering fine solids from the washery water. These fine solids should be recovered in the interest of conservation, and they must be removed to provide recirculating water of proper quality. If there is a plant effluent, it must meet increasingly stringent requirements against stream pollution. Vacuum filtration has been used for years at a few plants to recover the extreme fines, but its additional cost discouraged general adoption until recently. Now, with growing emphasis on better solids recovery, filtration is becoming more widespread. Many coal slurries filter readily, giving high cake rates and clean filtrates. Others, however, particularly those containing either a high proportion of material finer than 200-mesh or an appreciable amount of clay, are much more difficult to filter. Many of these refractory slurries can be rendered more filterable by flocculation. A previous report of Bureau of Mines research dealing with flocculation alone was published in 1940.5/

Jan 1, 1959

By W. D. Ludemann, E. A. Loria, E. A. Rowe

The isothermal recrystallization of electrorefined vanadium has been studied as a function of annealing time , temperature , and prior deformation . Specimens were cold- rolled from 30- to 75 - percent reduction in thickness , then annealed from 700 ° to 1,200 ° C at time periods ranging from 1 minute to 96 hours . The course of recrystallization was followed by means of hardness , metallographic , and X- ray techniques , and a recrystallization diagram was constructed . Interpretation of the data indicated that there was around 50- percent softening due to recovery ( first stage of softening) before recrystallization began . The defining of recrystallization limits with respect to the amount of deformation was precisely established for electrorefined vanadium . More than 30- percent reduction was necessary for recrystallization to occur at 850 ° C. With 60- percent reduction , it was initiated at 750 ° C and completed at 950° C. The activation energy for recrystallization , as derived from the data , was 95,300 cal per mole for 60 - percent reduction and annealing at 750 ° to 900 ° C. Recrystallization by the mechanism of nucleation and growth was the principal process during the second stage of softening . minor part of the second stage of softening took place as strain- induced boundary migration , which was observed in specimens reduced 30 percent , bent in L- shape , and annealed at 950 ° C. Grain size decreased significantly only with the largest reductions and annealing between 750 ° and 950 ° C. Grain growth was expressed by the empirical relation D = KKtt"" ,, the exponent being the same at 60- percent reduction and annealing from 750 ° to 900 ° C. Accordingly , the activation energy for grain growth was 75,000 cal per mole .

Jan 1, 1964

By E. K. Stanek

This report contains results of two major efforts related to electrical transients on mine electrical power systems. The first area concerns the use of digital computers to model mine electrical power systems and predict transients or duplicate field recordings of transients. Two existing general purpose circuit analysis programs were used. The first was the TRW Engineering System Simulator or TESS. The second was Electronic Circuit Analysis Program or ECAP. TESS proved to be superior to ECAP in several important characteristics, including system size limitations and modeling nonlinear elements. The second major topic covered in this report is the evaluation of commercially available surge suppression devices. These devices were found to be quite acceptable and guidelines for the selection and placement of surge suppressors were included. The final important item is a listing of the worst-case transients, from a design point of view, for ac and de utilization systems and ac distribution systems.

Jan 1, 1979

By K. J. Liles

The Federal Bureau of Mines conducts a comprehensive test program on clay and shale at the Tuscaloosa Metallurgy Research Center. All samples are subjected to standard preliminary ceramic tests, which include firing formed briquets at temperatures ranging from 1,000° to 1,250° C to identify firing range and colors, and quick-firing to determine bloating characteristics. Materials that shop potential as structural products are further tested after either extrusion or dry-pressing. If the quick-fire test is positive, bulk samples can be fired in a rotary kiln to evaluate their potential as light- weight aggregate A number of miscellaneous tests also can be conducted if requested. These tests determine properties such as refractoriness (pyrometric cone equivalency), oil-bleaching characteristics, oil absorbency, viscosity for drilling-mud applications, sand-bonding properties for foundry usage, and pelletizing characteristics.

Jan 1, 1977

By Edward D. Thimons

Inflatable stoppings are currently marketed for production use, and numerous mining companies have become interested in using such stoppings in rescue and recovery operations. The Bureau of Mines therefore evaluated the concept of using inflatable stoppings in emergency situations. The stoppings tested by the Bureau were 12-foot-diameter spheres inflated with a blower operated by a small battery pack. Experiments were conducted with the stoppings in a full-scale wooden mine model to evaluate their ability to withstand sliding or slipping at various internal and differential pressures, puncture resistance, various inflation techniques; and internal leakage from the stoppings. The stoppings were then installed and tested in the Bureau's Safety Research Coal Mine at Bruceton, Pa., to determine their effectiveness as mine air barriers. Despite some encouraging results obtained with the model and in-mine studies, the stoppings did not perform well in two operating metal mines where they proved difficult to erect and inadequate as air barriers.

Jan 1, 1976